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Full-Text Articles in Physical Sciences and Mathematics

Surface Treatments' Effects On The Capacitor's Dielectric Performance Under Electro-Thermal Stresses, Haider. M. Umran, Feipeng Wang Apr 2024

Surface Treatments' Effects On The Capacitor's Dielectric Performance Under Electro-Thermal Stresses, Haider. M. Umran, Feipeng Wang

Karbala International Journal of Modern Science

Biaxial-oriented polypropylene (BOPP) films are characterized by unfavorable aging behavior because of their poor susceptibility to high temperatures, humidity, and high electric fields. This makes them unqualified to withstand harsh operating conditions, such as in capacitor applications. This study investigates the impact of annealing BOPP samples at 100 °C for five hours after fluorination at different times (15, 30, and 60 minutes) on their electrical and mechanical performance under electro-thermal stresses. Scanning electron microscope (SEM) images confirm that there is an increase in surface roughness and the formation of a dense layer of fluorine-containing groups monotonically with fluorination time. So, …

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Thermal And Electrical Properties Of Nanocrystalline Superionic Naxcu1.75s (X=0.1, 0.15, 0.2, 25) Compounds, M.M. Kubenova, K.A. Kuterbekov, M.Kh. Balapanov, R.Kh. Ishembetov, B.M. Akhmetgaliev, A.M. Kabyshev, K.Zh. Bekmyrza, M.Kh. Zeleev, R.Sh. Palymbetov, B.U. Baikhozhaeva Mar 2023

Thermal And Electrical Properties Of Nanocrystalline Superionic Naxcu1.75s (X=0.1, 0.15, 0.2, 25) Compounds, M.M. Kubenova, K.A. Kuterbekov, M.Kh. Balapanov, R.Kh. Ishembetov, B.M. Akhmetgaliev, A.M. Kabyshev, K.Zh. Bekmyrza, M.Kh. Zeleev, R.Sh. Palymbetov, B.U. Baikhozhaeva

Eurasian Journal of Physics and Functional Materials

The paper presents the results of the studies of thermal properties of nanocrystalline superionic NaxCu1.75S (x = 0.1, 0.15, 0.2, 25) compositions, and preliminary results of Na0.1Cu1.75S using as energy stored cathode material in Na-ion half-cell with NaPF6 electrolyte and Na anode. The compositions contain a few copper sulfide phases: monoclinic chalcocite Cu2S, orthorhombic anilite Cu1.75S, triclinic roxbyite Cu1.74÷1.82S, also the compositions can contain monoclinic Na2Cu4S3, orthorhombic Na2S, cubic Cu2O as inclusion phases. The sizes …

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Research On Three-Component Responses Characteristics Of Axial Anisotropy Tunnel-Hole Transient Electromagnetic, Guo Jianlei, Gao Xiaowei, Hou Yanwei Jul 2022

Research On Three-Component Responses Characteristics Of Axial Anisotropy Tunnel-Hole Transient Electromagnetic, Guo Jianlei, Gao Xiaowei, Hou Yanwei

Coal Geology & Exploration

Large interpretation errors may exist in exploration areas with obvious conductivity anisotropy when applying tunnel-hole transient electromagnetic method. In this paper, the control equation is built by introducing the conductivity anisotropy tensor, which allows the current density of the rectangular loop source to be added into the Maxwell equation Ampere loop theorem based on the finite difference time domain (FDTD) algorithm in order to realize the loading of any current source. The control equation is discretized by the difference instead of the differential to realize the forward calculation of the tunnel-hole transient electromagnetic 3D model. Forward modeling is carried out …

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Experimental Study On The Influence Of Coal-Based Co2 Geological Storage On Roof Fracture Conductivity, Zhu Shiliang, Shao Liwei, Zhou Xiaozhi, Cao Yutong, Zhang Kun, Wang Jiandong Jun 2021

Experimental Study On The Influence Of Coal-Based Co2 Geological Storage On Roof Fracture Conductivity, Zhu Shiliang, Shao Liwei, Zhou Xiaozhi, Cao Yutong, Zhang Kun, Wang Jiandong

Coal Geology & Exploration

Coal-based CO2 geological storage is an important way to reduce greenhouse gas emissions, but there is also a safety risk of underground CO2 leakage. In order to evaluate the safety of coal-based CO2 geological storage, the roof samples of No.3 coal seam in Hudi Coal Mine, southern Qinshui Basin were collected, and the changes of artificial fracture morphology, whole rock mineral composition and CO2 conductivity of columnar samples in "CO2-H2O-Rock" reaction were studied by simulation experiments. The results show that calcite vein dissolution, secondary mineral filling and external effective stress jointly affect …

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Influence Of The Temperature To The Growth Of Thin Film Sno2, A.G. Gulyamov, M.U. Xajiev, X.N Juraev Jun 2019

Influence Of The Temperature To The Growth Of Thin Film Sno2, A.G. Gulyamov, M.U. Xajiev, X.N Juraev

Bulletin of Gulistan State University

The SnO2 thin films on glass substrate grown by methods of chemical vapor deposition (CVD) in conditions of quasiclosed volume by using a separate evaporator to obtain a saturated are investigated. It is suggested that under these conditions the germ growth occurs by diffusion coalescence. In the IR absorption spectra of SnO2 films, an absorption band in the range of 2500-3800 cm-1 is detected, the amplitude of which is correlated with the conductivity of the grown films.

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Investigation On The Electrical Properties Of Cdo/Zno Thin Films Using Thz Spectroscopy, Ramon Molina May 2019

Investigation On The Electrical Properties Of Cdo/Zno Thin Films Using Thz Spectroscopy, Ramon Molina

Macalester Journal of Physics and Astronomy

In this work, we study the electrical properties of transparent conducting oxides using physical and optical techniques. The objective is to characterize the conductivity of a series of cadmium oxide zinc-oxide thin films with varying cadmium concentrations using three methods. The Hall Effect estimates carrier concentration, sheet conductivity, and carrier mobility. Optical methods, such as FTIR spectroscopy, can provide estimates of the plasma frequency, which describes a metal’s transition from being transparent to opaque to light. THz spectroscopy extracts the complex conductivity of materials in the far infrared spectrum and provides insights on the optical transport properties of conductors. Our …

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Conductivity Measurements Of A Thermoelectric Nanomaterial Through Thz Spectroscopy, Michaela S. Koller, James Heyman, Gunnar Footh May 2017

Conductivity Measurements Of A Thermoelectric Nanomaterial Through Thz Spectroscopy, Michaela S. Koller, James Heyman, Gunnar Footh

Macalester Journal of Physics and Astronomy

In today’s society there is a great demand on energy output—in the United States alone we rely heavily on non-renewable energy sources. Thermoelectric materials may be able to be used to create more efficient energy systems or recover wasted heat from inefficient technologies. This paper focuses on the conductivity of a new thermoelectric material that incorporates copper into a tellurium nanowire PEDOT:PSS material. The addition of copper seems to increase the conductivity of the material, although the exact relationship between the percentage of copper to tellurium and its affect on the conductivity is uncertain from the results.

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Research Progress Of Intermediate Layers In Ti-Based Oxide Anodes, Xiu-Li Song, Hui-Min Yang, Zhen-Hai Liang Aug 2013

Research Progress Of Intermediate Layers In Ti-Based Oxide Anodes, Xiu-Li Song, Hui-Min Yang, Zhen-Hai Liang

Journal of Electrochemistry

Titanium (Ti)-based oxide anodes are excellent anode materials which have been applied widely in electrochemical fields all over the world. Adding intermediate layers in Ti-based oxide anodes can improve the conductivity, lengthen the lifetime and strengthen the stability between Ti base and metal oxides active layers of electrodes. This article reviews the research progress of intermediate layers in Ti-based oxide anodes. At the same time, current problems existed in the field of Ti-based oxide anodes are pointed out and future development trend in oxide electrode with intermediate layers is prospected.

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Preparation And Characterization Of A Novel Composite Electrolyte Ceria-Sulfate For Intermediate Temperature Solid Oxide Fuel Cells, Ze Tong, Yi-Mei Yin, Jie-Wei Yin, Zi-Feng Ma Jun 2013

Preparation And Characterization Of A Novel Composite Electrolyte Ceria-Sulfate For Intermediate Temperature Solid Oxide Fuel Cells, Ze Tong, Yi-Mei Yin, Jie-Wei Yin, Zi-Feng Ma

Journal of Electrochemistry

A novel composite electrolyte SDC-(Li/Na)2SO4 was prepared for intermediate temperature solid oxide fuel cells (ITSOFC). The phase structure and cross-sectional morphology were examined by XRD and SEM, respectively, and the ionic conductivity was investigated by AC impedance in a temperature range of 400 oC ~ 700 oC in air. It was found that the composite electrolyte was composed of two phases: crystal SDC and amorphous (Li/Na)2SO4. The conductivity of the composite electrolyte was significantly larger than that of SDC at intermediate temperatures (550 oC ~ 700 oC) and increased …

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Preparation And Electrochemical Performance Of Li_3v_2(Po_4)_3, Hou-Gang Fan, Tao Jiang, Chun-Zhong Wang, Gang Chen, Ying-Jin Wei Feb 2009

Preparation And Electrochemical Performance Of Li_3v_2(Po_4)_3, Hou-Gang Fan, Tao Jiang, Chun-Zhong Wang, Gang Chen, Ying-Jin Wei

Journal of Electrochemistry

The carbon coating Li3V2(PO4)3 powder samples were synthesized by carbon incorporation solid state reaction.The structure,morphology and electrochemical properties have been studied by X-ray powder diffraction,scanning electron microscopy and automatic battery tester system,respectively.Carbon coating on Li3V2(PO4)3 would prevent the particles from agglomerating,reduce the particle size,raise the conductivity and improve the samples′ electrochemical performance.

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Preparation Of The Protic Ionic Liquid/Pvdf-Hfp Composite Membranes And Its Performance For Dmfc, Rui-Ying Miao, Jian-Ling Li, Yong Fang, Xin-Dong Wang Feb 2009

Preparation Of The Protic Ionic Liquid/Pvdf-Hfp Composite Membranes And Its Performance For Dmfc, Rui-Ying Miao, Jian-Ling Li, Yong Fang, Xin-Dong Wang

Journal of Electrochemistry

The protic ionic liquid(PIL) α-methyl pyridinium trifluoroacetate([α-MPyH]Tfa) was synthesized by acid & alkali neutralization.Then PIL/PVDF-HFP composite membranes were prepared by means of phase inversion method using acetone as solvent.The conductivities of the composite membrane increased with the temperature and reached 8×10-3 S/cm,1×10-2 S/cm and 3×10-2 S/cm at room-temperature,30 ℃ and 80 ℃,respectively,by electrochemical impedance method.The properties of the methanol-rejecting of the membranes were measured by chronoamperometry as well.The results indicate that the properties of methanol-resistance of the membranes before and after IL combination were equivalent approximately.

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Dielectric Behavior Of The Catalyst Zeolite Nay, Ertuğrul İzci̇, Ali̇me İzci̇ Jan 2007

Dielectric Behavior Of The Catalyst Zeolite Nay, Ertuğrul İzci̇, Ali̇me İzci̇

Turkish Journal of Chemistry

Zeolites are crystalline hydrated aluminosilicates of alkaline and alkaline earth metals. The basic zeolite structure is an anionic frame of Si and Al T-atoms, which are tetrahedral and coordinated with oxygen atoms. The electrical properties of zeolites are of enormous technical importance due to their manifold applications as solid catalysts. Zeolite NaY was used in this investigation. Zeolite NaY is a synthetic zeolite and it has a faujasite structure. The electrical conductivity, dielectric permittivity, and loss factor of Na ion exchanged zeolite NaY was carried out in the 10^4-10^6 Hz frequency region at room temperature and different water contents using …

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The Optimal Sulfonation Conditions Of Self-Doped Polyaniline Obtained By Using Experimental Strategies, Wen-Yar Li, Chi-Chang Hu Nov 2005

The Optimal Sulfonation Conditions Of Self-Doped Polyaniline Obtained By Using Experimental Strategies, Wen-Yar Li, Chi-Chang Hu

Journal of Electrochemistry

The optimal sulfonation condition of self-doped sulfonated polyaniline(prepared from leucoemeraldinebase;denoted as LEB-SPANI) with a high electronic conductivity was obtained by experimental strategies,includingthe fractional factorial design(FFD) and central composite design(CCD).From the FFD experiment,the self-doped LEB-SPANI prepared at a lowtemperature(4oC),a short reaction time(1 h),and a small volume of fumingsulfuric acid(10 mL) showed a better conductivity(ca.127 mS/cm).In the CCD study coupled with a confirmationtest,the highest conductivity(ca.141 mS/cm) of the LEB-SPANI film was obtained under a sulfonation temperatureof 4oC,a sulfonation time of75 minutes,and a volume of8 mLof30% fuming sulfuric acid.The textural cha-racter-istics of self-doped LEB-SPANI were characterized by Fourier transform infrared(FTIR) spectroscopy,four-pointprobe method,and X-ray …

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Electrochemical Performance Of Gel Polymer Electrolyte Prepared By Thermal Initiating Polymerization Of Acrylates, Jin-Dan Piao, Li-Xia Yuan, Xin-Ping Ai, Han-Xi Yang, Yu-Liang Cao Feb 2005

Electrochemical Performance Of Gel Polymer Electrolyte Prepared By Thermal Initiating Polymerization Of Acrylates, Jin-Dan Piao, Li-Xia Yuan, Xin-Ping Ai, Han-Xi Yang, Yu-Liang Cao

Journal of Electrochemistry

A gel polymer electrolyte was prepared by thermal initiating polymerization of the acrylates in the EC/EMC/DMC electrolyte solution at 100℃. The LiCoO_2/MCMB polymer cells were assembled and their electrochemical properties were evaluated at various charge-discharge rate and temperatures. The ionic conductivity of the polymer electrolyte containing 85wt.% liquid electrolyte is around 3.2×10~(-3)S·cm~(-1) at 20℃ and 5.6×10~(-4)S·cm~(-1)at -30℃ respectively. The gel polymer electrolyte has good electrochemical stability up to 4.5V versus Li/Li~(+).The first charge-discharge efficiency of the polymer cell at 0.2C rate is almost 92.1%. The discharge capacity of the cell at 1.0C rate is 95% of the capacity at the …

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Proton Conduction In Pvpa --Benzimidazole Hybrid Electrolytes, Fatma Sevi̇l, Ayhan Bozkurt Jan 2005

Proton Conduction In Pvpa --Benzimidazole Hybrid Electrolytes, Fatma Sevi̇l, Ayhan Bozkurt

Turkish Journal of Chemistry

Proton conducting properties of benzimidazole (BnIm) doped poly(vinylphosphonic acid) (PVPA) were studied. The doping ratio, x, which is the number of moles of BnIm per mole of polymer repeat unit, varied from 0.5 to 2. The samples were characterized by FT-IR spectroscopy, thermogravimetric analysis (TG), differential scanning calorimetry (DSC) and impedance spectroscopy. The IR study indicates the protonation of heterocyclic units from the "free nitrogen" side. The proton conductivity and thermal stability of the blends increase with x. Maximum conductivity of PVPA x BnIm blends is approximately 10^{-3} S/cm at 150 °C.

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Defect Structure And Properties Of Sr-Doped La Cr O_{3-\Delta}, Mahmoud Omari, Ilhem Chadli, Salah Belaidi Jan 2004

Defect Structure And Properties Of Sr-Doped La Cr O_{3-\Delta}, Mahmoud Omari, Ilhem Chadli, Salah Belaidi

Turkish Journal of Chemistry

A defect chemical model for the behavior of acceptor-doped LaCrO_3 as a function of oxygen pressure is proposed. This is considered within the regime that corresponds to oxygen deficit oxygen. The mathematical approach allows us to calculate the oxygen partial pressure dependant properties of La_{1-x} Sr_x Cr O_{3-\delta} in the range 0.10 \le x \le 0.30. The results show that the conductivity was independent of pO_2 and was proportional to the dopant concentration at high pO_2. Therefore, under reducing conditions, the conductivity decreased exponentially with decreasing pO_2 and asymptotically approached a pO_2^{1/4} relationship. Stability regimes and compensation mechanisms at various …

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Recent Developments In The Electrolyte For Lic _6/Electrolyte/Cathode Battery, Cui-Ying Wang, Sheng-Liang Zhao, Guang-Ming Zhu, Jin-Kua You, Zu-Geng Lin May 2002

Recent Developments In The Electrolyte For Lic _6/Electrolyte/Cathode Battery, Cui-Ying Wang, Sheng-Liang Zhao, Guang-Ming Zhu, Jin-Kua You, Zu-Geng Lin

Journal of Electrochemistry

We present a reviewed the development and status of electrolyte for LiC 6/electrolyte/cathode battery. The effect of the salt, solvent, additive and impurity on the conductivity of the electrolyte, formation of the solid_electrolyte_interphase (SEI) and cycle life of the battery were described.

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Studies Of Electrochemical Characteristics Of Pasted Nickel Hydroxide Electrode With Surface Deposited Cobalt, Xianyou Wang, Yunshi Zhang, Jie Yan, Zheng Zhu, Huatang Yuan, Deying Song Feb 1999

Studies Of Electrochemical Characteristics Of Pasted Nickel Hydroxide Electrode With Surface Deposited Cobalt, Xianyou Wang, Yunshi Zhang, Jie Yan, Zheng Zhu, Huatang Yuan, Deying Song

Journal of Electrochemistry

The surface of the spherical nickel hydroxide particles used as an active material in pasted nickel electrodes is surface_deposited with cobalt. This paper investigated the effects of the amount of cobalt deposit on the characteristics of nickel hydroxide electrode. The performances of the electrode, such as discharge capacity, utilization of active material and reversibility of Ni(OH) 2/NiOOH redox reaction, were studied by comparing the charging/discharging curves and cyclic voltammograms. The mechanism of action of cobalt deposits has been described in terms of the electrochemical impedance spectroscopy of nickel hydroxide electrode.

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Thermodynamics Of The Dissociation Of Chromium Soap Solutions In Benzene-Dimethyl Formamide, Hüseyi̇n Topallar, Yüksel Bayrak Jan 1999

Thermodynamics Of The Dissociation Of Chromium Soap Solutions In Benzene-Dimethyl Formamide, Hüseyi̇n Topallar, Yüksel Bayrak

Turkish Journal of Chemistry

Critical micelle concentrations and dissociation constants for chromium soaps (myristate, palmitate and stearate) in a mixture of benzene and dimethyl formamide (7:3, vol/vol) were determined by means of conductivity measurements. These soaps behave as simple moderate electrolytes in dilute solutions. Critical micelle concentrations and dissociation constants decreased with increasing numbers of carbon atoms in the soap molecules. Thermodynamic parameters such as heat of dissociation, \DeltaH_d, change in free energy, \DeltaG_d, and entropy, \DeltaS_d, per mole for the dissociation process were also evaluated.

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Electrochemical Studies Of Zncl 2 Urea Melts, Peng Liu, Qiqin Yang, Guankun Liu, Yexiang Tong May 1996

Electrochemical Studies Of Zncl 2 Urea Melts, Peng Liu, Qiqin Yang, Guankun Liu, Yexiang Tong

Journal of Electrochemistry

The electric conductivities of ZnCl 2 Urea melts were determined.The influences of temperature and concentration on the conductance have been studied.The cylic voltammetry,potentiostatic electrolysis and open circuit potential time curve after electrolysis,X ray diffraction were used to investigate the electroreduction of Zn 2+ , electrodeposition of zinc on some electrodes in urea metal chlorides melt. The conductivity of urea NaCl ZnCl 2 melt can reach to over 30 ms·cm -1 (125 ℃), and has a liner relationship with temperature from 108 to 140 ℃. The electroreduction of Zn 2+ to zinc is reversible at one step, and CuZn 5 alloy …

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Diatoms Of Northeastern Iowa Fens, Stephen P. Main, David E. Busch Jan 1992

Diatoms Of Northeastern Iowa Fens, Stephen P. Main, David E. Busch

Journal of the Iowa Academy of Science: JIAS

Analysis of water samples from 10 fens in NE Iowa, collected 13-14 November 1987, revealed a gradient from acid, low conductivity water conditions (pH 5.6, alkalinity 30 mg/I HCO, conductivity 65 μmho, total hardness 30 mg/I Ca) to circumneutral, moderately conductive conditions (pH 7 .2, alkalinity 390 mg/I, conductivity 705 μmho, total hardness 380 mg/I Ca). Three sites along this gradient were sampled 15 May 1988 and 3 September 1988 to evaluate seasonal variation in water conditions. Examination of composite diatom samples collected concurrently with the water samples yielded 150 taxa, of which 14 are new Iowa distributional records and …

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