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Macalester Journal of Physics and Astronomy

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Full-Text Articles in Physical Sciences and Mathematics

Carrier Mobility In Methylammonium Lead Iodide Perovskite Solar Cells: Mobility Versus Composition In Spin Coated And Vapor Deposited Samples, Max A. Zinman, James Heyman May 2024

Carrier Mobility In Methylammonium Lead Iodide Perovskite Solar Cells: Mobility Versus Composition In Spin Coated And Vapor Deposited Samples, Max A. Zinman, James Heyman

Macalester Journal of Physics and Astronomy

We performed research on a set methylammonium lead iodide (MaPI) perovskite solar cell samples, including samples produced both by vapor deposition and spin coating. We used time resolved THz spectroscopy to measure carrier mobility in the samples and excitation of vibrational modes in the THz and IR spectra to gauge relative sample compositions (ratio of PbI to Ma). Plotting carrier mobilities against composition ratios, we found a peaked distribution of carrier mobilities suggesting an ideal ratio of lead iodide to methylammonium to maximize mobility. We also observed that the spin coated samples had considerably less variance in their composition ratios …


Effects Of Post-Deposition Annealing On Room Temperature Deposited Zinc Oxide, Ishan Rayen May 2024

Effects Of Post-Deposition Annealing On Room Temperature Deposited Zinc Oxide, Ishan Rayen

Macalester Journal of Physics and Astronomy

This study focuses on thin film deposition of ZnO onto a glass slide using magnetron sputtering. The focus of the study is to understand the effects of post-deposition annealing temperatures. The goal is to optimize crystal quality, conductivity, and transparency. The results attempt to answer the effects of room temperature deposition and changes in film properties once annealed. Annealing temperatures ranged from 100°C to 400°C with an annealing time of 30 minutes. This found an ideal temperature of 250°C for post-deposition annealing, resulting in approximately 3.86 times more conductivity with little to no decrease in transparency. However crystal quality did …


Probing Charge Recombination In Organic Solar Cells, Ally C. Hurd, Awwad Alotaibi, Acacia Patterson, Obaid Alqahtani, James Doyle, Brian Akira Collins May 2024

Probing Charge Recombination In Organic Solar Cells, Ally C. Hurd, Awwad Alotaibi, Acacia Patterson, Obaid Alqahtani, James Doyle, Brian Akira Collins

Macalester Journal of Physics and Astronomy

Printable and flexible organic solar panels are promising sources of inexpensive, large-scale renewable energy, where panels can be manufactured by printing from polymer inks. There are some limitations to these types of solar cells, however. First, toxic halogenated solvents have historically been necessary to dissolve polymers to make the ink. In addition, organic solar cells typically have high rates of recombination, which limits their efficiency. Here, we use a transient photovoltage (TPV) technique to measure charge lifetimes in cells made from two different organic solvents. The first solvent is toxic, halogenated dichlorobenzene (DCB) which is typically used to make organic …


Investigation Of Tantalum Sodium Lead Borate Glass Using Laser Ionization Time Of Flight Mass Spectrometry (Litof-Ms), Siri Erickson-Green May 2024

Investigation Of Tantalum Sodium Lead Borate Glass Using Laser Ionization Time Of Flight Mass Spectrometry (Litof-Ms), Siri Erickson-Green

Macalester Journal of Physics and Astronomy

Laser ionization time of flight mass spectrometry (LITOF-MS) is a spectrometry method which can measure, with exceptional accuracy, the composition of ions within a glass system. Additionally, unlike other spectroscopy and spectrometry methods, this technique allows insight into the abundance of each kind of ion within a given glass system. This specific project tackled the topic of tantalum-doped sodium and lead borate glasses, as sodium and lead borate glasses doped with a transition metal is a topic which has not been thoroughly explored. Our group synthesized such a glass and was able to use LITOF-MS to gain insights into how …


Strain Methods For Changing Local Electric Field Gradient In Bafe2as2, Caleb Williams May 2024

Strain Methods For Changing Local Electric Field Gradient In Bafe2as2, Caleb Williams

Macalester Journal of Physics and Astronomy

In this study, we introduce a novel approach aimed at advancing the investigation of local nematicity in BaFe2As2 via dynamically pulsed strain fields. Our research is motivated by the pursuit of a more sensitive alternative to existing static strain methods. Employing nuclear magnetic resonance techniques, we measure the nuclear quadrupolar energy splittings, utilizing them as a sensitive indicator of the electric field gradient (EFG) that couples strongly to the orbital occupations of the 75As p-orbitals. In the new method, we discern an EFG response through changes in the phase acquired by the nuclear magnetization while time-evolving in the strain field, …


Linking The Population Of Binary Black Holes With The Stochastic Gravitational-Wave Background, Olivia X. Laske May 2024

Linking The Population Of Binary Black Holes With The Stochastic Gravitational-Wave Background, Olivia X. Laske

Macalester Journal of Physics and Astronomy

The astrophysical stochastic gravitational-wave background (SGWB) is the product of overlapping waveforms that create a single unresolvable background. While current LIGO sensitivity is insufficient to uncover the SGWB, future space-based detectors and Third Generation (3G) experiments are expected to probe deep enough for detection. Predictions of the SGWB can constrain future searches as well as provide insight into star formation, merger history, and mass distribution. Here, three primary methods are used to calculate a theoretical SGWB. The first method integrates over a precomputed mass distribution probability grid, while the second and third employ Monte Carlo integration with simulated data. After …


Simulation Of Polymerization On Surfaces: Implications For Abiogenesis, Sylvia Greene May 2024

Simulation Of Polymerization On Surfaces: Implications For Abiogenesis, Sylvia Greene

Macalester Journal of Physics and Astronomy

How did life arise from the prebiotic conditions of the early earth? This problem has vexed scientists for decades with no consensus on its solution. Significant spontaneous formation of biopolymers such as proteins and nucleic acids in the aqueous phase appears to be improbable due to thermodynamic constraints. It has been proposed that mineral surfaces could have served as a catalyst for the initial formation of biopolymers. However, the feasibility of this mechanism has not been thoroughly studied. In this study, a particle simulation of polypeptide formation on surfaces is developed to assess the feasibility of this mechanism. Elementary processes …


The Hodgkin-Huxley Model For Neuron Action Potentials: A Computational Study, Uditi Chandrashekhar May 2024

The Hodgkin-Huxley Model For Neuron Action Potentials: A Computational Study, Uditi Chandrashekhar

Macalester Journal of Physics and Astronomy

Neurons are the fundamental units of the nervous system that receive stimuli as signals and pass on this information to other cells in different parts of the body. An action potential refers to the transmission of the electrical nerve impulse along the neuron. In their seminal work published in 1952, Alan L. Hodgkin and Andrew Huxley proposed a mathematical model of neuronal membrane action potentials based on a series of experiments they conducted using the giant squid neuron. This thesis is a study of the nature of the action potential used to transfer signals along the neuron based on the …


Variability Of High-Degree Modes Over Multiple Solar Cycles Using Local Helioseismic Data From Gong, Nicholas Cebula, Sushanta Tripathy, Kiran Jain, John M. Cannon May 2024

Variability Of High-Degree Modes Over Multiple Solar Cycles Using Local Helioseismic Data From Gong, Nicholas Cebula, Sushanta Tripathy, Kiran Jain, John M. Cannon

Macalester Journal of Physics and Astronomy

In this investigation we use the local helioseismic technique of ring diagrams to study the power, energy, and damping rates of high degree solar acoustic modes. Our data covers the period from the maximum phase of solar cycle 23 to the ascending phase of cycle 25. The goal is to examine the variations in the mode parameters with solar activity as well as the differences between different cycles. For this, we use different proxies of solar activity. We use 10.7 cm radio flux measurements and a measure of magnetic flux known as magnetic activity index from magnetograms.


Ammonia Emission In The Milky Way Galactic Bar Dust Lanes, Charles G. Burton May 2024

Ammonia Emission In The Milky Way Galactic Bar Dust Lanes, Charles G. Burton

Macalester Journal of Physics and Astronomy

The Central Molecular Zone (CMZ) of the Milky Way is a region of molecular gas within the inner few hundred parsecs of the Galaxy. This inner region of the Milky Way is hotter and more turbulent when compared with the disk of the Milky Way. Gas is thought to be funneled into the CMZ through dense gaseous dust lanes that are associated with the Galactic Bar. I studied two regions of one of these dust lanes using the NH3 inversion transitions of (J,K) = (1,1), (2,2), (3,3), and (4,4). Data has been obtained from the Green Bank Telescope targeting these …


Development Of A Particle-In-Cell/Monte Carlo Simulation For Weakly Ionized Plasmas, Xiaochuan (Chloe) Zheng, James Doyle Jun 2023

Development Of A Particle-In-Cell/Monte Carlo Simulation For Weakly Ionized Plasmas, Xiaochuan (Chloe) Zheng, James Doyle

Macalester Journal of Physics and Astronomy

A plasma is a gaseous system that contains large numbers of electrons and ions that are subject to forces produced by electric and magnetic fields. Weakly ionized plasmas, where the plasma density is much lower than the background gas density, are common in laboratory, atmospheric, and astrophysical situations. Theoretical calculations of plasma properties are challenging due to the complexity of the differential equations used to characterize fundamental physics. Particle-in-cell (PIC) simulations bypass the mathematical difficulties associated with analytic models, at the expense of more complex and time-consuming computer calculations. In this work we developed a one dimensional PIC simulation of …


Tools For Refining The Baryonic Tully-Fisher Relation, Ezra D. Wolf Jun 2023

Tools For Refining The Baryonic Tully-Fisher Relation, Ezra D. Wolf

Macalester Journal of Physics and Astronomy

This paper discusses the development of tools for galactic photometry using wise, and for reduction and analysis of 21cm galaxy spectra. These Python-based tools can then be applied to selected data in order to refine the Baryonic Tully-Fisher Relation. This relation, between baryonic mass and rotational velocity of a galaxy, proves useful for extragalactic research, particularly in calculating redshift-independent distances. While these tools could be further improved, they provide a robust process for calculation of particular galaxy characteristics.


Hydrosphere: Modeling The Planetary Structure Of Ocean Planets And Icy Moons, Karlee R. Taylor Jun 2023

Hydrosphere: Modeling The Planetary Structure Of Ocean Planets And Icy Moons, Karlee R. Taylor

Macalester Journal of Physics and Astronomy

In recent years, “water worlds” have become increasingly of interest to astrobiologists due to their high potential for habitability, as the large amount water on their surfaces is not only necessary for life, but also promises long-term climatic stability. However, also necessary for life is the exchange of chemical compounds between the geosphere and the hydrosphere - something which may be ob- structed by the presence of high pressure ices on these ocean planets and icy moons. In order to explore the habitability of bodies with various surface temperatures, water masses, and core radii, this project develops a model of …


From Experiment To Theory: Investigate The Effect Of Pump Beam Size On Photovoltaic Material Behavior, Dengyu Tu Jun 2023

From Experiment To Theory: Investigate The Effect Of Pump Beam Size On Photovoltaic Material Behavior, Dengyu Tu

Macalester Journal of Physics and Astronomy

In orde to investigate the effect of the pump beam size on an ultrafast conductivity measurement experiment, an experiment using Femto XL-500 laser and a simulation using Mathematica were performed. From the experiment data, we found that as the size of the pump beam decreases beyond certain limit, the Drude model can not accurately predict the relationship between conductivity and frequency. In addition, the simulation results corroborate with the experiment result that there is a limit for the size of the pump beam.


Machine Learning Refinements To Metallicity-Dependent Isotopic Abundances, Haoxuan Sun Jun 2023

Machine Learning Refinements To Metallicity-Dependent Isotopic Abundances, Haoxuan Sun

Macalester Journal of Physics and Astronomy

The project aims to use machine learning algorithms to fit the free parameters of an isotopic scaling model to elemental observations. The processes considered are massive star nucleosynthesis, Type Ia SNe, the s-process, the r-process, and p-isotope production. The analysis on the successful fits seeks to minimize the reduced chi squared between the model and the data. Based upon the successful refinement of the isotopic parameterized scaling model, a table providing the 287 stable isotopic abundances as a function of metallicity, separated into astrophysical processes, is useful for identifying the chemical history of them. The table provides a complete averaged …


Machine Learning Applications For Materials Science: Predicting Properties Of Two-Dimensional Magnetic Materials, Paige Stevenson Jun 2023

Machine Learning Applications For Materials Science: Predicting Properties Of Two-Dimensional Magnetic Materials, Paige Stevenson

Macalester Journal of Physics and Astronomy

We trained successful neural networks to predict the formation energy and magnetic moment of 2-dimensional ferromagnetic materials of similar structure to Cr2Ge2Te6. We collect elemental data on materials with known and unknown properties from easily accessible sources to screen for viable materials for use in future research. Random forest regressors were used to identify the most important predictors of our target qualities, which perform better on predictions of formation energy than magnetic moment. We predict the properties of 1225 materials that are candidates for further research in two-dimensional magnetism and identify several potential sources of error in our models that …


Measuring The Pulse Duration Of A Femtosecond Laser Using Intensity Autocorrelation, Ross N. Relic Jun 2023

Measuring The Pulse Duration Of A Femtosecond Laser Using Intensity Autocorrelation, Ross N. Relic

Macalester Journal of Physics and Astronomy

In this experiment, an intensity autocorrelator is set up in order to measure the pulse duration of a passively mode-locked Titanium-Sapphire laser with a power of 267mW producing femtosecond pulses. Then this measurement, as well as a measurement of the laser’s spectrum, is used to test the Uncertainty Principle. Intensity autocorrelation is a well-established technique for measuring pulse duration, and is among the more intuitive techniques for this purpose, which is why it was selected for this experiment. The experimental setup was computerized. The delay of one half of the pulse was controlled by a motorized translation stage which was …


Fabricating Perovskite Solar Cells: Fabrication Guide For Limited Lab Capabilities, Erin F. S. Leary Jun 2023

Fabricating Perovskite Solar Cells: Fabrication Guide For Limited Lab Capabilities, Erin F. S. Leary

Macalester Journal of Physics and Astronomy

Within the realm of emerging photovoltaics, Perovskite cells are one of the most intriguing technologies. Within a little over a decade, Perovskite solar cells have rivaled the efficiencies of traditional silicon solar cells and strongly outpaced other emerging photovoltaic technologies. This paper aims to show a fabrication guide for creating Perovskite solar cells in a limited lab setting. The fabrication guide created structures with strong physical reliability, but limited electrical reliability. More research is needed to ensure greater reliability and proper electrical function.


Solar Radio Bursts —Deployable Low-Band Ionosphere And Transients Experiment (Dlite) Arrays, Jonathan M. Kazor, Jason Kooi Jun 2023

Solar Radio Bursts —Deployable Low-Band Ionosphere And Transients Experiment (Dlite) Arrays, Jonathan M. Kazor, Jason Kooi

Macalester Journal of Physics and Astronomy

Solar radio bursts, phenomenon that often accompany CME, solar flares and other solar events, can be detected on earth and used in the prediction of solar weather that affects earth systems in several ways. As part of the NREIP Program supporting the Naval Research Laboratory, Remote Sensing Division, approximately ten interns participated in the analysis of data collected by DLITE and WAVES radio data. Data from DLITE is often used as a complement to data from WAVES due to differences in frequency range and resolution. The analysis helps to correlate the DLITE data with the data collected from other sources. …


Mapping The Tesseral Field Of Saturn, Aurora Hiveley Jun 2023

Mapping The Tesseral Field Of Saturn, Aurora Hiveley

Macalester Journal of Physics and Astronomy

Saturn's rotation rate is still uncertain, and while it is theorized to exhibit differential rotation much like Jupiter, this claim is somewhat disputed. By analyzing the properties of waves in the ring system of Saturn as measured by the Cassini spacecraft, we aim to provide observational evidence of this phenomenon. The results of wave analysis allow us to characterize the perturbers responsible for the production of these waves, which are believed to be mass anomalies in the interior of Saturn itself. By calculating the masses of these anomalies and attempting to pinpoint their locations inside of the planet, we provide …


Trinification With A Bi-Adjoint Higgs Field, Ross Ferguson Jun 2023

Trinification With A Bi-Adjoint Higgs Field, Ross Ferguson

Macalester Journal of Physics and Astronomy

In this paper, we propose a novel extension of the Standard Model of particle physics, based on the trinification gauge group $SU(3)_C \times SU(3)_L \times SU(3)_R$. Symmetry breaking is achieved using a bi-adjoint Higgs field (transforming under the left- and right-handed subgroups) along with a more conventional bi-triplet to ensure the correct breaking and pattern of fermion masses. To preserve a discrete $Z_2$ symmetry (T-parity), we also introduce a right-handed triplet to completely break trinification symmetry to the Standard Model. The minimization conditions and conditions for the boundedness of the potential for this model are calculated. Additionally, the Standard Model …


A High-Speed Portable Ground Heat Exchanger Model For Use In Various Energy Simulation Software, Ryan Davies, Matt Mitchell, Edwin Lee Jun 2023

A High-Speed Portable Ground Heat Exchanger Model For Use In Various Energy Simulation Software, Ryan Davies, Matt Mitchell, Edwin Lee

Macalester Journal of Physics and Astronomy

A portable component model (PCM) of a ground source heat pump system was developed and used as a test case in the creating of a PCM development framework. By developing this framework, new building energy simulation models will be able to be easily integrated into existing simulation software such as EnergyPlus and the Modelica Buildings Library. Our model uses a time responsive g-function and numerical methods to simulate ground source heat pumps for single time steps as well as long time scales. We validated our model against GHESim and GLHEPro and found that our model agrees with these two standards …


Extension Of The Lux-Zeplin Nr Background To 600 Phd, Jackson Codd Jun 2023

Extension Of The Lux-Zeplin Nr Background To 600 Phd, Jackson Codd

Macalester Journal of Physics and Astronomy

In June 2022, the LUX-ZEPLIN collaboration released its first results, with the
most precise measurements of any direct dark matter detector. The findings were
calculated using the expected spin-independent WIMP-nucleon interaction model,
which would result in small energies deposited in the detector. Therefore, the
background of non-dark interactions was calculated for events with S1 areas up to
80 phd (Aalbers et al. 2022). In order to increase the sensitivity to high energy
WIMP-nucleon interaction events, as predicted by other models, we extended the
non-dark NR background to events with S1 areas of up to 600 phd. We found a
large …


Adding Classical Novae Contribution To The Isotopic Scaling Model, Mengxi Chen Jun 2023

Adding Classical Novae Contribution To The Isotopic Scaling Model, Mengxi Chen

Macalester Journal of Physics and Astronomy

The Isotopic Scaling model(West & Heger, 2013) provides a complete average isotopic decomposition for our Milky Way as a function of metallicity and it requires an initial Solar Abundance Decomposition as a starting point. The previous Solar Abundance decomposition work is not perfect(West & Heger, 2013), since Classical Novae abundances are ignored. My research intends to improve the current solar abundance decomposition by adding Classical Novae Abundance contribution, then to update the Isotopic Scaling model.


Effectiveness Of Different Materials As Catalysts For Alkaline Water Electrolysis, Lance T. Bartol, James Doyle Jun 2023

Effectiveness Of Different Materials As Catalysts For Alkaline Water Electrolysis, Lance T. Bartol, James Doyle

Macalester Journal of Physics and Astronomy

We tested the catalytic properties of various nickel and molybdenum electrodes as potential replacements for platinum for usage in alkaline water electrolysis. After initial tests found molybdenum-based electrodes to be significantly more effective than nickel electrodes, we moved to calculate overpotentials. We found nickel electrode overpotentials at ± 10 mA current to be 939 and -960 mV. Conversely, molybdenum electrode overpotentials at the same currents were 244 and -681 mV respectively. While still significantly higher than overpotentials for platinum, these results indicate that, with more testing, molybdenum-based electrodes could eventually emerge as a cheaper, more abundant alternative to platinum electrodes.


Smart Grid Control: Demand Side Management In Household Refrigerators As A Tool For Load Shifting, Anogh Utkalika Zaman, James Doyle May 2022

Smart Grid Control: Demand Side Management In Household Refrigerators As A Tool For Load Shifting, Anogh Utkalika Zaman, James Doyle

Macalester Journal of Physics and Astronomy

With improved supply of renewable sources of energy the focus has shifted away from simply producing clean energy to efficient consumption of energy. Until cheaper methods of energy storage are developed, Demand Side Management (DSM) is the best option for maximising energy efficiency. This paper proposes a method of turning regular refrigerators into smart demand response fridges. First, we develop an algorithm that accounts for small fluctuations in price and switches the device for optimal performance and lowered running cost. Then, we use longer price fluctuations to predict suitable times for pre-cooling and investigate the reduction in price as a …


Twisting Lasers With The Faraday Effect, Harrison Werrell May 2022

Twisting Lasers With The Faraday Effect, Harrison Werrell

Macalester Journal of Physics and Astronomy

Our objective with this project was to create a system and procedure to quantify the magnetization of a material with polarized light by using the Faraday Effect, where the light is rotated according to the magnetization. This type of system has seen use in technologies such as magneto-optical drives and optical isolators, and is part of the study of optical materials, along with the similar MagnetoOptical Kerr Effect. Our system, specifically, is intended to be used as part of an advanced Physics Lab in the future. It uses an electromagnet to magnetize a sample, and a laser to observe the …


Electrical Analysis Of A Pem Electrolysis Cell, Joey Wehrley, James Doyle May 2022

Electrical Analysis Of A Pem Electrolysis Cell, Joey Wehrley, James Doyle

Macalester Journal of Physics and Astronomy

Polymer Electrolyte Membrane (PEM) electrolysis is a form of electrolysis that is heavily used in commercial capacities. It functions by using a membrane and an electric charge in order to perform electrolysis water, splitting it into its component parts - Hydrogen and Oxygen. These parts can then be used in a number of different applications, including reversing the electrolysis process to regenerate some energy in the form of electricity. During this experiment, multiple currents were run through a PEM cell, and voltages across the membrane were measured. It was found that a standard R/C charging model can be fit to …


The Interaction Of Topological Defects In Anisotropically-Elastic Nematic Liquid Crystals, Carter J. Swift May 2022

The Interaction Of Topological Defects In Anisotropically-Elastic Nematic Liquid Crystals, Carter J. Swift

Macalester Journal of Physics and Astronomy

Topological defects are very well understood so long as the medium in which they exist is isotropically-elastic. They lead to director fields which are easy to calculate and superpose linearly so that a system with any number of defects is analytically treatable. They also have an interaction which is simple in form and can be accurately described by the Peach-Koehler force. In an anisotropically-elastic medium, however, such defects are very poorly understood outside of the single-defect case which was solved by Dzyaloshinskii. In this project, numerical and approximate analytical techniques are applied in order to better understand the interaction between …


Neutrino Oscillations In The Presence Of A Magnetic Field, Chinhsan Sieng May 2022

Neutrino Oscillations In The Presence Of A Magnetic Field, Chinhsan Sieng

Macalester Journal of Physics and Astronomy

We calculate oscillation probabilities in the presence of an external magnetic field in a one-generation neutrino framework that includes both Majorana and Dirac mass terms. First, we write down the Euler-Lagrange equations and obtain a system of eight differential equations coupling together eight different neutrino states that can be distinguished by helicity, chirality, and particle/antiparticle-ness. We then solve this system of differential equations in various special cases, exhibiting different types of oscillations. When the magnetic field is in the direction of momentum, there are only four oscillation channels as helicity flip is forbidden. We observe that chirality flips are suppressed …