Physical Sciences and Mathematics Commons^™

Combinatorics And Diagonals Of Matrices., K. Balasubramanian Dr.

Doctoral Theses

This theale maindy desie with conbinatoriel aspocte of diayonale of natelees. or enurne, there are aleo eosulte which are nat sunbinatorial in naturos but thase ara neroly by-producta. Chapter-0 gives e very short nary ot the cnntenta of the theete. The raeulte aro ofr tuo kinde. (1) complately rev and (2) old results through rew rethude.Thịa thasle, wholly or pertly, has not baon subnittad to any othor Univerdity or Inatitute for e degree.I exprees hoceby ry doopost sonse of grotitude to br. KA. PARTHASARATHY, Haed of the Doparteant af Mathemties, Indian Inatituta of Tochmlogy, Redras, under uhana bonign guidance thie …

Optimum Yield And The Fcma: Uneven Distribution Of Management Burden, Herrick J. Johnson

Theses and Major Papers

Until the establishment of the Fishery Conservation and Management Act of 1976 (FCMA), fish outside the United States' twelve mile fishery zone were, according to international law, common property and belonged to the nation or individual that caught them. This common property law was based on the concept that fish resources were so large that no amount of fishing would interfere with the right of others to catch fish. Modern technology, however, has created equipment that enabled foreign and domestic fishermen to over-fish the resource. A reduced domestic catch led coastal fishermen to support a bill that unilaterally extended the …

Suitability Of Egyptian Raw Materials For The Production Of Cement Clinker Using The Dry Process, Lamia Rifaat Ismail

Archived Theses and Dissertations

No abstract provided.

An Analysis Of Nitrate Concentrations In The Ground-Water Of Antwerp Township, Van Buren County, Michigan, John Emil Klanke

Masters Theses

Private wells were tested for nitrate during the spring of 1979 throughout sections of Antwerp Township, Van Buren County, southwestern Michigan (sections 1-5, 7-22, 24-26, 28-31, 33-36). Water samples were collected from 159 private wells and analyzed for nitrate. Nitrate concentrations ranged from less than 1 mg/1 NO₃-N to 14.6 mg/1 NO₃-N. Seven wells were found to have nitrate concentrations equaling or exceeding the National Interim Primary Drinking Water Standard of 10 mg/1 NO₃-N. Nitrate concentrations were related to age of septic system, well depth below static water level, land use, and soil type. …

Structural Analysis Of Precambrian Metasedimentary Rocks Of The Swede Gulch Formation, Nahant, South Dakota, Richard G. Cookman

Masters Theses

Precambrian X tectonites deformed between thermal domes in the northern Black Hills 1.7 B.Y.B.P. display variably trending isoclinal folds cross-cut by southeast trending slip-folds developed in discrete shear zones. Eugeosynclinal sedimentary rocks consisting of shale, quartzarenite , sublitharenite, and graywacke were metamorphosed to phyllite, quartzite, and metagraywacke during two syntectonic phases and one post-tectonic phase. The earliest syntectonic metamorphism was associated with development of isoclinal folds and may have produced amphibolite or greenschist facies. It was succeeded by retrograde metamorphism of greenschist facies syntectonic with and post-tectonic to development of southeast trending folds.

Mica, chlorite, iron oxides, and graphite are …

Petrology Of Fluvial And Shoreline Sands In A Modern Arc-Trench Gap, Guatemala, James Robert Bartel

Masters Theses

Petrographic studies of modern sands, derived from areas with known source rocks, climate, relief, environments of deposition, and tectonic setting, are essential for compiling compositional models for ancient sandstones. The Pacific coastal plain of Guatemala is terminated 25-60 km inland by the steep slopes of a row of active Quaternary volcanic and granitic rocks.

Sands being deposited on the coastal plain by the Rio Nahulate, which drains the older volcanic and granitic terrane, show significant compositional differences with those supplied by the Rio Samala, which drains an area dominated by active volcanism: Q₉F₃₅L₅₆ vs. Q …

The Determination Of A Relative Chronology For A Surface Archeological Site Using The Obsidian Hydration Dating Method, Scott Preston Thomas

Dissertations and Theses

This methodological study is an attempt to develop relative chronologies for surface archaeological sites from the obsidian hydration analysis of waste flake samples. Two sites in southeastern Oregon were selected and their surface components sampled. The results of the obsidian hydration analysis indicate, that with the use of random sampling methods and general geochemical control, a fairly accurate representation of the history of an archaeological surface site can be obtained.

Chemistry Of Chromium Oxyfluorides And Group Vib Perfluoroglutarates, Bruce Michael Johnson

Dissertations and Theses

Pure chromium oxide trifluoride was prepared for the first time by reaction of CrO₃ and ClF with subsequent multiple fluorine treatments at 120°C. On the basis of its infrared spectrum, the purple CrOF₃ was assigned as a fluorine-bridged polymer with terminal oxygen groups. Chromium oxide trifluoride was found to be stable to 300°C, where it decomposes with the loss of oxygen to CrF₃.

Selected Shallow Electrical Resistivity Surveys At Volcano Cliffs, Bernalillo County, And Warm Springs, Sandoval County, New Mexico, Sidney S. Brandwein

Earth and Planetary Sciences ETDs

To help assess the applicability of shallow electrical resistivity measurements in New Mexico, two diverse areas in northwestern New Mexico were chosen as electrical resistivity survey sites: Volcano Cliffs and Warm Springs.

Volcano Cliffs, 15 km northwest of Albuquerque, is an area of Pleistocene volcanic activity which manifested itself in cinder cones and basalt flows. At Volcano Cliffs five different electrode configurations were employed to test the horizontality and derive the thicknesses and resistivities of the three geoelectric units present. All electrode configurations yielded reliable results. The ambiguities presented by the principle of equivalence were successfully treated. The first geoelectric …

Synthesis And Evaluation Of Polymer Supported Homogenous Oxidation Catalysts, Raymond J. Riley

Retrospective Theses and Dissertations

Polystyrene bis(salicylaldehyde)-propylene-1,3-diiminato Cobalt (II) [salen] and Polystyrene bis(2,4-pentanedione)-propylene-1,3-diiminato Cobalt (II) [BAE] were prepared stepwise from chloromethylated polystyrene. In addition, a new preparation of a Schiff base was attempted resulting in Polystyrene bis(salicylaldehyde)-isobutylene-1,3-diiminoato Cobalt (II) being produced. Optimum reaction conditions were determined with regard tot ime, temperature, reaction ratios and solvent for each step for the reaction. The ability of the above named Cobalt (II) Schiff bases to oxidize 3-methyl indole to give the corresponding o-formylaminoacetophenone was also studied. One polymer-bound Schiff base cobalt catalyst (co-salen) demonstrated a very small amount of catalytic activity resulting in a minimum amount of o-formylaminoacetophenone …

A Quantitative Description Of Migratory Behavior Of The Brown Shrimp (Penaeus Aztecus) With Applications In Fisheries Management, Anne Madolyn Babcock

OES Theses and Dissertations

A quantitative description of the migratory behavior of the brown shrimp, Penaeus aztecus, was established using the density approach. A theoretical time density was estimated by the proportion of catch and catch per boat hour NOAA-NMFS fisheries statistics collected in Pamlico Sound, the Neuse River, and Core Sound. A clear quantitative description of brown shrimp migratory timing is found in the time densities. The impact of various physical tactors on the progress of the fishery in time and space can be objectively evaluated by using the time density statistics as dependent variables in modeling efforts. The distributions also enable …

Synthesis Of Dihydroisoquinolines And Tetrahydroisoquinolines, John J. Schlager

Chemistry & Biochemistry Theses & Dissertations

Dihydroisoquinolines and tetrahydroisoquinolines are compounds which possess a variety of pharmacological activities. New easier methods of synthetic manipulations of these structures is of constant interest in the pharmaceutical industry.

This paper describes a new three step method of preparing 1-alkyl- and 1-aryl-tetrahydroisoquinolines from a tetrahydroisoquinoline. The synthesis involves the N-chlorination of tetrahydroisoquinoline followed by dehydrohalogenation with potassium superoxide. The reaction products are the dihydroisoquinolines. Overall yields range from 85-96%. The unsubstituted, 1-methyl-, and 1-phenyl-J,4-dihydroisoquinolines have been formed. Organometallation of the unsubstituted dihydroisoquinoline provides the 1-substituted tetrahydroisoquinoline. The 1-benzyl-, 1-n-butyl-, 1-ethyl-, 1-methyl-, and 1-phenyl-1,2,J,4-tetrahydroisoquinolines were prepared. The use of Grignard and …

Water Wave Refraction With Non-Linear Theory, Im Sang Oh

OES Theses and Dissertations

Two different kinds of wave refraction models are formulated in the present study using Stokes' third order wave theory. One type of model is utilized in a parametric study employing several different topographies. Wave trajectories obtained from this model, when obtained by using first and third order wave theory with and without the consideration of energy dissipation, show considerable differences. These differences are examined in more detail for a bottom of constant slope: (1) An approximate 10% difference occurs between the refraction coefficients obtained using the first and the third order wave theory. (2) Considerably different ray trajectories are detected …

A Study Of The Films Produced By The Aluminum/Water Reaction Using Rutherford Backscattering Spectroscopy, Reed L. Shilts

Masters Theses

This work compares the action of pure water to various aqueous electrolytes on aluminum surface film formation at about 100°C. The electrolytes were pure water with various inhibitor ions added. The ions were nitrate, tungstate, borate, molybdate, silicate, phosphate, a mixture of nitrate and molybdate, and a mixture of silicate and molybdate. The investigative technique was Rutherford backscattering spectroscopy (RBS) using 2 MeV alpha particles with an annular detector set at 180 degrees for maximum elemental resolution. RBS was chosen for this investigation because it offers in an easily interpretable manner a relatively fast and semi-quantitative method of analysis of …

A Geochemical Study Of The Sudbury Breccia, Kevin M. Prochaska

Masters Theses

The origin of the Sudbury Breccia surrounding the Sudbury Basin of Ontario, Canada has long been debated. The breccia has been described both as an igneous injection and as an abraded country rock formed by attrition in place.

A geochemical analysis of selected elements in matrix and clast samples from the breccia revealed distinct differences between the two sample groups. Matrix samples were lower in silicon and higher in heavy elements than the clasts. Matrix and clasts were comparable in light elements.

The results of the analysis favor an igneous process. Petrographic observations and structural evidence support this idea. The …

Dolomitization Of The Brassfield Formation (Lower Silurian) In Adams County, Ohio, Lisa L. Varga

Masters Theses

The Lower Silurian Brassfield Formation which outcrops in the Tri-state area of Ohio, Indiana and Kentucky is a transgressive sequence consisting of a series of interbedded shales, limestones and dolostones. Evidence from depositional environments, petrography and spatial relationships of dolomitized and undolomitized rock suggests dolomitization in southwestern Ohio was a two-stage process. Initial dolomitization was restricted to the basal Belfast Member and probably occurred penecontemporaneously on small supratidal islands in a manner analagous to that which occurs in the modern sabkha environment of the Persian Gulf. Regional dolomitization was a later diagenetic event related to the formation of a fresh-seawater …

Detector Geometry For Cascade Photon Experiments, Roger Minoru Munechika

Masters Theses

An observation of cascading optical photons can be used to determine an absolute excitation cross section for the intermediate state without the need of standard lamp calibration. In order to reduce the data an angular correlation function and an angular distribution function must be known. These functions depend on the alignment of the upper excited state and the polarization of the light emitted in the lower part of the cascade. However, at certain angles of observation the values of the required functions are known regardless of the alignment or polarization. A computer search is done to find these angles for …

The Hydrologic Factors That Control Carbonate Hardness In Kalamazoo County Lakes, Southwestern Michigan, Linda Brittain Fenner

Masters Theses

The range and distribution of carbonate hardness in Kalamazoo County lakes were determined and hydrologic factors thought to control hardness were evaluated. Surface-water samples were collected from thirty- five randomly selected lakes in October, 1980. Carbonate hardness ranged from 16 to 244 mg/1 with 61 percent above 120 mg/1. Ten hydrologic variables were analyzed with respect to lake hardness. Lakes with a surface-water inlet were a ll hard (greater than 180 mg/1) and lakes at least two meters higher than the approximate ground-water table were all relatively soft (less than 100 mg/1). No direct correlations were found between the other …

The Effect Of Hypercholesterolemia On The Membrane Lipids, 3-0-[¹⁴C] Methylglucose Transport, And 2,3-Diphosphoglycerate Levels In Rat Erythrocytes, Edwin J. Lester Jr.

Loma Linda University Electronic Theses, Dissertations & Projects

An increase in dietary cholesterol and cholic acid will produce hypercholesterolemia in rats. For ten months, two groups of rats (six in each group) were fed commercial rat pellets (control group) or rat pellets plus cholesterol (1%) and cholic acid (0.25%) (experimental group). A blood sample from each animal was divided into three aliquots for three separate experiments on the erythrocytes: a membrane cholesterol and phospholipid determination, a 3-0-[¹⁴C] methylglucose (30MG) transport determination, and a 2,3-diphosphoglycerate (2,3 DPG) determination. The 30MG transport and 2,3 DPG aliquots were each incubated in the same five concentrations of 30MG and glucose …

A Computer-Assisted Instructional System And Its Application To A Course On Computer Structures And Hardware, Tahir Mufti

Masters Theses

Computer-Assisted Instruction is a powerful tool which is fast becoming an integral part of the instructional system in schools.

The objective of this study is to review the techniques used to provide Computer-Assisted Instruction and to present such an instructional system called LEARN which is general enough to be applied towards the teaching of any subject. Also included are notes on the application of the LEARN system to a subject entitled "Computer Structures and Hardware".

The Petrology And Geochemistry Of Keweenawan Diabase Dikes In Ontonagon, Gogebic, Iron And Dickinson Counties, Michigan, James J. Hahnenberg

Masters Theses

Petrographic and chemical studies of Keeweenawan-age diabase dikes in Michigan's Upper Peninsula show two major groupings, Porcupine Mountain dikes and Lower Keweenawan dikes consist of two major rock types, fine-grained smaller dikes and the coarse-grained central portions of larger dikes. Major minerals are subophitic plagioclase and pyroxene. The rocks, as compared to the "average" basalts, are low in Al₂0₃, high in Ti0₂, K₂0, P₂0₅ and contain moderate amounts of Fe0_t. They are classified as quartz tholeiites. Several parental magma sources that would account for these and other …

The Creation Of Holograms Utilizing Fiber Optics, Abdul Rahim Omar

Masters Theses

Holography involves the interference of two light beams, namely a reference beam and an object beam. Instead of the conventional method using beam splitters and mirrors to direct the light path, fiber optic bundles are used and high quality holograms have been produced. When fiber optic bundles are used, a spatial filter is not needed to produce a "clean" beam of light for the reference beam. Fiber optic bundles also provide greater flexibility of illumination for the object beam and/or fir the reference beam. Also, it is easier to illuminate the object from many directions. Finally, the distance from the …

The Ecology And Natural History Of The Striped Skunk (Mephitis Mephitis) In The Cades Cove Campground, Great Smoky Mountains National Park, Tennessee, Deborah M. Goldsmith

Masters Theses

This study was initiated to collect information on several aspects of skunk ecology and natural history in a campground situation. The areas of skunk ecology and behavior, den site availability, activity behavior, and foraging behavior in the Cades Cove campground, GSMNP. Data collection for the study began in June 1979 and ended in August 1980.

The skunk population within the 156 ha study area, which included the campground and picnic area, was estimated by mark-recapture at 31 ± 4 skunks; in late July and early August the skunk population temporarily increased as the juveniles became independent and were caught more …

European Community Seaport Policy: Competition Or Cooperation, Michael J. Giari

Theses and Major Papers

The objective of this paper is to examine the development of Community port policy and analyze how and why certain factors have impeded progress in this sector of the EC. This paper will test the hypothesis that there are major economic, technological and political forces, outside of the EC, which are moving Community ports towards regional cooperation. Further European integration in a variety of fields, including ports and maritime transportation is not only desirable but inevitable. A new port-related organization to promote and direct this cooperative port effort will be proposed. Geographically this paper will focus on the North Sea …

Reactions Of (3-(Dimethylamino)-2-Azaprop-2-En-1-Ylidene) Dimethylammonium Chloride (Gold's Reagent) With Carboxylic Acid Derivatives And Grignard Reagents, Dale E. Polk

Retrospective Theses and Dissertations

An azavinamidium salt, [3-(Dimethylamino)-2-azaprop-2-en-l-ylidene] dimethylammonium chloride was reacted with primary amides, esters containing an ╬▒-methylene group and Grignard reagents. The reaction of this azavinamidium salt with amides and esters produced respectively, acyl amidines and enamino esters. Both of these products were produced in high yields by using relatively mild conditions. Reaction of the salt with Grignard reagents resulted in a novel synthesis of aldehydes. This aldehyde synthesis was shown to be of general utility and to proceed in high yields.

Some Physical And Mechanical Properties Of Iron Calcium Silicate Glasses-Iron Composites, Hani Louis Rizkalla

Archived Theses and Dissertations

No abstract provided.

Petroleum-Utilizing Bacteria: The Biological Line Defense Against Oil Pollution, Steven W. Sokolowski

Biological Sciences Theses & Dissertations

A silica gel-petroleum (SGP) medium was developed which is reliable, approximately the same cost as that of the corresponding agar-based petroleum medium, and can be made sufficiently firm to use in streaking or the spread-plate technique. Advantages of the medium include: the incorporation of all of the major ions of seawater in accordance with Dittmar's Law (the salinity of which can easily be varied from 0 to 35 parts per thousand); a wide workable pH range (5.5 to 11.6); negligable pH drift(~ 0.2 pH units after 166 days); the elimination of all but negligable amounts of syneresis, the ability to …

The Port Of Baltimore-Containers And Railroads: A Necessary Interaction, Thomas Sweeny

Theses and Major Papers

This paper came about as a synthesis of interests in ships, railroads and history. Perhaps no other port on the East Coast has such a strong blend of these three forces as the Port of Baltimore. This paper is about the interaction of railroads and the port and how this interaction continues to play a major role in the Port of Baltimore's development. The original hypothesis assumed that Baltimore's strong history with the railroads made her a railroad port. But hard times and competitive truck rates have driven the railroads out of Baltimore to such an extent that rail service …

Electrochemical And Spectroscopic Studies Of Some Less Stable Oxidation States Of Selected Lanthanide And Actinide Elements, David Edward Hobart

Doctoral Dissertations

The technique of simultaneous observation of electrochemical and spectroscopic properties (spectroelectrochemistry) at optically transparent electrodes (OTE's) has been applied to the generation and characterization of some less stable oxidation states of selected lanthanide and actinide elements (Ce, Pr, Sm, Eu, Tb, Yb, U, Np, Am, and Cm) in complexing and noncomplexing aqueous solutions. Optically transparent electrodes used in this study included reticulated vitreous carbon (RVC) and metal screen OTE's and a new OTE made from porous metal foam (PMF).

Cyclic voltammetry at microelectrodes was used in conjunction with spectroelectrochemistry for the study of oxidation-reduction (redox) couples. In some cases additional …

A Spectrophotometric Study Of The Rate Of Formation Of Violet Peroxychromate In Aqueous Solution, Stephen N. Witt

Honors Theses

The rate of formation of violet peroxychromate in aqueous solution was monitored spectrophotometrically at 540 nm. The method of initial rates enabled us to determine the exponents, x, y, and z, in the rate law for the violet species.