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Full-Text Articles in Physical Sciences and Mathematics

Dipole Moments In Thomas-Fermi-Dirac And Thomas-Fermi Theories., Jerry Goodisman Sep 1972

Dipole Moments In Thomas-Fermi-Dirac And Thomas-Fermi Theories., Jerry Goodisman

Chemistry - All Scholarship

It is shown that the electronic contribution to the dipole moment, calculated from a solution to the Thomas—Fermi—Dirac or Thomas—Fermi equations, should be equal and opposite to the nuclear contribution. Thus, the Thomas—Fermi—Dirac and Thomas—Fermi theories predict vanishing dipole moments for all molecular systems.


The Interpretation Of Lanthanide-Induced Shifts In 1h Nuclear Magnetic Resonance Spectra, Jerry Goodisman, R. S. Matthews Jan 1972

The Interpretation Of Lanthanide-Induced Shifts In 1h Nuclear Magnetic Resonance Spectra, Jerry Goodisman, R. S. Matthews

Chemistry - All Scholarship

Owing to the present accuracy of the data and various other factors, it is easy to obtain agreement with experimental results for lanthanide-induced shifts in 1H n.m.r. spectra; some considerations in the formulation of such models which have been ignored previously are discussed.


Dipeptide Complexes Of Palladium(Ii) And Platinum(Ii), Lewis Enos Nance Jan 1972

Dipeptide Complexes Of Palladium(Ii) And Platinum(Ii), Lewis Enos Nance

University of the Pacific Theses and Dissertations

Due to recent interest in the role of heavy metals in enzymes. oxygen-carrying molecules. and anticarcinogenic compounds, the study of metal-protein bonding has assumed a new importance. Studies have been made utilizing platinum compounds as anticarcinogenic agents in several different types of cancerous activity. No study of the mechanism by which Pd(II) and Pt(II) compounds exhibit anticarcinogenic properties has been made to date.

The purpose of this research was to investigate the nature of bonding of Pd(II) and Pt(II) with various dipeptides, which were chosen in this study as a basic unit of protein-like material. These compounds have the advantage …