Physical Sciences and Mathematics Commons^™

Up-To-Date Probabilistic Temperature Climatologies, Nir Krakauer, Naresh Devineni

Publications and Research

With ongoing global warming, climatologies based on average past temperatures are increasingly recognized as imperfect guides for current conditions, yet there is no consensus on alternatives. Here, we compare several approaches to deriving updated expected values of monthly mean temperatures, including moving average, exponentially weighted moving average, and piecewise linear regression. We go beyond most previous work by presenting updated climate normals as probability distributions rather than only point estimates, enabling estimation of the changing likelihood of hot and cold extremes. We show that there is a trade-off between bias and variance in these approaches, but that bias can be …

Electromechanical Magnetization Switching, Eugene M. Chudnovsky, Reem Jaafar

Publications and Research

We show that the magnetization of a torsional oscillator that, in addition to the magnetic moment also possesses an electrical polarization, can be switched by the electric field that ignites mechanical oscillations at the frequency comparable to the frequency of the ferromagnetic resonance. The 180° switching arises from the spin-rotation coupling and is not prohibited by the different symmetry of the magnetic moment and the electric field as in the case of a stationary magnet. Analytical equations describing the system have been derived and investigated numerically. Phase diagrams showing the range of parameters required for the switching have been obtained.

The Use Of A Statistical Model Of Storm Surge As A Bias Correction For Dynamical Surge Models And Its Applicability Along The U.S. East Coast, Haydee Salmun, Andrea Molod

Publications and Research

The present study extends the applicability of a statistical model for prediction of storm surge originally developed for The Battery, NY in two ways: I. the statistical model is used as a biascorrection for operationally produced dynamical surge forecasts, and II. the statistical model is applied to the region of the east coast of the U.S. susceptible to winter extratropical storms. The statistical prediction is based on a regression relation between the “storm maximum” storm surge and the storm composite significant wave height predicted ata nearby location. The use of the statistical surge prediction as an alternative bias correction for …

Role Of Engineering In Sustainable Water Management, Balázs M. Fekete, János J. Bogárdi

Publications and Research

The recognition of the limits of resources is almost as old as the realization that our planet is a sphere leading to concerns about sustainable resources management. Water resources in particular receive growing attention given its uneven distribution in many parts of the world. Engineering solutions to address water management challenges played significant roles in the past in areas such as access to clean water and sanitation, providing water for irrigation, offering protection against floods, allowing power generation, etc. Despite their proven benefits, engineering solutions are receiving increasing criticism due to their negative environmental and societal impacts and the high …

Identifying And Analyzing Rna Pseudoknots Based On Graph-Theoretical Properties Of Dual Graphs: A Partitioning Approach, Louis Petingi

Publications and Research

In this paper we propose the study of properties of RNA secondary structures modeled as dual graphs, by partitioning these graphs into topological components denominated blocks. We give a full characterization of possible topological configurations of these blocks, and, in particular we show that an RNA secondary structure contains a pseudoknot if and only if its corresponding dual graph contains a block having a vertex of degree at least 3. Once a dual graph has been partitioned via computationally-efficient well-known graph-theoretical algorithms, this characterization allow us to identify these sub-topologies and physically isolate pseudoknots from RNA secondary structures and analyze …

Synthesis Of Dinucleoside Acylphosphonites By Phosphonodiamidite Chemistry And Investigation Of Phosphorus Epimerization, William H. Hersh

Publications and Research

The reaction of the diamidite, (iPr2N)2PH, with acyl chlorides proceeds with the loss of HCl to give the corresponding acyl diamidites, RC(O)P(N(iPr)2)2 (R = Me (7), Ph (9)), without the intervention of sodium to give a phosphorus anion. The structure of 9 was confirmed by single-crystal X-ray diffraction. The coupling of the diamidites 7 and 9 with 5′-O-DMTr-thymidine was carried out with N-methylimidazolium triflate as the activator to give the monoamidites 3′-O-(P(N(iPr)2)C(O)R)-5′-O-DMTr-thymidine, and further coupling with 3′-O-(tert-butyldimethylsilyl)thymidine was carried out with activation by pyridinium trifluoroacetate/Nmethylimidazole. The new dinucleoside acylphosphonites could be further oxidized, hydrolyzed to the H-phosphonates, and sulfurized to …

Theories In Spin Dynamics Of Solid-State Nuclear Magnetic Resonance Spectroscopy, Eugene S. Mananga, Jalil Moghaddasi, Ajaz Sana, Mostafa Sadoqi

Publications and Research

This short review article presents theories used in solid-state nuclear magnetic resonance spectroscopy. Main theories used in NMR include the average Hamiltonian theory, the Floquet theory and the developing theories are the Fer expansion or the Floquet-Magnus expansion. These approaches provide solutions to the time-dependent Schrodinger equation which is a central problem in quantum physics in general and solid-state nuclear magnetic resonance in particular. Methods of these expansion schemes used as numerical integrators for solving the time dependent Schrodinger equation are presented. The action of their propagator operators is also presented. We highlight potential future theoretical and numerical directions such …

A Recipe For The Estimation Of Information Flow In A Dynamical System, Deniz Gencaga, Kevin H. Knuth, William B. Rossow

Publications and Research

Information-theoretic quantities, such as entropy and mutual information (MI), can be used to quantify the amount of information needed to describe a dataset or the information shared between two datasets. In the case of a dynamical system, the behavior of the relevant variables can be tightly coupled, such that information about one variable at a given instance in time may provide information about other variables at later instances in time. This is often viewed as a flow of information, and tracking such a flow can reveal relationships among the system variables. Since the MI is a symmetric quantity; an asymmetric …

Variation In Rheumatoid Hand And Wrist Surgery Among Medicare Beneficiaries: A Population-Based Cohort Study, Lin Zhong, Kevin C. Chung, Onur Baser, David A. Fox, Huseyin Yuce, Jennifer F. Waljee

Publications and Research

Objective. To examine the rate and variation in rheumatoid arthritis (RA)-related hand and wrist surgery among Medicare (elderly) beneficiaries in the United States, and to identify the patient and provider factors that influence surgical rates.

Methods. Using the 2006–2010 100% Medicare claims data of beneficiaries with RA diagnosis, we examined rates of rheumatoid hand and wrist arthroplasty, arthrodesis, and hand tendon reconstruction in the United States. We used multivariate logistic regression models to examine variation in receipt of surgery by patient and regional characteristics (density of providers, intensity of use of biologic disease-modifying antirheumatic drugs).

Results. Between 2006 and 2010, …

Stereoselective Radical C–H Alkylation With Acceptor/Acceptor-Substituted Diazo Reagents Via Co(Ii)-Based Metalloradical Catalysis, Xin Cui, Xue Xu, Li-Men Jin, Lukasz Wojtas, X. Peter Zhang

Publications and Research

Co(II)-based metalloradical catalysis has, for the first time, been successfully applied for asymmetric intramolecular C–H alkylation of acceptor/acceptor-substituted diazo reagents. Through the design and synthesis of a new D₂-symmetric chiral amidoporphyrin as the supporting ligand, the Co(II)-based metalloradical system, which operates at room temperature, is capable of 1,5-C–H alkylation of α-methoxycarbonyl-α-diazosulfones with a broad range of electronic properties, providing the 5-membered sulfolane derivatives in high yields with excellent diastereoselectivities and enantioselectivities. In addition to complete chemoselectivity toward allylic and allenic C–H bonds, the Co(II)-based metalloradical catalysis for asymmetric C–H alkylation features a remarkable degree of functional group tolerance.

Configurationally Stable, Enantioenriched Organometallic Nucleophiles In Stereospecific Pd-Catalyzed Cross-Coupling Reactions: An Alternative Approach To Asymmetric Synthesis, Chao-Yuan Wang, Joseph Derosa, Mark R. Biscoe

Publications and Research

Several research groups have recently developed methods to employ configurationally stable, enantioenriched organometallic nucleophiles in stereospecific Pd-catalyzed cross-coupling reactions. By establishing the absolute configuration of a chiral alkyltin or alkylboron nucleophile prior to its use in cross-coupling reactions, new stereogenic centers may be rapidly and reliably generated with preservation of the known initial stereochemistry. While this area of research is still in its infancy, such stereospecific cross-coupling reactions may emerge as simple, general methods to access diverse, optically active products from common enantioenriched organometallic building blocks. This minireview highlights recent progress towards the development of general, stereospecific Pd-catalyzed crosscoupling reactions …

Toxins In Newtown Creek, Burl Yearwood, Cho Cho Aung, Ridima Pradhan, Jennifer Vance

Publications and Research

Newtown Creek is a 3.5 mile river which empties into the East River in New York, United States. The river runs the boundary between the Queens and Brooklyn Burroughs. A thriving sight of industry, this river has been the location of much pollution for over a century. Battered by oil spills and oil seepage, raw sewage, trash carried by rain water, cement, animal fat, and a 15 meter sludge on the bottom of the riverbed, Newtown Creek is one of the most polluted waterways in the United States. In this article, data for nitrate, phosphate, lead, copper, dissolved iron, and …

Early Detection And Monitoring Of Malaria, Md Zahidur Rahman, Leonid Roytman, Abdelhamid Kadik, Howard Miller, Dilara A. Rosy

Publications and Research

Global Earth Observation Systems of Systems (GEOSS) are bringing vital societal benefits to people around the globe. In this research article, we engage undergraduate students in the exciting area of space exploration to improve the health of millions of people globally. The goal of the proposed research is to place students in a learning environment where they will develop their problem solving skills in the context of a world crisis (e.g., malaria). Malaria remains one of the greatest threats to public health, particularly in developing countries. The World Health Organization has estimated that over one million die of Malaria each …

Numeracy Infusion Course For Higher Education (Niche), 1: Teaching Faculty How To Improve Students' Quantitative Reasoning Skills Through Cognitive Illusions, Frank Wang, Esther I. Wilder

Publications and Research

We describe one of the eight units of a professional development program, the Numeracy Infusion Course for Higher Education (NICHE), which introduces research on cognition, including dual-processing theories, to university faculty. Under the dual-processing framework, System 1 (intuition) quickly proposes intuitive answers to judgment problems as they arise, while System 2 (deliberation) monitors the quality of these proposals, which it may endorse, correct, or override. We present several classic questions that demonstrate the pitfalls of overreliance on intuition without analytical thinking, then describe faculty participants’ responses to these questions and their ideas on how to apply cognitive illusion research to …

Liquidity Premiums In A Levy Market, Mei Xing

Publications and Research

This paper gives a theorem for the continuous time super-replication cost of European options where the stock price follows an exponential Levy process. Under a mild assumption on the legend transform of the trading cost function, the limit of the sequence of the discrete super-replication cost is proved to be greater than or equal to an optimal control problem. The main tool is an approximation multinomial scheme based on a discrete grid on a finite time interval [0,1] for a pure jump Levy model. This multinomial model is constructed similar to that proposed by (Szimayer & Maller, Stoch. Proce. & …

Tipping Point Of A Conifer-Based Ecosystem Under Severe Drought, Kaicheng Huang, Chuixiang Yi, Donghai Wu, Tao Zhou, Xiang Zhao, William J. Blanford, Suhua Wei, Hao Wu, Du Ling, Zheng Li

Publications and Research

Drought-induced tree mortality has recently received considerable attention. Questions have arisen over the necessary intensity and duration thresholds of droughts that are sufficient to trigger rapid forest declines. The values of such tipping points leading to forest declines due to drought are presently unknown. In this study, we have evaluated the potential relationship between the level of tree growth and concurrent drought conditions with data of the tree growth-related ring width index (RWI) of the two dominant conifer species (Pinus edulis and Pinus ponderosa) in the Southwestern United States (SWUS) and the meteorological drought-related standardized precipitation evapotranspiration index …

Heterometallic Titanium–Gold Complexes Inhibit Renal Cancer Cells In Vitro And In Vivo, Jacob Fernandez-Gallardo, Benelita T. Elie, Tanmoy Sadhukha, Swayam Prabha, Mercedes Sanau, Susan A. Rotenberg, Joe W. Ramos, Maria Contel

Publications and Research

Following recent work on heterometallic titanocene–gold complexes as potential chemotherapeutics for renal cancer, we report here on the synthesis, characterization and stability studies of new titanocene complexes containing a methyl group and a carboxylate ligand (mba ¼ S–C6H4–COO) bound to gold(I)-phosphane fragments through a thiolate group [(h-C5H5)2TiMe(m-mba)Au(PR3)]. The compounds are more stable in physiological media than those previously reported and are highly cytotoxic against human cancer renal cell lines. We describe here preliminary mechanistic data involving studies on the interaction of selected compounds with plasmid (pBR322) DNA used as a model nucleic acid, and with selected protein kinases from a …

Hydrodynamics With Gauge Anomaly: Variational Principle And Hamiltonian Formulation, V. Parameswaran Nair, Gustavo Monteiro, Alexander G. Abanov

Publications and Research

We present a variational principle for relativistic hydrodynamics with gauge-anomaly terms for a fluid coupled to an Abelian background gauge field. For this we utilize the Clebsch parametrization of the velocity field. We also set up the Hamiltonian formulation and the canonical framework for the theory. While the equations of motion only involve the density and velocity fields, i.e., the Clebsch potentials only appear in the combination which is the velocity field, the generators of symmetry transformations (including the Hamiltonian) depend explicitly on one of the Clebsch potentials, if the background field is time-dependent. For the special case of time-independent …

Global Trends In Extreme Precipitation: Climate Models Versus Observations, Behzad Asadieh, Nir Y. Krakauer

Publications and Research

Precipitation events are expected to become substantially more intense under global warming, but few global comparisons of observations and climate model simulations are available to constrain predictions of future changes in precipitation extremes. We present a systematic global-scale comparison of changes in historical (1901–2010) annual-maximum daily precipitation between station observations (compiled in HadEX2) and the suite of global climate models contributing to the fifth phase of the Coupled Model Intercomparison Project (CMIP5). We use both parametric and non-parametric methods to quantify the strength of trends in extreme precipitation in observations and models, taking care to sample them spatially and temporally …

Wetchimp-Wsl: Intercomparison Of Wetland Methane Emissions Models Over West Siberia, T. J. Bohn, J. R. Melton, A. Ito, T. Kleinen, R. Spahni, B. D. Stocker, B. Zhang, X. Zhu, R. Schroeder, M. V. Glagolev, S. Maksyutov, V. Brovkin, G. Chen, S. N. Denisov, A. V. Eliseev, A. Gallego-Sala, K. C. Mcdonald, M. A. Rawlins, W. J. Riley, Z. M. Subin, H. Tian, Q. Zhuang, J. O. Kaplan

Publications and Research

Wetlands are the world’s largest natural source of methane, a powerful greenhouse gas. The strong sensitivity of methane emissions to environmental factors such as soil temperature and moisture has led to concerns about potential positive feedbacks to climate change. This risk is particularly relevant at high latitudes, which have experienced pronounced warming and where thawing permafrost could potentially liberate large amounts of labile carbon over the next 100 years. However, global models disagree as to the magnitude and spatial distribution of emissions, due to uncertainties in wetland area and emissions per unit area and a scarcity of in situ observations. …

The Effect Of Milling Additives On Powder Properties And Sintered Body Microstructure Of Nio, L. Jay Deiner, Michael A. Rottmayer, Bryan C. Eigenbrodt

Publications and Research

The evolution of powder particle size, crystal structure, and surface chemistry was evaluated for micron scale NiO powders subjected to impact milling with commonly employed milling additives: methanol, Vertrel XF, and amorphous carbon. The effect of the different comminution protocols on sintered body microstructure was evaluated for high temperature sintering in inert atmosphere (N2). X-ray photoelectron spectroscopy showed that NiO powder surface chemistry is surprisingly sensitive to milling additive choice. In particular, the proportion of powder surface defect sites varied with additive, and methanol left an alcohol or alkoxy residue even after drying. Upon sintering to intermediate temperatures (1100 ℃), …

Examination Of Geophysical Signatures Of Ethanol-Water Mixtures In A Homogeneous Sand Column Using Ground Penetrating Radar And Time-Domain Reflectometry, Angelo Lampousis, Neil Terry, Lee Slater

Publications and Research

In recent years there has been an increase in the frequency of incidents involving ethanol-blended gasoline affecting the groundwater. Near-surface geophysical methods hold promise for site characterization at ethanol contaminated sites. We attempted to record the broadband dielectric properties of ethanol at various concentrations as it was circulating through a closed tank containing either sand or a sand-clay mixture. Two high frequency GPR antennas were positioned symmetrically on either side of the sample holder to obtain transmission measurements. In the first part of the experiment we used a sample consisting of sand. In the second part of the experiment we …

Matrix Multiplication, Trilinear Decompositions, Apa Algorithms, And Summation, Victor Pan

Publications and Research

Matrix multiplication (hereafter we use the acronym MM) is among the most fundamental operations of modern computations. The efficiency of its performance depends on various factors, in particular vectorization, data movement and arithmetic complexity of the computations, but here we focus just on the study of the arithmetic cost and the impact of this study on other areas of modern computing. In the early 1970s it was expected that the straightforward cubic time algorithm for MM will soon be accelerated to enable MM in nearly quadratic arithmetic time, with some far fetched implications. While pursuing this goal the mainstream research …

Differentiability Of Correlations In Realistic Quantum Mechanics, Alejandro Cabrera, Edson De Faria, Enrique Pujals, Charles Tresser

Publications and Research

We prove a version of Bell’s theorem in which the locality assumption is weakened. We start by assuming theoretical quantum mechanics and weak forms of relativistic causality and of realism (essentially the fact that observable values are well defined independently of whether or not they are measured). Under these hypotheses, we show that only one of the correlation functions that can be formulated in the framework of the usual Bell theorem is unknown. We prove that this unknown function must be differentiable at certain angular configuration points that include the origin. We also prove that, if this correlation is assumed …

Automated Computation Of Scattering Amplitudes From Integrand Reduction To Monte Carlo Tools, Hans Van Deurzen, Gionata Luisoni, Pierpaolo Mastrolia, Giovanni Ossola, Zhibai Zhang

Publications and Research

After a general introduction about the calculation of one-loop scattering amplitudes via integrand-level techniques, which led to the construction of efficient and automated computational tools for NLO predictions, we briefly describe an approach to the reduction of scattering amplitudes based on integrand-level reduction via multivariate polynomial division also applicable beyond one-loop amplitudes. We also review the main features of the GoSam 2.0 automated framework for NLO calculations and show some of its application to Standard Model processes involving the production massive particles, such as the Higgs boson or top-quark pairs, obtained embedding of the virtual amplitudes produced by GoSam within …

A Principle Of Economy Predicts The Functional Architecture Of Grid Cells, Xue-Xin Wei, Jason Prentice, Vijay Balasubramanian

Publications and Research

Grid cells in the brain respond when an animal occupies a periodic lattice of ‘grid fields’ during navigation. Grids are organized in modules with different periodicity. We propose that the grid system implements a hierarchical code for space that economizes the number of neurons required to encode location with a given resolution across a range equal to the largest period. This theory predicts that (i) grid fields should lie on a triangular lattice, (ii) grid scales should follow a geometric progression, (iii) the ratio between adjacent grid scales should be √e for idealized neurons, and lie between 1.4 and 1.7 …

Framing The Question, "Who Governs The Internet?", Robert J. Domanski

Publications and Research

There remains a widespread perception among both the public and elements of academia that the Internet is “ungovernable”. However, this idea, as well as the notion that the Internet has become some type of cyber-libertarian utopia, is wholly inaccurate. Governments may certainly encounter tremendous difficulty in attempting to regulate the Internet, but numerous types of authority have nevertheless become pervasive. So who, then, governs the Internet? This book will contend that the Internet is, in fact, being governed, that it is being governed by specific and identifiable networks of policy actors, and that an argument can be made as to …

Proceedings Of The 2nd Annual Cuny Games Festival, Robert O. Duncan, Joe Bisz, Francesco Crocco, Carlos Hernandez, Kathleen Offenholley, Maura A. Smale, Deborah Sturm, Cuny Games Network

Publications and Research

Proceedings of the CUNY Games Conference, held from January 16-17, 2015, at the CUNY Graduate Center and Borough of Manhattan Community College.

Health Games - Language and Composition - Design: Classroom Considerations - Games in the Physical Environment - Games and Behavioral Science - Play, Politics & Economics - Gaming Curricula, Disciplines & Programs - Gaming and History - Institutional Programming with Games - Philosophy and Roleplaying - Ed. Game Design: Strategy & Tactics - Repurposing Game Genres - Narrative, Storytelling & Games - Community & Social Justice - Extemporaneity - Personal & Social Transformation - Cognition, Design & Play …