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2015

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Articles 5101 - 5123 of 5123

Full-Text Articles in Physical Sciences and Mathematics

Manganese Dioxide-Anchored Three-Dimensional Nitrogen-Doped Graphene Hybrid Aerogels As Excellent Anode Materials For Lithium Ion Batteries, Zhu Yin Sui, Caiyun Wang, Kewei Shu, Quan-Sheng Yang, Yu Ge, Gordon G. Wallace, Bao Hang Han Jan 2015

Manganese Dioxide-Anchored Three-Dimensional Nitrogen-Doped Graphene Hybrid Aerogels As Excellent Anode Materials For Lithium Ion Batteries, Zhu Yin Sui, Caiyun Wang, Kewei Shu, Quan-Sheng Yang, Yu Ge, Gordon G. Wallace, Bao Hang Han

Australian Institute for Innovative Materials - Papers

The capacity of manganese dioxide (MnO2) deteriorates with cycling due to the irreversible changes induced by the repeated lithiation and delithiation processes. To overcome this drawback, MnO2/nitrogen-doped graphene hybrid aerogels (MNGAs) were prepared via a facile redox process between KMnO4 and carbon within nitrogen-doped graphene hydrogels. The three-dimensional nitrogen-doped graphene hydrogels were prepared and utilized as matrices for MnO2 deposition. The MNGAs-120 obtained after a deposition time of 120 min delivered a very high discharge capacity of 909 mA h g-1 after 200 cycles at a current density of 400 mA g-1 …

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Guanidinium Octahydrotriborate: An Ionic Liquid With High Hydrogen Storage Capacity, Weidong Chen, Zhenguo Huang, Guotao Wu, Teng He, Zhao Li, Juner Chen, Zaiping Guo, Hua-Kun Liu, Ping Chen Jan 2015

Guanidinium Octahydrotriborate: An Ionic Liquid With High Hydrogen Storage Capacity, Weidong Chen, Zhenguo Huang, Guotao Wu, Teng He, Zhao Li, Juner Chen, Zaiping Guo, Hua-Kun Liu, Ping Chen

Australian Institute for Innovative Materials - Papers

For chemical hydrogen storage, capacity is one key criterion that has spurred intense efforts to investigate compounds with high hydrogen content. The guanidinium cation and the octahydrotriborate anion possess 6 H+ and 8 H-, respectively. The combination of these two ions yields guanidinium octahydrotriborate with 13.8 wt% hydrogen. This paper presents its facile synthesis, as confirmed by 11B and 1H nuclear magnetic resonance spectroscopy. The results show that guanidinium octahydrotriborate is an ionic liquid with a melting point below -10°C, which makes it a possible injectable/pumpable hydrogen carrier. It decomposes selectively to hydrogen, in stark …

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Influence Of Biopolymer Loading On The Physiochemical And Electrochemical Properties Of Inherently Conducting Polymer Biomaterials, Paul J. Molino, Peter C. Innis, Michael J. Higgins, Robert M. I Kapsa, Gordon G. Wallace Jan 2015

Influence Of Biopolymer Loading On The Physiochemical And Electrochemical Properties Of Inherently Conducting Polymer Biomaterials, Paul J. Molino, Peter C. Innis, Michael J. Higgins, Robert M. I Kapsa, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

The physicochemical and electrochemical properties of polypyrrole (PPy) doped with the biological dopant dextran sulphate (DS) were shown to be significantly altered as a function of varying the salt concentration (0.2, 2 or 20 mg/ml) in the polymerisation electrolyte. Films grown in the presence of 0.2 mg/ml DS generated the highest potential during galvanostatic growth, with the potential decreasing with each subsequent increase in DS concentration. The electroactivity of the polymers was similar for all three DS concentrations, with the 20 mg/ml film drawing slightly more current upon reduction in PBS. Increasing the DS concentration reduced film interfacial roughness and …

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Efficient, Absorption-Powered Artificial Muscles Based On Carbon Nanotube Hybrid Yarns, Marcio D. Lima, Mohammad W. Hussain, Geoffrey M. Spinks, Sina Naficy, Daniela Hagenasr, Julia S. Bykova, Derrick Tolly, Ray H. Baughman Jan 2015

Efficient, Absorption-Powered Artificial Muscles Based On Carbon Nanotube Hybrid Yarns, Marcio D. Lima, Mohammad W. Hussain, Geoffrey M. Spinks, Sina Naficy, Daniela Hagenasr, Julia S. Bykova, Derrick Tolly, Ray H. Baughman

Australian Institute for Innovative Materials - Papers

A new type of absorption-powered artificial muscle provides high performance without needing a temperature change. These muscles, comprising coiled carbon nanotube fibers infiltrated with silicone rubber, can contract up to 50% to generate up to 1.2 kJ kg−1. The drive mechanism for actuation is the rubber swelling during exposure to a nonpolar solvent. Theoretical energy efficiency conversion can be as high as 16%.

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Electrochemical Synthesis Of Mesoporous Pt Nanowires With Highly Electrocatalytic Activity Toward Methanol Oxidation Reaction, Cuiling Liu, Victor Malgras, Saad Alshehri, Jung Ho Kim, Yusuke Yamauchi Jan 2015

Electrochemical Synthesis Of Mesoporous Pt Nanowires With Highly Electrocatalytic Activity Toward Methanol Oxidation Reaction, Cuiling Liu, Victor Malgras, Saad Alshehri, Jung Ho Kim, Yusuke Yamauchi

Australian Institute for Innovative Materials - Papers

Self-supported one-dimensional (1D) mesoporous Pt nanowires (NWs) are prepared by confining micelle assembly in channels of a polycarbonate (PC) membrane. The obtained mesoporous Pt NWs show very high electrochemical activity and excellent durability as catalysts for methanol oxidation reaction (MOR) in comparison with the commercially available Pt black (PtB) catalyst. This work demonstrates that an appropriate combination of both self-supported 1D shape and mesoporous architecture indeed improve the electrocatalytic performances which is critical for further implementation and practical applications.

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A Bio-Friendly, Green Route To Processable, Biocompatible Graphene/Polymer Composites, Eoin Murray, Sepidar Sayyar, Brianna C. Thompson, Robert A. Gorkin Iii, David L. Officer, Gordon G. Wallace Jan 2015

A Bio-Friendly, Green Route To Processable, Biocompatible Graphene/Polymer Composites, Eoin Murray, Sepidar Sayyar, Brianna C. Thompson, Robert A. Gorkin Iii, David L. Officer, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Grapene-based polymer composites are a very promising class of compounds for tissue engineering scaffolds. However, in general the methods of synthesis are environmentally hazardous and residual toxic materials can affect the biocompatibility significantly. In this paper a simple, scalable, environmentally-friendly, microwave-assisted synthesis is described that results in conducting graphene/polycaprolactone composites that retain the processability and biocompatibility of the pristine polymer without introducing possibly hazardous reducing agents. Composites of polycaprolactone and graphene oxide were synthesised in a single step by the ring-opening polymerisation of ε-caprolactone in the presence of dispersed graphene oxide nanosheets under microwave irradiation. The graphene oxide provides a …

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A Class Of Rare Antiferromagnetic Metallic Oxides: Double Perovskite Amn(3)V(4)O(12) (A = Na+, Ca2+, And La3+) And The Site-Selective Doping Effect, Guangbiao Zhang, Yuan Xu Wang, Zhenxiang Cheng, Yuli Yan, Chengxiao Peng, Chao Wang, Shuai Dong Jan 2015

A Class Of Rare Antiferromagnetic Metallic Oxides: Double Perovskite Amn(3)V(4)O(12) (A = Na+, Ca2+, And La3+) And The Site-Selective Doping Effect, Guangbiao Zhang, Yuan Xu Wang, Zhenxiang Cheng, Yuli Yan, Chengxiao Peng, Chao Wang, Shuai Dong

Australian Institute for Innovative Materials - Papers

We have investigated the structural, electronic, and magnetic properties of A-site-ordered double-perovskitestructured oxides, AA'3B4O12 (A = Na, Ca, and La) with Mn and V at A' and B sites, respectively, using firstprinciple calculations based on the density functional theory. Our calculation results show that the antiferromagnetic phase is the ground state for all the compounds. By changing the A-site ions from Na+ to Ca2+ and then to La3+, the transfer of charge between Mn and O ions was changed from 1.56 to 1.55 and then to 1.50, and that between the …

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Two-Step Self-Assembly Of Hierarchically-Ordered Nanostructures, Qiannan Liu, Ziqi Sun, Yuhai Dou, Jung Ho Kim, S X. Dou Jan 2015

Two-Step Self-Assembly Of Hierarchically-Ordered Nanostructures, Qiannan Liu, Ziqi Sun, Yuhai Dou, Jung Ho Kim, S X. Dou

Australian Institute for Innovative Materials - Papers

Due to their unique size- and shape-dependent physical and chemical properties, highly hierarchically-ordered nanostructures have attracted great attention with a view to application in emerging technologies, such as novel energy generation, harvesting, and storage devices. The question of how to get controllable ensembles of nanostructures, however, still remains a challenge. This concept paper first summarizes and clarifies the concept of the two-step self-assembly approach for the synthesis of hierarchically-ordered nanostructures with complex morphology. Based on the preparation processes, two-step self-assembly can be classified into two typical types, namely, two-step self-assembly with two discontinuous processes and two-step self-assembly completed in one-pot …

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Unique Urchin-Like Ca2ge7o16 Hierarchical Hollow Microspheres As Anode Material For The Lithium Ion Battery, Dan Li, Chuanqi Feng, Hua-Kun Liu, Zaiping Guo Jan 2015

Unique Urchin-Like Ca2ge7o16 Hierarchical Hollow Microspheres As Anode Material For The Lithium Ion Battery, Dan Li, Chuanqi Feng, Hua-Kun Liu, Zaiping Guo

Australian Institute for Innovative Materials - Papers

Germanium is an outstanding anode material in terms of electrochemical performance, especially rate capability, but its developments are hindered by its high price because it is rare in the crust of earth, and its huge volume variation during the lithium insertion and extraction. Introducing other cheaper elements into the germanium-based material is an efficient way to dilute the high price, but normally sacrifice its electrochemical performance. By the combination of nanostructure design and cheap element (calcium) introduction, urchin-like Ca2Ge7O16 hierarchical hollow microspheres have been successfully developed in order to reduce the price and maintain the …

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Tuneable Magnetic Phase Transitions In Layered Cemn2ge2-Xsix Compounds, M F. Md Din, Jianli Wang, Zhenxiang Cheng, S X. Dou, Shane J. Kennedy, Maxim Avdeev, Stewart J. Campbell Jan 2015

Tuneable Magnetic Phase Transitions In Layered Cemn2ge2-Xsix Compounds, M F. Md Din, Jianli Wang, Zhenxiang Cheng, S X. Dou, Shane J. Kennedy, Maxim Avdeev, Stewart J. Campbell

Australian Institute for Innovative Materials - Papers

The structural and magnetic properties of seven CeMn2Ge2-xSix compounds with x = 0.0-2.0 have been investigated in detail. Substitution of Ge with Si leads to a monotonic decrease of both a and c along with concomitant contraction of the unit cell volume and significant modifications of the magnetic states - a crossover from ferromagnetism at room temperature for Ge-rich compounds to antiferromagnetism for Si-rich compounds. The magnetic phase diagram has been constructed over the full range of CeMn2Ge2-xSix compositions and co-existence of ferromagnetism and antiferromagnetism has been observed in CeMn …

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Ray Optics Behavior Of Flux Avalanche Propagation In Superconducting Films, Pavlo Mikheenko, Tom H. Johansen, Supratim Chaudhuri, I J. Maasilta, Y Galperin Jan 2015

Ray Optics Behavior Of Flux Avalanche Propagation In Superconducting Films, Pavlo Mikheenko, Tom H. Johansen, Supratim Chaudhuri, I J. Maasilta, Y Galperin

Australian Institute for Innovative Materials - Papers

Experimental evidence of wave properties of dendritic flux avalanches in superconducting films is reported. Using magneto-optical imaging the propagation of dendrites across boundaries between a bare NbN film and areas coated by a Cu layer was visualized, and it was found that the propagation is refracted in full quantitative agreement with Snell's law. For the studied film of 170 nm thickness and a 0.9μm thick metal layer, the refractive index was close to n=1.4. The origin of the refraction is believed to be caused by the dendrites propagating as an electromagnetic shock wave, similar to damped modes …

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Soft, Flexible Freestanding Neural Stimulation And Recording Electrodes Fabricated From Reduced Graphene Oxide, Nicholas V. Apollo, Matias I. Maturana, Wei Tong, David A. X Nayagam, Mohit N. Shivdasani, Javad Foroughi, Gordon G. Wallace, Steven Prawer, Michael R. Ibbotson, David J. Garrett Jan 2015

Soft, Flexible Freestanding Neural Stimulation And Recording Electrodes Fabricated From Reduced Graphene Oxide, Nicholas V. Apollo, Matias I. Maturana, Wei Tong, David A. X Nayagam, Mohit N. Shivdasani, Javad Foroughi, Gordon G. Wallace, Steven Prawer, Michael R. Ibbotson, David J. Garrett

Australian Institute for Innovative Materials - Papers

There is an urgent need for conductive neural interfacing materials that exhibit mechanically compliant properties, while also retaining high strength and durability under physiological conditions. Currently, implantable electrode systems designed to stimulate and record neural activity are composed of rigid materials such as crystalline silicon and noble metals. While these materials are strong and chemically stable, their intrinsic stiffness and density induce glial scarring and eventual loss of electrode function in vivo. Conductive composites, such as polymers and hydrogels, have excellent electrochemical and mechanical properties, but are electrodeposited onto rigid and dense metallic substrates. In the work described here, strong …

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Sodium And Lithium Storage Properties Of Spray-Dried Molybdenum Disulfide-Graphene Hierarchical Microspheres, Sujith Kalluri, Kuok Hau Seng, Zaiping Guo, Aijun Du, Konstantin K. Konstantinov, Hua-Kun Liu, S X. Dou Jan 2015

Sodium And Lithium Storage Properties Of Spray-Dried Molybdenum Disulfide-Graphene Hierarchical Microspheres, Sujith Kalluri, Kuok Hau Seng, Zaiping Guo, Aijun Du, Konstantin K. Konstantinov, Hua-Kun Liu, S X. Dou

Australian Institute for Innovative Materials - Papers

Developing nano/micro-structures which can effectively upgrade the intriguing properties of electrode materials for energy storage devices is always a key research topic. Ultrathin nanosheets were proved to be one of the potential nanostructures due to their high specific surface area, good active contact areas and porous channels. Herein, we report a unique hierarchical micro-spherical morphology of well-stacked and completely miscible molybdenum disulfide (MoS2) nanosheets and graphene sheets, were successfully synthesized via a simple and industrial scale spray-drying technique to take the advantages of both MoS2 and graphene in terms of their high practical capacity values and high …

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Observation Of Topological Transition Of Fermi Surface From A Spindle Torus To A Torus In Bulk Rashba Spin-Split Bitecl, Feixiang Xiang, Xiaolin Wang, Menno Veldhorst, S X. Dou, Michael S. Fuhrer Jan 2015

Observation Of Topological Transition Of Fermi Surface From A Spindle Torus To A Torus In Bulk Rashba Spin-Split Bitecl, Feixiang Xiang, Xiaolin Wang, Menno Veldhorst, S X. Dou, Michael S. Fuhrer

Australian Institute for Innovative Materials - Papers

The recently observed large Rashba-type spin splitting in the BiTeX(X=I,Br,Cl) bulk states enables observation of the transition in Fermi surface topology from spindle torus to torus with varying the carrier density and offers an ideal platform for achieving practical spintronic applications and realizing nontrivial phenomena such as topological superconductivity and Majorana fermions. Here we use Shubnikov-de Haas oscillations to investigate the electronic structure of the bulk conduction band of BiTeCl single crystals with different carrier densities. We observe the topological transition of the Fermi surface (FS) from a spindle torus to a torus. The Landau-level fan diagram reveals the expected …

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Characterisation Of Torsional Actuation In Highly Twisted Yarns And Fibres, Shazed Aziz, Sina Naficy, Javad Foroughi, Hugh Ralph Brown, Geoffrey M. Spinks Jan 2015

Characterisation Of Torsional Actuation In Highly Twisted Yarns And Fibres, Shazed Aziz, Sina Naficy, Javad Foroughi, Hugh Ralph Brown, Geoffrey M. Spinks

Australian Institute for Innovative Materials - Papers

Highly twisted oriented polymer fibres and carbon nanotube yarns show large scale torsional actuation from volume expansion that can be induced, for example, thermally or by electrochemical charging. When formed into spring-like coils, the torsional actuation within the fibre or yarn generates powerful tensile actuation per muscle weight. For further development of these coil actuators and for the practical application of torsional actuators, it is important to standardise methods for characterising both the torsional stroke (rotation) and torque generated. By analogy with tensile actuators, we here introduce a method to measure both the free stroke and blocked torque in a …

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Nano-Carbon Electrodes For Thermal Energy Harvesting, Mark S. Romano, Joselito M. Razal, Dennis Antiohos, Gordon G. Wallace, Jun Chen Jan 2015

Nano-Carbon Electrodes For Thermal Energy Harvesting, Mark S. Romano, Joselito M. Razal, Dennis Antiohos, Gordon G. Wallace, Jun Chen

Australian Institute for Innovative Materials - Papers

Thermogalvanic cells are capable of converting waste heat (generated as a by-product of almost all human activity) to electricity. These devices may alleviate the problems associated with the use of fossil fuels to meet the world's current demand for energy. This review discusses the developments in thermogalvanic systems attained through the use of nano-carbons as the electrode materials. Advances in cell design and electrode configuration that improve performance of these thermo converters and make them applicable in a variety of environments are also summarized. It is the aim of this review to act as a channel for further developments in …

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Hierarchically Porous Carbon-Zirconium Carbide Spheres As Potentially Reusable Transmutation Targets, Nicholas Scales, Jun Chen, Tracey L. Hanley, Daniel P. Riley, Gregory R. Lumpkin, Vittorio Luca Jan 2015

Hierarchically Porous Carbon-Zirconium Carbide Spheres As Potentially Reusable Transmutation Targets, Nicholas Scales, Jun Chen, Tracey L. Hanley, Daniel P. Riley, Gregory R. Lumpkin, Vittorio Luca

Australian Institute for Innovative Materials - Papers

The preparation of hierarchically porous phase-pure carbon-zirconium carbide spheres with surface areas upwards of 70 m2/g and diameters in the 1-2 mm range has been achieved. The zirconium carbide beads were prepared through carbothermal reduction of polyacrylonitrile-zirconium composites prepared via three different routes including infiltration of a zirconium precursor into preformed polyacrylonitrile (PAN) beads and two one-pot co-precipitation methods. Depending on the route used to prepare the composites, relatively high surface area phase-pure zirconium carbides with the radial macroporous internal structure of the PAN template could be prepared. The adsorption of the elements U, Mo, Cs and Sr …

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Nano-Bioelectronics Via Dip-Pen Nanolithography, Cathal O'Connell, Michael J. Higgins, Simon E. Moulton, Gordon G. Wallace Jan 2015

Nano-Bioelectronics Via Dip-Pen Nanolithography, Cathal O'Connell, Michael J. Higgins, Simon E. Moulton, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

The emerging field of nano-biology is borne from advances in our ability to control the structure of materials on finer and finer length-scales, coupled with an increased appreciation of the sensitivity of living cells to nanoscale topographical, chemical and mechanical cues. As we envisage and prototype nanostructured bioelectronic devices there is a crucial need to understand how cells feel and respond to nanoscale materials, particularly as material properties (surface energy, conductivity etc.) can be very different at the nanoscale than at the bulk. However, the patterning of organic bioelectronic materials is often not achievable using conventional fabrication techniques, especially on …

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Functionalised Inherently Conducting Polymers As Low Biofouling Materials, Binbin Zhang, Alexander Nagle, Gordon G. Wallace, Timothy W. Hanks, Paul J. Molino Jan 2015

Functionalised Inherently Conducting Polymers As Low Biofouling Materials, Binbin Zhang, Alexander Nagle, Gordon G. Wallace, Timothy W. Hanks, Paul J. Molino

Australian Institute for Innovative Materials - Papers

Diatoms are a major component of microbial biofouling layers that develop on man-made surfaces placed in aquatic environments, resulting in significant economic and environmental impacts. This paper describes surface functionalisation of the inherently conducting polymers (ICPs) polypyrrole (PPy) and polyaniline (PANI) with poly(ethylene glycol) (PEG) and their efficacy as fouling resistant materials. Their ability to resist interactions with the model protein bovine serum albumin (BSA) was tested using a quartz crystal microbalance with dissipation monitoring (QCM-D). The capacity of the ICP-PEG materials to prevent settlement and colonisation of the fouling diatom Amphora coffeaeformis (Cleve) was also assayed. Variations were demonstrated …

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Semimetal-Semiconductor Transition And Giant Linear Magnetoresistances In Three-Dimensional Dirac Semimetal Bi0.96sb0.04 Single Crystals, Zengji Yue, Xiaolin Wang, Shi-Shen Yan Jan 2015

Semimetal-Semiconductor Transition And Giant Linear Magnetoresistances In Three-Dimensional Dirac Semimetal Bi0.96sb0.04 Single Crystals, Zengji Yue, Xiaolin Wang, Shi-Shen Yan

Australian Institute for Innovative Materials - Papers

Three-dimensional (3D) Dirac semimetals are new quantum materials and can be viewed as 3D analogues of graphene. Many fascinating electronic properties have been proposed and realized in 3D Dirac semimetals, which demonstrate their potential applications in next generation quantum devices. Bismuth-antimony Bi1− x Sb x can be tuned from a topological insulator to a band insulator through a quantum critical point at x ≈ 4%, where 3D Dirac fermions appear. Here, we report on a magnetotransport study of Bi1− x Sb x at such a quantum critical point. An unusual magnetic-field induced semimetal-semiconductor phase transition was observed in the Bi0.96Sb0.04 …

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The Effect Of Symmetry On Resonant And Nonresonant Photoresponses In A Field-Effect Terahertz Detector, J D. Sun, H Qin, Roger A. Lewis, Xiaoyu Yang, Y F. Sun, Zhenpu Zhang, Xianghu Li, Xiaoqin Zhang, Y Cai, D M. Wu, B S. Zhang Jan 2015

The Effect Of Symmetry On Resonant And Nonresonant Photoresponses In A Field-Effect Terahertz Detector, J D. Sun, H Qin, Roger A. Lewis, Xiaoyu Yang, Y F. Sun, Zhenpu Zhang, Xianghu Li, Xiaoqin Zhang, Y Cai, D M. Wu, B S. Zhang

Australian Institute for Innovative Materials - Papers

The effect of the symmetries in the terahertz (THz) field distribution and the field-effect channel on THz photoresponse is examined. Resonant excitation of cavity plasmon modes and nonresonant self-mixing of THz waves are demonstrated in a GaN/AlGaN two-dimensional electron gas with symmetrically designed nanogates, antennas, and filters. We found that the self-mixing signal can be effectively suppressed by the symmetric design and the resonant response benefits from the residual asymmetry. The findings suggest that a single detector may provide both high sensitivity from the self-mixing mechanism and spectral resolution from the resonant response by optimizing the degree of geometrical and/or …

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Synthesis Of Different Cuo Nanostructures By A New Catalytic Template Method As Anode Materials For Lithium-Ion Batteries, Xiaohang Ma, Shuang Zeng, Bangkun Zou, Xin Liang, Jia-Ying Liao, Chunhua Chen Jan 2015

Synthesis Of Different Cuo Nanostructures By A New Catalytic Template Method As Anode Materials For Lithium-Ion Batteries, Xiaohang Ma, Shuang Zeng, Bangkun Zou, Xin Liang, Jia-Ying Liao, Chunhua Chen

Australian Institute for Innovative Materials - Papers

CuO powders composed of different rod-like clusters or dandelion-like nanospheres are prepared by a low-temperature thermal decomposition process of Cu(OH)2 precursors, which are obtained via a catalytic template method. A tentative mechanism is proposed to explain the formation and transformation of different Cu(OH)2 nanostructures. X-ray diffraction, thermogravimetric analysis, scanning electron microscopy, field-emission scanning electron microscopy, transmission electron microscopy, infrared spectra analysis, Brunauer-Emmett-Teller measurements, and galvanostatic cell cycling are employed to characterize the structures and electrochemical performance of these CuO samples. The results show that these CuO samples obtained after 500 °C calcination have a stable cycling performance with a reversible …

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Effects Of Cu Substitution For Sn On The Electrochemical Performance Of La0.7mg0.3al0.3mn0.4sn0.5−Xcuxni3.8 (X = 0-0.5) Alloys For Ni-Mh Batteries, Julio Cesar Serafim Casini, Zaiping Guo, Hua-Kun Liu, Rubens Nunes Faria, Hidetoshi Takiishi Jan 2015

Effects Of Cu Substitution For Sn On The Electrochemical Performance Of La0.7mg0.3al0.3mn0.4sn0.5−Xcuxni3.8 (X = 0-0.5) Alloys For Ni-Mh Batteries, Julio Cesar Serafim Casini, Zaiping Guo, Hua-Kun Liu, Rubens Nunes Faria, Hidetoshi Takiishi

Australian Institute for Innovative Materials - Papers

The effects of substitution of Cu for Sn on the electrochemical discharge capacity performance of La0.7Mg0.3Al0.3Mn0.4Sn0.5−xCuxNi3.8 (x = 0.0, 0.1, 0.2, 0.3, and 0.5) negative electrode alloys were investigated. Results indicate that increasing Cu content enhanced electrochemical behavior by increasing the maximum discharge capacity from 239.8 mA·h/g (x = 0) to 305.2 mA·h/g (x = 0.5), the discharge capacity retention at the 100th cycle from 78.0% (x = 0) to 81.8% (x = 0.5), and the high rate dischargeability (HRD) from 25.7% (x = 0) to 80.6% (x = 0.5).

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