Physical Sciences and Mathematics Commons^™

Synthesis Of Chiral Surfactants For Enantioselective Organic Synthesis., Kalyan Mondal

Electronic Theses and Dissertations

The first step of the synthesis of the hydrocarbon-based chiral surfactant (2) involved the methylation of (S)-leucinol to give (2S)-N-hexadecyl-N,N-dimethyl-(1-hydroxy-4-methyl-1-pentyl)-2-ammonium bromide (2.92g, 67%). The chiral surfactant was synthesized by reacting (2S)-N,N-dimethyl-2-amino-4-methyl-1-pentanol (1) with bromohexadecane (2.06g, 71%). The functionalized styrene for the polymer supported chiral catalyst (6) was synthesized by reacting (1) with 4-vinylbenzyl chloride. The polymerization was carried out with 10% of the functionalized monomer (5) (1.26g, 70.2%), 5% cross-linking agent divinylbenzene, and 85% of styrene with AIBN as the initiator. The structure of each of the products was confirmed by using FTIR and NMR spectroscopy. The activity of the …

Placing Monitoring Devices In Electric Power Networks Modeled By Block Graphs., David Wayne Atkins

Electronic Theses and Dissertations

The problem of monitoring an electric power system by placing as few measurement devices in the system as possible is closely related to the well known vertex covering and dominating set problems in graph theory. A set S of vertices is defined to be a power dominating set of a graphs if every vertex and every edge in the system is monitored by the set S (following a set of rules for power system monitoring). The minimum cardinality of a power dominating set of a graph is its power domination number. In this thesis, we investigate the power domination number …

Winning An Independence Achievement Game., Mark C. Taylor

Electronic Theses and Dissertations

The game "Generalized Kayles (or Independence Achievement)" is played by two players A and B on an arbitrary graph G. The players alternate removing a vertex and its neighbors from G, the winner being the last player with a nonempty set from which to choose. In this thesis, we present winning strategies for some paths.

Spectroscopic Examination Of The Catalytic Decomposition Of Hydrogen Peroxide By A Copper (Ii) Complex Of A Dissymmetric Schiff Base And An Imidazole Derivative., John D. Davis Jr.

Electronic Theses and Dissertations

Previous studies involving copper (II) complexed with a dissymmetric Schiff base and imidazole derivatives had identified catalase activity of these complexes towards H₂O₂. Reactions such as this are of great interest due to the important role of copper-based complexes in biological systems. Our research has been conducted to add to the base of knowledge regarding the efforts of other researchers to investigate copper complexes that exhibit similar reactivity as copper-based proteins towards dioxygen. The copper complex chosen for this study contained a tri-dentate Schiff base adduct which, when complexed with an imidazole derivative, limited the manner …

A Re-Evaluation Of The Us Epa Radon Risk Categorization For Unicoi County, Tennessee., William Grant Parsons

Electronic Theses and Dissertations

Effective risk communication is based on appropriate risk characterization. A reevaluation of the 1987 US EPA radon risk categorization of Unicoi County Tennessee was conducted using in-home radon concentrations, determined in a long-term monitoring study. Radon concentrations were measured in 69 homes using Electret Passive Environmental Radon Monitors (E-PERM’s), following standard methods. Radon concentrations determined in this study (avg. 4.03 ± 3.04) were significantly higher than those measured in the USEPA study (avg. 1.96 ± 1.08). Using this study’s data, the risk categorization was recalculated with the US EPA Radon Index Matrix Model. The model re-categorized Unicoi County from a …

Application Adaptive Bandwidth Management Using Real-Time Network Monitoring., Amit Grover

Electronic Theses and Dissertations

Application adaptive bandwidth management is a strategy for ensuring secure and reliable network operation in the presence of undesirable applications competing for a network’s crucial bandwidth, covert channels of communication via non-standard traffic on well-known ports, and coordinated Denial of Service attacks. The study undertaken here explored the classification, analysis and management of the network traffic on the basis of ports and protocols used, type of applications, traffic direction and flow rates on the East Tennessee State University’s campus-wide network. Bandwidth measurements over a nine-month period indicated bandwidth abuse of less than 0.0001% of total network bandwidth. The conclusion suggests …

Categorizing Non-Functional Requirements Using A Hierarchy In Uml., James David Moody

Electronic Theses and Dissertations

Non-functional requirements (NFRs) are a subset of requirements, the means by which software system developers and clients communicate about the functionality of the system to be built. This paper has three main parts: first, an overview of how non-functional requirements relate to software engineering is given, along with a survey of NFRs in the software engineering literature. Second, a collection of 161 NFRs is diagrammed using the Unified Modelling Language, forming a tool with which developers may more easily identify and write additional NFRs. Third, a lesson plan is presented, a learning module intended for an undergraduate software engineering curriculum. …

Parameter Estimation For A Modified Cable Model Using A Green's Function And Eigenvalue Perturbation., Scott Lewis La Voie

Electronic Theses and Dissertations

In this thesis we developed the Green's Function for a tapered equivalent cylinder model of dendritic electrical propagation. We then use the Green's Function to develop a Carleman linear embedding scheme which is used to estimate the effects of a nonlinear ion channel hot-spot on the tapered cylinder solution. Mathematica^© was used to implement the Carleman embedding scheme.

Bounds On Total Domination Subdivision Numbers., Lora Shuler Hopkins

Electronic Theses and Dissertations

The domination subdivision number of a graph is the minimum number of edges that must be subdivided in order to increase the domination number of the graph. Likewise, the total domination subdivision number is the minimum number of edges that must be subdivided in order to increase the total domination number. First, this thesis provides a complete survey of established bounds on the domination subdivision number and the total domination subdivision number. Then in Chapter 4, new results regarding bounds on the total domination subdivision number are given. Finally, a characterization of the total domination subdivision number of caterpillars is …

Factors In The Design And Development Of A Data Warehouse For Academic Data., Margaret C. Lester

Electronic Theses and Dissertations

Data warehousing is a relatively new field in the realm of information technology, and current research centers primarily around data warehousing in business environments. As new as the field is in these environments, only recently have educational institutions begun to embark on data warehousing projects, and little research has been done regarding the special considerations and characteristics of academic data, and the complexity of analyzing such data. Educational institutions measure success very differently from business-oriented organizations, and the analyses that are meaningful in such environments pose very unique and intricate problems in data warehousing. This research describes the process of …

Extensions To Opengl For Cagd., Chunyan Ye

Electronic Theses and Dissertations

Many computer graphic API’s, including OpenGL, emphasize modeling with rectangular patches, which are especially useful in Computer Aided Geomeric Design (CAGD). However, not all shapes are rectangular; some are triangular or more complex. This paper extends the OpenGL library to support the modeling of triangular patches, Coons patches, and Box-splines patches. Compared with the triangular patch created from degenerate rectangular Bezier patch with the existing functions provided by OpenGL, the triangular Bezier patches can be used in certain design situations and allow designers to achieve high-quality results that are less CPU intense and require less storage space. The addition of …

Relative Invertebrate Availability In Nebraska's Conservation Reserve Management Access Program, Ronald J. Leathers

Electronic Theses and Dissertations

The Conservation Reserve Management Access Program (CRP-MAP) is a joint effort of the Nebraska Game and Parks Commission and Pheasants Forever of Nebraska that seeks to address brood habitat needs of pheasants (Phasianus colchicus) and other grassland birds by light disking and interseeding legumes into portions of aging CRP fields. The program has two specific goals - increasing the total invertebrate availability as a food source for pheasant chicks and increasing the structural complexity of vegetation. This study compares invertebrate biomass and structural complexity of vegetation in treated (disked and interseeded with legumes) and idle portions of CRP-MAP fields to …

Data Mining With Newton's Method., James Dale Cloyd

Electronic Theses and Dissertations

Capable and well-organized data mining algorithms are essential and fundamental to helpful, useful, and successful knowledge discovery in databases. We discuss several data mining algorithms including genetic algorithms (GAs). In addition, we propose a modified multivariate Newton's method (NM) approach to data mining of technical data. Several strategies are employed to stabilize Newton's method to pathological function behavior. NM is compared to GAs and to the simplex evolutionary operation algorithm (EVOP). We find that GAs, NM, and EVOP all perform efficiently for well-behaved global optimization functions with NM providing an exponential improvement in convergence rate. For local optimization problems, we …

Models And Graphics In The Analysis Of Categorical Variables: The Case Of The Youth Tobacco Survey., Deborah Susan Hosler

Electronic Theses and Dissertations

Youth Tobacco Surveys have been conducted in several states in the U.S. in recent years, in order to design policies with the goal of reducing tobacco use among young people. Some primary analysis of those surveys has been done, but few analyses include modeling, and the study of independence has been addressed, mainly, in the bivariate context.

In this work contemporary methods, which are of relative recent appearance in categorical data analysis, will be examined, including logistic and log-linear modeling as well as graphical displays and correspondence analysis. These methods will be applied to data from the 2000 Tennessee Youth …

On The Construction Of Linear Prewavelets Over A Regular Triangulation., Qingbo Xue

Electronic Theses and Dissertations

In this thesis, all the possible semi-prewavelets over uniform refinements of regular triangulations have been studied. A corresponding theorem is given to ensure the linear independence of a set of different pre-wavelets obtained by summing pairs of these semi-prewavelets. This provides efficient multiresolutions of the spaces of functions over various regular triangulation domains since the bases of the orthogonal complements of the coarse spaces can be constructed very easily.

Construction Of Piecewise Linear Wavelets., Jiansheng Cao

Electronic Theses and Dissertations

It is well known that in many areas of computational mathematics, wavelet based algorithms are becoming popular for modeling and analyzing data and for providing efficient means for hierarchical data decomposition of function spaces into mutually orthogonal wavelet spaces. Wavelet construction in more than one-dimensional setting is a very challenging and important research topic. In this thesis, we first introduce the method of construction wavelets by using semi-wavelets. Second, we construct piecewise linear wavelets with smaller support over type-2 triangulations. Then, parameterized wavelets are constructed using the orthogonality conditions.

Coverage Properties Of The Inverse Sinh Transformation And The Adjusted Wald Confidence Intervals For The Odds Ratio And The Relative Risk., Troy Allen Bowman

Electronic Theses and Dissertations

The inverse sinh transformation on the Woolf interval is used to calculate the confidence interval for the odds ratio and the relative risk in a 2 x 2 table. According to Robert Newcombe, the new interval should improve the coverage probabilities and shorten the width of the confidence interval for these ratios, but the new interval requires evaluation of coverage properties. In this thesis, we will evaluate the exact coverage properties of this modified interval in extreme cases. Also, we will compare the coverage properties of this new interval to other widely-used adjusted intervals. Through comparisons of exact coverage probabilities …

Scalable And Reliable File Transfer For Clusters Using Multicast., Hardik Dikpal Shukla

Electronic Theses and Dissertations

A cluster is a group of computing resources that are connected by a single computer network and are managed as a single system. Clusters potentially have three key advantages over workstations operated in isolation—fault tolerance, load balancing and support for distributed computing.

Information sharing among the cluster’s resources affects all phases of cluster administration. The thesis describes a new tool for distributing files within clusters. This tool, the Scalable and Reliable File Transfer Tool (SRFTT), uses Forward Error Correction (FEC) and multiple multicast channels to achieve an efficient reliable file transfer, relative to heterogeneous clusters. SRFTT achieves scalability …

Integrated Software System For The Collection And Evaluation Of Wellness Information., Rebecca Elizabeth Sweeney

Electronic Theses and Dissertations

There is an absence of a complete, easy to use, software system that can evaluate all areas of wellness. Although there are software programs and equipment available to examine certain aspects of wellness, they are incomplete. The solution to the difficulties of assessing wellness is the design and development of a software system that can be used to collect and evaluate wellness information. The system allows for complete reporting as it entails the six major components to wellness: demographics, body composition, lab work, nutritional intake, physical activity, and body measures. The system allows for ease of use by providing a …

Comparison Of Inheritance Evaluation Algorithms For Express Edition 3., Judy Dawn Greer

Electronic Theses and Dissertations

Information exchanged between computer applications is difficult, thus the need for data exchange standards. The ISO STEP project defines data exchange standards using the EXPRESS language, which supports inheritance. Currently there are two algorithms used to evaluate an inheritance hierarchy: the Test and Generate algorithms. In this thesis, enhancements are made to both algorithms to support the Total Over Constraint, which is proposed for the third edition of EXPRESS. A formal algorithm is derived for the Test algorithm. The two enhanced algorithms are compared and shown to be result equivalent. However, it is shown that the Test algorithm is the …

Use Of High Pressure Liquid Chromatography To Detect And Quantify Oxytetracycline Marks In Walleye Otoliths And Dorsal Spines, Michael J. Hawkins

Electronic Theses and Dissertations

Oxytetracycline (OTC) is used to chemically mark calcified structures in walleye Stizostedion vitreum fry and fingerlings. Current visual methods for detection of these marks are subjective, and biologists are unable to quantify the amount of OTC in a sample. The goal of this study was to determine if high pressure liquid chromatography (HPLC) is a feasible and superior alternative for detecting and quantifying OTC in otoliths of fry-marked and spines of fingerlingmarked walleyes. Study objectives were to validate methodology of extraction of OTC from calcified tissue, detect and quantify extracted OTC using HPLC, and determine a cost comparison of current …

A Meta-Analysis And Risk Assessment Of Heavy Metal Uptake In Common Garden Vegetables., Trent David Lecoultre

Electronic Theses and Dissertations

Peer reviewed literature was searched to identify research pertaining to the uptake of heavy metals (As, Cd, Pb and Zn) by vegetables (cabbage, carrot, lettuce, and radish). The objectives of this research were to 1) determine the relationship between heavy metal concentrations in the soil and heavy metal concentrations in vegetables, and 2) determine the level of risk associated with exposure to heavy metals through ingestion of contaminated vegetables. Highly variable estimates and biologically implausible regression equations resulted from this meta-analysis. Exposure to arsenic through the ingestion of lettuce grown on contaminated soil significantly increases cancer risk, especially in children. …

Hazardous Materials Transportation Flow Survey: An Evaluation Of Hazardous Materials Transported In Washington County., Daniel John O'Brien

Electronic Theses and Dissertations

This study examines the transportation of hazardous materials through Washington County, Tennessee. This study incorporates federal, state, and local data in assessing current transportation trends. Data gathering activities included local chemical inventories, hazardous materials transportation flow surveys, hazardous materials rail transportation trends, and hazardous materials incident data.

All data were compiled and then analyzed to identify hazardous materials transportation trends in Washington County, Tennessee. This information is pertinent to emergency planners for the preparation of hazardous materials transportation incidents. The data gathered further revealed the need for this type of study to identify changing trends in the transportation of hazardous …

Image Compression By Wavelet Transform., Panrong Xiao

Electronic Theses and Dissertations

Digital images are widely used in computer applications. Uncompressed digital images require considerable storage capacity and transmission bandwidth. Efficient image compression solutions are becoming more critical with the recent growth of data intensive, multimedia-based web applications.

This thesis studies image compression with wavelet transforms. As a necessary background, the basic concepts of graphical image storage and currently used compression algorithms are discussed. The mathematical properties of several types of wavelets, including Haar, Daubechies, and biorthogonal spline wavelets are covered and the Enbedded Zerotree Wavelet (EZW) coding algorithm is introduced. The last part of the thesis analyzes the compression results to …

Using Software Engineering Metrics In Ap Modularization., Kwaku Owusu-Tieku

Electronic Theses and Dissertations

Significant amount of work has been done in software engineering in terms of reuse. With the use of object-orientation and design patterns that support the development of reusable modules, it appears that the development and reuse of software modules in creating new systems is becoming more and more common. The software engineering world, however has taken reuse more seriously than database; more research and improvement in reuse has been made in software engineering than in database. This paper investigates how software engineering metrics can be applied in the development of reusable database modules. This research provides a model for predicting …

Synthesis And Use Of Chiral Surfactants., Xiaoye Yang

Electronic Theses and Dissertations

It has been previously shown that micelles formed from surfactants with chiral head groups serve to induce a chiral reaction medium, leading to enhanced enantioselectivities in the reaction products. This utilization of chiral surfactants will offer an economical alternative to traditional chial solvents while simultaneously reducing organic waste. We have successfully dimethlated S-leucinol in an 85% yield, and have synthesized a hydrocarbon-based surfactant with this molecule as a head group. We have also formed polymeric surfactants that have polydimethylsiloxane as the hydrophobic portion with the (S)-dimethylleucinol as a head group. Tests of the solubility of these surfactants have been conducted. …

Theoretical Study On The Mechanism Of Removing Nitrogen Oxides Using Isocyanic Acid., Taraneh Nowroozi-Isfahani

Electronic Theses and Dissertations

The mechanism of RAPRENO_x reactions - RAPid REduction of Nitrogen Oxides using Isocyanic acid - proposed by Robert A. Perry¹ in an attempt to help control the emission of nitrogen oxides pollutant into the atmosphere, has been re-investigated theoretically. The study of reaction mechanisms was carried out using Chemist software². All mathematically possible elementary steps have been evaluated and the chemically reasonable ones have been considered to propose new sets of reaction mechanisms. Density Functional Theory (B3LYP/6-31 G**) calculations using Gaussian 98³ were made in order to study the relative energies of all species and …

Investigation Of Perceptions Of Environmental Management Systems And Its Perceived Importance In A Corporation Undergoing Iso 14001 Certification., Charlette Michelle Clark

Electronic Theses and Dissertations

The International Organization of Standardization (ISO) has created a series of voluntary standards (ISO 14000) which promote waste reduction and improve businesses’ environmental management. ISO 14001 is the Environmental Management System portion of ISO 14000 requiring employee awareness and involvement. The Robert Bosch Corporation is undergoing ISO 14001 certification.

In this study, a 23-question survey was used to evaluate Bosch employees’ awareness of ISO 14000 and their support of a waste reduction program at four plants (Johnson City, TN; Sumter, South Carolina; Ashland, Ohio; and South Bend, Indiana). Employees surveyed were not yet familiar with ISO 14000 and that their …

Life Annuities Under Random Rates Of Interest., Lesley J. Baker

Electronic Theses and Dissertations

We begin by examining the accumulated value functions of some annuities-certain. We then investigate the accumulated value of these annuities where the interest is a random variable under some restrictions. Calculations are derived for the expected value and the variance of these accumulated values and present values. In particular we will examine an annuity-due of k yearly payments of 1. Then we will consider an increasing annuity-due of k yearly payments of 1, 2, ⋯ , k. And finally, we examine a decreasing annuity-due of k yearly payments of n, n - 1, ⋯ , n - k …

Integration Of Student Academic Record And Major Requirements Through Xml., Zhujun Hou

Electronic Theses and Dissertations

The purpose of this thesis is to develop a software application based on previous studies by 1997 Oak Ridge Design Studio Team that matches students' progress with major requirements in their college career. This study addresses the problems of previous studies and suggests a solution. A powerful new technique, XML, is used to model, store and process the data of major requirements and student records. This application produces an HTML file that provides detailed information of a student's academic progress towards graduation.