Physical Sciences and Mathematics Commons^™

Nuclear Structure Studies In 90Y, Ronald E. Goans

Masters Theses

Differential cross sections (12.5° to 47.5°) were measured for the ⁸⁹Y (d,p) reaction with 33.3 Mev deuterons from the Oak Ridge Isochronous Cyclotron. Proton spectra up to 5 Mev excitation in the ⁹⁰Y were observed in nuclear emulsions exposed in the focal plane of the broad range spectrograph. The resolution was approximately 25 Kev. The excitation energies agreed within experimental error with (d,p) experiments at 12 Mev and 15 Mev. Comparisons were made with DWBA calculations and ℓ-transfers were assigned to 25 levels. The ℓ-transfers and spectroscopic factors are in satisfactory agreement with previous papers for most strong …

Transpiration Measurements Of The Decomposition Pressures Of Barium Hexafluorosilicate, Kemal Cankaya

Masters Theses

No abstract provided.

Simultaneous Knudsen- And Torsion- Effusion Measurements Of The Vapor Pressures Of Tetraphenyltin And Hexaphenylditin, Dale Keiser

Masters Theses

No abstract provided.

The Effect Of The Rate Of Formation On The Structure And Properties Of Paper, William M. Reif

Masters Theses

Paper contains an uneven distribution of fiber fractions through its cross section. The objective of this study was to determine how the rate of formation affected the structure and properties of paper. The structure of paper was analyzed with reference to the cross-sectional distribution of fines and the fines to long fibers ratio in the paper.

The formation rate and distribution of fins were varied by applying a vacuum to the British sheetmold system. As the fines were a different color than the long fibers, their distribution was determined by analyzing the brightness values of layers split from the paper. …

Preparation And Lead Tetraacetate Oxidation Of Aldehydic Hydrazones, Alan J. Quarfoot

Masters Theses

No abstract provided.

A Study Of Some Matrix Elements For The Four-Pion Decay Mode Of Neutral Bosons, George Victor Weller

Masters Theses

No abstract provided.

The Elastic Scattering Of 1.33 Mev Gamma Rays From Tin, J. Edward Terdal

Masters Theses

No abstract provided.

Inelastic Deuteron Scattering From 151Eu, Gerald Ralph Boss

Masters Theses

No abstract provided.

The Wittig Reaction Of Stabalized Phosphonium Ylids With Derivatives Of D-Ribose, George Robert Wellman

Masters Theses

No abstract provided.

The Mossbauer Effect In Ferric Stearate And Ferric Oleate, Ronald L. Wilson

Masters Theses

No abstract provided.

Angular Correlation Of Positron Annihilation Radiation In Damaged Nickel And Iron, Hsien Chen Huang

Masters Theses

No abstract provided.

Knudsen- And Torsion- Effusion Measurements Of The Vapor Pressure Of Manganese(Ii) Fluoride, Walter Clayton Hitchingham

Masters Theses

No abstract provided.

Elastic Scattering Of 1.33 Mev Gamma Rays From Lead, William Jack Merrow

Masters Theses

No abstract provided.

Elastic Scattering Of 1.33 Mev Gamma Rays From Uranium, David Rood Schwandt

Masters Theses

No abstract provided.

Fabrication Of Lithium Drifted Germanium Detectors Of Planar Structures, Khin M. Yin

Masters Theses

No abstract provided.

A Geochemical Study Of The Maquoketa Formation In Pike County, Missouri, John Siegfried Trapp

Masters Theses

"Statistical interpretation of geochemical data was used to determine the environment of deposition of the Maquoketa Formation in Pike County, Missouri. A cyclic sequence was noted which can be best explained by cyclic climatic changes. During the study it was found that elemental relationships which would be expected in a freshly deposited sediment can be found in core samples. In samples from outcrops and quarry faces these relationships have been destroyed. As these elemental relationships reflect mineralogical relationships, serious doubts have arisen as to the validity of petrographic studies of samples taken from outcrops. This study indicates weathering may be …

Trace Element Anomalies In The Igneous Wall Rocks Of Hydrothermal Veins In The Searchlight District, Nevada, Zuhair Al-Shaieb

Masters Theses

"Two hundred and fifty vein and wall rock samples were collected from Chief of the Hill and the Duplex Mines of Searchlight District, Nevada. The samples were collected along lines approximately normal to the veins. They were analyzed for lead, copper, zinc, silver, gold, arsenic, selenium, and molybdenum using neutron actication analysis and atomic absorption spectrophotometry. Gold, silver, copper, lead and zinc show well-developed anomalies in the wall rocks. In most cases, the concentration of these elements decreases gradually with increasing distance from the vein and reaches background values at a distance of 40-120 feet from the vein. Molybdenum and …

Thermochemical Investigations Of The Methanol-Isopropanol System, Elmer Lee Taylor

Masters Theses

"Heats of solution and partial molar excess volumes at infinite dilution were determined for n-butanol, acetone, chloroform, and water in pure methanol, pure isopropanol, and several mixtures of the two at 25.0⁰C. The partial molar excess enthalpies of methanol and isopropanol were also determined and were combined to obtain integral heats of mixing. All heat data were obtained using a calorimeter of the heat-leak design, containing approximately 300 ml of solvent. Sample sizes ranged for 0.1 to 8 ml. Individual heat measurements were reproducible to 0.05 calories and reported values are considered to be accurate to 1% + 0.5 calorie …

Isotopic Anomalies Of Noble Gases In Natural Gas, Garry A. Bennett

Masters Theses

"This investigation of the abundance and isotopic composition of noble gases in helium-rich gas wells was undertaken in order to obtain new data which might be used to elucidate the origin of isotopic anomalies of noble gases in the atmosphere. Since noble gases are presently leaking to the atmosphere (Damon and Kulp, 1958a; Bieri et al., 1967-) the isotopic composition of the present atmosphere is not static. The direction of change, and ultimately the origin of anomalous noble gases, might therefore be discovered in studying the noble gases presently leaking from the earth. Since the two major noble gas isotopes …

Stratigraphy And Economic Geology Of Uranium-Bearing Sediments In The Poison Spider District, Natrona County, Wyoming, Carlos Enrique Reijenstein D'Acierno

Masters Theses

"Geologic, stratigraphic, and mineralogic characteristics of the Eocene Wind River and Oligocene White River Formations were determined for the southern portion of the Poison Spider District, Natrona County, Wyoming. Sieve analysis and heavy mineral techniques were used to recognize stratigraphic units, determine their environment of deposition, obtain a better knowledge of the grain size distribution, and to identify a possible source area for the sediments. Particular emphasis was concentrated on the evaluation and interpretation of the available geophysical data (gamma ray and resistivity logs), and geological information which had led to the establishment of several relationships between the local geology …

Michael Reactions Part Iv Syntheses With Carboalkoxycarbenes, Frederick Ralph Carman

Masters Theses

"A preliminary investigation has been made involving syntheses with dicarboalkoxycarbenes for the purpose of developing new heterocyclic and alicyclic synthese employing functionalized carbenes. The ultimate goals were the development of a stereospecific synthesis of trans fused and angularly substituted ring systems suitable for conversion to natural products and the development of useful synthetic paths to the azabullvalene system. Although these ultimate goals were not realized, new and improved syntheses of alkyl substituted anisoles and diazomalonic esters, including the first reported synthesis of di-tert-butyl-diazomalonate were accomplished. The addition of dicarboalkoxycarbenes to di-, tri- and tetra- substituted ethylenes, tropilidene and 7-aza-tropilidenes by …

Stratigraphy And Correlation Of Precambrian Volcanic Rocks, Eminence, Missouri, Henry Hugh Fisher

Masters Theses

"A portion of the Precambrian rocks located in the vicinity of Eminence, Missouri are studied and describes. These rocks are exposed as rhyolitic knobs protruding through hills of Ordovician sediments. The Precambrian rocks under study consist principally of rhyolite, with smaller amounts of tuff and creccis. The rhyolite is a potash rhyolite porphyry, both flow banded and unbanded, with phenocrysts of kaolinized orthoclase in a matrix of quartz and orthoclase. The tuffs contain devitrified glass shards and occasional ash balls such as those exhibited at Cott Mountain. A stratigraphic sequence was determined with the oldest rocks to the south at …

The Incorporation Of Oxygen-18 Into Oxindole Acid By Cells Of Hygrophorous Conicus, William Green Allen

Masters Theses

"To understand the mechanism of a biological oxidation in which oxygen is incorporated into a substrate, it is necessary to determine the origin of the incorporated oxygen. The objective of this investigation was to determine the origin of the oxygen atom incorporated into indoleacetic acid (IAA) by the IAA oxidase of Hygrophorous conicus through the use of oxygen-18. To determine the source of the oxygen atom incorporated into IAA it is necessary to incubate H. conicus cells with tryptamine or IAA in the presence of ¹⁸O₂ and H₂¹⁶O in one case and ¹⁶O₂ and H₂¹⁸O in another. An examination of …

Studies In Syntheses Of Non-Isoprenoid Sesquiterpenes, Raojibhai Javerbhai Patel

Masters Theses

The purpose of this study was to find the shortest route to prepare the 1,9-dimethyl decalone system I, a key intermediate in the synthesis of non-isoprenoid sesquiterpenes. The decalone system I was prepared in good yield by dehydrating the hydroxyketone II with 50% H₂SO₄. The dehydration of hydroxyketone II was also affected by heating in the presence of iodine crystals to yield 80% of the decalone system I.

The basic kinds of approaches under investigation were the Diels-Alder reaction and the Robinson annellation. The Diels-Alder reaction between the conjugated diene, 1-acetoxybutadiene (III) and 2,3-dimethylcyclohexenone (IV) under …

The Vapor-Liquid And Liquid-Liquid Phase Equilibria For The Partially Miscible System Methanol-Cyclohexane, Richard A. Christman

Masters Theses

By use of techniques of previous workers for determining liquid-liquid equilibrium and through the use of a circulation still, the complete phase diagram for the partially miscible system, methanol-cyclohexane, was determined. Tile accuracy of earlier liquid-liquid phase data was not improved upon although it was closely approximated. The critical solution temperature was found to be 46.4 degrees C., which is within the range of temperatures reported in earlier measurements.

Activity coefficients of methanol and cyclohexane were calculated from the phase boundaries of the boiling point diagram determined in the present investigation. These activity coefficients were in agreement with the Gibbs-Duhem …

Infrared Cooling Near Atmospheric Temperature Inversions And Absorber Concentration Variations, Joey Keith Tuttle

Masters Theses

"Cooling due to infrared radiation near temperature inversions is investigated. Temperature inversions tend to hold pollution below the inversion level. The pollution itself may contribute to the stability of the inversion by selectively cooling certain portions of the atmosphere. A method is developed for evaluating infrared cooling rates at discreet points in the atmosphere. Several sample calculations are given to demonstrate the effects of variations of absorber concentration and lapse rate"--Abstract, page i.

An Experimental Comparison Of Various Nuclei Counters, Joel William Mansell

Masters Theses

"A series of simultaneous nuclei concentration measurements, with four different nuclei counters, have been made. these counters were a Pollak and a Gardner counter supplied by Mr. Paul Allee of the Environmental Science Services Administration, Boulder, Colorado, and a Pollak and a G.E. counter supplied; by Mr. Norman White of the National Center for Air Pollution Control, Cincinnati, Ohio. In the absence of any knowledge of the absolute concentrations in the samples, the data for each of the individual counters have been compared to the averages computed from all four counters. The results of these comparisons indicate the following: (1) …

Vertical And Lateral Variations In A Welded Tuff, Ted Richard Dinkel

Masters Theses

"During the Tertiary period, nuée ardente type eruptions spread large deposits of welded tuffs over southwestern Utah and southeastern Nevada. The Wah Wah Springs Tuff is a member of one of the most extensive of these units, the Needles Range Formation of Oligocene age. Its known outcrop area is estimated at 13,000 square miles. Relief was slight in the area during the time of eruption to enable the flows to spread over so large an area. In an effort to analyze the lateral and vertical continuity of the member, a petrographic study was undertaken. The average composition of the Wah …

The Background Concentrations Of Copper, Lead, And Zinc In Streams Of The "New Lead Belt", Missouri, Nicholas Howard Tibbs

Masters Theses

"This study was initiated to determine the background concentrations of copper, lead, and zinc in the streams of the Viburnum Trend or New Lead Belt of southeast Missouri. Analytical methods were developed for atomic adsorption spectroscopy. These methods initially consisted of coextraction of cooper, lead, and zinc using the APDC/MIBK system, and finally of extraction of copper by APDC/MIBK and direct analysis of lead and zinc using the newly developed "Sampling Boat" technique. The data obtained from these analyses were arranged in histograms and critically analyzed. The background concentrations were established to be 4-6 ppb for all three elements. Methods …

A Low Frequency Phase Shift Method, Ronnie Carroll Mcmillan

Masters Theses

"The phase shift method of measuring atomic lifetimes is particularly useful because it allows us to make measurements in the steady state mode instead of in the transient mode. High frequency phase shift techniques cause many problems. The equipment, which was designed and built to make low frequency phase shift techniques possible, is shown schematically and discussed. The new experimental techniques employed in our apparatus are a phase multiplier and a unique method of using a photomultiplier as a mixer. In the photomultiplier the final dynode is used as the grid of a triode. The next to the last dynode …