Physical Sciences and Mathematics Commons^™

An Integrated Machine Learning Geological Field Tool In The Age Of Big Data And Drones, Guillermo Vargas

Open Access Theses & Dissertations

Unmanned aerial vehicles (UAVs) and machine learning are relatively new research tools in the geosciences that can be used to collect and analyze large data sets rapidly. We combine the power of rapid data collection using unmanned aerial vehicles with machine learning algorithms to develop a field-based system to identify targeted geological features. For data collection, we have used a commercial-grade UAV which carried visible-wavelength and multispectral (visible- infrared) cameras. We analyzed the data with machine learning and machine vision algorithms that can classify rock units exposed in a field area. We have identified algorithms that in previous literature have …

Electrocatalysts Based On Organic Macrocycles For Electrochemical Water Splitting, Yanyu Wu

Open Access Theses & Dissertations

Water splitting, which is the dissociation of water into hydrogen and oxygen gases, can be separated into two half reactions corresponding to the hydrogen evolution reaction and oxygen evolution reaction (HER and OER, respectively). Both reactions offer a promising way for storing energy into the form of chemical bonds, which is an important strategy for the development of clean-energy technologies. A main area of interest while studying HER and OER is to design effective and robust electrocatalysts made from earth-abundant materials. This dissertation describes several homogeneous and heterogeneous systems for the electrocatalytic generation of hydrogen and oxygen gases.

In Chapter …

Geostatistical And Geospatial Distribution Of Multiple Metallic Elements In Agricultural Regions Of The Mid-Continental Usa, Najwah Alssaeidi Ahmed Almesleh

Open Access Theses & Dissertations

Regional geochemical mapping constitute the chemistry of the surface of the earth in a large scale and relatively low sample density. It is widely accepted scientific activity and man uses some cases to identify contamination. In the present study, data present in national geochemical survey database was used to investigate the chemical loading loading of the agricultural soil. In the mid-continent region of the United States. Several traditional parameters were used mainly the enrichment factor (EF), and geoaccumulation index (I geo). Total chemical influence (TCI) maps were used to guide sampling. In addition, regional trace element chemistry of bedrock was …

Integrated Statistical And Machine Learning Algorithms For Predicting And Classifying G Protein-Coupled Receptors, Fredrick Ayivor

Open Access Theses & Dissertations

G protein-coupled receptors (GPCRs) are transmembrane proteins with important functions in signal transduction and often serve as drug targets. With increasing availability of protein sequence information, there is much interest in computationally predicting GPCRs and classifying them according to their biological roles. Such predictions are cost-efficient and can be valuable guides for designing wet lab experiments to help elucidate signaling pathways and expedite drug discovery. There are existing computational tools of GPCR prediction that involve principal component analysis (PCA), intimate sorting (IS), support vector machine, and random forest (RF) techniques using various sequence derived features. While accuracies of over 90\% …

Detection Of Pharmaceuticals And Personal Care Products In The Rio Grande And Their Effects On A Model Aquatic Invertebrate (Rotifera, Monogononta: Plationus Patulus), Enrique David Garcia

Open Access Theses & Dissertations

Rivers, including the Rio Grande, receive discharges from urban, agricultural, and industrial areas. These discharges have potentially harmful contaminants that may affect life span, fecundity, and/or behaviors of aquatic organisms. In this project, water quality was analyzed near a discharge point source and impacts of pharmaceuticals and personal care products (PPCPs) on a non-target organism (Plationus patulus) were investigated. Long-term and integrative organic samplers (POCIS) were left in situ for about 1 month near a wastewater treatment plant that discharges effluent into the Rio Grande. Over 40 PPCPs, including carbamazepine (ranging from 17.50 to 584.29 ng/L), erythromycin (ranging from 0.51 …

A Framework To Audit Scheduling Events In The Linux Operating System, Edward G. Hudgins

Open Access Theses & Dissertations

Soft real-time systems have responsiveness requirements that are desirable but not critical for operational effectiveness. This Thesis describes a new scheduler logging framework named "Integrated Process Scheduler Archiver" (IPSA) intended to assist with this analysis. Due to human sensitivity to interface delays on gesture-driven devices, mobile devices are a common case of soft-real time systems. Mobile systems generally do not incorporate real-time schedulers, but instead utilize over-provisioning and a variety of scheduling heuristics to generally provide acceptable responsiveness. These devices are highly multi-programmed Energy limitations on mobile limit the extent of overprovisioning, thereby increasing the sensitivity of system behavior to …

Comparison Of Mesoscopic Fracture Analysis Techniques: A Case Study Near Onion Creek Diapir, Paradox Basin, Utah, Muhammed Tarik Iraz

Open Access Theses & Dissertations

Faults and fractures are abundant along the diapir contact in the Onion Creek Diapir in eastern Utah and relate to the mechanisms of diapir formation. Western Onion Creek exhumes two spectacular exposures of the diapir contact and adjacent wall rocks providing two nearly orthogonal transects oriented ~E-W and S-N. In this study, I used field measurements from natural outcrops and a 3D model developed using Structure-from-Motion/Multiview Stereo photogrammetry to evaluate fracture reservoir development along diapir margins. The 3D-Model was developed using Agisoft Photoscan from ~3200 ground-based images and was georeferenced using 76 ground control points located with a GPS unit …

Onshore-Offshore Velocity Models North Of The Mendocino Triple Junction In Northern California, Alan Jacquez

Open Access Theses & Dissertations

The Mendocino Triple Junction (MTJ) marks the boundary where the Gorda plate, North American Plate, and Pacific Plate meet, separating the Cascadia subduction zone to the North from transform tectonics of the San Andreas plate boundary. This actively deforming region experiences high seismic activity and young geological features. Here we examine offshore and onshore seismic wide-angle reflection and refraction data north of the MTJ crossing the Cascadia subduction zone from offshore northern California to the Western edge of the Sierra Nevada. We image subsurface structures in this region by creating P-wave velocity models using datasets collected in 1993 to 1994 …

Environmental Injustice And Racial/Ethnic Heterogeneity In Houston, Texas, Michel G. Loustaunau Garcia

Open Access Theses & Dissertations

This Thesis seeks to contribute to distributive environmental justice (EJ) research by analyzing racial/ethnic and intra-ethnic disparities in potential health risks from exposure to hazardous air pollutants (HAPs) in Harris County, the most populous county in Texas. Previous EJ research in this urban area has not examined intra-ethnic heterogeneity in exposure to air pollutants or attempted to compare social disparities in exposure to air pollution caused by vehicular (mobile) and point (stationary) sources. The goal of this study is to determine how the EJ implications of cancer risks from inhalation exposure to HAPs from mobile and stationary sources differ across …

A Combined Field, Experimental And Modeling Approach To Understand The Impacts Of Flood Irrigation On Pedogenic Caco3 And Co2 Dynamics In Drylands, Anna Cristina Ortiz

Open Access Theses & Dissertations

Soil salinization is a global problem affecting 10% of agricultural soils, particularly in irrigated arid-lands. This study investigated salt loading through flood-irrigation, particularly of calcite (CaCO3) salt in the southwest of the United States. To evaluate the impact that flood-irrigation has on CaCO3 buildup and its effect on C-cycling, a natural soil and two agricultural soils were sampled: a pecan orchard and an alfalfa field in the El Paso, TX region. Agricultural soils in this study are flood irrigated by the Rio Grande river and by ground waters in its absence, both of which are oversaturated with calcite.

To trace …

Data-Driven Predictive Framework For Modeling Complex Multi-Physics Engineering Applications, Arturo Schiaffino Bustamante

Open Access Theses & Dissertations

Computational models are often encountered in multiple engineering application, such as structural design, material science, heat transfer and fluid dynamics. These simulations offer the engineers the capability of understanding complex physical situations before putting them to practice, either through experimentation or prototyping. The current advances in computational sciences, hardware architecture, software development and big data technology, have allowed the construction of sturdy predicting frameworks for analyzing a wide array of natural phenomena across different disciplines, either through the implementation of statistical methods, such as big data, and uncertainty quantification, or through high performance computing of a numerical model. The objective …

Integration Of Heterogeneous Traffic Data To Address Mobility Challenges In The City Of El Paso, Daniel Michael Mejia

Open Access Theses & Dissertations

Transportation performance measures are defined as quantitative and qualitative indicators that rely on data or information to explain mobility, traffic congestion, safety, environmental sustainability and other factors. Although performance measures have been used for freeways and other highways, not many have been specified and applied to the freight transportation system. Under the Fixing America's Surface Transportation Act (FAST Act), state transportation agencies and metropolitan planning organizations in the United States are implementing freight performance measurement systems for performance assessment. This research aims to expand the existing limited freight performance measures and organize them into a comprehensive framework that can be …

Optimization Of Neural Network Architecture For Classification Of Radar Jamming Fm Signals, Alberto Soto

Open Access Theses & Dissertations

Radar jamming signal classification is valuable when situational awareness of radar systems is sought out for timely deployment of electronic support measures. Our Thesis shows that artificial neural networks can be utilized for effective and efficient signal classification. The goal is to optimize an artificial Neural Network (NN) approach capable of distinguishing between two common radar waveforms, namely bandlimited white Gaussian jamming noise (BWGN) and the ubiquitous linearly frequency modulated (LFM) signal. This is made possible by creating a theoretical framework for NN architecture testing that leads to a high probability of detection (PD) and a low probability of false …

Bimetallic Centers With Open Coordination Sites And Magnetic Nanocomposites For Water Remediation, Karen Ventura

Open Access Theses & Dissertations

The development of effective, renewable and environmentally friendly energy sources is essential to supply the growing global energy demands. The use of fossil fuels to fulfill those energy demands have led to the increase of greenhouse gases and water contamination. The extraction of oil and gas requires a large amount of pressurized water, resulting in contaminated water as a byproduct. Meanwhile, ensuring access to clean water is one of the greatest global challenges of this century.

The following study is presented in three sections. In the first section, a bimetallic system with open coordination sites that can be used as …

Constraining Times Of Extension In The Southern Rio Grande Rift And Basin And Range Using Apatite And Zircon (U-Th)/He Thermochronology, Julian Biddle

Open Access Theses & Dissertations

The Rio Grande rift and the Basin and Range are adjacent extensional domains that have evolved contemporaneously in western North America. Although the rift is often considered to be the easternmost boundary of Basin and Range extension, there is geologic and geophysical evidence that suggests the two are discrete provinces. Existing low-temperature thermochronologic data indicate that a period of synchronous extension occurred across the entire length of the rift from ~25-10 Ma. However, these studies were more focused on the northern and central sections of the rift, and thermochronologic data remains sparse in southern New Mexico. We collected rock samples …

A Study Of Hippocampal Microglia Distribution In Pre-Adolescent Mice Chronically Exposed To Lead, Salvador Dominguez

Open Access Theses & Dissertations

Background: Lead is a major unresolved child health hazard. Children are uniquely vulnerable to the effects of lead exposure, which include disruption of brain development and brain function. How lead exposure alters brain development and brain function is not currently known. Our laboratory has been developing a mouse model to understand effects of low-level lead exposure in the developing brain. In previous studies, we have shown that early chronic low level lead exposure diminished the number of microglia in the dentate gyrus region of the hippocampus, an area responsible for learning and memory. Building on the results of the previous …

Structural Modifications In The Rbxcs1-Xpo 4 (0 ≤ X ≤ 1) Superprotonic Conductor Series: A Single-Crystal X-Ray Diffraction And Impedance Spectroscopy Study, Andres Jose Encerrado Manriquez

Open Access Theses & Dissertations

We have used single-crystal X-ray diffraction measurements to investigate the structural modifications induced by Rb-doping of the protonic conductor CsH2PO4. Data collected on the RbxCs 1-xH2PO4 (0 ≤ x ≤ 1) series shows that the monoclinic P21/m CsH2PO4 presentation persists upon Rb-doping up until x = 0.8. Rb0.8Cs0.2H2PO 4 exhibits a previously unreported P21/c monoclinic structure, where the mirror plane is lost and disorder is present in the PO4 tetrahedra even at room temperature. Higher levels of x display a tetragonal I-42d unit cell isomorphic with the known structure of RbH2PO 4. The temperature dependence of the proton conductivity determined …

Spectroscopic And Microscopic Analysis Of Graphene For Sensor Applications, Tamanna Tasneem Khan

Open Access Theses & Dissertations

As a two-dimensional material, graphene shows very good thermal and electrical conductivities, which, with its unique optical properties, makes it suitable for a variety of applications. In this study, we present detailed investigations by confocal Raman and Drude model analysis of the material's changes and improvements, as it transitioned from 3D graphite to 2D graphene. Besides Raman spectral recording, which can detect single, a few, and multi-layers of graphene, confocal Raman mapping allows distinction of such domains and direct visualization of material inhomogeneity. Moreover, far-infrared transmittance measurements, which are related to electrical conductivity, demonstrate a distinct increase of conductivity with …

Sample Size Estimation For Linear Mixed Models With Dependent End Points, Michael Nsiah-Nimo

Open Access Theses & Dissertations

The primary objective is sample size estimation in linear mixed model settings. Sample size estimation is an important component of planning a well thought out scientific experiment. Whenever sample size estimation is performed, taking into account a priori model based inferences will provide a sample size estimate that will achieve the desired power without inflating the type I error rate of the study.

One common practice is a traditional approach cited in the literature that uses the largest sample size after you Bonferroni the type I error rate to estimate sample sizes as such. We are going to take into …

Evaluating Binary Splits On Nominal Inputs, Isaac Xoese Ocloo

Open Access Theses & Dissertations

The maximally selected statistic approach in building tree models is shown to be a cause of variable selection bias. In this study we propose three methods to solve this problem in building regression trees with nominal predictor variables. Out of the three methods

proposed we explored only two in detail and defer one for further research. We developed an exact method to compute the p-value corresponding to the maximized splitting statistic in regression trees for nominal predictor variables with at most 10 distinct levels and a

method to estimate the best cutoff point as a parameter in a parametric nonlinear …

Compressive Vector Reconstruction: Hypothesis For Blind Image Deconvolution, Alonso Orea Amador

Open Access Theses & Dissertations

Alternative imaging devices propose to acquire and compress images simultaneously. These devices are based on the compressive sensing (CS) theory. A reduction in the measurement required for reconstruction without a post-compression sub-system allows imaging devices to become simpler, smaller, and cheaper. In this research, we propose a new algorithm to compress and reconstruct blurred images for CS imaging devices. Blur effect in images is common due to relative motion, lens, limited aperture dimensions, lack of focus, and/or atmospheric turbulence. Our intention is to compress a blurred image with CS techniques and then reconstruct a blur-free version using the proposed algorithm. …

Cycling Of Gypsiferous White Sands Aerosols In The Shallow Critical Zone At White Mountain, New Mexico, Patrick Richard Rea

Open Access Theses & Dissertations

Dry deposition significantly affects evolution of the critical zone by nutrient supply and contributing to soil genesis. Dust influx and cycling in soils are difficult to quantify because dust sources can be chemically similar to local soils. White Sands, New Mexico, emits gypsum dust with a unique chemical and isotopic signature, providing an opportunity to investigate dust deposition and its movement in soils. This study evaluated the mobility of White Sands dust particles in the critical zone at White Mountain, New Mexico, a highland 100 km downwind. Four soil profiles were collected over limestone, igneous, mixed limestone and dolostone, and …

Household Water Consumption In El Paso, Texas: Perceptions And Behaviors Towards Water In Urban Households, Diego Armando Sanchez

Open Access Theses & Dissertations

The main objective of this research is to determine perceptions and behaviors of household water consumption and to examine how those may affect the patterns of water use and consumption levels in households of El Paso, Texas.

I conducted a qualitative exploratory research to collect important data that is often left unexplored in quantitative research. The collected data is a mixture of qualitative and quantitative. I do report the quantitative data using descriptive statistics, which help the reader see basic patterns in the study.

Qualitative data can help to understand the reasons that impact water consumption perceptions and behaviors in …

Renewable Energy Systems Optimization Using Monte Carlo Simulation And Evolutionary Algorithms, Nicolas Lopez

Open Access Theses & Dissertations

This Dissertation explores the Renewable Energy Integration Problem, and proposes a Genetic Algorithm embedded with a Monte Carlo simulation to solve large instances of the problem that are impractical to solve via full enumeration. The Renewable Energy Integration Problem is defined as finding the optimum set of components to supply the electric demand to a hybrid

microgrid. The components considered are solar panels, wind turbines, diesel generators, electric batteries, connections to the power grid and converters, which can be inverters and/or rectifiers. The methodology developed is explained as well as the combinatorial formulation. In addition, 2 case studies of a …

Genesis Of Unique Carbonate Fans In A Pre-Salt Reservoir Analogue, Indio Mountains, West Texas, Andre Llanos

Open Access Theses & Dissertations

Hydrocarbon exploration in pre-salt sediments of rift basins on the South Atlantic Margin have proven to be successful major oil plays. Located on the western margin of the rift, the Brazilian pre-salt reservoirs of the Santos, Campos, and Espirito Santo Basins are hosted by lacustrine/marine-influenced carbonates that comprise laterally extensive, laminated microbialite facies. The Indio Mountains, located in West Texas, provide well-exposed outcrops of Lower Cretaceous marine and non-marine rift basin strata that can be considered a reservoir-analog to the South Atlantic Margin pre-salt facies. Of particular interest for hydrocarbon exploration are unique carbonate features that have been discovered in …

Classification Of Radar Jammer Fm Signals Using A Neural Network Approach, Ariadna Estefania Mendoza

Open Access Theses & Dissertations

A Neural Network (NN) used to classify radar signals is proposed for the purpose of military survivability and lethality analysis. The goal of the NN is to correctly differentiate Frequency-Modulated (FM) signals from Additive White Gaussian Noise (AWGN) using limited signal pre-processing. The FM signals used to test the NN approach are the linear or chirp FM and the power-law FM. Preliminary simulations using the moments of the signals in the time and frequency domain yielded better results in the frequency domain, suggesting that time domain training would not be as effective frequency domain training. To test this hypoThesis, we …

A Quantitative Analysis Of The Fretted Terrain Valleys, Arabia Terra, Mars, Kelsey Anne Mason

Open Access Theses & Dissertations

Fretted terrain describes regions on Mars with low-lying, flat valleys separated by steep cliffs that often form polygonal-shaped mesas. The fretted terrain valleys have a morphology distinct from other valleys found on Mars, and their unknown origin may hold insights into critical questions about Mars' tectonic, magmatic, and hydrologic history. Current hypoThesis for the formation of the fretted terrain include fracturing as well as hydrological flow processes such as fluvial or glacial erosion. The region for this study is located in eastern Arabia Terra and is the type-location for fretted terrain. By qualitatively and quantitatively documenting the planform, or map-view, …

A New Method For Ultra-Low Sulfate Extraction And A Pilot Study In Arid Soils, Marisela Montelongo

Open Access Theses & Dissertations

Sulfur in soils is a crucial nutrient for all organisms including plants. Sulfate (SO42-), a water soluable anion, is a good source of this important element. Because of the importance of sulfur for agriculture, the use of sulfate has been well studied in temperate climate zones, and it is generally accepted that microbes play a critical role in controlling the availability of sulfate. Organically bound sulfur, such as sulfate esters and carbon-bonded sulfur, compounds that are generated and decomposed by microbes, are essential sulfur sources for plants under these conditions. For arid environments, knowledge of sulfate turnover in soils by …

Complementary Charged Molecular Imprints Of West Nile Virus Antibodies, Julio Rincon

Open Access Theses & Dissertations

There is a significant demand for robust and stable receptor molecules that can mimic biological molecules, such as antibodies. Relying only on natural recognition molecules have greatly limited the uses and capabilities of many aspects of health sciences due to product expense and stability. This is especially important in medically underserved areas where the lack of resources and faulty or limited cold-chain makes antibody based diagnostics very difficult to implement.

With molecular imprinting, it is possible to recognize diseases with the added advantage of product stability, long term use, fast preparation and ease of scalability, all while being cost effective. …

Using Underground Radon To Detect Inactive Geological Faults, Germán Rodríguez Ortiz

Open Access Theses & Dissertations

This Thesis presents the results of an investigation of the concentration of radon in soil around a fault in the East Franklin Mountains in the El Paso area in West Texas. The connection between underground radon exhalations near active faults has been known for decades, but possible similar increases of underground radon levels around inactive faults have not been studied as thoroughly. Arguing that the dilatancy-diffusion model used to explain the phenomenon near active faults does not apply to the case of inactive faults, a hypoThesis is formulated under which increased levels of underground radon must be present near inactive …