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Full-Text Articles in Physical Sciences and Mathematics
Effect Of Aluminum Alloy Surface Modification On Adhesion Of The Modified Polyurethane Coating And Its Corrosion Protective Performance, Xian-Yin Kuang, Shao-Qiang Jin, Yan-Hui Cao, Yan-Mei Zhang, Shi-Gang Dong, Long-Hui Zhu, Li-Wen Lin, Chang-Jian Lin
Effect Of Aluminum Alloy Surface Modification On Adhesion Of The Modified Polyurethane Coating And Its Corrosion Protective Performance, Xian-Yin Kuang, Shao-Qiang Jin, Yan-Hui Cao, Yan-Mei Zhang, Shi-Gang Dong, Long-Hui Zhu, Li-Wen Lin, Chang-Jian Lin
Journal of Electrochemistry
The ordinary organic coatings on aluminum alloy usually encounter a problem of low adhesion to the substrate, which results in destruction and failure of the long-term protective performance of the anticorrosion systems. The surface modification of aluminum alloy is able to enhance the adhesion of organic coating on aluminum alloys, and to improve their protective performance. In this work, a combined surface modification of anodic oxidation and mussel adhesion protein/CeO2/3-aminopropyltriethoxysilane composite film (MCA) was developed on the aluminum alloy. The adhesion of modified polyurethane coated on the treated aluminum alloy and its corrosion protective performance were evaluated comprehensively …
Fuel Cells Reactor For Chemicals And Electric Energy Cogeneration, Zhi-Lin Heng, Xiao-Zi Yuan, Yi-Mei Yin, Zi-Feng Ma
Fuel Cells Reactor For Chemicals And Electric Energy Cogeneration, Zhi-Lin Heng, Xiao-Zi Yuan, Yi-Mei Yin, Zi-Feng Ma
Journal of Electrochemistry
As an energy conversion device, fuel cells can efficiently convert chemical energy into electrical energy. With the developing of technology, it is used as a reactor to conduct the synthesis of high value-added chemicals while generating electrical energy. Having benefits such as mild reaction conditions, controllability of the reaction process, high selectivity of the product, as well as high efficiency of energy utilization, it is widely used in many fields such as preparation of high value-added industrial products, gas separation, water treatment, etc. This paper introduces the current trends and statuses of fuel cell reactors in the cogeneration of chemicals …
Photogenerated Cathodic Protection Of Stainless Steel, Cheng-Gang Lin, Ze-Quan Lin, Jing Li, Chang-Jian Lin
Photogenerated Cathodic Protection Of Stainless Steel, Cheng-Gang Lin, Ze-Quan Lin, Jing Li, Chang-Jian Lin
Journal of Electrochemistry
A highly ordered Co-doped TiO2 nanotube layers were fabricated by potentiostatic anodization of pure titanium in fluorinated electrolyte solutions followed by ion-exchange method. The structure and composition of the as-prepared Co-doped TiO2 nanotube layers were characterized by SEM, XRD, UV-Vis, and XPS. The effects of dopant content on the morphologies, structural and photochemical properties of the TiO2 nanotube arrays were investigated. The performances of photogenerated cathodic protection and the photoelectrochemical response for the Co-doped TiO2 nanotube arrays under illumination and dark conditions were evaluated through the electrochemical measurements. The Co-doped TiO2 nanotubes showed a stronger absorption in the visible light …
Fabrication Of Superhydrophilic Aluminum Oxide Through Single-Step Anodic Oxidation, Qin Zhang, Qi-Ming Yin, Jia-Ming Ye, Yuan-Rong Zhu
Fabrication Of Superhydrophilic Aluminum Oxide Through Single-Step Anodic Oxidation, Qin Zhang, Qi-Ming Yin, Jia-Ming Ye, Yuan-Rong Zhu
Journal of Electrochemistry
Hydrophilic aluminum oxide is popularly used for heat exchanger of air-condition.Herein,we developed a simple method to prepare superhydrophilic aluminum oxide on the surface of aluminum through single-step electrochemical oxidization.The morphologies and water contact angles on surfaces of alumina fabricated under different electrochemical conditions were investgated.Superhydrophilic surfaces fabricated by this method have good stability and high mechanical strength with water contact angle almost 0°.Coated with low surface energy materials,superhydrophilc alumina will be converted to superhydrophobic.
Electrochemical Oxidation Of Organic Additives In Tin Plating Electrolytes, Yin-Mei Cheng, Lan-Kun Cai, Qiang Song
Electrochemical Oxidation Of Organic Additives In Tin Plating Electrolytes, Yin-Mei Cheng, Lan-Kun Cai, Qiang Song
Journal of Electrochemistry
Cyclic voltammetry(CV) was used to characterize the voltammetric behaviours of organic additives,e.g.PSA(phenolsulfonic acid)、EN(ethoxylatedα-naphthol) and ENSA(ethoxylatedα-naphthol sulfonic acid),on the anode surface.In PSA solutions,an anodic peak was obtained and the peak potential was about 1.2V.In EN and ENSA solutions,two anodic peaks were obtained and the peak potentials were about(0.95V) and 1.3V.The products of galvanostatic electrolysis were separated by HPLC(high performance liquid chromatography) and analyzed by EI/MS(electron ionizing mass spectrometry).The mechnism of the electrochemical oxidation was also disussed.
Electrochemical Study On The Anodic Process Of Fes, Hong-Hui Xu
Electrochemical Study On The Anodic Process Of Fes, Hong-Hui Xu
Journal of Electrochemistry
Ferrous sulfide (FeS) was synthesized with spectrum-pure Fe and S at high-temperature, and its anodic behaviors in the solution of 0.5 mol·L~(-1) H_2SO_4 + 0.5 mol·L~(-1) K_2SO_4 was studied by using voltage sweep and step voltage techniques. The effects of acidity on the anodic polarization curves of FeS were investigated. The transfer coefficient β and exchange current density I_0 in the anodic electrode process, and the solid diffusion coefficient D_(Fe) of Fe~(2+) in FeS were measured. And also the activation energies of anodic reaction at different voltages was also determined.
Investigation Of Sodium Hypophosphite Anodic Oxidizing Behavior In The Process Of Acid Electroless Nickel Deposition, Meiyuan Wang, Yafei Kuang, Yan Xu
Investigation Of Sodium Hypophosphite Anodic Oxidizing Behavior In The Process Of Acid Electroless Nickel Deposition, Meiyuan Wang, Yafei Kuang, Yan Xu
Journal of Electrochemistry
The anodic oxidizing behavior of sodium hypophosphite in the process of electroless nickle deposition(pH=5.5) was investigated with the linear potential sweep method and alternating current impedance.The results indicated that,the oxidation of NaH 2PO 2 was a complicated electrochemical process and affected by the concentration of NaH 2PO 2, the temperature of the bath,the sweep rate and the existence of nickel ion. The NaH 2PO 2 electrooxidation reaction was very likely preceded by heterogeneous interface transformation process,which might be the control step of the whole anodic process.
Aes Multi_Layer Structural Analysis Of Si Based Anodic Porous Alumina Films And Studies On Its Formation Mechanism, Junhui Wu, Jianping Zou, Qing Zhu, Ximao Bao
Aes Multi_Layer Structural Analysis Of Si Based Anodic Porous Alumina Films And Studies On Its Formation Mechanism, Junhui Wu, Jianping Zou, Qing Zhu, Ximao Bao
Journal of Electrochemistry
nm aluminum films were deposited onto a p_type,0.5 Ω·cm, 〈100〉 oriented silicon wafers using electron beam evaporation technique.Then,the wafers was immersed in 15 wt% H 2SO 4 for porous_type over_anodization under a constant voltage of DC 60V.During the anodization,the temperature of the electrolyte was maintained at 0 ℃.The obtained samples were investigated by means of transmission electron microscopy,scanning electron microscopy,and AES depth profile for multi_layer structural information.In addition, the basic anodic formation mechanism of the Si_based aluminum films was brielfly discussed.