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Full-Text Articles in Physical Sciences and Mathematics
The Fabrication And Study Of Silver Nanoparticle Structures, Aubrie Pfirman
The Fabrication And Study Of Silver Nanoparticle Structures, Aubrie Pfirman
All Theses
Nanotechnology and the synthesis of nanoparticle systems are attractive in part because of interesting, tunable optical and electrical properties that are not observed with bulk material. Silver nanoparticles (Ag NPs) interact with visible light more efficiently than any other system due to the excitation of plasmon resonances, which are the collective oscillations of the free electron density. These collective oscillations produce an enhanced local electromagnetic (EM) field: this field is responsible for highly-utilized phenomena such as surface enhanced Raman scattering (SERS), enhanced fluorescence, surface enhanced infrared absorption (SEIRA), and many others. Many experiments have been conducted to optimize and tailor …
Synthesis And Characterization Of Metallic, Core-Shell And Composite Nanoparticles, Amar Kumbhar
Synthesis And Characterization Of Metallic, Core-Shell And Composite Nanoparticles, Amar Kumbhar
All Dissertations
ABSTRACT
Silver nanoparticles exhibit size, shape and the surrounding dielectric medium dependent optical properties (scattering and absorption) in the visible spectral region. These optical properties can be explained in terms of the collective oscillation of the 'free conduction band electrons' or 'surface plasmons' induced by an external electromagnetic field. Dipole and Quadrupole Plasmon resonances have been observed for silver particles less than 100nm in diameter prepared using various synthetic techniques. However higher order resonances have been elusive due to lack of experimental techniques to prepare colloidal solutions of large silver nanoparticles in the size range above 100nm. Controlled hydrogen reduction …