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Theses/Dissertations

Chemistry

Spectroscopy

Clemson University

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Full-Text Articles in Physical Sciences and Mathematics

Synthesis And Applications Of Novel Silver Nanoparticle Structures, Kyle Dukes Aug 2012

Synthesis And Applications Of Novel Silver Nanoparticle Structures, Kyle Dukes

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ABSTRACT
The field of nanotechnology is rapidly expanding across disciplines as each new development is realized. New exciting technologies are being driven by advances in the application of nanotechnology; including biochemical, optical, and semiconductors research. This thesis will focus on the use of silver nanoparticles as optical labels on cells, methods of forming different small structures of silver nanoparticles, as well as the use of silver nanoparticles in the development of a photovoltaic cell.
Silver nanoparticles have been modified with self-assembled monolayers of hydroxyl-terminated long chain thiols and encapsulated with a silica shell. The resulting core-shell nanoparticles were used as …


Synthesis Of Complex Fluorides For Optical Applications, Seth Stepleton Aug 2009

Synthesis Of Complex Fluorides For Optical Applications, Seth Stepleton

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Large single crystals of alkali metal fluorides are desirable for many reasons. Fluoride laser crystals have a wide transmission range and on account of their low phonon energies, many efficient laser emissions have been obtained from 285 nm to 4.34 µm.1,2 Inorganic fluoride single crystals feature large bandgaps, very wide optical transmittance ranges from vacuum-ultraviolet (VUV) to mid-IR wavelength regions, lower refractive indices than those of oxides, and typically lower phonon energies (which drastically reduce multiphonon relaxation rates of rare earth ions).3
The main goal of this work was to investigate the hydrothermal synthesis of alkali metal fluorides. Melt techniques …