Physical Sciences and Mathematics Commons^™

Measurement Of The Removal Of Selected Vocs From A Municipal Treatment Plant, Hong Yu

Theses

Industrial wastewater contains a variety of volatile chemical constituents. The large majority of the volatiles are organics. Many of these volatile or¬ganic compounds (VOCs) end up in the effluent to wastewater treatment plants. It is necessary to estimate the emission of the VOCs from sewerage plants in order to study the fate of these volatile organic compounds.

This study focuses on the estimation and comparison of the emission of 28 volatile organic compounds from the water and air in four operation units of Linden Roselle Sewerage Authority (LRSA) wastewater treatment plant. The removal rates of these target compounds have been …

Biomass Conversion Of Solid-Waste (Newsprint) Into A Clean Fuel (Ethanol) By Enzymic Hydrolysis And Fermentation, Nimesh V. Gandhi

Theses

A feasibility study has been performed with two bioprocesses for conversion of newsprint waste to an environmentally safe fuel (ethyl alcohol) and carbon dioxide.

The following areas were investigated to accomplish this task: one hour pretreatment of newsprint by attrition, saccharification of paper slurry to glucose by cellulase and cellobiase, effects of pH, temperature and concentration of enzymes on conversion of paper to sugar, fermentation of glucose to ethanol and carbon dioxide by immobilized yeast, and simultaneous saccharification and fermentation of paper to ethanol and carbon dioxide using enzymes and immobilized yeast.

Results indicate that the enzymic hydrolysis of newsprint …

Experiments In Aerobic And Anaerobic Biodegradation Of Trichloroethylene, Qiong Liao

Theses

The removal of trichloroethylene (TCE) from industrial waste has been intensively studied in recent years, Biodegradation has been determined to be an effective treatment for TCE in the environment. Many researchers have studied the biodegradation of TOE and obtained successful results based on the use of specific isolated bacteria. At the NJIT Biotechnology Laboratory, a new method is being developed in which immobilized activated sludge is used to degrade several toxic chemicals in various reactor configurations. The objective of this research is to determine if these methods can be extended to treat TCE.

Activated sludge from a wastewater treatment plant …

A Study In Systems Integration Architecture, Sashidhar M. Prasad

Theses

This Thesis studies the two architectures OSCA and ANSA which support the ODPSE principle in the first two parts. In the third part the framework for integrating these two architectures is described. The idea of integration architectures in relation to open architectures is studied using the enabling technologies.

The Effects Of Oxygen Tension On Nitrate Reduction By Pseudomonas Isolate, Hao-Jan Hsing

Theses

It is a generally accepted concept that nitrate reduction only occurs under anaerobic conditions. Oxygen inhibits denitrification. However many studies of nitrate reduction under low oxygen tension have shown what has been called aerobic denitrification. This project examines the process of aerobic denitrification.

Oxgyen affects cell growth and the amount of nitrate utilized. When oxygen is absent, the cell growth rate is lower and nitrate utlization is higher then when oxygen is present.

Nitrate is reduced to nirite under anaerobic conditions. Nitrite accumulation did not continue increase. But increased then decreased producing a "Z" shaped graph when plotted.

Stratigraphic And Paleontologic Studies Of Paleocene And Oligocene Carbonate Facies Of The Eastern Gulf Coastal Plain, Jonathan Russel Bryan

Doctoral Dissertations

Shallow marine Paleogene carbonates of the Eastern Gulf Coastal Plain contain a variety of unique and largely undocumented facies. The Late Paleocene Salt Mountain Limestone of southwestern Alabama is a coral-algal-sponge buildup composed of large foram-algal packstone, algal bindstone, and sponge-coral bafflestone. Abundant coralline algae and a low diversity coral fauna are characteristic of Paleocene reefs, but sponges are rare in earliest Tertiary sediments. Their abundance in the Salt Mountain could indicate an opportunistic response of sponges as reef constructors after the extinction of rudist-coral communities in the Late Cretaceous.

The Bridgeboro Limestone, a rhodolith and coral-bearing limestone in southwestern …

Design And Analysis Of Asynchronous Adders, Khalid Khanfar

Masters Theses

The aim of this study is to come up with a fast adder suitable for use in self-timed subsystems. 7 adders were evaluated.

The findings from this study indicated that a Conditional Sum Adder (CSA) is the best candidate for high speed addition. One of the two resulting adders was given the name High Speed Conditional Sum Adder (HSCSA) .

Reductive Cleavage Of Cyclopentadienylmanganese Tricarbonyl, Mani S. Iyer

Masters Theses

Since the isolation of ferrocene in 1951, it has been shown to behave like benzene and may be acylated, sulfonated, metalated, and arylated. Like benzene, it also resists hydrogenation.

Daniel Trifan and Louis Nicholas (1957) were the first to show that ferrocene can be smoothly degraded by lithium and ethylamine. The isolation of free cyclopentadienyl ion on hydrolysis of the reaction mixture indicates that the cleavage leads initially to cyclopentadienyl lithium salt. A similar procedure applied to cyclopentadienylmanganese tricarbonyl also resulted in the formation of cyclopentadienyl lithium salt. This, when added to ferrous chloride, gave ferrocene. This technique can be …

Selected Studies On Certain Iron Sandwich Complexes, Mashitah M. Yusoff

Masters Theses

In these studies, the synthesis of [2.3](1,3)cyclopentadiendoparacyclophane was attempted. Like ferrocene and [2.2]paracyclophane, it is expected to exhibit transannular π-electronic interaction throughout its molecular structure and therefore, one dimensional semiconductivity.

The preparation of dialkylferrocenes had resulted in complex inseparable mixtures. Due to the fluxional nature of its intermediates, their conversion to stable Diels-Alder adducts would facilitate analysis. In this project, certain Diels-Alder adducts of bis-cyclopentadienyliron dicarbonyl intermediates were prepared for analysis.

Very few transition metal complexes of pyrrole are currently known. [2.2](2,5)Pyrroloparacyclophane was perceived to be stable especially as a part of an iron sandwich complex. The final phase …

Structural, Depositional, And Diagenetic Controls On Reservoir Development: St. Peter Sandstone, Newaygo County, Michigan, Mark S. Caldwell

Masters Theses

Enhanced reservoir quality in the Middle Ordovician St. Peter Sandstone is observed in gas bearing zones in wells located on domal structures. Geometry and degree of this enhanced porosity development is the result of the interplay of structural, depositional, and diagenetic controls. An integrated subsurface study of the Woodville/Goodwell field area was performed in order to document controls on hydrocarbon accumulation.

Recurrent structural growth of domal features throughout the Paleozoic is well documented by isopach mapping. Burial and thermal history studies indicate that hydrocarbons were generated in Ordovician aged source rocks during late Devonian to early Mississippian time, and accumulated …

Resonant Electron Transfer And K-Shell Excitation Of Lithiumlike Projectiles In Collisions With Molecular Hydrogen, M. Anwar Kamal

Masters Theses

An experimental investigation of resonant transfer and excitation (RTE) for collisions of Mg⁹⁺ (lithiumlike) projectile ions with a molecular hydrogen gas target has been made. The experimental cross sections for projectile K-shell x rays coincident with electron capture in the energy of 33- to 60-MeV are found to be in good agreement with theoretical RTE calculations. The present results confirm the agreement between experiment and theory which has been reported for RTE involving K-shell excitation for projectiles with atomic numbers between 9 and 92 incident on H₂ and He targets.

Cross sections for total K-shell x-ray production and …

Study Of The Heavy Fermion/Spin-Glass System, Ce1-X GdX Al3, Using 155Gd Mossbauer Spectroscopy, Nicholas G. Ruggiero

Physics Theses & Dissertations

The magnetic properties of Ce_1-xGd_x.Al₃ have been studied using ¹⁵⁵Gd Mossbauer spectroscopy. It has been shown that the magnetic moments of the host GdAl₃ are constrained to the basal plane. The magnetic properties of GdAl₃ can best be described in the framework of RKKY theory. Prior studies of Ce_1-xGd_xAl₃, have revealed complex magnetic behavior throughout the series. As observed with Mossbauer spectroscopy magnetic ordering occurs for x ≥ 0.5, though not at the reported spin glass temperatures. For x = 0.23 and x = 0.18, the …

The Sloan Sag: A Mid-Miocene Volcanotectonic Depression, North-Central Mccullough Mountains, Southern Nevada, Hayden L. Bridwell

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the Hidden Valley area of the north-central McCullough Mountains, southern Nevada, mid-Miocene andesite and dacite domes, flows and pyroclastic units (the Sloan volcanics) partially fill a sag in the underlying Hidden Valley volcanics. The 13.5 km diameter sag formed during and/or after the eruption of the Sloan volcanics. Sagging was accommodated by a combination of movement on the McCullough Wash fault system, and subsidence into evacuated chambers.

Major, trace and rare-earth element geochemistry suggests that the rocks of the Sloan volcanics belong to four groups, each of which were produced by partial melting of chemically distinct sources. With the …

A Case Study In Software Reuse: The Rntds Architecture, Barry J. Stevens

Computer Science Theses & Dissertations

It has been asserted that the most significant gains in software productivity will come from increased levels of software reuse. Some economic models for predicting savings through software reuse exist, but none are based on actual project experience. This paper surveys those models and presents the results of a case study, the Restructured Naval Tactical Data Systems (RNTDS) architecture, in the light of those models. According to the models, software reuse via the RNTDS architecture has enabled the production of fourteen major computer programs at five to twenty-one percent of the cost to create them without software reuse. Organizational characteristics …

Convection In The Melt, John Bryant Drake

Doctoral Dissertations

A physical problem involving the melting/freezing of a phase-change material (PCM) is the applied setting of this research. The development of models that couple the partial differential equations for energy transport and fluid motion with phases of differing densities is a primary goal of the research. In Chapter 2, a general framework is developed for the formulation of conservation laws that admit interfaces. A notion of weak solution is developed and its relation with classical and other weak formulations is discussed. Conditions that hold across various kinds of interfaces are also developed. The formulation is examined for the conservation of …

Preliminary Epidemiological Interpretation Of The Intrinsic And Extrinsic Factors Contributing To The Coverage And Participation Rates Of The Vaccination Program In Arssi, Ethiopia, Muchie Kidanu

Electronic Theses and Dissertations

Many immunization programs in developing countries arr now undergoing a period of rapid utilization. Innovative strategies, such as immunization holidays, are being tried. Political commitment and enthusiasm are high. There is a strong desire by health professionals to protect the lives of many children from the untimely death and/or disability resulting from infectious diseases preventable by vaccination.

Evaluation of an immunization program can benefit other elements of the health system, particularly those that are not amenable to objective evaluation as immunization. In this case, immunization can serve as an indicator of the overall performance of the health system. The problems …

Community Structure Of The Macrobenthos In Back Bay, Virginia, Michael F. Lane

Biological Sciences Theses & Dissertations

A study of the subtidal macrobenthos in Back Bay, Virginia was conducted to examine community structure in relation to sedimentary and water quality characteristics. Samples were collected in August and November of 1987 and February and May of 1988 at ten stations.

Three site groups and three temporal groups were identified by cluster analyses of species abundance. Species composition between site groups was relatively homogeneous and eight species accounted for most of the variation between site groups. A comparison of plots of the biological and physical data in discriminant space suggested that variations in the biological data between site groups …

Computer Simulation Techniques To Assess Bias And Precision In The Roving Creel Survey Estimator, David L. Wade

Biological Sciences Theses & Dissertations

Fisheries scientists use roving creel survey methods to estimate total catch and total effort of recreational fisheries. Bias in the roving creel estimators had been known to the scientific community, but it had not been quantified. I developed a roving-creel-survey computer simulation model to investigate the bias and precision of roving creel estimators, and estimated parameters for the model based on field observations from the blue crab (Callinectes sapidus) fishery of the Chesapeake Bay. The computer model was used to identify bias in roving-creel effort and catch estimators and to demonstrate survey methods that will reduce this bias. …

The Geomorphology Of Alluvial Fan Deposits On The West Flank Of The Blue Ridge, Augusta County, Virginia, Debra Lynn Duffy

OES Theses and Dissertations

Large coalescing alluvial fans mantle the carbonate and shale formations west of the Blue Ridge mountains near Stuarts Draft, Virginia. Fan sediments are predominantly boulder and cobble gravels derived from the Antietam Quartzite, The fan complex consists of three alluvial units of significantly different ages. The surface of each fan unit was mapped using relative geomorphic position, soil color, clay content and thickness of Bt horizons, clast weathering, and degree of removal of depositional surfaces by stream incision. A five-category quartzite clast weathering scale developed for this study was very effective as a measure to distinguish map units. Stratigraphic data …

Approaches To High Speed Networks, Frank Charles Paterra

Computer Science Theses & Dissertations

This work investigates possible methods by which existing potentially available communication bandwidth can be used by communication intensive applications. Presently fiber optic media are available that can provide multiple gigabits of throughput. Unfortunately, because of the computation overhead required to insure that data are reliably transmitted this capacity has not been tapped.

A survey of work toward enabling the use of the potential bandwidth is presented. The parallel paradigm is identified as a strong candidate for providing significant increases in system usable bandwidth. Performing communication processing in parallel, however, presents the developer with several implementation options. These options are considered …

Processes Affecting The Behavior Of Redox-Sensitive Elements In Chesapeake Bay, Maria Lourdes San Diego-Mcglone

OES Theses and Dissertations

Several processes can affect variations in the chemical composition of an estuary, including (1) biogeochemical reactions in the water column, (2) advective transport, and (3) diffusion from underlying sediments.

The purpose of the study was to establish whether estuarine redox reactions are controlled by a complex interaction of processes 1 to 3. Short-term and long-term studies were conducted in Chesapeake Bay. Redox species involved in redox cycling include oxygen, iron, manganese, hydrogen sulfide, nitrogen species, arsenic and antimony species, while phosphate is indirectly involved in redox cycles. Silicate was used as a non-redox tracer.

For the short-term study, a Lagrangian …

Domain Limitations And Interface Requirements For Expert Developed Knowledge Based Systems, Bernard Lee Lewis

Engineering Management & Systems Engineering Theses & Dissertations

The expanded use of graphical, case-based and object oriented techniques in expert systems creation has made it more practical for domain experts to develop their own applications. This thesis focuses on the elements necessary in an expert/developer interface and looks at various forms and techniques that exemplify such an approach. The spreadsheet metaphor is used for an interface or managed set of interfaces that a domain expert can use in building his own expert system or prototype. criteria are established for such interfaces and recent commercial offerings that make expert-created knowledge-bases more practical are reviewed for techniques that qualify. Approaches …

Thermal Characterization Of Carbon Monoxide Oxidation Catalysts Using Thermogravimetric Analysts And Differential Scanning Calorimetry, Rene A. Bartgis

Chemistry & Biochemistry Theses & Dissertations

Catalysts composed of platinum and/or palladium on tin (IV) oxide supports, with and without silica gel, as well as catalysts composed of gold on manganese oxide, have been developed for the recombination of carbon monoxide and oxygen to form carbon dioxide for use in carbon dioxide lasers. A thermogravimetric method and a differential scanning calorimetric method have been developed for the thermal characterization of these catalysts. The mass loss data and the enthalpy changes determined as the catalysts lost water were then related to existing activity data for these catalysts. No relationship was found between the thermal data and the …

Reactions Of Aqueous Chlorine With Valine In Model Solutions And In Wastewater, Erika Forrer Mccormick

Chemistry & Biochemistry Theses & Dissertations

Solutions of the amino acid valine were chlorinated to seven chlorine-to-nitrogen mole (Cl/N) ratios and analyzed by high performance liquid chromatography, gas chromatography/mass spectroscopy, infrared spectroscopy, and nuclear magnetic resonance spectroscopy. The chlorination products found were N-chlorovaline, isobutyraldehyde, isobutyronitrile, and N-chloroisobutyraldimine. Their product distribution depends on the level of chlorination and pH. The main products identified at the lower CI/N mole ratios were N-chlorovaline and isobutyraldehyde, whereas at the higher CI/N mole ratios isobutyronitrile and N-chloroisobutyraldimine were identified as the main products. The concentration and the chlorination products of valine in municipal wastewater were also determined. The chlorination products of …

Dysfunctional Attitudes, Life Stress And Coping Processes, Deborah Desalliers

Loma Linda University Electronic Theses, Dissertations & Projects

The findings of recent investigations earmarked chronic daily stressors as being highly related to stress levels. In addition, researchers are promoting a more integrative model of stress. The stress response is no longer thought of in strictly linear terms, i.e. an event causes stress. Rather, cognitive factors, existing within the human mind itself, strongly influence our coping processes and the chronic stress we experience.

Canonical correlation analysis was used to study how dysfunctional attitudes, a negative cognitive factor, were related to individuals' daily hassles and coping processes. An increase in dysfunctional attitudes was found to correspond to an increase in …

Biodegradation Of Diflufenican Using Anaerobic Microbial Consortia, Velukumar T. Nanjagowder

Theses

In this thesis I examine the feasibility of using anaerobic microbial consortia from digested anaerobic sludge to degrade Diflufenican, a fluorinated herbicide released into the environment as a result of agricultural usage. The compound is manufactured by Rhone Poulenc and it is an active ingredient of agricultural herbicides. The anaerobic digested sludge served both as a source of microorganisms and as a growth medium. Initial studies were conducted by making a stock solution of 1 ppm concentration of Diflufenican in acetone, the optimal solubility of the compound as suggested in the material safety data sheet is 0.05 ppm in water. …

Low Pressure Chemical Vapor Deposition (Lpcvd) Of Silicon Carbide From Diethylsilane, Yi-Tong Shi

Theses

The depositions of amorphous and cubic-crystal SiC from a new chemical vapor deposition source, diethylsilane(DES), have been studied. Amorphous SiC thin films and crystalline cubic-SiC materials have been deposited on silicon wafers at temperature lower and higher than 850C, respectively. The activation energy and a reaction mechanism involving the production and subsequent desorption of diethylsilene has been suggested, which explains the observed deposition dependency with the temperature and reactor pressure. A model based on the polymerization of DES is offered and the deposition rate is found to be the result of a large number of simultaneously occuring deposition processes for …

Work-Preserving Real-Time Emulation Of Meshes On Butterfly Networks, Alf-Christian Achilles

Theses

The emulation of a guest network G on a host network H is work-preserving and real-time if the inefficiency, that is the ratio W_G/W_H of the amounts of work done in both networks, and the slowdown of the emulation are O(1).

In this thesis we show that an infinite number of meshes can be emulated on a butterfly in a work-preserving real-time manner, despite the fact that any emulation of an s x s-node mesh in a butterfly with load 1 has a dilation of Ω(logs).

The recursive embedding of a mesh in a butterfly presented by …

An Experimental Investigation Of The Finite Time Efficiency Of A Peltier Refrigeration Device, Thomas Schneider

Dissertations and Theses

Since the need of energy conservation has become more and more urgent in the past decades, there has been an increased interest in the study and development of more efficient energy conversion systems. One of the fields that have arisen from that endeavor is a branch of physics called Finite Time Thermodynamics (FIT). It may be said that FIT was initiated through the famous paper by Curzon and Ahlborn (1975) that established new bounds on the efficiency of a finite time Carnot heat engine. Before, the traditional treatments gave a fundamental upper limit on the efficiency of any heat engine. …

An Analysis Of Hydrogeologic Factors Affecting Aquifer Vulnerability In Southwestern Michigan, Steven E. Benton

Masters Theses

In southwestern Michigan aquifers are threatened by human activities. Parameter/factor weighting systems are used to rate aquifer vulnerability. Hydrogeologic factors affecting aquifer vulnerability were investigated in this study.

Well records, soil surveys, hydrogeologic reports, and partial chemical analyses were used to obtain data on the aquifers, soil types, glacial sediments, and types of contaminants. Data analysis included comparisons of means and medians, factor analysis, and Pearson and Spearman Correlation analysis.

The results indicate that the aquifers in Kalamazoo County are not protected. Depending on the type of glacial sediment, hydrogeologic factors that protect aquifers are clay thickness and the depth …