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Articles 1 - 9 of 9
Full-Text Articles in Physical Sciences and Mathematics
Particulate And Dissolved Organic Matter In Stormwater Runoff Influences Oxygen Demand In Urbanized Headwater Catchments, Kelly M. Mccabe, Erik M. Smith, Susan Q. Lang, Claudia Benitez-Nelson
Particulate And Dissolved Organic Matter In Stormwater Runoff Influences Oxygen Demand In Urbanized Headwater Catchments, Kelly M. Mccabe, Erik M. Smith, Susan Q. Lang, Claudia Benitez-Nelson
Faculty Publications
Increasing inputs of organic matter (OM) are driving declining dissolved oxygen (DO) concentrations in coastal ecosystems worldwide. The quantity, source, and composition of OM transported to coastal ecosystems via stormwater runoff have been altered by land use changes associated with urbanization and subsequent hydrologic flows that accompany urban stormwater management. To elucidate the role of stormwater in the decline of coastal DO, rain event sampling of biochemical oxygen demand (BOD) in samples collected from the outfall of stormwater ponds and wetlands, as well as samples of largely untreated runoff carried by stormwater ditches, was conducted across a range of urban …
Short Term Effects Of Hurricane Irma And Cyanobacterial Blooms On Ammonium Cycling Along A Freshwater-Estuarine Continuum In South Florida, Justyna J. Hampel, Mark J. Mccarthy, Megan H. Reed, Silvia E. Newell
Short Term Effects Of Hurricane Irma And Cyanobacterial Blooms On Ammonium Cycling Along A Freshwater-Estuarine Continuum In South Florida, Justyna J. Hampel, Mark J. Mccarthy, Megan H. Reed, Silvia E. Newell
Faculty Publications
Lacustrine and coastal systems are vulnerable to the increasing number and intensity of tropical storms driven by climate change. Strong winds associated with tropical storms can mobilize nutrients in sediments and alter nitrogen and phosphorus cycling, leading to amplification of preexisting conditions, such as eutrophication and cyanobacterial blooms (cyanoHABs). In 2016, Florida declared a State of Emergency within and downstream of Lake Okeechobee (LO) due to toxic cyanobacterial blooms (primarily Microcystis). The blooms originated in LO, but flood control measures released water from LO to the brackish St. Lucie Estuary (SLE). In September 2017, Hurricane Irma traversed the Florida …
Expansion Of The Manage Database With Forest And Drainage Studies, Daren R. Harmel, Laura E. Christianson, Matthew W. Mcbroom, Douglas R. Smith, Kori D. Higgs
Expansion Of The Manage Database With Forest And Drainage Studies, Daren R. Harmel, Laura E. Christianson, Matthew W. Mcbroom, Douglas R. Smith, Kori D. Higgs
Faculty Publications
The “Measured Annual Nutrient loads from AGricultural Environments” (MANAGE) database was published in 2006 to expand an early 1980s compilation of nutrient export (load) data from cultivated and pasture/range land at the field or farm scale. Then in 2008, MANAGE was updated with 15 additional studies, and nitrogen (N) and phosphorus (P) concentrations in runoff were added. Since then, MANAGE has undergone significant expansion adding N and P water quality along with relevant management and site characteristic data from: (1) 30 runoff studies from forested land uses, (2) 91 drainage water quality studies from drained land, and (3) 12 additional …
Biogenic Nitrogen Gas Production At The Oxic–Anoxic Interface In The Cariaco Basin, Venezuela, E. Montes, M. A. Altabet, F. E. Muller-Karger, M. I. Scranton, R. C. Thunell, Claudia R. Benitez-Nelson, L. Lorenzoni, Y. M. Astor
Biogenic Nitrogen Gas Production At The Oxic–Anoxic Interface In The Cariaco Basin, Venezuela, E. Montes, M. A. Altabet, F. E. Muller-Karger, M. I. Scranton, R. C. Thunell, Claudia R. Benitez-Nelson, L. Lorenzoni, Y. M. Astor
Faculty Publications
Excess nitrogen gas (N2xs) was measured in samples collected at six locations in the eastern and western sub-basins of the Cariaco Basin, Venezuela, in September 2008 (non-upwelling conditions) and March 2009 (upwelling conditions). During both sampling periods, N2xs concentrations were below detection in surface waters, increasing to ~ 22 μmol N kg−1 at the oxic–anoxic interface ([O2] < ~ 4 μmol kg−1, ~ 250 m). Below the oxic–anoxic interface (300–400 m), the average concentration of N2xs was 24.7 ± 1.9 μmol N kg−1 in September 2008 and 27.5 ± 2.0 μmol N kg−1 in March 2009, i.e., N2xs concentrations within this depth interval were ~ 3 μmol N kg−1 higher (p < 0.001) during the upwelling season compared to the non-upwelling period. These results suggest that N-loss in the Cariaco Basin may vary seasonally in response to changes in the flux of sinking particulate organic matter. We attribute the increase in N2xs concentrations, or N-loss, observed during upwelling to: (1) higher availability of fixed nitrogen derived from suspended and sinking particles at the oxic–anoxic interface and/or (2) enhanced ventilation at the oxic–anoxic interface during upwelling.
Inorganic Nitrogen Transformations At High Loading Rates In An Oligohaline Estuary, R. Eugene Turner, Q. Dortch, Nancy N. Rabalais
Inorganic Nitrogen Transformations At High Loading Rates In An Oligohaline Estuary, R. Eugene Turner, Q. Dortch, Nancy N. Rabalais
Faculty Publications
A well-defined nitrogen retention and turnover budget was estimated for a shallow oligohaline lake (Lake Pontchartrain, Louisiana, USA). In 1997 a month-long diversion of the Mississippi River filled the Lake with highly concentrated river water (80 µM nitrate) and lowered the salinity to 0 psu within 2 weeks. After the spillway was closed the Lake mixed with estuarine tidal waters and came to equilibrium over 4 months with the riverine, atmospheric and offshore water nitrogen sources. A flushing rate of 1.78% d−1 was estimated by analyzing a plot of ln salinity versus time for the first 120 days after the …
Suspended Sediment, C, N, P, And Si Yields From The Mississippi River Basin, R. Eugene Turner, Nancy N. Rabalais
Suspended Sediment, C, N, P, And Si Yields From The Mississippi River Basin, R. Eugene Turner, Nancy N. Rabalais
Faculty Publications
The annual loads of C,N,P, silicate, total suspended sediment (mass) and their yields (mass area−1) were estimated for six watersheds of the Mississippi River Basin (MRB) using water quality and water discharge records for 1973 to 1994. The highest load of suspended sediments is from the Missouri watershed (58 mt km2 yr−1), which is also the largest among the six major sub-basins. The Ohio watershed delivers the largest load of water (38%). The Upper Mississippi has the largest total nitrogen load (32%) and yield (1120 kg TN km2 yr−1). The loading of organic carbon, total phosphorus and silicate from the …
First-Principles Calculations For Nitrogen-Containing Single-Walled Carbon Nanotubes, James P. Lewis, Mingwen Zhao, Yueyugan Xia, Ruiqin Zhang
First-Principles Calculations For Nitrogen-Containing Single-Walled Carbon Nanotubes, James P. Lewis, Mingwen Zhao, Yueyugan Xia, Ruiqin Zhang
Faculty Publications
We present calculations for possible configurations of nitrogen-containing single-walled carbon nanotubes and their electronic properties obtained with the ab initio tight-binding FIREBALL method. It is found that nitrogen atoms can be energetically incorporated into the carbon network in three forms: Substitution, substitution with formation of a vacancy structure, and chemical adsorption. The different forms exhibit different local densities of states near the Fermi levels, which might suggest a potential method to control the electronic properties of nitrogen-doped carbon nanotubes
Global Patterns Of Dissolved N, P And Si In Large Rivers, R. Eugene Turner, Nancy N. Rabalais, D. Justic', Q. Dortch
Global Patterns Of Dissolved N, P And Si In Large Rivers, R. Eugene Turner, Nancy N. Rabalais, D. Justic', Q. Dortch
Faculty Publications
The concentration of dissolved inorganic nitrogen (DIN), dissolved nitrate-N, Total-N (TN), dissolved inorganic phosphate (DIP), total phosphorus (TP), dissolved silicate-Si (DSi) and their ratios in the world's largest rivers are examined using a global data base that includes 37% of the earth's watershed area and half its population. These data were compared to water quality in 42 subbasins of the relatively well-monitored Mississippi River basin (MRB) and of 82 small watersheds of the United States. The average total nitrogen concentration varies over three orders of magnitude among both world river watersheds and the MRB, and is primarily dependent on variations …
The Impact Of Accelerating Land-Use Change On The N-Cycle Of Tropical Aquatic Ecosystems: Current Conditions And Projected Changes, J. A. Downing, M. Mcclain, R. Twilley, J. M. Melack, J. Elser, Nancy N. Rabalais, W. M. Lewis Jr., R. Eugene Turner, J. Corredor, D. Soto, A. Yanez Arancibia, J. A. Kopaska, R. W. Howarth
The Impact Of Accelerating Land-Use Change On The N-Cycle Of Tropical Aquatic Ecosystems: Current Conditions And Projected Changes, J. A. Downing, M. Mcclain, R. Twilley, J. M. Melack, J. Elser, Nancy N. Rabalais, W. M. Lewis Jr., R. Eugene Turner, J. Corredor, D. Soto, A. Yanez Arancibia, J. A. Kopaska, R. W. Howarth
Faculty Publications
Published data and analyses from temperate and tropical aquatic systems are used to summarize knowledge about the potential impact of land-use alteration on the nitrogen biogeochemistry of tropical aquatic ecosystems, identify important patterns and recommend key needs for research. The tropical N-cycle is traced from pre-disturbance conditions through the phases of disturbance, highlighting major differences between tropical and temperate systems that might influence development strategies in the tropics. Analyses suggest that tropical freshwaters are more frequently N-limited than temperate zones, while tropical marine systems may show more frequent P limitation. These analyses indicate that disturbances to pristine tropical lands will …