Physical Sciences and Mathematics Commons^™

Application Of Titrations For Verification Of Small Molecule Interaction In Relation To Amidoximated Fibers For Uranium Extraction From Seawater, Kc Michael Mote

Masters Theses

Nuclear energy is a promising substitute for fossil fuels due to possessing low carbon emissions and providing scalable base-load power. However, one major drawback of using nuclear fuel as an energy source is that it needs a steady source of uranium. While the most economical method of obtaining uranium is through conventional terrestrial mining of the ore uranite, mining uranium ores is both harmful to the environment and limited by the terrestrial uranium supply, which is estimated at only 100 more years. However, more than 1000× more uranium is dissolved in seawater than is reasonably inferred and assured in terrestrial …

A Structural And Stratigraphic Study Of The A-2 Carbonate In Southwest Michigan And Reservoir Characterization Of An A-2 Carbonate Gas Storage Field, Clayton Joupperi

Masters Theses

The Overisel and Salem gas storage fields of southwest Michigan annually store 34 Bcf of natural working gas in the upper dolomitized portion of the Silurian A-2 Carbonate. Porosity and permeability in these fields is thought to be enhanced by fracturing and dolomitization associated with the dissolution and collapse of underlying salt units. This study utilizes wire-line logs from 383 wells to explore the structural and stratigraphic controls on the deposition and diagenesis of the A-2 Carbonate in southwest Michigan. Core and thin sections from 4 wells serve as the primary data for investigating the depositional and diagenetic history of …

Evaluating Microgrid Effectiveness In Transitioning Energy Portfolios, Jacob Marshal Hale

Masters Theses

"Microgrid energy systems have emerged as a potential solution to rising greenhouse gas emissions from dependence on fossil fuels. This research provides a framework for evaluating the utility of microgrids. Three key findings are presented: use of a state-of-the-art matrix (SAM) analysis to identify gaps in key research areas that inhibit wide-spread microgrid adoption, development of a system dynamics (SD) model, and a cost benefit analysis case study to evaluate microgrid feasibility in partially meeting the energy demand of a building. Governments play a central role in developing clean energy strategies. A SAM was developed to determine if key microgrid …

Processing Different Mixtures Of Regionally Available Resources To Create Pellets That Meet A Minimum Standard, Jacob Hixson

Masters Theses

There are several ways to produce energy today, one of the oldest is the gasification of biomass. This process uses a fire to heat the material until it starts to produce gasses that are used as fuel. There are several types of biomass that can be used, many of which have large pieces with low bulk densities. By pelletizing the biomass bulk density increases and allows the opportunity to add in other biomass materials.

There are standards for condensing large pieces of biomass to smaller pelletized materials. Pellet Fuels Institute has set minimum standards for pellets used in the different …

Multiscale Approaches Toward Advanced Lithium-Ion Battery: From Nano To Meso Scale, Susmita Sarkar

Masters Theses

“Battery performance and its degradation are determined by various aspects such as the transport of ions and electrons through heterogeneous internal structures composed of constituent particles, kinetic reactions at the interfaces, and a corresponding interplay between mechanical, chemical, and thermal responses. Further, modern battery materials require a variety of engineering processes such as coating, doping and mixing. As a result, in order to fully understand the behavior of the battery material and improve battery performance, it is necessary to understand and control the individual particle behavior and then connect it to the electrode. This study elucidated the physical phenomena associated …

Study Of Surface Complexation And Mineral Dissolution During Water-Rock Interaction In High Salinity Waterflooding At Elevated Temperatures, Sameer Salasakar

Masters Theses

"High salinity waterflooding for carbonate reservoirs is efficient and cheap method used for improved oil recovery. Various mechanisms have been proposed including adsorption/desorption on rock surface, mineral dissolution and precipitation, multicomponent ion exchange, interfacial tension reduction, fine migration and double layer expansion. These all process alter the wettability which leads to improved oil recovery.

Objective of this study was to understand processes that occur during water-rock interaction when high salinity water is flooded into the reservoir. In this work, effect of temperature on water-rock interaction is studied along with effect of pH and specific surface areas of calcite at normal …

The Use Of Sodium Persulfate In Hydraulic Fracturing Fluids: A Degradation Study Based On Furfural, Katherine Elizabeth Manz

Masters Theses

Hydraulic fracturing has allowed natural gas to become a viable energy source via extraction of unconventional shale reserves, but this process requires an enormous amount of water. To ensure a productive fracture, a proprietary blend of chemical additives is added to the water. In this research, a hydraulic fracturing chemical additive – an enzyme breaking agent – is analyzed for organic components using gas chromatography mass spectrometry. The chemical changes that occur over the course of a fracture are also investigated using one model chemical found in the additive, furfural, in order to help assess the environmental risk that hydraulic …

Oxidative Dehydrogenation Of Light Alkanes With Carbon Dioxide, Marktus A. Atanga

Masters Theses

”Most experts studying the global ecosystem and climate suggest that rising anthropogenic CO₂ emissions have contributed to significant global climate change in the last half-century. The development of effective strategies that convert CO₂ into energy, fuels, and chemicals are greatly preferable to oceanic or geologic sequestration options because they offer the potential to create new commercially-viable products from renewable carbon feedstock. On the other hand, the selective oxidative dehydrogenation of light alkanes (C₂-C₄) to corresponding olefins, methane reforming, and methane coupling are the major challenges for producing valuable and versatile feedstocks. The oxidative dehydrogenation …

White-Rot Fungi As Pretreatment Agents For Wood Destined For Biofuel Applications, Ryan M. Kalinoski

Masters Theses

Efficient and economical conversion of lignocellulosic biomass to biofuels is often hampered by the chemical recalcitrance of the material. Inexpensive and environmentally-friendly pretreatment processes are therefore desirable in order to lower the cost of biofuel production and minimize negative environmental impacts. To that end, we have explored the use of a naturally occurring white-rot fungus, Trametes versicolor, as a direct pretreatment agent for hardwood destined for biofuel applications. Specifically, we examined the pretreatment effects on the hardwood mixture after treatment with the wild-type strain of T. versicolor (52J) compared with those from a cellobiose dehydrogenase (CDH)-deficient strain (m4D) , …

Experimental Limestone Dissolution And Changes In Multiscale Structure Using Small- And Ultra Small- Angle Neutron Scattering, Chad Alan Novack

Masters Theses

Small angle neutron scattering (SANS), ultra-small angle neutron scattering (USANS), and backscatter electron (BSE) imaging, along with neutron computed tomography (NCT) were used in this study to experimentally quantify pore size, distribution, and connectivity of dissolved limestone geometries. Eight samples of Indiana limestone of two different initial permeabilities (2-4 mD and 70 mD ) [millidarcy] were reacted with HCl [hydrochloric acid] solutions at differing pH (2 and 4), and flow rates (0.1 and 10 cm³/min) [cubic centimeters per minute] to describe a broad range of parameters that affect limestone dissolution. NCT was first used to image the dissolution …

Characterizing Groundwater Ch4 And 222rn In Relation To Hydraulic Fracturing And Other Environmental Processes In Letcher County, Ky, St. Thomas Majeau Ledoux

Masters Theses

Hydraulic fracturing of shale deposits has greatly increased the productivity of the natural gas industry by allowing it to exploit previously inaccessible reservoirs. However, previous research has demonstrated that this practice can contaminate shallow aquifers with CH₄ [methane] from deeper formations. This study compares concentrations and isotope compositions of CH₄ sampled from domestic groundwater wells in Letcher County, Kentucky in order to characterize its occurrence and origins in relation to neighboring hydraulically fractured natural gas wells. Additionally, this study tests the reliability of ²²²Rn [radon] as an alternative tracer to CH₄ in identifying processes of gas …

Role Of Feedstock And Process Conditions On Biomass Gasification For Synthesis Gas Production, Mayoorey Murugathasan

Masters Theses

In this study gasification of three different biomasses were performed to study the impact of process conditions and different feed stocks on final syngas composition. Final composition of the syngas determines the energy value of the resulting syngas and the suitability of syngas in chemical synthesis applications. Three kinds of feedstocks studied include switch grass pellets:wood chips 50:50 mixture, wood pellets:wood chips 50:50 mixture and wood pellets.

The effect of process conditions including temperature and feed stock composition on syngas composition were studied. Gas chromatography was used to analyze the final gas composition of syngas samples collected at five different …

A Gis-Based Multi-Objective Optimization Of A Lignocellulosic Biomass Supply Chain: A Case Study In Tennessee, Zidong Wang

Masters Theses

To achieve an economically and environmentally sustainable lignocellulosic biomass (LCB)-based biofuel industry sector, the design and location of a sustainable LCB supply chain is important. In this study, a multi-objective optimization model integrated with high-resolution geographical data was developed to examine the optimal switchgrass supply chain for a potential biorefinery in Tennessee, specifically evaluating the potential tradeoffs between the objectives of minimizing plant-gate cost and GHG emissions from the switchgrass supply chain. The key findings of this study are as follows: both plant-gate feedstock cost and GHG emissions were sensitive to the type of land converted into switchgrass production, the …

Evaluating The Effectiveness Of The All Power Labs Power Pallet As A Training Tool For Biomass Gasification Education, Christopher Che Frederick

Masters Theses

The purpose of this study was to provide a better understanding of classroom training with regard to renewable energies. A lecture series and survey were developed by the principle researcher and presented to students in the Alternative and Renewable Energy Systems class and Machine Design class at Eastern Illinois University. The lecture series introduced students to biomass gasification and its application at Eastern Illinois University. The survey analyzed participant's level of knowledge of gasification technologies. The survey's pre and post test scores were used to validate the effectiveness of the training.

The All Power Labs Power Pallet was utilized as …

Co2 Injection Into A Deep Saline Aquifer: Porosity Measurements, Numerical Modeling, And Costs Associated With Uncertainty Of Petrophysical Parameters, Michael John Gragg

Masters Theses

Anthropogenic levels of atmospheric greenhouse gases, particularly carbon dioxide (CO₂) have increased rapidly over the last several decades and coincide with rising temperatures globally. One possible solution is to capture CO₂ before it is released into the atmosphere by large point sources, such as fossil fuel power plants. Once captured, the CO₂ can be condensed and transported to a storage facility. Of the available options for storage of condensed CO₂, geologic sequestration in deep saline aquifers is considered the most viable option.

Porosity measurements were obtained for nearly 100 core samples of the Knox …

Economic Feasibility Of Ethanol, Methanol And Alcohol-Gasoline Blends As Alternatives To Gasoline As Motor Fuels, Marjorie Diane Pettypool

Masters Theses

The major emphasis of this study is the economic feasibility of the use of alcohol-gasoline blends (gasohol) and alcohol fuels; but all major issues concerning the use of gasohol and alcohol fuels are explored. The specific objectives of the investigation include the determination of the specific performance properties of the fuels, their pollutant emissions (compared to gasoline), and their costs compared to gasoline.

While opponents to the use of alcohol fuels are more vocal than proponents, citing high cost and the lack of raw materials as objections, proponents believe new processes that can use any cellulose containing material as a …