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Full-Text Articles in Physical Sciences and Mathematics

Aes Multi_Layer Structural Analysis Of Si Based Anodic Porous Alumina Films And Studies On Its Formation Mechanism, Junhui Wu, Jianping Zou, Qing Zhu, Ximao Bao Nov 1999

Aes Multi_Layer Structural Analysis Of Si Based Anodic Porous Alumina Films And Studies On Its Formation Mechanism, Junhui Wu, Jianping Zou, Qing Zhu, Ximao Bao

Journal of Electrochemistry

nm aluminum films were deposited onto a p_type,0.5 Ω·cm, 〈100〉 oriented silicon wafers using electron beam evaporation technique.Then,the wafers was immersed in 15 wt% H 2SO 4 for porous_type over_anodization under a constant voltage of DC 60V.During the anodization,the temperature of the electrolyte was maintained at 0 ℃.The obtained samples were investigated by means of transmission electron microscopy,scanning electron microscopy,and AES depth profile for multi_layer structural information.In addition, the basic anodic formation mechanism of the Si_based aluminum films was brielfly discussed.


Investigation Of Sodium Hypophosphite Anodic Oxidizing Behavior In The Process Of Acid Electroless Nickel Deposition, Meiyuan Wang, Yafei Kuang, Yan Xu Nov 1999

Investigation Of Sodium Hypophosphite Anodic Oxidizing Behavior In The Process Of Acid Electroless Nickel Deposition, Meiyuan Wang, Yafei Kuang, Yan Xu

Journal of Electrochemistry

The anodic oxidizing behavior of sodium hypophosphite in the process of electroless nickle deposition(pH=5.5) was investigated with the linear potential sweep method and alternating current impedance.The results indicated that,the oxidation of NaH 2PO 2 was a complicated electrochemical process and affected by the concentration of NaH 2PO 2, the temperature of the bath,the sweep rate and the existence of nickel ion. The NaH 2PO 2 electrooxidation reaction was very likely preceded by heterogeneous interface transformation process,which might be the control step of the whole anodic process.