Physical Sciences and Mathematics Commons^™

Mercury Emissions From Iron Mining And Copper Mining In The Upper Peninsula, Michigan, Ahmed Al Rahbi

Honors Theses

The wealth in the Upper Peninsula of Michigan has been intimately linked with mining, particularly the extraction of iron and copper. Iron was deposited in the Upper Peninsula 1.9 billion years ago (Gogebic and Ranges, 2020), and copper deposits are believed to be 1.1 billion years old (Blakemore et al., 2016). In the Upper Peninsula, mercury occurs naturally in taconite (iron ore) as elemental mercury (Hg⁰), and within the copper ores as “Mercury copper amalgam” (CuHg). When elemental mercury is released from the ores, it oxidizes in the atmosphere to form inorganic mercury (Hg²⁺) (Risher, 2003; …

Surface Reconstruction Library, Jhye Tim Chi

Honors Theses

The project aims to convert an arbitrary point cloud into a triangular mesh. Point clouds are a list of 3d points that model the topology of an object. Point clouds can have various issues, such as missing or noisy data. For the scope, we had no control over point cloud generation. We were also unable to deal with underlying registration or alignment problems. Triangular meshes are a list of triangles that have 3d vertices. This aggregate list of triangles defines the reconstructed surface. Our project implementation is based on Alexander Hornung and Leif Kobbelt’s method for surface reconstruction using the …

Class Scheduling Web App, Anubhav Rawal

Honors Theses

This Scheduling Web Application in Django was built to allow a user to create a schedule for upcoming semesters. Users with appropriate privileges could upload an excel schedule to which instructors could be assigned. Additionally features included dynamic editing for admin users and viewing the main schedule for general users. Our goal was to create an application from the ground up using the Django framework to accomplish these tasks.

Iron Geochemistry Across An Estuary-To-Coastal Gradient, Lissett G. Diaz

Honors Theses

Iron is a ubiquitous earth element that participates in biogeochemical processes that occur in marine sediments. Microorganisms utilize iron for many purposes, including cell growth, conserving energy, and for maintaining metabolic activity. In coastal sedimentary settings, understanding the redox reactions involving ferric iron, Fe³⁺, and ferrous iron, Fe²⁺, in its solid phase and pore-water phases, respectively, enable an appreciation of biogeochemical transformations occurring in the coastal zone. In this study, iron concentrations in sediment of ranging permeability were determined at four stations marking an estuary-coast transition zone in Singleton Swash in Myrtle Beach, South Carolina. The …

An Argument For The Second Nuclear Era: Salvaging The Atomic Age In Response To Climate Change, Ian Sager

Honors Theses

No abstract provided.

Ferris Bakes, Ferris Dehart

Honors Theses

No abstract provided.

Investigation Of N-Sulfonyliminium Ion Triggered Cyclizations For The Synthesis Of Piperidine Scaffolds, Kaitlyn Birkhoff

Honors Theses

In consideration of the on-going global pandemic, immediate access to Food and Drug Administration approved pharmaceutical medications and vaccines is a matter of utmost priority to our national healthcare system. One significant modality in managed care is the dispensation of prescription drugs for the prevention or treatment of illnesses and diseases. According to the Centers for Disease Control and Prevention, physicians order and provide over 2.9 billion prescriptions each year with analgesics, antihyperlipidemics, and dermatological agents being the most prescribed therapeutic classes. Within those classes exists a disparate variety of chemical structures that must be prepared on a metric ton …

Techniques For The Enantioselective Asymmetric Synthesis Of Benzyl Substituted Malonic Acid Esters, Madison Hansen

Honors Theses

A popular method for the enantioselective synthesis of substituted malonic half esters is hydrolysis via Pig Liver Esterase (PLE), however some substrates produce low enantiomeric excess, namely benzyl-substituted malonic esters. Presented here are alternative methods explored for this synthesis, the first being phase-transfer catalyzed hydrolysis via N-benzyl quaternary ammonium salts derived from cinchona alkaloids. The second method utilized chiral auxiliary directed benzylation with auxiliaries including menthol and oxazolidinones. Though unsuccessful, this research provided valuable groundwork in the investigation for the enantioselective asymmetric synthesis of benzyl-substituted malonic acid esters.

Keywords: Pig Liver Esterase, Enantioselectivity, Phase-Transfer Catalysis, Cinchona Alkaloids, Quaternary Ammonium …

Analysis Of The Photodegradation Of The Pro-Herbicide Benzobicyclon Hydrolysate Using A Seawater Gradient And Constituent Ions, Margaret A. Knight

Honors Theses

No abstract provided.

The Influence Of Bottom Type And Water Column Stratification On Reef Fish Community Structure At Gray’S Reef National Marine Sanctuary, Bridget Campbell

Honors Theses

Understanding the physical and oceanographic differences across reef habitats can help researchers assess how those differences influence fish distribution and community structure, which leads to a better understanding of what a healthy reef system looks like. The traditional methods used to assess fish communities on temperate reefs are limited and often focus solely on either the reef structure or water column conditions alone. An assessment of both data sets yields a more complete understanding of the ecosystem as a whole. In this study, Gray’s Reef National Marine Sanctuary (GRNMS) was surveyed both inside and outside a Marine Protected Area (MPA) …

Differences In Erosion Rates And Elevation Among Natural, Living And Hardened Shorelines In Mississippi, And Alabama, Brittany Juneau

Honors Theses

Shoreline erosion is a phenomenon that currently threatens both natural ecosystems and human settlements along the coast. With trends showing gradual sea level rise as a result of climate change, erosion is becoming an increasing threat to these communities. This research aims to provide more insight into the relationship between shoreline morphology and three shoreline protection techniques: natural marsh, living shoreline, and hardened structures. Six sites along the Alabama and Mississippi coast that had all three shoreline types were evaluated to determine what the average erosion rate and slope was for each shoreline. Erosion rates were calculated by image analysis …

Heavy Metal Contamination In Drinking Water And Its Connection To Superfund Site Related Environmental Injustice, Emily Caruso

Honors Theses

Equal access to clean, potable drinking water is crucial for our society’s health and advancement. In 2014, the infamous water crisis in Flint, Michigan, shed light on the widespread water quality issues impacting numerous communities in America. In response to the Flint water crisis, Union College established the Union College Water Initiative, providing free drinking water analyses to the public. This initiative aims to raise awareness and educate people by analyzing heavy metals commonly found in drinking water—specifically lead, copper, and zinc.

As a part of this initiative, I collected over 300 cold drinking water samples from residences, schools, and …

Developing Prediction Models For Kidney Stone Disease, Joseph Palko

Honors Theses

Kidney stone disease has become more prevalent through the years, leading to high treatment cost and associated health risks. In this study, we explore a large medical database and machine learning methods to extract features and construct models for diagnosing kidney stone disease.

Data of 46,250 patients and 58,976 hospital admissions were extracted and analyzed, including patients’ demographic information, diagnoses, vital signs, and laboratory measurements of the blood and urine. We compared the kidney stone (KDS) patients to patients with abdominal and back pain (ABP), patients diagnosed with nephritis, nephrosis, renal sclerosis, chronic kidney disease, or acute and unspecified renal …

Analysis Of Possible Hybrid Meson Decay, Jasper Bergh

Honors Theses

This research looked at data from the GlueX experiment at the Thomas Jefferson National Accelerator Facility to search for evidence of the π1(1600) particle, an exotic hybrid meson, decaying to an eta' and π0. We specifically looked into decays of the eta' to an eta, π+, and π-, with the eta decaying to 3 πo's. We successfully reconstructed an eta from the 3 πo's, and an eta' from the eta, π+, and π-. However, we did not observe the π1(1600), but, a 6:1 ratio of signal to background in the eta' mass. With more statistics this would be a viable …

Iot Garden Frost Alarm, Andrew James

Honors Theses

Home gardeners are faced with yearly challenges due to spring frosts harming young plants. This is frequently mitigated by covering crops with frost blankets, but only on nights when a frost is predicted. In areas with less predictable climate, an unexpected frost can kill vulnerable plants, reducing the amount of food produced. A system is proposed and designed here to use internet of things (IoT) technology to enable a small weather station in the home garden to report current climate data and predict frosts, then alert the gardener in time for them to cover their plants.

The system as designed …

A Theoretical Study Of Synchronous Proton Transfer In (Hf)N, (H2O) N, And (Hcl) N Where N = 3, 4, 5, Johnny Yang

Honors Theses

For (HF)_n, (H₂O)_n, and (HCl)_n (n = 3 − 5), we have rigorously characterized the structures for the minima and transition states for synchronous proton transfer (SPT) with the CCSD(T) method and aug-cc-pVTZ basis set. The electronic barrier heights (∆E^†) associated with these transition states have also been computed with the explicitly correlated CCSD(T)-F12 method and the aug-cc-pVQZ-F12 basis set (abbreviated aQZ-F12). (HCl)_n (n = 3 − 5) SPT transition states have not been previously identified to the best of our knowledge, and they have been found …

Initial Investigation Of Wildflower Honey Using Headspace Solid-Phase Microextraction Coupled With Gas Chromatography-Mass Spectrometry For Geographical Information, Tyra Countiss

Honors Theses

Honey has been used as a food, sugar substitute, and flavor enhancer forever. The uses for honey are extremely varied from food to medicine. It is widely touted that you can address seasonal allergies, especially those following a move, by eating local honey. For this to be true the composition of the local honey, including trapped pollen, would allow allergy symptoms to be eliminated. In this project, the volatile and semi-volatile aroma compounds in wild flower honey from several different locations were analyzed. Headspace solid phase microextraction (HS-SPME) coupled with gas chromatography-mass spectrometry (GC-MS) was used to help develop the …

One-Pot Synthesis Of Disubstituted Primary Amines From Nitriles Via Grignard Addition And Metal-Alcohol Reduction, Joshua Peltan

Honors Theses

The process of developing a working base case procedure for a novel one-pot-two-step synthesis of primary amines from Grignard reagents, nitriles, sodium metal or alkali metal loaded silica gel, and alcohol is described. Initial steps towards applying the process broadly are detailed. The process has the potential to be an affordable, convenient, safer, greener, and more accessible alternative to exiting methods of accomplishing the same transformation. The reaction scheme has been proven to provide yields and purity comparable to existing methods for certain pairs of substrates; however, its utility as a general-purpose method for transforming arbitrary pairs of Grignard reagent …

Assessing Sustainability At Ccu, Savannah Billings

Honors Theses

An assessment of sustainability initiatives and culture at Coastal Carolina University, recommending stronger institutional support for sustainability.

Cosmological Inflation In N-Dimensional Gaussian Random Fields With Algorithmic Data Compression, Connor A. Painter

Honors Theses

The leading modern theories of cosmological inflation are increasingly multi-dimensional. The “inflaton field” φ that has been postulated to drive accelerating expansion in the very early universe has a corresponding potential function V , the details of which, such as the number of dimensions and shape, have yet to be specified. We consider a natural hypothesis that V ought to be maximally random. We realize this idea by defining the V as a Gaussian random field in some number N of dimensions. We repeatedly simulate of the evolution of φ given a set of conditions on the “landscape” of V …

Characterization Of Mechanical Responses Of Helical Antenna For Satellite Communications, Scott Chumley

Honors Theses

The purpose of this work was to identify and analyze the vibrational modes of a helical structure to model the vibrational characteristics of an L-band helical antenna for satellite communications. This project focused on the vibrational modes between 1 and 50 Hz. Using COMSOL Multiphysics finite element modeling of helices were performed to predict mode shapes and frequencies to compare with both continuous wave (CW) and impulsive measurements. In the initial phase of the experimental work, five helical samples were constructed and evaluated. In the second phase of the study, one sample was chosen for more detailed quantitative measurements. In …

Modernizing Legacy Business Practices And Maintaining Backwards Compatibility When Replacing Legacy Software, Thomas Hillebrandt

Honors Theses

As technology advances and hardware as well as user expectations becomes more advanced, software systems must change alongside or go obsolete. When software is no longer developed, decisions must be made regarding its future. Through various methods, legacy software may continue to see usage far past its obsolescence, however legacy software will sooner or later face replacement by new applications, built for state-of-the-art machines, to comply with modern requirements. When writing new software to replace older programs, the added challenge for developers is to help the client also modernize their workflow. When a program has been in long time use …

Determination Of Metals And Microplastics In Sediment From Oyster Reefs In The Mississippi Sound, Shelby Goza

Honors Theses

This research centers on the determination of metals (Cd, Pb, V, Cr, Mn, Fe, Co, Ni, Cu) and microplastics (MPs) in marine sediment from oyster reefs in the Mississippi Sound Estuary. Oysters (Crassostrea virginica) are a vital part of the Gulf Coast economy, but their population has dramatically declined in recent years due to multiple stressors, including oil spills and fluctuations in salinity from flooding. Increasingly frequent flooding events also introduce high loads of MPs and sediments containing heavy metals from the Mississippi River. These pollutants can have deleterious effects on oyster biology; however, they have not been adequately …

Investigations Involving Mononuclear And Dinuclear Transition Metal Catalysts For Photochemical Carbon Dioxide Reduction, Ansu Edwards

Honors Theses

There is currently a global energy crisis, which is in desperate need of solutions. New energy sources are required that will not pollute as much as our longstanding reliance on nonrenewable fossil fuels as an energy source. This pollution involves large amounts of greenhouse gas emissions, predominantly carbon dioxide (CO₂), that contribute to environmental problems such as climate change. In this context, a fairly recent research direction to address this problem is the development of transition metal catalysts that can convert CO₂ into reduced carbon products that can serve as chemical fuels. This work focuses on the …

Applications Of Sodium Azide In The Synthesis Of Tetrazines And Hydrolysis Reactions, My Le

Honors Theses

The inverse electron demand Diels−Alder cycloadditions of heterocyclic azadienes have provided a robust methodology for synthesizing highly substituted and functionalized heterocycles. It is widely used in organic synthesis and the pharmaceutical industry in the divergent construction of screening libraries and bioorthogonal conjugation. Each heterocyclic azadiene was found to possess a unique reactivity toward different classes of dienophiles, display predictable modes of cycloaddition, and exhibit substantial substituent electronic effects impacting their intrinsic reactivity and cycloaddition regioselectivity. Synthesis of 1,2,4,5-tetrazine has been reported in the literature since the late 19th century, showing scientists' tremendous interest in its application.

Herein we attempt to …

Computational Investigation Of Stellar Cooling, Noble Gas Nucleation, And Organic Molecular Spectra, Jax Dallas

Honors Theses

Since the advent and optimization of the Hartree-Fock method, quantum chemistry has been utilized to investigate systems operating on timeframes and environments traditionally unavailable to bench-top chemistry. As computational methods have grown more robust and less time consuming, quantum chemistry has been utilized to investigate a range of fields, including the steadily growing discipline of computational astrochemistry. Through the lens of computational astrochemistry, chemistry that occurred billions of years ago can be explored with equal clarity to that which is currently happening in the cosmos. The work presented throughout this thesis is a series of investigations into different timeframes of …

Effects Of Halogen Bonding On 13c Nmr Shifts Of Various Tolan Species, Anthony Lybrand

Honors Theses

Halogen bonding is slowly becoming a more and more useful part of the world of chemistry and is beginning to be incorporated into various aspects of the chemical industry. This study’s purpose is to determine whether or not halogen bonding can cause any effect in the 13C NMR shifts. The specific purpose of this study is to determine whether these chemical shifts change when a Lewis Base is added to the dissolved sample. In order to do this, the tolan species (4-iodotolan and 4-chlorotolan) had to be synthesized. Once synthesized, the tolan species were analyzed via NMR. NMR data indicated …

Effects Of Crowding Agents On I-Motif Dna, Hayden Brines

Honors Theses

Deoxyribonucleic acid (DNA) is a well-known double stranded, helical, biological molecule. In addition to its more commonly known structure, DNA can also form more complicated structures like G-quadruplexes and i-motifs (iM). The iMs are formed by cytosine rich DNA and are a four stranded structure that is typically looped around itself. The iM formation is typically pH-dependent and is favored in more acidic conditions; the pKa value is approximately 6.5. This pKa value allows for potential in vivo formation, since the cells have a pH of approximately 7.3. Due to this, iMs are thought to be powerful, innovative molecules for …

End Group Modification Of Linear Dendritic Block Copolymers (Ldbcs), Chinwe Udemgba

Honors Theses

Linear dendritic block copolymers are amphiphilic molecules that consist of a dendritic hydrophilic portion and a linear hydrophobic portion. Its unique ability to self-assemble into spherical nanoaggregates while having the potential to uptake and transport both hydrophilic and hydrophobic drugs makes these polymers an item of interest in regard to the drug delivery field. The synthesis of polyamidoamine-polylactide linear dendritic block copolymers was designed to address the common issues in drug delivery systems, including problems in permeability, solubility, stability, specificity, and retention. Though this linear dendritic block copolymer has previously been synthesized in our lab with cationic amine surface functionalities, …

Isolating And Manipulating Microorganisms Using Ureolysis For Creating Extraterrestrial Microbial Biotechnology Systems, Nina M. Wendel

Honors Theses

The conversion of CO2 into valuable feedstocks, such as high energy sugars would create paradigm shifting technologies for applications on earth and for interplanetary exploration. Microbes and microbe consortia may be one way to accomplish this conversion. Approximately 70% of the Earth’s microorganisms live in the dark marine biosphere (DMB). The DMB, which covers more than two-thirds of the Earth, is known as the most isolated region of the Earth’s largest CO2 sink. Despite its role in reducing CO2 and its vast majority of microorganisms, only about 5% of the sea floor has been explored. Due to the limited knowledge …