Physical Sciences and Mathematics Commons^™

Environmental Tradeoffs In Bioenergy Production And Agricultural Practices, Alicia Lynn English

Open Access Dissertations

The focus of this dissertation is the environmental tradeoffs of stover removal within the Corn Belt. The environmental tradeoffs considered are mainly concerned with managing soil erosion and soil quality. The analysis layers soil characteristics, management strategies and per acre costs using an integrated RUSLE2/WEPS model and an economic optimization model to illuminate a lower bound supply response. Different assumptions were tested in regards to sustainability, prices, and market integration for five states and 18,760 soil types throughout the Corn Belt. Sustainability was defined to limit soil erosion from wind and water to 5 tons/acre/year and the soil organic matter …

Nanoscale Semiconductor Materials And Devices Employing Hybrid 1d And 2d Structures For Tunable Electronic And Photonic Applications, Suprem Ranjan Das

Open Access Dissertations

Das, Suprem R. Ph.D., Purdue University, December 2013. Nanoscale Semiconductor Materials and Devices employing Hybrid 1D and 2D structures for Tunable Electronic and Photonic Applications. Major Professor: Dr. David B. Janes.

Continued miniaturization of microelectronic devices over past decades has brought the device feature size towards the physical limit. Likewise, enormous `waste energy' in the form of self-heating in almost all of the electronic and optoelectronic devices needs an `energy-efficient low power' and `high performance' material as well as device with alternate geometry. III-V semiconductors are proven to be one of the alternate systems of materials for various applications including …

Spectroscopic And Kinetic Study Of Copper-Exchanged Zeolites For The Selective Catalytic Reduction Of Nox With Ammonia, Shane Adam Bates

Open Access Dissertations

The recent application of metal-exchanged, small-pore zeolites for use in the selective catalytic reduction (SCR) of NO_x with ammonia NH₃ for automotive deNO_x applications has been a great stride in achieving emission standard goals. Copper-exchanged SSZ-13 (Cu-SSZ-13), the small-pore zeolite in this study, has been shown to be very hydrothermally stable and active under conditions presented in the exhaust of the lean-burn diesel engine. In this work, detailed studies were performed to identify many aspects of the active site(s) in Cu-SSZ-13 in order to learn about the standard SCR mechanism.

A series of seven Cu-SSZ-13 samples were …

Efficient Spectral-Element Methods For Acoustic Scattering And Related Problems, Ying He

Open Access Dissertations

This dissertation focuses on the development of high-order numerical methods for acoustic and electromagnetic scattering problems, and nonlinear fluid-structure interaction problems.

For the scattering problems, two cases are considered: 1) the scattering from a doubly layered periodic structure; and 2) the scattering from doubly layered, unbounded rough surface. For both cases, we first apply the transformed field expansion (TFE) method to reduce the two-dimensional Helmholtz equation with complex scattering surface into a successive sequence of the transmission problems with a plane interface. Then, we use Fourier-Spectral method in the periodic structure problem and Hermite-Spectral method in the unbounded rough surface …

Improving Reuse In Software Development For The Life Sciences, Nicholas Vincent Iannotti

Open Access Dissertations

The last several years have seen unprecedented advancements in the application of technology to the life sciences, particularly in the area of data generation. Novel scientific insights are now often driven primarily by software development supporting new multidisciplinary and increasingly multifaceted data analysis. However, despite the availability of tools such as best practice frameworks, the current rate of software development is not able to keep up with the needs of scientists. This bottleneck in software development is largely due to code reuse generally not being applied in practice.

This dissertation presents Legwork, a class library of reuse-optimized design pattern implementations …

Response Of Plasma Facing Components In Tokamaks Due To Intense Energy Deposition Using Particle-In-Cell(Pic) Methods, Filippo Genco

Open Access Dissertations

Damage to plasma-facing components (PFC) due to various plasma instabilities is still a major concern for the successful development of fusion energy and represents a significant research obstacle in the community. It is of great importance to fully understand the behavior and lifetime expectancy of PFC under both low energy cycles during normal events and highly energetic events as disruptions, Edge-Localized Modes (ELM), Vertical Displacement Events (VDE), and Run-away electron (RE). The consequences of these high energetic dumps with energy fluxes ranging from 10 MJ/m2 up to 200 MJ/m2 applied in very short periods (0.1 to 5 ms) can be …

Mispronunciation Detection For Language Learning And Speech Recognition Adaptation, Zhenhao Ge

Open Access Dissertations

The areas of "mispronunciation detection" (or "accent detection" more specifically) within the speech recognition community are receiving increased attention now. Two application areas, namely language learning and speech recognition adaptation, are largely driving this research interest and are the focal points of this work.

There are a number of Computer Aided Language Learning (CALL) systems with Computer Aided Pronunciation Training (CAPT) techniques that have been developed. In this thesis, a new HMM-based text-dependent mispronunciation system is introduced using text Adaptive Frequency Cepstral Coefficients (AFCCs). It is shown that this system outperforms the conventional HMM method based on Mel Frequency Cepstral …

Enabling Richer Insight Into Runtime Executions Of Systems, Karthik Swaminathan Nagaraj

Open Access Dissertations

Systems software of very large scales are being heavily used today in various important scenarios such as online retail, banking, content services, web search and social networks. As the scale of functionality and complexity grows in these software, managing the implementations becomes a considerable challenge for developers, designers and maintainers. Software needs to be constantly monitored and tuned for optimal efficiency and user satisfaction. With large scale, these systems incorporate significant degrees of asynchrony, parallelism and distributed executions, reducing the manageability of software including performance management. Adding to the complexity, developers are under pressure between developing new functionality for customers …

Elucidation Of Chiral Recognition Mechanisms Of Solutes By Amylose Tris[(S)-Alpha-Methylbenzylcarbamate] Sorbent, Hung-Wei Tsui

Open Access Dissertations

Enantioselective separations of chiral molecules are important in various chemical fields, such as pharmaceuticals and agrochemicals industries. Polysaccharide-based sorbents have been widely used in chiral liquid chromatography. The recognition mechanisms which determine their enantioselectivities are not completely understood.

In this dissertation, the chiral recognition mechanisms of a widely used commercial sorbent, amylose tris[(S)-alpha-methylbenzylcarbamate], for benzoin (B) enantiomers were first studied. The HPLC data for benzoin with pure n-hexane as the mobile phase have been obtained. The behavior of sorbent-solute-hexane systems can be interpreted by considering only sorbent solute two-component interactions. Infrared (IR) spectra showed evidence of substantial hydrogen bonding (H-bonding) …

Improved Kernel Security Through Code Validation, Diversification, And Minimization, Dannie Michael Stanley

Open Access Dissertations

The vast majority of hosts on the Internet, including mobile clients, are running one of three commodity, general-purpose operating system families. In such operating systems the kernel software executes at the highest processor privilege level. If an adversary is able to hijack the kernel software then by extension he has full control of the system. This control includes the ability to disable protection mechanisms and hide evidence of compromise.

The lack of diversity in commodity, general-purpose operating systems enables attackers to craft a single kernel exploit that has the potential to infect millions of hosts. If enough variants of the …

Scholarly Collaboration In Engineering Education: From Big-Data Scientometrics To User-Centered Software Design, Hanjun Xian

Open Access Dissertations

Engineering education research has grown into a flourishing community with an-ever increasing number of publications and scholars. However, recent studies show that a significant amount of engineering education knowledge retains a clear disciplinary orientation. If the gaps in scholarly collaboration continue to be prevalent within the entire community, it will become increasingly difficult to sustain community memory. This will eventually inhibit the propagation of innovations and slow the movement of research findings into practice.

This dissertation studies scholarly collaboration in the engineering education research community. It provides a clear characterization of collaboration problems and proposes potential solutions. The dissertation is …

Atomistic Simulation Of Plasma Interaction With Plasma Facing Components In Fusion Reactors, Xue Yang

Open Access Dissertations

The interaction between plasma and fusion relevant materials is one of the critical issues in successfully using those materials in Tokamak reactors. This research uses molecular dynamics, kinetic Monte Carlo and binary collision approximation methods to model fusion relevant material bombarded by energetic particles to investigate retention, deposition, sputtering, erosion, blistering effects, diffusion, and so on.

The deuterium bombardment of monocrystalline tungsten was modeled by LAMMPS code using Tersoff type interatomic potential. The deuterium trapping rate, implantation depth, and stopping time in 600-2000 K tungsten bombarded by 5-100 eV deuterium atoms were simulated. Irradiated monocrystalline tungsten became amorphous prior to …

Dependence-Based Source Level Tracing And Replay For Networked Embedded Systems, Man Wang

Open Access Dissertations

Error detection and diagnosis for networked embedded systems remain challenging and tedious due to issues such as a large number of computing entities, hardware resource constraints, and non-deterministic behaviors. The run-time checking is often necessitated by the fact that the static verification fails whenever there exist conditions unknown prior to execution. Complexities in hardware, software and even the operating environments can also defeat the static analysis and simulations. Record-and-replay has long been proposed for distributed systems error diagnosis. Under this method, assertions are inserted in the target program for run-time error detection. At run-time, the violation of any asserted property …

Preparation Of Mesoporous Silica Supported Ruthenium Oxides And The Application And Kinetic Study In The Catalysis Of Water Oxidation, Yang Zhang

Open Access Dissertations

Photo-induced water splitting of water into H2 and O2 has been a major focus in the development of clean and renewable energy. The development of viable and efficient catalysts that facilitates O2 production remains the major challenge in the study of the corresponding half-reaction of water oxidation. There are plenty of metal oxides reported active in the catalysis of water oxidation. However, several important performance bench marks of those materials, such as the non-stoichiometric production of O2, slow reaction rate and/or low quantum efficiency, remain to be improved.

Ruthenium oxide (RuO2) has long been known as one of the most …

Predictive Duty Cycling Of Radios And Cameras Using Augmented Sensing In Wireless Camera Networks, Joonhwa Shin

Open Access Dissertations

Energy efficiency dominates practically every aspect of the design of wireless camera networks (WCNs), and duty cycling of radios and cameras is an important tool for achieving high energy efficiencies. However, duty cycling in WCNs is made complex by the camera nodes having to anticipate the arrival of the objects in their field-of-view. What adds to this complexity is the fact that radio duty cycling and camera duty cycling are tightly coupled notions in WCNs.

Abstract In this dissertation, we present a predictive framework to provide camera nodes with an ability to anticipate the arrival of an object in the …

Automated Failure Explanation Through Execution Comparison, William Nicholas Sumner

Open Access Dissertations

When fixing a bug in software, developers must build an understanding or explanation of the bug and how the bug flows through a program. The effort that developers must put into building this explanation is costly and laborious. Thus, developers need tools that can assist them in explaining the behavior of bugs. Dynamic slicing is one technique that can effectively show how a bug propagates through an execution up to the point where a program fails. However, dynamic slices are large because they do not just explain the bug itself; they include extra information that explains any observed behavior that …

Utilizing Electron Microscopy And Spectroscopy Methods To Understand Water Structure And Water Doping, Lior Miller

Open Access Dissertations

Water is the second most common element in the universe and the most studied material on earth. Most of the studies concerning water are from the fields of chemistry and biology. Hence, the structure of water molecules and short range order and interactions are well characterized and understood. However, the collective arrangement of water molecules and the long range order are still missing. Understanding of this long range order in water is needed, as it is the key to many water activities.

To fill this gap, this study utilizes a new direct method for characterization of water in the vapor …

Control-Theoretic Decision Support For Mitigation Of Modeled Software Project Cost Overruns, Scott David Miller

Open Access Dissertations

Despite sixty years of practice, the production of software remains an endeavor that is difficult to manage according to a schedule. Control theory studies the ability to influence the dynamical behavior of systems to achieve desired behaviors or eliminate undesired behaviors. In this work, the management problem of software project schedule adherence is re-cast as a problem in control theory.

Below, a modeling framework is proposed for capturing the constraints and dependencies found in the arbitrary organization specific work-flows underlying software production. Combined with proposed models for productivity, defect introduction, and defect detection, the framework completes a method for producing …

Methods For Increasing Domains Of Convergence In Iterative Linear System Solvers, David Michael Imberti

Open Access Dissertations

In this thesis, we introduce and improve various methods for increasing the domains of convergence for iterative linear system solvers. We rely on the following three approaches: making the iteration adaptive, or nesting an inner iteration inside of a previously determined outer iteration; using deflation and projections to manipulate the spectra inherent to the iteration; and/or focusing on reordering schemes. We will analyze a specific combination of these three strategies. In particular, we propose to examine the influence of nesting a Flexible Generalized Minimum Residual algorithm together with an inner Recursive Projection Method using a banded preconditioner resulting from the …

Applicability Of Continuum Fracture Mechanics In Atomistic Systems, Shao-Huan Cheng

Open Access Dissertations

By quantitating the amplitude of the unbounded stress, the continuum fracture mechanics defines the stress intensity factor K to characterize the stress and displacement fields in the vicinity of the crack tip, thereby developing the relation between the stress singularity and surface energy (energy release rate G). This G-K relation, assigning physical meaning to the stress intensity factor, makes these two fracture parameters widely used in predicting the onset of crack propagation. However, due to the discrete nature of the atomistic structures without stress singularity, there might be discrepancy between the failure prediction and the reality of nanostructured materials. Defining …

Simulating Land Use Land Cover Change Using Data Mining And Machine Learning Algorithms, Amin Tayyebi

Open Access Dissertations

The objectives of this dissertation are to: (1) review the breadth and depth of land use land cover (LUCC) issues that are being addressed by the land change science community by discussing how an existing model, Purdue's Land Transformation Model (LTM), has been used to better understand these very important issues; (2) summarize the current state-of-the-art in LUCC modeling in an attempt to provide a context for the advances in LUCC modeling presented here; (3) use a variety of statistical, data mining and machine learning algorithms to model single LUCC transitions in diverse regions of the world (e.g. United States …

Information Measures For Statistical Orbit Determination, Alinda Kenyana Mashiku

Open Access Dissertations

The current Situational Space Awareness (SSA) is faced with a huge task of tracking the increasing number of space objects. The tracking of space objects requires frequent and accurate monitoring for orbit maintenance and collision avoidance using methods for statistical orbit determination. Statistical orbit determination enables us to obtain estimates of the state and the statistical information of its region of uncertainty given by the probability density function (PDF). As even collision events with very low probability are important, accurate prediction of collisions require the representation of the full PDF of the random orbit state. Through representing the full PDF …