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Articles 61 - 85 of 85
Full-Text Articles in Physical Sciences and Mathematics
Remediation Of Cr(Vi) Via Combined Self-Reduction And Adsorption Bychemically Modified Carbon Sorbents, Mohamed E. Mahmoud, Amr. A. Yakout, Asmaa M. Halbas, Maher M. Osman
Remediation Of Cr(Vi) Via Combined Self-Reduction And Adsorption Bychemically Modified Carbon Sorbents, Mohamed E. Mahmoud, Amr. A. Yakout, Asmaa M. Halbas, Maher M. Osman
Turkish Journal of Chemistry
Hexavalent chromium, Cr(VI), is a highly toxic species, while trivalent chromium, Cr(III), is an essential trace element for humans and other organisms. In the present work, a simple, rapid, and efficient procedure for water treatment of Cr(VI) is described. Active carbon (AC) was chemically treated with HCl and NaOH for the formation of surface modified Acidic-AC and Basic-AC sorbents, respectively. In addition, AC sorbent was treated with HNO$_{3}$ as an oxidizing agent and sodium sulfite as a reducing agent for the formation of Ox-AC and Rd-AC sorbents, respectively. The modified AC sorbents were tested to identify their potential applications in …
Spectrophotometric Determination Of Mercury Using Vortex-Assisted Liquid-Liquid Microextraction, Tatiana Antolova, Serhii Zaruba, Jana Sandrejova, Livia Kocurova, Andriy B. Vishnikin, Yaroslav Bazel, Vasil Andruch, Ioseph S. Balogh
Spectrophotometric Determination Of Mercury Using Vortex-Assisted Liquid-Liquid Microextraction, Tatiana Antolova, Serhii Zaruba, Jana Sandrejova, Livia Kocurova, Andriy B. Vishnikin, Yaroslav Bazel, Vasil Andruch, Ioseph S. Balogh
Turkish Journal of Chemistry
A novel method for the determination of mercury(II) is suggested. The procedure is based on the formation of an ion associate between the bromide complex of Hg(II) and Astrazon Red 6B dye and vortex-assisted liquid-liquid microextraction of the ion associate formed, with subsequent spectrophotometric detection. The variables that affect the procedure, such as pH, the concentration of ligand and dye, the type and volume of extraction solvent, and the rate and time of vortex mixing, were optimized. Under optimum conditions (pH 2.0, 0.01 mol L$^{-1}$ KBr, 2 $\times $ 10$^{-4}$ mol L$^{-1}$ AR6B, 50 $\mu $L of the extraction mixture …
Synthesis And Structural Properties Of $N$-3,4-(Dichlorophenyl)-3-Oxo-3- Phenyl-2-(Phenylcarbonyl)Propanamide And Its Cu(Ii) Complex, Ahmet Oral Sarioğlu, Tuğba Taşkin Tok, Mehmet Akkurt, Muhammad Nawaz Tahir, Mehmet Sönmez
Synthesis And Structural Properties Of $N$-3,4-(Dichlorophenyl)-3-Oxo-3- Phenyl-2-(Phenylcarbonyl)Propanamide And Its Cu(Ii) Complex, Ahmet Oral Sarioğlu, Tuğba Taşkin Tok, Mehmet Akkurt, Muhammad Nawaz Tahir, Mehmet Sönmez
Turkish Journal of Chemistry
A new N-carboxamide compound (3) was synthesized by the reaction of dibenzoylaceticacid-$N$-carboxyethyla\-mide (1) and 3,4-dichloroaniline (2). The $N$-(3,4-dichlorophenyl)-3-oxo-3-phenyl-2-(phenylcarbonyl) propanamide (3) subsequently reacted with Cu salt to produce its Cu(II) complex compound (4). The compounds were characterized by analytical and spectral methods. In addition, X-ray diffraction was performed to characterize and obtain detailed information about the structure of 3. The fully optimized geometries of compounds 3 and 4 were calculated at different basis sets by using the Gaussian09 (G09) software to investigate their 3D geometries and electronic structures. Comparisons between the calculated and experimental data including molecular structures, fundamental vibrational modes, …
Comparative Density Functional Study Of Antioxidative Activity Of The Hydroxybenzoic Acids And Their Anions, Zoran Markovic, Jelena Djorovic, Jasmina M. Dimitric Markovic, Radomir Biocanin, Dragan Amic
Comparative Density Functional Study Of Antioxidative Activity Of The Hydroxybenzoic Acids And Their Anions, Zoran Markovic, Jelena Djorovic, Jasmina M. Dimitric Markovic, Radomir Biocanin, Dragan Amic
Turkish Journal of Chemistry
Hydroxybenzoic acids (HBAs) and their anions play an important role in the food and pharmaceutical industries because of their antioxidant activity. In this study, we examined the mechanisms of the free radical scavenging action of HBAs and their anions using density functional theory (DFT) methods. Reaction enthalpies related to the mechanisms of free radical scavenging by the investigated species were calculated by DFT methods in water, DMSO, pentylethanoate, and benzene. Hydrogen atom transfer (HAT) is a preferred reaction pathway in benzene, while sequential proton loss electron transfer (SPLET) is a predominant reaction pathway in polar solvents, water, and DMSO for …
Durability Of Carbon/Conducting Polymer Composite Supported Pt Catalysts Prepared By Supercritical Carbon Dioxide Deposition, Gamze Bozkurt, Fulya Memi̇oğlu, Ayşe Bayrakçeken Yurtcan
Durability Of Carbon/Conducting Polymer Composite Supported Pt Catalysts Prepared By Supercritical Carbon Dioxide Deposition, Gamze Bozkurt, Fulya Memi̇oğlu, Ayşe Bayrakçeken Yurtcan
Turkish Journal of Chemistry
Polypyrrole (PPy)/carbon (C) composites were synthesized by oxidative chemical polymerization and used as support material for Pt nanoparticles. PPy/C supported Pt nanoparticles were prepared by using a promising catalyst preparation method, supercritical carbon dioxide (scCO$_{2})$ deposition. The prepared materials were characterized by using BET, TGA, XRD, and TEM techniques. Cyclic voltammetry was used in order to determine the electrocatalytic activity of the prepared catalyst for hydrogen oxidation and oxygen reduction reactions that occur in proton exchange membrane fuel cells (PEMFCs). The Pt loading obtained over the composite material was around 10{\%}. TEM results showed highly dispersed and small nanoparticles over …
Voltammetric Determination Of Famotidine On A Disposable Pencil Graphite Electrode, Iulia Gabriela David, Dana Elena Popa, Andreea-Alexandra Calin, Mihaela Buleandra, Emilia-Elena Iorgulescu
Voltammetric Determination Of Famotidine On A Disposable Pencil Graphite Electrode, Iulia Gabriela David, Dana Elena Popa, Andreea-Alexandra Calin, Mihaela Buleandra, Emilia-Elena Iorgulescu
Turkish Journal of Chemistry
The present paper describes the use of a disposable pencil graphite electrode (PGE) for the voltammetric determination of famotidine. Cyclic voltammetric studies using different supporting electrolytes emphasized an irreversible oxidation of famotidine on the PGE. The electrode process is diffusion-controlled and pH-dependent. Differential pulse voltammetry (DPV) in phosphate buffer solution of pH 6.81 was employed for famotidine's quantitative determination. The anodic peak current of famotidine varies linearly with the analyte concentration in the range 4.72 $\times $ 10$^{-7}$--4.95 $\times $ 10$^{-4}$ M. Detection and quantification limits were 1.51 $\times $ 10$^{-7}$ M and 5.04 $\times $ 10$^{-7}$ M famotidine, respectively. …
Synthetic Approaches Towards The Synthesis Of Beta-Blockers (Betaxolol, Metoprolol, Sotalol, And Timolol), Furqan Ahmad Saddique, Ameer Fawad Zahoor, Muhammmad Yousaf, Muhammmad Irfan, Matloob Ahmad, Asim Mansha, Zulfiqar Ali Khan, Syed Ali Raza Naqvi
Synthetic Approaches Towards The Synthesis Of Beta-Blockers (Betaxolol, Metoprolol, Sotalol, And Timolol), Furqan Ahmad Saddique, Ameer Fawad Zahoor, Muhammmad Yousaf, Muhammmad Irfan, Matloob Ahmad, Asim Mansha, Zulfiqar Ali Khan, Syed Ali Raza Naqvi
Turkish Journal of Chemistry
Numerous efficient synthetic methodologies have been elaborated for the synthesis of $\beta $-blockers since the introduction of propranolol (a beta-blocker) in 1968. In this review, focus is placed on the more concise asymmetric and bioenzymatic synthetic approaches attempted towards the synthesis of beta-blockers (betaxolol, metoprolol, sotalol, and timolol).
Synthesis Of Graft Copolymer Of Kappa-Carrageenan Using Microwave Energy And Studies Of Swelling Capacity, Flocculation Properties, And Preliminary Acute Toxicity, Tapan Kumar Giri, Minakshi Pradhan, Dulal Krishna Tripathi
Synthesis Of Graft Copolymer Of Kappa-Carrageenan Using Microwave Energy And Studies Of Swelling Capacity, Flocculation Properties, And Preliminary Acute Toxicity, Tapan Kumar Giri, Minakshi Pradhan, Dulal Krishna Tripathi
Turkish Journal of Chemistry
Grafting of acrylamide (AAm) onto kappa-carrageenan (KC) was carried out using microwave irradiation in the presence of ammonium persulfate (APS) as initiator. The effect of reaction variables including the concentration of APS, AAm, and KC; time duration; and microwave power was studied. Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM) were carried out to characterize the graft copolymer. The graft copolymer possesses slightly sensitive activities to external pH and shows reversible on--off switching swelling characteristics. Flocculation efficacy of the graft copolymer was studied in coal fine suspension toward potential application as …
The Role Of N-Heterocyclic Carbene Substituents On Ruthenium(Ii) Complexes In The Catalytic Transfer Hydrogenation Of Acetophenone, Muhammet Emi̇n Günay, Gülcan Gençay Çoğaşlioğlu
The Role Of N-Heterocyclic Carbene Substituents On Ruthenium(Ii) Complexes In The Catalytic Transfer Hydrogenation Of Acetophenone, Muhammet Emi̇n Günay, Gülcan Gençay Çoğaşlioğlu
Turkish Journal of Chemistry
The novel ruthenium(II) complexes [RuCl$_{2}$(NHC)($p$-cymene)], \textbf{3a}--\textbf{e}, containing 1-alkyl-3-benzylimidazol-2-ylidene ligands were prepared. All synthesized compounds were characterized by NMR spectroscopy and elemental analyses. Ru(II)-NHC complexes were tested as catalysts for the transfer hydrogenation of acetophenone, showing modest to high activity in this reaction. The results revealed that efficiencies depend on the substituents of the benzene ring of the benzyl on the N atom of the NHC ring.
Synthetic Access To Some New Benzothiazole-Based 1,3,4-Thiadiazole And 1,3-Thiazole Derivatives, Kamal M. Dawood, Eman A. Ragab, Korany A. Ali
Synthetic Access To Some New Benzothiazole-Based 1,3,4-Thiadiazole And 1,3-Thiazole Derivatives, Kamal M. Dawood, Eman A. Ragab, Korany A. Ali
Turkish Journal of Chemistry
1-(Benzothiazol-2-yl)-3-phenylthiourea\textbf{ 2} was prepared and treated with hydrazonoyl chlorides \textbf{3a}--\textbf{e }to yield the corresponding 5-(benzothiazol-2-ylimino)-1,3,4-thiadiazole derivatives \textbf{6a}--\textbf{e}, respectively. Reaction of the thiourea derivative \textbf{2} with ethyl 2-chloro-3-oxobutanoate \textbf{9} afforded the corresponding 2-(benzothiazol-2-ylimino)thiazole-5-carboxylate derivative \textbf{11}. The newly synthesized heterocyclic derivatives were confirmed from their elemental and spectral analyses.
Suppression Of Interfering Ions By Using Ionic Liquid And Micelle Moieties In Spectrofluorimetric Analysis Of Manganese, Özlem Öter, Müge Aydin, Kadri̇ye Erteki̇n
Suppression Of Interfering Ions By Using Ionic Liquid And Micelle Moieties In Spectrofluorimetric Analysis Of Manganese, Özlem Öter, Müge Aydin, Kadri̇ye Erteki̇n
Turkish Journal of Chemistry
Eosin-Y exhibits high affinity and emission based spectral response to most of the major ions in water samples. In the present study we performed selective spectrofluorimetric analysis of manganese with eosin-Y in the presence of potential interferents. We employed green chemistry reagents, ionic liquids (ILs) and two different micelles, to suppress the effect of conventional cations and anions on the response of eosin-Y. The experimental data revealed that different test moieties caused enhanced analytical response to Mn$^{2+}$. The highest analytical signal of eosin-Y was obtained in the presence of Triton X-100 at a concentration of 2.0 $\times $ 10$^{-3}$ mol …
Synthesis And Application Of Polyvinylimidazole-Based Bronsted Acidic Ionic Liquid Grafted Silica As An Efficient Heterogeneous Catalyst In The Preparation Of Quinoxaline Derivatives, Bahman Tamami, Alireza Sardarian, Elaheh Ataollahi
Synthesis And Application Of Polyvinylimidazole-Based Bronsted Acidic Ionic Liquid Grafted Silica As An Efficient Heterogeneous Catalyst In The Preparation Of Quinoxaline Derivatives, Bahman Tamami, Alireza Sardarian, Elaheh Ataollahi
Turkish Journal of Chemistry
Two types of polymer-grafted silica based on polyvinylimidazole Bronsted acidic ionic liquids were prepared and used as new heterogeneous catalysts for the preparation of pharmaceutically important quinoxaline derivatives. These catalysts were characterized by thermogravimetric analysis, FT-IR spectroscopy, and titration. They could be recycled without considerable loss in their catalytic activity. High efficiency of the catalysts along with short reaction times, high yields, easy purification, recyclability, and simple procedure are among the advantages of these catalytic systems.
Synthesis, And Prediction Of Molecular Properties And Antimicrobial Activity Of Some Acylhydrazones Derived From $N$-(Arylsulfonyl)Methionine, Esra Tatar, Sevi̇l Şenkardeş, Hasan Erdi̇nç Selli̇tepe, Şükri̇ye Güni̇z Küçükgüzel, Şengül Alpay Karaoğlu, Ari̇f Bozdeveci̇, Erik De Clercq, Christophe Pannecouque, Tai̇bi̇ Ben Hadda, İlkay Küçükgüzel
Synthesis, And Prediction Of Molecular Properties And Antimicrobial Activity Of Some Acylhydrazones Derived From $N$-(Arylsulfonyl)Methionine, Esra Tatar, Sevi̇l Şenkardeş, Hasan Erdi̇nç Selli̇tepe, Şükri̇ye Güni̇z Küçükgüzel, Şengül Alpay Karaoğlu, Ari̇f Bozdeveci̇, Erik De Clercq, Christophe Pannecouque, Tai̇bi̇ Ben Hadda, İlkay Küçükgüzel
Turkish Journal of Chemistry
A series of 38 new acylhydrazones [3-40], derived from (2$S)$-4-(methylsulfanyl)-2-[[(4-methylphenyl)sulfonyl] amino]butanoic acid hydrazide [2], were synthesized and evaluated for their anti-HIV and antimicrobial activity with the further aim to develop acylhydrazones carrying an amino acid side chain. All tested compounds possess stronger activity against gram (+) bacteria. Compound 23 was found active against methicillin-resistant Staphylococcus aureus (MRSA) with a MIC value of 3.9 $\mu $g/mL. The MIC value of compound 30 against Enterococcus faecalis, Listeria monocytogenes, and Bacillus cereus was 8 $\mu $g/mL. A computational study for prediction of ADME and drug-like properties (solubility, drug-likeness, and drug score) as well …
Prostereoisomerism And Biological Activity: Possible Implications For Drug Design, Sosale Chandrasekhar
Prostereoisomerism And Biological Activity: Possible Implications For Drug Design, Sosale Chandrasekhar
Turkish Journal of Chemistry
Prostereoisomerism (PIM), representing a subgroup within the achiral class of molecules, is manifested in a chiral environment. Although this is regardless of the orientation of the prostereoisomeric (PIC) molecule, PIM is manifested most emphatically in relation to a chiral surface (`two-dimensional chirality'). Then PIM is tantamount to `de facto chirality' as attachment of the PIC molecule to the surface leads to diastereomeric possibilities (cf. Ogston's hypothesis). Furthermore, the formation of host--guest complexes requires a steric complementarity between the component molecules. The fact that the weak dispersive forces involved therein require an optimum distance implies a `snugness of fit' criterion. This …
Electrochemical Investigation Of2-[8-Hydroxyquinoline-5-Yl)Azo]Benzo[$C$]Cinnoline On A Platinum Electrode In Dimethysulfoxide, Funda Öztürk, Zehra Yazan, Oznur Olmez, Emi̇ne Kiliç, Esma Kiliç
Electrochemical Investigation Of2-[8-Hydroxyquinoline-5-Yl)Azo]Benzo[$C$]Cinnoline On A Platinum Electrode In Dimethysulfoxide, Funda Öztürk, Zehra Yazan, Oznur Olmez, Emi̇ne Kiliç, Esma Kiliç
Turkish Journal of Chemistry
2-[8-hydroxyquinoline-5-yl)azo]benzo[c]cinnoline was synthesized for the first time and shown to possess electrochromic characteristic, i.e. changing color during the forward and back electrolysis at --1.35 V and 0.00 V, respectively, in DMSO medium. Therefore, the electrochemical investigation of this compound appears to be worthwhile. The electrochemical reduction of 2-[8-hydroxyquinoline-5-yl)azo]benzo[c]cinnoline was investigated by cyclic voltammetry, controlled potential electrolysis, and chronoamperometry techniques in the presence of 0.10 mol L$^{-1}$ tetrabutylammonium tetrafluoroborate in dimethyl sulfoxide at platinum electrode. 2-[8-Hydroxyquinoline-5-yl)azo]benzo[c] cinnoline displays three sharp cathodic peaks and three anodic peaks in the cyclic voltammogram. The diffusion coefficients and the number of electrons transferred were calculated …
Characterization Of An Al$^{3+}$-Selective Fluorescent Probe Based On A Benzoyl Hydrazine Derivative And Its Application In Cell Imaging, Yuxiang Ji, Chunwei Yu, Shaobai Wen, Jun Zhang
Characterization Of An Al$^{3+}$-Selective Fluorescent Probe Based On A Benzoyl Hydrazine Derivative And Its Application In Cell Imaging, Yuxiang Ji, Chunwei Yu, Shaobai Wen, Jun Zhang
Turkish Journal of Chemistry
A fluorescent probe based on benzoyl hydrazine was synthesized and characterized as an Al$^{3+}$-selective fluorescent probe. This probe showed good selectivity towards Al$^{3+\, }$compared to other common ions. Under optimized experimental conditions, the probe exhibited a linear dynamic response for Al$^{3+}$ from 5.0 $\times $ 10$^{-7}$ to 4.5 $\times $ 10$^{-6}$ M with a detection limit of 1.3 $\times $ 10$^{-7}$ M in ethanol-water solution (9:1, v:v, pH 6.8, 20 mM HEPES). Furthermore, it was used for imaging of Al$^{3+}$ in living cells with satisfying results.
Isoquinoline-Substituted Triazole And Pyran Derivatives: Synthesis And Computational Studies, Duygu Yeni̇dede, Selçuk Gümüş, Ayşegül Gümüş
Isoquinoline-Substituted Triazole And Pyran Derivatives: Synthesis And Computational Studies, Duygu Yeni̇dede, Selçuk Gümüş, Ayşegül Gümüş
Turkish Journal of Chemistry
The one-pot synthesis of novel 1,4-disubstituted 1,2,3-triazoles from isoquinoline-substituted homopropargyl alcohol backbone is described (42%-88% yields). A ring closing metathesis reaction and an intramolecular Pauson-Khand reaction of enyne system derived from a homopropargyl alcohol backbone to afford the corresponding isoquinoline-substituted dihydropyran and cyclopentenone-pyran, respectively, are also described (54% and 78% yields). Information about the structural, electronic, and physico-chemical properties of the novel compounds, obtained by density functional theory application, is also reported.
Zr(Iv) Complexes Of Some Heterocyclic Ligands: Synthesis, Characterization, And Ethylene Polymerization Activity, Hamdi Ali Elagab
Zr(Iv) Complexes Of Some Heterocyclic Ligands: Synthesis, Characterization, And Ethylene Polymerization Activity, Hamdi Ali Elagab
Turkish Journal of Chemistry
Thirty-one complexes of bis-(benzimidazole, benzothiazole, and benzoxazole) compounds with Zr(IV) metal centers were synthesized, characterized, activated with methylaluminoxane (MAO), and then tested for catalytic ethylene polymerization. The activities of the various catalysts were found to be functions of the heteroatoms in the ligand frameworks and the structure around the active metal center. The highest activity was obtained with 38/MAO (424 kg E/mol cat. h). The produced polyethylenes showed high molecular weights (41/MAO, 1.9 $\times$ 10$^{6}$ g/mol) and broad molecular weight distributions (38/MAO, M$_{w}$ = 9.64 $\times $ 10$^{5}$ g/mol, PD = 23). This could result from different interactions of the …
Bismuth(Iii)-Sio$_{2}$ Catalyzed Synthesis Of Polysubstituted Imidazoles With The Participation Of Azaaryl Derivatives Of Aniline In Four-Component Reactions, Zarrin Ghasemi, Ziba Zakeri, Maryam Allahvirdinesbat
Bismuth(Iii)-Sio$_{2}$ Catalyzed Synthesis Of Polysubstituted Imidazoles With The Participation Of Azaaryl Derivatives Of Aniline In Four-Component Reactions, Zarrin Ghasemi, Ziba Zakeri, Maryam Allahvirdinesbat
Turkish Journal of Chemistry
A series of novel polyaromatic derivatives of imidazole were synthesized by Bi(III) nitrate-SiO$_{2}$ catalyzed four-component reactions of benzil, ammonium acetate, aromatic aldehydes, and $N$-heterocyclic derivatives of aniline under solvent-free conditions.
Production, Purification, And Characterization Of A Thermo-Alkali Stable And Metal-Tolerant Carboxymethylcellulase From Newly Isolated Bacillus Methylotrophicus Y37, Yonca Duman, Yonca Yüzügüllü Karakuş, Arzu Sertel, Fi̇kri̇ye Polat
Production, Purification, And Characterization Of A Thermo-Alkali Stable And Metal-Tolerant Carboxymethylcellulase From Newly Isolated Bacillus Methylotrophicus Y37, Yonca Duman, Yonca Yüzügüllü Karakuş, Arzu Sertel, Fi̇kri̇ye Polat
Turkish Journal of Chemistry
A carboxymethylcellulose (CMC)-degrading bacterium was isolated from soil, identified as Bacillus methylotrophicus according to the physiological properties and analyses of 16S rRNA and a partial sequence of the gyrase A (gyrA) gene, and named as B. methylotrophicus Y37. The CMCase enzyme was purified to homogeneity by 20.4-fold with 21.73% recovery using single-step hydrophobic interaction chromatography and biochemically characterized. CMCase showed a molecular weight of approximately 50 kDa as determined by SDS-PAGE. The activity profile of the CMCase enzyme exhibited optimum activity at 45 $^{\circ}$C and pH 5.0. The activity was highly stable at alkaline pH levels. More than 90% of …
An Indirect Model For Sintering Thermodynamics, Yüksel Sarikaya, Müşerref Önal
An Indirect Model For Sintering Thermodynamics, Yüksel Sarikaya, Müşerref Önal
Turkish Journal of Chemistry
A model was proposed and used to calculated the changes in enthalpy $(\Delta H^{o})$, entropy $(\Delta S^{o}),$ and Gibbs energy $(\Delta G^{o})$, as well as equilibrium constant $(K)$ relating to the sintering of alumina compacts. Specific nanopore volume $(V)$ of the compacts was assumed as a thermodynamic variable. A hypothetical equilibrium constant $(K_{h})$ and corresponding Gibbs energy $(\Delta G_{h}^{o})$ were calculated depending on the $V$ value measured after each sintering. The thermodynamic relationships with the SI units were respectively evaluated for the initial-stage $(i)$ sintering between 1000 and 1200 $^{\circ}$C and final-stage $(f)$ sintering between 1200 and 1600 $^{\circ}$C in …
Determination Of Hexavalent Chromium In Aqueous And Alkaline Soil Extracts, Tsvetomil Voyslavov, Stefan Tsakovski, Sonya Ganeva
Determination Of Hexavalent Chromium In Aqueous And Alkaline Soil Extracts, Tsvetomil Voyslavov, Stefan Tsakovski, Sonya Ganeva
Turkish Journal of Chemistry
A fast, simple, and reliable method for determination of hexavalent chromium species in soil aqueous and alkaline extracts has been developed. The procedure is based on the ion-pair extraction of Cr(VI) with methyltrioctylammonium chloride (Aliquat 336) into xylene. The extract is analyzed by flame (FAAS) or electrothermal atomic absorption spectrometry (ETAAS). The method allows the detection of up to 2 mg kg$^{-1}$ Cr(VI) by FAAS and up to 25 $\mu $g kg$^{-1}$ Cr(VI) by ETAAS. The relative standard deviation varied in the range 2%-12% depending on the Cr(VI) levels in the samples. The analysis of certified reference material CRM041-30G Chromium …
An Application Of Coacervate-Based Extraction For The Separation And Preconcentration Of Cadmium, Lead, And Nickel Ions Prior To Their Determination By Flame Atomic Absorption Spectrometry In Various Water Samples, Anies Awad Satti, İlknur Durukan Temuge, Sema Bektaş, Çi̇ğdem Arpa Şahi̇n
An Application Of Coacervate-Based Extraction For The Separation And Preconcentration Of Cadmium, Lead, And Nickel Ions Prior To Their Determination By Flame Atomic Absorption Spectrometry In Various Water Samples, Anies Awad Satti, İlknur Durukan Temuge, Sema Bektaş, Çi̇ğdem Arpa Şahi̇n
Turkish Journal of Chemistry
Cloud point extraction (CPE), which is the most popular coacervate-based extraction method, was utilized for the separation and preconcentration of trace amounts of cadmium, lead, and nickel. Quinalizarin was used as complexing agent and Triton X-114 was used as surfactant. After extraction, analyte ions were determined by flame atomic absorption spectrometry. The detection limits (3$s)$ of 1.8 $\mu $g L$^{-1}$ for Cd(II), 3.2 $\mu $g L$^{-1}$ for Pb(II), and 2.8 $\mu $g L$^{-1}$ for Ni(II) were obtained using 50 mL of solutions. The relative standard deviation was calculated as 4.3% for 10 $\mu $g L$^{-1}$ Cd(II), 4.9% for 50 $\mu …
Ionic Liquid Based Microextraction Combined With Derivatization For Efficient Enrichment/Determination Of Asulam And Sulfide, Habibollah Eskandari, Mahnaz Shahbazi-Raz
Ionic Liquid Based Microextraction Combined With Derivatization For Efficient Enrichment/Determination Of Asulam And Sulfide, Habibollah Eskandari, Mahnaz Shahbazi-Raz
Turkish Journal of Chemistry
This study reports 2 new simple derivatization-based dispersive liquid-liquid microextraction (DLLME) methods for spectrophotometric ultratrace determination of asulam and sulfide. 1-Naphthol (in the presence of nitrite) and N,N-diethyl-p-phenylenediamine (in the presence of Fe(III)) were used to derivatize asulam and sulfide, respectively. In the enrichment methods, the formed derivatives were preconcentrated into microdroplets of the in situ formed water insoluble ionic liquid (IL), 1-hexyl-3-methylimidazolium hexafluorophosphate. Monitoring was performed at 526 nm for asulam and at 664 nm for sulfide, after dissolution of the IL-rich phases into the basic ethanolic solution and ethanol for asulam and sulfide, respectively. Beer's law was obeyed …
Separation And Preconcentration Of Pb(Ii) And Cu(Ii) Ions Via Carrier Element-Free Coprecipitation Using An Acetohydrazide Derivative, Süreyya Oğuz Tümay, Murat Yazar, Duygu Özdeş, Hakan Bektaş, Celal Duran
Separation And Preconcentration Of Pb(Ii) And Cu(Ii) Ions Via Carrier Element-Free Coprecipitation Using An Acetohydrazide Derivative, Süreyya Oğuz Tümay, Murat Yazar, Duygu Özdeş, Hakan Bektaş, Celal Duran
Turkish Journal of Chemistry
A new method based on the combination of carrier element-free coprecipitation and flame atomic absorption spectrometric determination has been investigated for simultaneous separation and preconcentration of Pb(II) and Cu(II) ions in some environmental solid and liquid samples. The 2-{3-(4-methylbenzyl)-4-[2-(1H-indol-3-yl)ethyl]-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl} -N'-(phenylmethylene) acetohydrazide (MITA) was utilized as an organic coprecipitating agent without using a carrier element for coprecipitation of the analyte ions. The effects of experimental conditions including aqueous solution pH, MITA quantity, sample volume, standing time, and centrifugation rate and time were investigated in detail and optimized. The influences of some foreign ions were also evaluated on the quantitative recoveries of …