Physical Sciences and Mathematics Commons^™

Gravimetrically Characterizable Common Alkali Reducing Agents And Ligand Design Of A New Electron Rich Guanidinate, Efrain Maximiliano Castillo

Open Access Theses & Dissertations

SynThesis, isolation and characterization of 12 new alkali arenides was performed by the addition of the chelating base 18-crown-6. Electrochemistry, UV-vis/NIR spectroscopy and XRD studies were performed.

The incoorporation of an imidazolin-2-iminato group to the background of a guanidinate showed that this kind of ligand is electronically flexible and metal dependent. It was found that is more electron donating than some previously reported guanidinates and ketimine guanidinates.

Minimizing Environmental Impacts For Hub And Spoke Distribution Network Problems Through The Use Of Multi-Objective Evolutionary Algorithms, Ileana Delgado

Open Access Theses & Dissertations

While transportation is crucial to our economy and our personal lives, as a sector it is also a significant source of greenhouse gas (GHG) emissions. The AASHTO report states, "America's transportation system has served us well, but now faces the challenges of congestion, energy supply, environmental impacts, climate change, and threatens the economic, social, and environmental future of the nation". With respect to the environment, transportation is the most visible aspect of supply chains. Transportation emissions can be reduced by implementing approaches that contribute to GHG emissions reduction, for example, the use of low-carbon fuels, new and improved vehicle technologies, …

Sample Size Estimation For Genomics Experiments With Dependent End Points, Desmond Koomson

Open Access Theses & Dissertations

In typical genomics studies involving numerous association tests of gene mutations with a disease, error rate control via multiplicity adjustment is paramount because even if all genes were to be non-differentially associated, we would still make some false positives. Many methods exist that incorporate the control of multiplicity for normally distributed endpoints in sample size estimation, but none addresses the issue for non-normally correlated endpoints.

One common practice in the literature is to assume an equal correlation among all differentially associated or expressed genes, thereby using the generalized binomial or beta-binomial model to compute the comparison-wise power of detecting these …

Structural And Stratigraphic Development Of A Salt Diapir Shoulder, Gypsum Valley, Colorado, Joshua Coleman Mcfarland

Open Access Theses & Dissertations

A salt shoulder is a low-angle segment of the salt-sediment interface where the margin of a passive diapir steps abruptly inboard. The Late Triassic Chinle Formation overlies caprock on the northeastern margin of Gypsum Valley (GV) at the salt-sediment interface in the natural amphitheater of Bridge Canyon. Modern erosion of the Dolores River has created 3D outcrop of the salt shoulder, expressed by a 500 meter wide, sub-horizontal platform that dips abruptly into the subsurface to the northeast toward the Dry Creek minibasin. Within Bridge Canyon, seven facies associations have been recognized and interpreted within the Chinle Formation: 1) non-caprock …

An Evaluation Framework For Scientific Programming Productivity, W.K. Umayanganie Munipala Munipala

Open Access Theses & Dissertations

Substantial time is spent on building, optimizing and maintaining large-scale software that is run on supercomputers. However, little has been done to utilize overall resources efficiently when it comes to including expensive human resources. The community is beginning to acknowledge that optimizing the hardware performance such as speed and memory bottlenecks contributes less to the overall productivity than does the development lifecycle of high-performance scientific applications. Researchers are beginning to look at overall scientific workflows for high performance computing. Scientific programming productivity is measured by time and effort required to develop, configure, and maintain a simulation experiment and its constituent …

An Integrated Geophysical Survey Of Kilbourne Hole, Southern New Mexico: Implications For Near Surface Exploration Of Mars And The Moon, Nisa Maksim

Open Access Theses & Dissertations

Features such as the Home Plate plateau on Mars, a suspected remnant of an ancient phreatomagmatic eruption, can reveal important information about paleohydrologic conditions. The eruption intensity of a phreatomagmatic volcano is controlled mainly by the quantity of water and magma, the internal geometry of the volcano, and the depth of the interaction zone between magma and water. In order to understand the paleohydrologic conditions at the time of eruption, we must understand all the factors that influenced the phreatomagmatic event. I conducted an integrated geophysical survey, which are magnetic and gravity surveys, and a ground-penetrating radar (GPR) surveys at …

Combining Interval And Probabilistic Uncertainty In Engineering Applications, Andrew Martin Pownuk

Open Access Theses & Dissertations

In many practical application, we process measurement results and expert estimates. Measurements and expert estimates are never absolutely accurate, their result are slightly different from the actual (unknown) values of the corresponding quantities. It is therefore desirable to analyze how this measurement and estimation inaccuracy affects the results of data processing. There exist numerous methods for estimating the accuracy of the results of data processing under different models of measurement and estimation inaccuracies: probabilistic, interval, and fuzzy. To be useful in engineering applications, these methods should provide accurate estimate for the resulting uncertainty, should not take too much computation time, …

National Evaluation For Development And Exploration Potential Of Mineral Commodities In Produced Waters, Stephanie Ray

Open Access Theses & Dissertations

The U.S. Geological Survey recently updated a geochemical database consisting of data for approximately 160,000 produced waters samples, primarily from petroleum and geothermal reservoirs. Using major and trace elements from conventional and unconventional well types from the database, this Thesis provides a comprehensive, national evaluation for mineral commodity potential in produced waters. Produced waters contain virtually every naturally occurring element and can range in salinity to several times that of seawater. Despite the typical outlook to view produced waters as a waste, they have potential for natural resource development.

This Thesis provides, for each mineral commodity found in the produced …

Modeling Of Piezoelectric Traveling Wave Rotary Ultrasonic Motors With The Finite Volume Method, Ivan Arturo Renteria Marquez

Open Access Theses & Dissertations

In 1983 Toshiiku Sashida developed a new motor concept called Piezoelectric Traveling Wave Rotary Ultrasonic Motor (PTRUSM). The advantages of these motors include high torque at low speed, absence of a generated magnetic field, and high potential for miniaturization. Unfortunately PTRUSMs have some disadvantages that limit the areas of applications for these types of motors. The disadvantages are a short operating life (about 1000 hours), small output power, and the need of a complex motor controller.

On one hand, these motors have been used in satellites, mobile phones, photocopiers, robotic arms, telescopes, automobiles, and camera autofocusing. On the other hand, …

Improving The Engineering Properties Of Pla For 3d Printing And Beyond, Carmen R. Rocha

Open Access Theses & Dissertations

Additive manufacturing (AM), now more commonly known as 3D printing, has been classified as efficient, fast, and practical in the prototyping sector of product development. In the work presented here, we will use one of the AM techniques known as Material extrusion 3D printing (ME3DP), which has all the advantages of AM. However, one of the biggest challenges facing ME3DP technologies is the limitation of the range of materials used by this technique. Acrylonitrile butadiene styrene (ABS) and poly-lactic acid (PLA) are currently the most common thermoplastics materials used in ME3DP because of their ability to melt and be reprocessed. …

Development Of Efficient Simultaneous Confidence Bounds For Linear Mixed Models With Applications In Alcohol Research, Emmanuel Joseph Sequeira

Open Access Theses & Dissertations

Multiplicity corrections are necessary to ensure the accuracy of conclusions made in studies that carry out multiple inferences simultaneously. This Thesis uses the methodology derived by Hunter and Worsley to obtain improved simultaneous confidence bounds (SCBs) that are less conservative than the highly used Bonferroni SCBs, for studies using linear mixed modeling. Empirical coverage rates were obtained for data that was generated using simulations, to compare the accuracy of the Hunter-Worsley SCBs with that of the Bonferroni SCBs. The bounds were also applied to data in the field of alcohol research, where comparisons were made to determine the moderating effect …

Investigation Of Lunar Subsurface Cavities Using Thermal Inertia And Temperature Maximum To Minimum Ratios, Rachel Ann Slank

Open Access Theses & Dissertations

Previous studies have revealed a small number of subsurface cavities, including lava tubes, as well as skylights, lava flow pits, and impact melt pits on the Moon. The interiors of subsurface cavities would have been protected from micrometeorite bombardment, solar radiation, space weathering, and extreme diurnal temperature swings over long periods of geologic time. As a result, subsurface cavities can provide access to pristine crustal samples and stratigraphy. These cavities may also harbor important volatiles, such as water ice, that would enable future exploration missions by relieving many operational constraints, including the supply of propellants and life support. In addition, …

3-D Structure Of Colombia From 1-D Constrained Joint Inversion Of Receiver Functions And Surface Wave Dispersion, Nick Talavera

Open Access Theses & Dissertations

The country, Colombia, resides at the northwest corner of the South America with seismicity and volcanism due to the intersections of the Nazca, South America and Caribbean tectonic plates (Figure 1). The boundaries of the South America plate, on which Colombia lies, borders between 60 to 200 kilometers from its coasts. A dense spot of seismicity known as the Bucaramanga Nest has had many theories to explain its existence. Two tectonic microplates suspected in this region have not been well understood. With many mysteries of the behavior of the tectonic plates beneath Colombia, using new methods may shed light on …

Ontology-Driven Integration Of Data For Freight Performance Measures, Eduardo J. Torres

Open Access Theses & Dissertations

Transportation performance measures are defined as quantitative and qualitative indicators that rely on data or information to explain mobility, congestion, safety, environmental and other factors. Though performance measures have been used for freeways and other highways, not many have been specified and applied to the freight transportation system. Recently, freight performance measures have been recommended by Federal Highway Administration to quantify the operating efficiency of the freight transportation system on existing infrastructures. This research seeks to expand this concept and to develop a comprehensive freight performance measurement framework. The expanded framework recommended in this Thesis consists of four criteria: safety, …

Computational Modeling Of A 60kw Oxy-Methane Direct Power Extraction Combustor, Omar Daniel Vidana

Open Access Theses & Dissertations

ANSYS Fluent was used to optimize components of a direct power extraction combustor. This includes the fuel injector, nozzle, and cooling units. Changes in the injector's inlet location impacted pressure and velocity distribution. An angle of 115 degrees with respect to the x-axis was found to increase distribution efficiency. Temperature and velocity data from the combustor and nozzle were calculated using NASA CEA and Fluent. Magnitudes of temperature and velocity for CEA and Fluent matched within 9% and 4%, respectively. For the cooling system it is expected that cavitation will not occur since the saturation temperature of water is not …

Secondary Mathematics Teachers' Disposition Toward Challenge And Its Impact On Teaching Practice, Yirah Mariana Valverde

Open Access Theses & Dissertations

This two phase, sequential exploratory study focused on mathematics teachers' disposition toward challenge and its impact in their teaching practice and students' performance. This heavily qualitative study employed a mixed methodology to answer the following guiding research question: how do teachersâ?? disposition towards challenge affect teaching practice and what is the nature of that relationship?

During the initial phase (quantitative), two teachers who were enrolled in a graduate mathematics at a University in the southwestern U.S. were selected for the study (N=5). The goal of the class was to increase the participants' mathematical knowledge for teaching. The purposive selection was …

Using The Wrf Model To Simulate The Playa Breeze Over Dugway Proving Ground, Daniela Maria Spade

Open Access Theses & Dissertations

The aim of this model and observation based study is to investigate the Advanced Research Weather Research and Forecasting Model's (WRF-ARW, although WRF from hereout) ability to simulate the three-dimensional structure of playa breezes and drainage flows occurring in Dugway Proving Ground, Utah using sub-km nesting in addition to improved land use and terrain datasets (as compared to the default datasets provided with WRF), in addition to studying the diurnal cycle and interactions between the playa breeze and drainage flows. A playa breeze is a thermally forced air circulation system that develops near the edge of playas, which have properties …

Three Essays On Global Ict Phenomenon: Productivity Paradox, Organizational Ict Use, And Privacy In Social Networks, Faruk Arslan

Open Access Theses & Dissertations

This Dissertation aims to investigate the global diversity in information systems by studying three distinctive phenomena. The first essay investigates the existence of "IT Productivity Paradox" within firms operating in developing countries using an empirical approach. IT Productivity Paradox has been a widely investigated topic within the context of developed countries and primarily studied within the context of developing countries using a single country. Our research addresses a gap in the literature, which is the study of IT Productivity Paradox across several developing countries with diverse characteristics. The second essay studies the contextual factors (firm characteristics and perception of external …

Dynamic Triggering In The Coso Geothermal Field, 2004-2013, Richard A. Alfaro-Diaz

Open Access Theses & Dissertations

We take advantage of EarthScope’s USArray Transportable Array (TA), regional seismic networks to investigate 154 M ≥ 7 earthquakes over a ten-year period (2004- 2013), in search of remotely triggered seismicity within the continental United States. We conduct an automated search to detect high frequency signals (which may indicate triggering of small local earthquakes) using a time window of 5 hours before and after each mainshock. The automated detection applies a short-term average (STA) to long-term-average (LTA) algorithms, to create a catalogue of detections. Using the catalog we search for an increase in detection rates after each main-shock. Sharp increases …

Evaluating Methods Of Field-Based 3d Visualization And Their Application To Mapping Metamorphic Terranes: An Example From The Panamint Mountains, California, Jade Ashley Brush

Open Access Theses & Dissertations

Field geology has traditionally relied on 2D, paper-based workflows, but digital mapping techniques are rapidly replacing these outdated methods because they allow for more efficient and accurate mapping. This research applies digital mapping techniques and two terrestrially-based 3D visualization technologies, photogrammetry and Light Detection and Ranging (LiDAR), to the study of metamorphic terranes in the Panamint Mountains, California. This study reports on the spatial accuracy of TINs (triangulated irregular networks) generated from both photogrammetry and ground-based LiDAR using a terrestrial laser scanner (TLS) and discusses how spatial accuracy can be increased. Two levels of comparison were used to test spatial …

Aerosol Physical And Chemical Properties Over Tropical Atlantic Ocean, Elsa Castillo

Open Access Theses & Dissertations

The atmospheric aerosol mass size distributions, modal characteristics, and a comparative analysis of the characteristic of PM2.5 versus trace gases: CO, O3, and SO2 over tropical Atlantic Ocean have been evaluated for Nov-Dec 2013. This study took place during the IX AEROSE expedition while the National Oceanic and Atmospheric Administration (NOAA) research vessel Ronald H. Brown traveled south along 23°W between 3°N and 5°S.

Aerosol mass size distributions were measured directly with a California Instruments Model PC-2H Quartz Crystal Microbalance (QCM). The corresponding values of average mass for accumulation, nuclei and coarse mode obtained were: 0.00124±0.00077, 0.00506±0.00254, and 0.00176±0.00114 μg/m …

Novel Endohedral Derivatives Of Sc3n@C2n (N = 34, 40) And Unique Tether Controlled Bis-Functionalization Of Fullerenes, Maira Raquel Ceron Hernandez

Open Access Theses & Dissertations

Since the discovery of fullerenes in 1985, their exohedral functionalization has been necessary to increase their solubility and explore their properties and potential applications in materials science and medicinal chemistry. This Thesis provides a short overview of the importance of electronic, size and shape complementarity in determining the structures of specific endohedral fullerene compounds. This is followed by a description of a new method for the separation of scandium nitride endohedral fullerenes Sc3N@C2n (n = 34, 39 and 40), and their monofunctionalization.

We also present the regioselective synThesis of easily isolable bis-derivatives of C60, C70, and M3N@Ih-C80 (M = Sc, …

Understanding The Contractional History Of Surprise Canyon, California Through Digital Field Mapping, 3d Modeling, And U-Pb Zircon Geochronology, Joshua A. Cobb

Open Access Theses & Dissertations

Detailed digital mapping of lower-middle Surprise Canyon has revealed a more complex structure than previously interpreted. Rock units derived from the metamorphosed equivalents of the Pahrump Group exposed in Surprise Canyon display juxtapositions inconsistent with stratigraphic variations suggested in previous studies. This study proposes a contractional history of the central Panamint Mountains defined by two kinematically distinct and geochronologically constrained deformation events. D1 is characterized by a shallow dipping, NNW striking L and LS tectonite fabric ubiquitously observed in all metasedimentary and basement units. F1 folds are mesoscopic in scale and isoclinal with an axial planar S1 foliation. A prominent …

A Pilot Study Of Arsenic In Young Children From Two Rural West Texas Communities: Blood Levels, Household Water Levels, And Behavioral Outcomes, Michelle Del Rio

Open Access Theses & Dissertations

Background & Significance: Heavy metals have been identified as a child health hazard because children are highly vulnerable to the effects of exposure, which can be physical, cognitive, and behavioral. Levels of arsenic (As) greater than the EPA Maximum Contaminant Level (10μg/L) were identified in some household water samples in two rural west Texas communities located within 20 miles of the U.S.-Mexico border by a Health Impact Assessment conducted in 2013 (Hargrove, Juarez-Carillo, & Korc 2015). Whether home water samples predicted child blood As levels needed to be examined. Since lead (Pb) is another common heavy metal contaminant in the …

Numerical Study Of The Supercritical Solution Of The Stationary Forced Korteweg-De Vries (Sfkdv) Equation, Sumi Dey

Open Access Theses & Dissertations

The time independent surface waves on a two dimensional incompressible and inviscid fluid flow passing over a bump on a flat bottom are considered. The stationary forced Korteweg-de Vries (fKdV) equation is defined in an unbounded interval. In this project, this unbounded interval is considered as three parts - on the bump, left hand side of the bump and right hand side of the bump. Exact boundary conditions are applied to the end points of the bump. All the possible combination of boundary conditions are used. A numerical approach is proposed to find the solitary wave solutions of fKdV equation …

Quantifying Weathering Rates On Tropical Volcanic Basse-Terre Island, French Guadeloupe: Insights From U-Series Isotopes In Weathering Rinds, Jacqueline Engel

Open Access Theses & Dissertations

Weathering of volcanic rocks plays many important roles at Earth’s surface such as modifying landscapes, providing nutrients to soil, and regulating atmospheric CO2. U-series isotopes (e.g. 238U-234U-230Th and 232Th) have been established as a chronometer used to constrain the formation rates of weathering rinds in tropical island environments. Here, U-series isotopes and major element concentrations were analyzed in two basaltic-andesite weathering rinds collected from the Deshaies watershed located in the northern, relatively dry (mean annual precipitation (MAP) = 1800 mm) region of tropical Basse-Terre Island, Guadeloupe. The two clasts are referred to as clasts AN-14-7.5 and AN-14-7.6. Elemental mobility trends …

Transition States And Modeling For Co9s8/Mos2 Catalysis, Gabriel Angel Gonzalez

Open Access Theses & Dissertations

Transition state computational studies of the sulfur removal from dibenzothiophene (DBT) molecule have herein been performed considering the Co9S8/MoS2 interface existing on unsupported Co/MoS2 catalysts. The linear synchronous transit (LST) and quadratic synchronous transit (QST) methods integrated in a density functional theory (DFT) program such as Dmol3 were used for the calculations of energy barriers of the transition states. Three different configurations present on the Co9S8/MoS2 interface have been envisaged as possible catalytic sites: sulfur-sulfur (S, S) sites, and molybdenum-sulfur (Mo, S) and molybdenum-molybdenum (Mo, Mo) edge sites. This study revealed that the (Mo, Mo) edge site is the most …

Total Synthesis Of Syringolides 1 And 2, Sudhakar Kalagara

Open Access Theses & Dissertations

The total synthesis of Syringolides is described. The synthetic pathway was designed in order to synthesize Syringolides in high yields using inexpensive starting materials. The synthesis strategy features a preparation of the linear tricarbonyl compound followed by intramolecular cyclization. The linear precursor is divided into two fragments, β-keto acid and protected D-xylulose, which are the key fragments and were synthesized from α,β-unsaturated compound followed by asymmetric dihydroxylation. The α,β-unsaturated compound was efficiently prepared by a Wittig reaction between aldehyde and ylide fragments. The butenolide derivative was also achieved by the Knoevenagel condensation of the tricarbonyl compound.

The Impacts Of Water Availability On Macroinvertebrate, Ector Matias Martell

Open Access Theses & Dissertations

In many regions around the world climate is changing and biotic communities are changing with it. In areas like the southwestern U.S., drought is one of the major sources of disturbance. Although droughts are an integral part of the natural hydrological cycles, they can have devastating effects on freshwater ecosystems when disrupted by extended periods of drought, resulting in changes to the structure and function of biotic communities. In this study, we surveyed four streams in the Sacramento Mountains of New Mexico from 2010 to 2014: Agua Chiquita, Rio Peñasco, Wills Creek, and the Sacramento River; These years encompassed an …

Synchronization Of Bistatic Radar Using Chaotic Amplitude And Frequency Modulated Signals, Chandra Sekhar Pappu

Open Access Theses & Dissertations

The purpose of this work is to develop a synchronization scheme for bistatic radar that uses a 3-D chaotic system to generate and process wideband AM and FM signals, which allows for the extraction of high range-resolution information from targets. For AM bistatic radar, the setup includes a drive oscillator at the transmitter and a response oscillator at the receiver. The challenge is synchronizing the response oscillator to the drive oscillator with a scaled version of the transmitted signal sr(t, x) = αs t(t, x), where x is a chaotic state variable and α is a scaling factor. Here, α …