Physical Sciences and Mathematics Commons^™

Spectroscopic Studies Of Metal-Cyanide Complexes, Roy L. Mccullough

Chemistry and Chemical Biology ETDs

Part 1: Infrared and Visible Absorption Studies of Cyanide Complexes of Ni(II) in Aqueous Solution

Part 2: An Analysis of the Infrared Vibrational Spectra of the Tetracyanonickelate(II) Ion in the Solid State

In this work, further evidence has been collected establishing the existence of a new ionic species in solutions of sodium tetracyanonickelate(II) and sodium cyanide. Contrary to the literature, however, this work shows that the species is [Ni(CN)₅]^-3 rather than [Ni(CN)₆]^-4.

Studies Of Surface Films Formed By Adsorption Of Polar Organic Molecules On Activated Metal Surfaces, Roy Leo Bennett

Doctoral Dissertations

The investigation of adsorption has been a valuable aid in under­ standing the properties of metal surfaces. The surface of a metal differs from the interior of the material due to unsatisfied valence forces which impart an affinity for adsorbed materials. This high sur­face energy is illustrated by the fact that when two clean metal sur­faces are placed in contact, that is, when there is no intervening adsorbed film, cold welding results. The resulting bond is equivalent to the bonding in the rest of the metal. This has been demonstrated by Bowden and Young,l who showed that mere contact of …

An Investigation Of The Effect Of High Temperature On The Schumann-Runge Ultraviolet Absorption Continuum Of Oxygen, John Stanton Evans

Masters Theses

A theoretical and experimental investigation of the absorption coefficient of molecular oxygen at high temperature is reported here. The wavelength range covered is in the vacuum ultraviolet region from 1300 A to 1740 A. The theoretical treatment covers all temperatures from 300° to 10,000° K. The experimental investigation was carried out in the temperature range of 4,000° to 10,000° K. All values of the absorption coefficient found apply only to oxygen for which the vibrational degree of freedom is fully excited.

The final results for the high temperature absorption coefficient as a function of temperature and wavelength are listed in …

Groups And Algebraicity In Complete Rank Rings, Robert James Smith

Doctoral Dissertations

Introduction: It is well known that many of the results in classical linear algebra have an unequivocal extension to the more general situation when the scalars are drawn from an arbitrary division ring K. There are, however, three distinct theories of determinants for matrices over a division ring. One of these, originated by Study, "apples only to very particular non-communicative fields and to matrices of special type" (Dieudonne) and will not concern us here. The remaining two, one due to Ore and the other due to Dieudonne, reflect together, if not separately, the basic properties of the classical determinant. The …

An In Situ Method For Alteration Of Catalytic Activity By Generation Of A Reactant On The Surface Of The Catalyst, Clyde Dunn Alley

Doctoral Dissertations

In many researches dealing with catalysis there are properties of the catalyst that are attributed to the effect of hydrogen on the surface of the catalyst. The interpretations of the effect of hydrogen on the catalyst surface range from statements which indicate that surface hydrogen is necessary for the reactions to proceed to statements that surface hydrogen is a poison on the reaction. A clearly interpreted picture of the role of hydrogen at the present time is not available.

Rearrangements Of The Benzilic Acid Type; Preparation And Use Of Dialkali Metal Adducts Of Aromatic Ketones., Stanley Selman

Doctoral Dissertations

Introduction: The benzilic acid rearrangement is the base-catalyzed transformation of an α-diketone to the salt of an α-hydroxy acid. This rearrangement can be effected in aromatic, semi-aromatic (o-quinones), in alicyclic, and aliphatic, as well as in heterocyclic α-diketones. Examples of the rearrangement in the above type compounds are illustrated in equations 1-6.

Four Dimensional Graphs Of Complex Functions, Malcom Lee Murrill

Master's Theses

Complex functions of a single complex variable involve four unknowns, two independent and two dependent variables, and thus cannot be adequately represented in two- or three- dimensional space. Various geometric constructions in both two and three dimensions have been devised in the past, however, in attempts to illuminate complex function theory. The standard and most useful, of these representations is that developed by Gauss and Riemann employing two complex planes simultanesously. These show the correspondence between a particular curve or region in the object plane and its image, as mapped by a given transformation, in the image plane.

Studies On The Biological Oxidation Of Ferrous Iron And Chalcopyrite, Loral Alvin Decker

Theses and Dissertations

The purpose of this investigation was to determine the effectiveness of the leaching streams from waste copper ore dumps as a nutrient solution for subsequent biological oxidation and solubilization of sulfide minerals. The copper in the leaching streams is precipitated by displacement with iron. As a result of this procedure the solution is high in ferrous iron concentration and has a pH of near 3.7. The bacteria in the leaching streams are capable of oxidizing ferrous iron to the ferric state and sulfide minerals to sulfates. The effects of temperatures, pH, urea, and aeration rate on the oxidation of the …

The Cytochrome Composition Of Bacillus Subtilis And Bacillus Megaterium, John Harvey Mangum

Theses and Dissertations

A spectroscopic and enzymatic investigation of the cytochromes of B. megaterium and B. subtilis was conducted. Attempts were made to isolate and characterize the individual cytochromes as well as to determine the locale of such activities as cytochrome c oxidase, DPNH oxidase, succinic dehydrogenase, cytochrome c reductase and diaphorse. Only two methods proved effective in liberating the cytochromes; disruption of the cells with sonic osillations and grinding tlhe cells with alumina. These procedures caused a fragmentation of the cell membrane. It was found that the entire cytochrome complement of these two bacteria was bound intimately to particles which most likely …

Substituted Triphenyl Tetrazolium Chlorides, Lawrence Donald Hanback

Master's Theses

The work in this thesis is a continuation of a project started at the University of Richmond in 1952 by A. G. Richardson under the directorship of Dr. J. S. Pierce and Dr. George z.Williams, Director of Clinical Pathology, National Institutes of Health, Bethesda, Maryland.

The purpose of the research was to prepare triphenyl tetrazolium salts, substituted, particularly in the ortho and para positions, with various electron accepting and electron donating groups. It was hoped that these substitutions would impart enough differences in the properties of the compounds so as to allow d etection of certain biological reactions. The tetrazolium …

A Numerical Solution For Weak Disturbances In A Large Scale Hydromagnetic Field, Patrick J. Blewett

Physics & Astronomy ETDs

Our concern here will be to investigate the form of certain solutions of equation (7); we will be content with a two-dimensional analysis.

Conversion Of Electromagnetic Waves Into Magnetohydrodynamic Waves At The Interface Of A Dielectric And Incomprehensible Fluid, Ralph L. Marsten

Physics & Astronomy ETDs

Consider space to be separated into two semi-infinite regions by a rigid boundary. On one side lies medium A--a perfect, rigid, dielectric, with electric permittivity € and magnetic permeability µ. On the other side is medium B; a perfect, fluid, perfectly conducting, also with magnet permeability µ. Throughout all spaces exist a uniform static magnetic field H.

Now such a fluid as medium B is capable of supporting a magnetohydrodynamic (MHD) wave; and of course a perfect dielectric will support an electromagnetic (EM) wave. Suppose then, that a uniform plane EM wave in medium A is incident at arbitrary angle …

Method For Interpreting Extensive Air Shower Data, Darrell C. Kent

Physics & Astronomy ETDs

Three major topics are discussed in this thesis. The first of these has immediate application to analysis of air shower data which is presently being gathered by two large scintillation tanks located immediately behind the University of New Mexico physics building. The data with which the other two topics are concerned cannot be gathered with present equipment, but these preliminary calculations have been performed in anticipation of the installation of the appropriate apparatus.

A Study Of The Radioactive Decay Of The Two Isomers Of Pd109 And Of The Associated Low-Lying Levels Of Ag109, John W. Starner

Physics & Astronomy ETDs

The radiations of Pd¹⁰⁹ (13.45 ± 0.01 hr) and Pd^109m(4.69 ± 0.01 min) have been investigated with a coincidence scintillation spectrometer and a solenoidal beta-ray spectrometer. Pd^109m was observed to have only one mode of decay: a 188-kev (E3) isomeric transition to Pd¹⁰⁹. The principal beta-ray group (>99.9%) of Pd¹⁰⁹ was found to have an end-point energy of 1.025 ± 0.005 Mev. Gamma rays of the following energies (kev) and approximate intensities (photons/10⁵ disintegrations) were observed to acccmpany the decay of Pd¹⁰⁹: 773 (4), 707 (2), 643 (10), 602 …

Characteristics And Calibration Of A Large Liquid Scintillator, James R. Barcus

Physics & Astronomy ETDs

It is the purpose of this thesis to present in some detail the method and results of the calibration -- in particular, the determination of the single particle pulse height which is crucial to any meaningful interpretation of the observational data.

Mineral Deposits Of The Granite Gap Area, Hidalgo County, New Mexico, David N. Cargo

Earth and Planetary Sciences ETDs

The Granite Gap area lies in the central part of the Peloncillo Mountains about 28 miles southwest of Lordsburg, New Mexico. Ores of lead, zinc, silver, and tungsten from four separate deposits have been mined there during the past seventy years.

An Experimental Method Of Determining The Shape Of Millimicrosecond Radiation Pulses, Robert Braslau

Physics & Astronomy ETDs

The problem with which this investigation is concerned was to construct suitable apparatus to measure accurately the shape and the duration of a pulse of δ-radiation of approximately 10 Mev energy and 20 mμ sec duration. In particular, the shape of the tail of the pulse had to be determined as accurately as possible, so that millimicrosecond half lives can be measured accurately with the betatron.

Recording Of Geomagnetic Field Variations In An Orthogonal System, Chistian Schroeder

Physics & Astronomy ETDs

Magnetic field variations in both magnitude and direction are known to occur due to such phenomena as atmospheric tides and solar activity. Magnetic storms caused by solar activity may bring about variations in excess of one percent of the magnitude of the earth's normal magnetic field; but in general the changes are slight and require sensitive instruments for their measurement.

The Geology Of The Flag Pond Quadrangle, Tennessee-North Carolina, Ebraham Shekarchi

Doctoral Dissertations

Purpose and Scope of the Investigation:

Several workers, as indicated in the following section, have commented upon the geology of the Flag Pond Quadrangle, but none have mapped or studied the area in detail--nor indeed, much of the adjacent region. Consequently, the purpose of this investigation is to obtain a comprehensive picture of the geology of the quadrangle.

The geology of the quadrangle is divisible into two natural units or parts, each with problems unique unto itself. The first of these units is the crystalline complex, the second is the sedimentary sequence which rests upon the crystalline rocks. The purpose …

Part I: The Catalytic Hydrogenation Of Nitro Compounds Over Supported Rhodium In Acetic Acid; Part Ii: The Exchange Of Deuterium Gas And Methanol In The Presence Of Raney Nickel, Burch Byron Stewart

Doctoral Dissertations

An improved effusiometry apparatus for analyzing hydrogen and deuterium mixtures was constructed and utilized to study the exchange reaction of deuterium with methanol over Raney nickel catalyst.

The exchange reaction was zero order with respect to deuterium pressure and pseudo-zero order with respect to methanol concentration. The apparent activation energy was found to be 3.5 kcal./mole. The specific reaction rate was 2.9 1. mm. min.^-1 g.^-1.

The effects of nitro compounds upon the exchange of deuterium with methanol over Raney nickel were studied. All of the compounds decreased the exchange at very low concentrations and all, except …

Part I: A Study Of The Catalytic Hydrogenation Of Hydroxybenzenes Over Plantinum And Rhodium Catalysts; Part Ii: The Kinetics Of The Acid-Catalyzed Hydrolysis Of The Dimethyl Esters Of Cyclohexanedicarboxylic Acids, Billy Lee Stump

Doctoral Dissertations

Summary: The dimethyl esters of isometric 1,2-, 1,3-, and 1,4-cyclo-hexanedicarboxylic acids have been prepared and the rates of their acid catalyzed hydrolyses in 70 per cent acetone have been determined. All hydrolysis reactions wre run at four temperatures, 25°, 35°, 45°, and 55°. The rate constants for the hydrolyses at each of these temperatures, along with the activation energies for the reactions, have been tabulated in Table IV.

The rates of hydrolysis of the cis-1,3 and trans-1,4 diesters were found to be almost identical. Similarly, the reaction rates of the trans-1,3 and cis-1,4 diesters were found …

A Study Of The Volume Change During The Setting Of Silicic Acid Gel, Richard Joseph Miller

Honors Theses

An investigation of the volume change during the setting of silicic acid gel was made using a precision mercury dilatometer. The effects of varying the silicate and acid concentrations were studies. The heat of neutralization of the acetic acid and sodium silicate was compensated for to prevent any heat expansion in the gel. Also discussed are the theories of the setting of the gel.

Microscopic Radial Lines In Gels, Robert Peter Frosch

Honors Theses

There are many interesting formations which may be prepared in gels. Probably the best known are Liesegang rings, first prepared in the latter nineteenth century and observed previously in such naturally occurring materials as agate. Besides rings periodic radial structures have been observed in gelatin. Some of these radial formations are visible to the naked eye; others may be observed only under a microscope. It is one of the radial formations of the layer type which will be discussed in this paper. For want of a better name the formation to be discussed will simply be referred to as radial …

The Photogalvanic Effect, George Henry Hofmann

Honors Theses

The photogalvantic effect has been studied by relatively few people. Perhaps the largest contribution to the study of this effect has been by E. Rabinowitch while the Massachusetts Institute of Technology and terminated in 1940. At this time Rabinowitch indicated the possibilities in the utilization of solar energy by the photogalvantic effect (1). Presented here is a study of the effect using a modified form of the apparatus used by Rabinowitch. An attempt is made at explaining the results obtained, the advantages and disadvantages of the apparatus used and suggestions are given for improvement. A specific photogalvantic system of high …

A Study Of Aluminum Phosphates Using Infrared Spectroscopy, Michael Miller

Honors Theses

The infrared spectra of aluminum metaphosphate, aluminum pyrophosphate, and the ortho acid phosphates were studies in the 2u to 15u region. The distinct absorption regions of each compound were located. The type of bond which caused the absorption is suggested. The spectra of the aluminum phosphates were found to be very similar to the spectra of other phosphates.

Light Scattering By Silicic Acid Gel-Forming Mixtures, Bruce Monroe Manzer

Honors Theses

In this investigation the scattering of light by silicic acid gel-forming mixtures has been studied during the process of gel formation in an effort to extend the work already done on their structure and the mechanism of gel formation. The intensity of the scattered light has been measured by means of Fisher Nefluoro-photometer and an attempt has been made to use the results in explaining the change which the gel-forming mixtures undergo during gel formation.

Studies Of Reductions Of Unsaturated Compounds With Lithium Aluminum Hydride, Robert William Barito

Honors Theses

Our work has involved the reduction of certain alpha-beta unsaturated carbonyl compounds and the reduction of two compounds that did not contain alpha-beta unsaturated carbonyls.

Paper Chromatography Of The Dicarboxylic Acids And The Polyhydric Alcohols, Albert Esposito

Honors Theses

The objective of this work was to develop a paper chromato­graphic technique applicable to the separation and identification of the dicarboxylic acids and the polyhydric alcohols.

An Investigation Regarding Faculty-Student Ratio In The Medical-Surgical Area In Accredited Collegiate Schools Of Nursing, Frances Louise Fickess

Loma Linda University Electronic Theses, Dissertations & Projects

Statement of the Problem: the purpose of this study was to find out the current faculty-student ratio in the medical-surgical area in collegiate school of nursing which were fully accredited by the National League for Nursing and the number of students with which instructors felt comfortable in their clinical instructions.

Method: the descriptive survey method with a questionnaire was used to collect data from the study. Eighty-six instructors returned the questionnaire.

Summary of Findings: most instructors were responsible for teaching more than one class level of students and were teaching in a hospital without segregated service. Forty-eight …

An Evaluation Form For Professional Staff Nurses, Barbara Jean Brauer

Loma Linda University Electronic Theses, Dissertations & Projects

The problem of this study was to develop an evaluation form to measure the differentiation in quality of nursing care given by professional staff nurses. It was hoped that the evaluation form could be used by administrators of nursing service as a basis for giving pay increases based on nursing performance.

A review of nursing literature did not reveal the existence of an evaluation form based on verifiable data of performance upon which an objective evaluation could be made.

The critical incident technique was used to gather the data for the study. The respondents were nursing supervisory personnel employed in …