Physical Sciences and Mathematics Commons^™

Effect Of Storage Time And Temperature On Recovery Of Synergistes Jonesii From Rumen Fluid And Feces, W. M. Andrew, M. J. Williams, M. J. Allison, C. C. Chase Jr., C. G. Chambliss, R. S. Kalmbacher, W. E. Kunkle

IGC Proceedings (1997-2023)

Synergistes jonesii is a rumen bacterium that degrades 3,4-dihydroxypyridine (3,4 DHP), the toxic breakdown product of mimosine in leucaena (Leucaena leucocephala). Fecal culture is the most practical way to determine S. jonesii presence in zoological ruminants, particularly if feces can be collected from night penning facilities. Fresh rumen fluid and fecal or fecal slurry (sheep [Ovis spp.] only, 1:4 wt to vol. feces and culture media) from cattle (Bos spp.) and sheep, known to be colonized by S. jonesii, were subjected various storage times (0, 6, 12, and 24 h) and temperatures (5, 23, and …

Raman Studies Of 1,3,5,7 Cyclooctatetraene At High Pressure, Martin Galley, Ed Romano, Sergey Tkachev, Michael Pravica

Undergraduate Research Opportunities Program (UROP)

We performed Raman spectroscopic studies of 1,3,5,7-cyclooctatetraene at elevated pressures up to 10 GPa with the aim of examining possible planarization of the molecule and further studying two prior-discovered phases of the solid with pressure. The Raman excitation source was a Krypton-ion laser operating at 674.1 nm (give wavelength).

1,3,5,7 Cyclooctatetraene has an octagonal formation however it is not aromatic or anti-aromatic (not a subject to the 4n+2 Huckel’s rule) [1]. As a result, its adopts a somewhat reactive tub shape. Upon the addition or removal of one to two electrons under ambient conditions, the molecule planarizes and becomes aromatic …