Physical Sciences and Mathematics Commons^™

Knot Flow Classification And Its Applications In Vehicular Ad-Hoc Networks (Vanet), David Schmidt

Electronic Theses and Dissertations

Intrusion detection systems (IDSs) play a crucial role in the identification and mitigation for attacks on host systems. Of these systems, vehicular ad hoc networks (VANETs) are difficult to protect due to the dynamic nature of their clients and their necessity for constant interaction with their respective cyber-physical systems. Currently, there is a need for a VANET-specific IDS that meets this criterion. To this end, a spline-based intrusion detection system has been pioneered as a solution. By combining clustering with spline-based general linear model classification, this knot flow classification method (KFC) allows for robust intrusion detection to occur. Due its …

Synthesis And Characterization Of Carbon Monoxide Producers Bipyridine Flavonolate Palladium(Ii) And Platinum(Ii) Complexes: Potential Anti-Cancer Agents, Sarah Whitfield

Electronic Theses and Dissertations

Novel designed metal ligand complexes as prodrugs are useful in the effort to find more effective and selective anti-cancer treatments. Carbon monoxide, CO, is known to induce mitochondrial collapse in cancer cells. Herein is described the synthesis of seven novel bipyridine flavonolate palladium(II) and platinum(II) complexes with the property of releasing carbon monoxide, and their characterization with FTIR, UV-Vis, fluorescence, NMR, and ESI mass spectra. Their ability to release carbon monoxide was investigated through oxygenation reaction under various conditions of temperature and light irradiation. The nitroxygenation reaction of the palladium complexes was also studied with nitrosyl hydride, HNO, generated in …

Characterization Of Surface Karst Using Lidar And Field Traverses, Fort Hood Military Installation, Coryell County, Texas, Heather Jaclyn Dailey

Electronic Theses and Dissertations

The Fort Hood Military Installation is a karst landscape that has been significantly altered for training exercises that include heavy vehicle maneuvers and simulated combat. Traditional karst surveys are often time-consuming and require extensive field analyses to adequately characterize large areas. Bias is given to areas that are most easily accessible and false negatives are common. Previous studies conducted in the eastern and western portion of the base have understated the abundance and spatial distribution of karst, particularly in the western portion.

This study used field traverses and 0.5-meter Light Detection and Ranging (LiDAR) data to characterize surface karst depressions, …

Applications Of Digital Remote Sensing To Quantify Glacier Change In Glacier And Mount Rainier National Parks, Brianna Clark

Electronic Theses and Dissertations

Digital remote sensing and geographic information systems were employed in performing area and volume calculations on glacial landscapes. Characteristics of glaciers from two geographic regions, the Intermountain Region (between the Rocky Mountain and Cascade Ranges) and the Pacific Northwest, were estimated for the years 1985, 2000, and 2015. Glacier National Park was studied for the Intermountain Region whereas Mount Rainier National Park was representative of the glaciers in the Pacific Northwest. Within the thirty year period of the study, the glaciers in Glacier National Park decreased in area by 27.5 percent while those on Mount Rainier only decreased by 5.7 …

Using Saddlepoint Approximations And Likelihood-Based Methods To Conduct Statistical Inference For The Mean Of The Beta Distribution, Bryn Brakefield

Electronic Theses and Dissertations

The prevalence of conducting statistical inference for the mean of the beta distribution has been rising in various fields of academic research, such as in immunology that analyzes proportions of rare cell population subsets. For our purposes, we will address this statistical inference problem by using likelihood-based applications to hypothesis testing, along with a relatively new statistical method called saddlepoint approximations. Through simulation work, we will compare the performance of these statistical procedures and provide both the statistical and scientific communities with recommendations on best practices.

A Novel Mathematical Model Of The Trojan Y-Chromosome Strategy With Optimal Control, Christopher Turner

Electronic Theses and Dissertations

Invasive species are a prevalent problem all over the world. Controlling and eradicating an invasive species is an even more diffcult problem. The Trojan Y Chromosome (TYC) eradication strategy is one control method. This method alters the female to male sex ratio by introducing sex reversed males called supermales. These sex reversed males can only produce male progeny. Mathematical models of this strategy have shown that a population can be driven to extinction with a continuous supply of these sex reversed males. There are many different mathematical models of this strategy, but most have serious flaws, such as negative solutions …

Functional Nanomaterials By Combining Aminooxy Chemistry And Iodine Activation At Momolayer Protected Clusters., Tirtha Raj Sibakoti

Electronic Theses and Dissertations

Aminooxy (-ONH₂) groups are most commonly known for their chemoselective reaction with carbonyl compounds (aldehydes/ketones) under mild reaction conditions. Aminooxy-based click chemistry is a versatile means of ligation as evidenced by broad application in material science, biology, biochemistry, analytical chemistry, and nanoscience. Our work exploits the facile reaction of aminooxy groups presented on the surface of gold (Au) or palladium (Pd) monolayer protected clusters (MPCs) with various aldehydes via oximation reactions, which form the robust oxime ether adducts. The functionalization of hexanethiolate-stabilized Au MPCs with a newly developed trifunctional amine-containing aminooxy alkanethiol ligand by thiol place-exchange affords aminooxylated …

Computational Modeling Of Photolysis And Catalysis Reactions In Vitamin B12-Dependent Enzymes., Abdullah Al Mamun

Electronic Theses and Dissertations

Vitamin B₁₂ is a complex organometallic molecule, the derivatives of which such as adenosylcobalamin (AdoCbl) and methylcobalamin (CH₃Cbl) act as a cofactor in numerous enzymatic reactions. These two biologically active cofactors contain a unique organometallic Co-C σ bond. Important feature of this Co-C bond is that it can be activated by both thermally and photolytically inside the enzymatic environment as well as in the solution. In the case of enzymatic reactions where AdoCbl molecule act as a cofactor, the cleavage of the Co-C bond constitutes the key catalytic step. The most intriguing features of this cleavage is …

Novel Bayesian Methodology For The Analysis Of Single-Cell Rna Sequencing Data., Michael Sekula

Electronic Theses and Dissertations

With single-cell RNA sequencing (scRNA-seq) technology, researchers are able to gain a better understanding of health and disease through the analysis of gene expression data at the cellular-level; however, scRNA-seq data tend to have high proportions of zero values, increased cell-to-cell variability, and overdispersion due to abnormally large expression counts, which create new statistical problems that need to be addressed. This dissertation includes three research projects that propose Bayesian methodology suitable for scRNA-seq analysis. In the first project, a hurdle model for identifying differentially expressed genes across cell types in scRNA-seq data is presented. This model incorporates a correlated random …

Analyzing The Effects Of Of Seasonal Land Cover And Precipitation On The Sediment Delivery Ratio Of An Agriculture Dominated Watershed., Jonah Liebman

Electronic Theses and Dissertations

Soil erosion is of escalating importance as increasing population and climate change have put increasing pressures on agricultural food production. Vegetation and precipitation are two factors that control the amount of soil erosion extant within a region. Sediment delivery ratios (SDRs) assess the ratio of soil eroded from a watershed system that is permanently removed from the system through stream sediment discharge. Using 1) river discharge and sediment concentration data and 2) the Revised Universal Soil Loss Equation (RUSLE), this thesis analyzes fluctuations in monthly SDRs for an average hydroclimatological crop-harvest season for the Senachwine Creek watershed, IL. Through calculating …

Electrochemical Reduction Of Carbon Dioxide And Carbon Monoxide For The Production Of Green Fuels And Chemicals., Jacob M. Strain

Electronic Theses and Dissertations

It has become apparent that closing the carbon cycle on this planet in order to mitigate disastrous consequences of runaway global warming has become one of the most pressing issues of our civilization. One of the ways we need to accomplish this goal is by finding news methods to generate fuels that will be carbon neutral. Renewable fuels and green chemicals will be a major component of closing the carbon cycle and restoring our planet’s ecosystem into a sense of balance. A method that can help achieve this goal is the reduction of CO₂. If CO₂ can …

Assessing Predictors Of Harmful Algal Blooms In The Western Lake Erie Basin., Katherine M. Weigle

Electronic Theses and Dissertations

Harmful algal blooms (HABs) have been a recurring issue in the Western Lake Erie Basin for more than a decade, despite policies implemented to improve the water quality of the Great Lakes. HABs describe algae that can be harmful to both ecosystem function and human health. The Western Lake Erie Basin, in particular, experiences Microcystis aeruginosa blooms in the summer months due to a multitude of factors leading to increased phosphorus and nitrogen loads in the contributing watersheds. In this study, lake water surface temperature, land cover, river discharge, and precipitation were examined as potential triggers for the occurrence and …

The Effect Of Radium Partitioning On Hydrothermal Fluid Flow Determination Across Guaymas Basin, Charlotte R. Kollman

Electronic Theses and Dissertations

Analysis of the distribution of radium through sedimentary porewater profiles is a promising method for constraining diffuse discharge/recharge flow rates in hydrothermal settings; these parameters are critical for evaluating hydrothermal circulation and its chemical and biological implications. The short-lived 224Ra (T1/2 = 3.54 days) is an effective tracer due to its behavior in marine environments and changes in activity due to ingrowth/decay. However, the distribution of radium may be influenced by its varying solid:aqueous partitioning coefficients (Kd) and is critical to understand for any study utilizing radium as a tracer. This project explores Kd across the hydrothermally active Guaymas Basin …

Community Involvement In Flood Mitigation: A Survey-Based Approach In Marion County, Sc, Lillian C. Howie

Electronic Theses and Dissertations

Marion County is located in northern South Carolina between the Great Pee Dee and Little Pee Dee Rivers. Because Marion County was the location of severe flooding during hurricanes Matthew (2016) and Florence (2018), the South Carolina Floodwater Commission identified Marion County as a location for drainage system improvement by the Infrastructure and Shoreline Armoring Task Force. In order to align plans for drainage system improvement with the needs of the local communities, commission chairman Thomas Mullikin requested a community survey to gauge the residents' personal experiences and views on what changes should be made to address the problem. The …

Investigating Dorsal Fin Hydrodynamic Function Of The Lemon Shark, Negaprion Brevirostris, Vivian Lynn Turner

Electronic Theses and Dissertations

Many sharks are considered highly efficient swimmers. Their swimming efficiency is partially governed by their morphological features such as dorsal fins, which play a role in their hydrodynamics. Most sharks feature two dorsal fins that can vary in size and location over the body. The first dorsal fin has been shown to improve stabilization, maneuverability, and increase thrust production during swimming, whilst the hydrodynamic role of the second dorsal fin is largely unknown. An understanding of the hydrodynamic function of the dorsal fins can be utilized in engineering applications, e.g., to replicate fins on underwater autonomous vehicles to increase energy …

Temporal Transport Dynamics Of The Amazon River Plume Revealed Using Radium Isotope Analysis, Elana J. Ames

Electronic Theses and Dissertations

The Amazon River is the largest river by discharge in the world. It carries terrestrial nutrients into the Western Tropical North Atlantic via a buoyant freshwater plume, conveying water hundreds to thousands of kilometers away and driving critical biogeochemical cycles near the coast. Factors controlling the delivery of nutrients offshore by the plume are complicated and interconnected, yet these nutrients impact the foundation of phytoplankton community structures across the entire plume ecosystem. To better understand the temporal dynamics of this massive, highly influential region, we employ naturally occurring radium isotopes (223Ra, 224Ra, 226Ra, and 228Ra) to analyze mixing and transport …

Controlling Transition Metal-Catalyzed Alkyne Annulations Utilizing Polarized Ynol Ethers, Brandon L. Coles-Taylor

Electronic Theses and Dissertations

Transition metal-catalyzed alkyne annulations have developed into incredibly powerful synthetic tools over there the past quarter century. These reactions provide rapid access to important organic scaffolds such as indole, quinoline, isoquinoline, indene, and isocoumarin scaffolds. Transition metal mediated alkyne annulations have proven invaluable in synthetic fields, such as natural product total synthesis, by offering efficient pathways to otherwise synthetically difficult to access substrates.

Foundational works performed by chemist such as Larock, Ackermann, Satoh, and Miura have been established through relying upon the usage of symmetrical alkynes. When unsymmetrical alkynes are used in annulation processes mixtures of regioisomers are often isolated. …

Examining Artifacts Of The Watershed Segmentation, Emily Jo Armitage

Electronic Theses and Dissertations

The watershed segmentation is an algorithm used to systematically track cell intercalary behaviors during germ band extension of the Drosophila embryo. Neighboring cells share a contracting vertical interface, called a T1, which continues contracting to a single point, a T2, and extending in the horizontal direction to create what is called a T3 interface (Fig. 1). Additionally, higher order vertices called rosettes occur when five or more cells meet at a common vertex. Simulated T2 events demonstrate that cell angle and not noise level in the image contributes to the incorrect detection of artifactual T1s in more acute angled cells …

Iron In Urban Air Pollution, Joseph R. Salazar

Electronic Theses and Dissertations

The processes by which iron is solubilized are largely unknown. There are three hypotheses on how iron is soluble: 1) iron is thought to undergo an acid based solubilization process, 2) iron undergoes an oxidation/reduction process and reduces iron(III) to the more soluble iron(II), and 3) iron is bound to organic molecules, which solubilizes it. The 3 hypotheses on iron water-solubilized are explored by presenting two individual studies.

The first study investigates iron directly from car exhaust. Exhaust particles were collected from 32 vehicles. Iron solubility in these samples ranged from 0%-82% with the average iron solubility being 30%. X-ray …

Urban Informality, Environmental Xenophobia, And Infrastructures Of Citizenship: The Political Lives Of Nicaraguan Migrants In The Informal Settlement Of La Carpio, Costa Rica, Nikolai Alexander Alvarado

Electronic Theses and Dissertations

This dissertation examines urban politics, environmental justice, and infrastructure from the vantage point of South-South migration. It focuses on the work of Nicaraguan migrants living in the informal settlement of La Carpio in San José, Costa Rica, as they negotiate rights in the form of urban services. Nicaraguans in La Carpio have organized politically since 1993 to self-install, demand, and negotiate services such as potable water and electricity. In the process, they successfully compel local authorities to allocate these services and grant them an implicit recognition of their right to remain and live a decent life, regardless of their status. …

Investigating New Methods To Develop Perovskite Solar Cells, Amani Hussain Alfaifi

Electronic Theses and Dissertations

Discovering the potential of organic-inorganic metal halide perovskites (MHP) as a harvesting material in solar cells has strongly affected the research direction in solar energy. The fascinating optical and electronic properties offered by MHP combined with tremendous effort from scientists around the world have improved the efficiency to about 25% in a decade.

In the first part of the dissertation, we studied the lamination process as a new fabrication method for producing self-encapsulated perovskite solar cells based on laminating half stacks,as opposed to the conventional layer-by-layer method. Our work focused on optimizing the lamination process of complex triple cations perovskite …

Using Natural Language Processing To Categorize Fictional Literature In An Unsupervised Manner, Dalton J. Crutchfield

Electronic Theses and Dissertations

When following a plot in a story, categorization is something that humans do without even thinking; whether this is simple classification like “This is science fiction” or more complex trope recognition like recognizing a Chekhov's gun or a rags to riches storyline, humans group stories with other similar stories. Research has been done to categorize basic plots and acknowledge common story tropes on the literary side, however, there is not a formula or set way to determine these plots in a story line automatically. This paper explores multiple natural language processing techniques in an attempt to automatically compare and cluster …

The Effects Of Adverse Childhood Experiences On Behavioral Outcomes, Jennifer Thomas

Electronic Theses and Dissertations

This study intends to explore the intersection of two vulnerable populations, early childhood development and risks associated with exposure to adverse childhood experiences (ACEs). This study examines how age plays a role in the long-term relationship between ACEs and internal and external behaviors. This study seeks to answer the question of: How does age influence the relationship between number of ACEs and internal and external behaviors? The participants in this study include those aged 0 – 16 from the National Survey of Child and adolescent Well-Being (NSCAW) dataset. The NSCAW study consists of five waves of data where Wave I …

Deep Reinforcement Learning For The Optimization Of Building Energy Control And Management, Jun Hao

Electronic Theses and Dissertations

Most of the current game-theoretic demand-side management methods focus primarily on the scheduling of home appliances, and the related numerical experiments are analyzed under various scenarios to achieve the corresponding Nash-equilibrium (NE) and optimal results. However, not much work is conducted for academic or commercial buildings. The methods for optimizing academic-buildings are distinct from the optimal methods for home appliances. In my study, we address a novel methodology to control the operation of heating, ventilation, and air conditioning system (HVAC).

We assume that each building in our campus is equipped with smart meter and communication system which is envisioned in …

Spatial And Temporal Controls On Streamflow Variability In The San Juan Mountains, Colorado, Christopher Lewis Hancock

Electronic Theses and Dissertations

This project characterizes and examines changes to the annual hydroclimatic cycle throughout alpine regions of Colorado with a focus on trends in snowpack and snowmelt hydrology. Datasets analyzed for this research include 79 SNOTEL sites throughout Colorado (24 in the San Juan Mountains) which provide climate metrics for Water Years 1988-2018. Impacts on streamflow are evaluated in the San Juan Region through a network of 11 USGS stream gauges. Correlation matrices and linear regression methods examine the relative controls on the magnitude and timing of discharge, and trend detection using the regional Kendall test quantifies the rate of change within …

The Interplay Between Economic Growth And The Environment: The Case Of China, Christian D. Carpio-Thomas

Electronic Theses and Dissertations

Historically, economic development has come at the cost of environmental degradation. Since the 1980s, neoliberalism rooted in neoclassical theory has dominated mainstream economic thought. The result has been a dramatic increase in environmental degradation in favor of economic growth. The neoliberal recommendations toward development are encapsulated in the Washington and post-Washington Consensuses which promote the liberalization of trade and foreign investment as well as a reliance on market mechanisms. Ultimately, the goal of neoliberalism is to generate growth regardless of the impact that it places on the environment. The case of China presents an example of an economy which pursued …

Gas Adsorption In Carbon Nanohorns: Equilibrium And Kinetics, Justin Matthew Petucci

Electronic Theses and Dissertations

A study of gas adsorption has been carried out with the focus of better understanding the relationships between the individual properties of the adsorbent/adsorbate (e.g. material structure, interactions, gas size and shape, etc.) and the overall adsorptive properties of the combined system (e.g. capacity, binding strength, equilibration time, etc.) as a function of thermodynamical variables. This is useful from the perspective of a comprehensive and fundamental understanding as well as for practical applications. The equilibrium regime of adsorption on carbon nanostructure materials (nanohorns, nanotubes, and graphite) is investigated using molecular statics (MS) and grand canonical monte carlo (GCMC) methods for …

Automated Change Detection In Privacy Policies, Andrick Adhikari

Electronic Theses and Dissertations

Privacy policies notify Internet users about the privacy practices of websites, mobile apps, and other products and services. However, users rarely read them and struggle to understand their contents. Also, the entities that provide these policies are sometimes unmotivated to make them comprehensible. Due to the complicated nature of these documents, it gets even harder for users to understand and take note of any changes of interest or concern when these policies are changed or revised.

With recent development of machine learning and natural language processing, tools that can automatically annotate sentences of policies have been developed. These annotations can …

Instrument And Application Development In Saturation Recovery And Rapid Scan Electron Paramagnetic Resonance, Joseph E. Mcpeak

Electronic Theses and Dissertations

Enhanced signal sensitivity by the use of Rapid Scan (RS) electron paramagnetic resonance (EPR), a technique that allows for much faster magnetic field scans than traditional field-swept techniques, has facilitated improved data acquisition for many types of samples. For example, irradiated fingernails for radiation dosimetry have been studied using RS-EPR, which resulted in substantial decreases in detection limits. Samarium-mediated reduction mechanisms in organic synthesis have been investigated by RS-EPR providing evidence for a radical intermediate. Spectra of organic radicals exhibiting both narrow lines and closely spaced hyperfine interactions have been recorded via RS-EPR. Well-resolved spectra can be recorded at a …

Development Towards An Ethylene Sensing Artificial Metalloenzyme, Mitchell Lee Ellinwood

Electronic Theses and Dissertations

Ethylene (ethene) is the essential ripening hormone for climacteric plants, and consequently its detection and quantification is of considerable interest to the horticulture industry. Its detection however is a non-trivial pursuit, traditionally requiring expensive and inaccessible instrumentation that fail to provide in vivo information about ethylene. A ruthenium based fluorescent probe for the selective detection of ethylene has recently been developed, and it was envisioned that this probe could be made biocompatible by encasing it within a protein scaffold making it an artificial metalloenzyme. To this end biotinylated N-heterocyclic carbenes (NHCs) were synthesized, which can be appended onto the ruthenium …