Physical Sciences and Mathematics Commons^™

Reaction Rates For The Dehalogenation Of Trichloroethylene Using Various Types Of Zero-Valent Iron, Neil Stewart

Electronic Theses and Dissertations

Remediation of trichloroethylene (TCE) and other chlorinated solvents is of great concern due to their toxicity and their persistence in the environment. Iron has been used extensively in the past decade as a subsurface reactive agent for the remediation of dense, nonaqueous-phase liquids (DNAPLs). Permeable reactive barrier walls (PRBW) have been installed at many sites around the country to treat contaminated plumes resulting from the presence of DNAPL pools. The use of zero-valent metals, such as iron, to effectively reductively dechlorinate DNAPLs has been employed as the reactive material in these PRBWs (Gillham et al., 1993). However, limited work has …

Part I : Isolation Of Dipentyl 2-(4-(Pentan-3-Yl) Phenyl) Malonate From Sanguisorba Officinalis Labill Part Ii: Synthesis Of A Novel Family Of Ethers Of Podocarpic Acid, Manjeera Yalavarty

Electronic Theses and Dissertations

The goal of part I of this thesis was to isolate pure anti cancer compounds from the Russian plant Sanguisorba officinalis. This plant was selected for investigation because it showed 100% activity against leukemia (L1210 mouse leukemia cells) during the preliminary screening of approximately 100 Russian plant extracts. This work has resulted in the isolation of novel compound 11 using traditional chromatography techniques. Compound 11 was characterized with spectroscopic techniques such as IR, 1H NMR, 13C NMR, DEPT, DQCOSY and MS. Compound 11 was assigned the structure dipentyl 2-(4-(pentan-3-yl) phenyl) malonate. The goal of part II of this thesis was …

Planning And Scheduling For Large-Scaledistributed Systems, Han Yu

Electronic Theses and Dissertations

Many applications require computing resources well beyond those available on any single system. Simulations of atomic and subatomic systems with application to material science, computations related to study of natural sciences, and computer-aided design are examples of applications that can benefit from the resource-rich environment provided by a large collection of autonomous systems interconnected by high-speed networks. To transform such a collection of systems into a user's virtual machine, we have to develop new algorithms for coordination, planning, scheduling, resource discovery, and other functions that can be automated. Then we can develop societal services based upon these algorithms, which hide …

Graph-Theoretic Approach To Modeling Propagation And Control Of Network Worms, Zoran Nikoloski

Electronic Theses and Dissertations

In today's network-dependent society, cyber attacks with network worms have become the predominant threat to confidentiality, integrity, and availability of network computing resources. Despite ongoing research efforts, there is still no comprehensive network-security solution aimed at controling large-scale worm propagation. The aim of this work is fivefold: (1) Developing an accurate combinatorial model of worm propagation that can facilitate the analysis of worm control strategies, (2) Building an accurate epidemiological model for the propagation of a worm employing local strategies, (3) Devising distributed architecture and algorithms for detection of worm scanning activities, (4) Designing effective control strategies against the worm, …

Contributions To Automatic Particle Identification In Electron Micrographs: Algorithms, Implementation, And Applications, Vivek Singh

Electronic Theses and Dissertations

Three dimensional reconstruction of large macromolecules like viruses at resolutions below 8 Ã… - 10 Ã… requires a large set of projection images and the particle identification step becomes a bottleneck. Several automatic and semi-automatic particle detection algorithms have been developed along the years. We present a general technique designed to automatically identify the projection images of particles. The method utilizes Markov random field modelling of the projected images and involves a preprocessing of electron micrographs followed by image segmentation and post processing for boxing of the particle projections. Due to the typically extensive computational requirements for extracting hundreds of …

Multizoom Activity Recognition Using Machine Learning, Raymond Smith

Electronic Theses and Dissertations

In this thesis we present a system for detection of events in video. First a multiview approach to automatically detect and track heads and hands in a scene is described. Then, by making use of epipolar, spatial, trajectory, and appearance constraints, objects are labeled consistently across cameras (zooms). Finally, we demonstrate a new machine learning paradigm, TemporalBoost, that can recognize events in video. One aspect of any machine learning algorithm is in the feature set used. The approach taken here is to build a large set of activity features, though TemporalBoost itself is able to work with any feature set …

The Effects Of Electrode Geometry On Current Pulse Caused By Electrical Discharge Over An Ultra-Fast Laser Filament, Matthew Bubelnik

Electronic Theses and Dissertations

The time-resolved electrical conductivity of a short-pulse generated plasma filament in air was studied. Close-coupled metal electrodes were used to discharge the stored energy of a high-voltage capacitor and the resulting microsecond-scale electrical discharge was measured using fast current sensors. Significant differences in the time dependence of the current were seen with the two electrode geometries used. Using sharp-tipped electrodes additional peaks in the time-resolved conductivity were seen, relative to the single peak seen with spherical electrodes. We attribute these additional features to secondary electron collisional ionization brought about by field enhancement at the tips. Additional discrepancies in the currents …

An Introduction To Hellmann-Feynman Theory, David Wallace

Electronic Theses and Dissertations

The Hellmann-Feynman theorem is presented together with certain allied theorems. The origin of the Hellmann-Feynman theorem in quantum physical chemistry is described. The theorem is stated with proof and with discussion of applicability and reliability. Some adaptations of the theorem to the study of the variation of zeros of special functions and orthogonal polynomials are surveyed. Possible extensions are discussed.

A New Hybrid Diffractive Photo-Mask Technology, Jin Won Sung

Electronic Theses and Dissertations

In the field of photolithography for micro-chip manufacturing, the photo-mask is used to print desired patterns on a proper photo-resist on wafer. The most common type of photo-mask is binary amplitude mask made an opaque layer of chrome. The principle and potential application of hybrid photo-mask with diffractive phase element and binary amplitude is presented in this dissertation paper from both numerical modeling and experimental research. The first important application is the characterization of aberration in the stepper system using hybrid diffractive photo-mask. By utilizing multiple diffractive illumination conditions, it is possible to characterize Zernike wave front aberration coefficients up …

Simulation Studies Of Self-Assembly And Phase Diagram Of Amphiphilic Molecules, Geuorgui Kostadinov Bourov

Electronic Theses and Dissertations

The aim of this dissertation is to investigate self-assembled structures and the phase diagram of amphiphilic molecules of diverse geometric shapes using a number of different computer simulation methods. The semi-realistic coarse-grained model, used extensively for simulation of polymers and surfactant molecules, is adopted in an off-lattice approach to study how the geometric structure of amphiphiles affects the aggregation properties. The results of simulations show that the model system behavior is consistent with theoretical predictions, experiments and lattice simulation models. We demonstrate that by modifying the geometry of the molecules, self-assembled aggregates are altered in a way close to theoretical …

Spectral Signature Modification By Application Of Infrared Frequency-Selective Surfaces, Brian Monacelli

Electronic Theses and Dissertations

It is desirable to modify the spectral signature of a surface, particularly in the infrared (IR) region of the electromagnetic spectrum. To alter the surface signature in the IR, two methods are investigated: thin film application and antenna array application. The former approach is a common and straightforward incorporation of optically-thin film coatings on the surface designated for signature modification. The latter technique requires the complex design of a periodic array of passive microantenna elements to cover the surface in order to modify its signature. This technology is known as frequency selective surface (FSS) technology and is established in the …

Affective Design In Technical Communication, Michael Alan Rosen

Electronic Theses and Dissertations

Traditional human-computer interaction (HCI) is based on 'cold' models of user cognition; that is, models of users as purely rational beings based on the information processing metaphor; however, an emerging perspective suggests that for the field of HCI to mature, its practitioners must adopt models of users that consider broader human needs and capabilities. Affective design is an umbrella term for research and practice being conducted in diverse domains, all with the common thread of integrating emotional aspects of use into the creation of information products. This thesis provides a review of the current state of the art in affective …

Assessment And In Vitro Repair Of Damaged Dna Templates From Forensic Stains, Ashley Hall

Electronic Theses and Dissertations

DNA extracted from biological stains is often intractable to analysis. This may due to a number of factors including a low copy number (LCN) of starting molecules, the presence of soluble inhibitors or damaged DNA templates. Remedies may be available to the forensic scientist to deal with LCN templates and soluble inhibitors but none presently exist for damaged DNA. In fact, only recently has the biochemical nature, the extent of DNA damage in physiological stains and the point at which the damage inflicted upon a particular sample precludes the ability to obtain a genetic profile for purposes of identification been …

Liquid Crystal Optics For Communications, Signal Processing And 3-D Microscopic Imaging, Sajjad Khan

Electronic Theses and Dissertations

This dissertation proposes, studies and experimentally demonstrates novel liquid crystal (LC) optics to solve challenging problems in RF and photonic signal processing, freespace and fiber optic communications and microscopic imaging. These include free-space optical scanners for military and optical wireless applications, variable fiber-optic attenuators for optical communications, photonic control techniques for phased array antennas and radar, and 3-D microscopic imaging. At the heart of the applications demonstrated in this thesis are LC devices that are non-pixelated and can be controlled either electrically or optically. Instead of the typical pixel-by-pixel control as is custom in LC devices, the phase profile across …

Structural Study Of Disease Related Proteins, Ayse Sinem Ozyurt

Electronic Theses and Dissertations

The availability of complete sequences for the genomes of many organisms changes the researcher's attention from genome sequencing to finding the function of gene products, the proteins. The three dimensional (3D) structure of a protein is helpful to understand its function, because tertiary structure is more conserved in evolution than sequence. The 3D structures can be found quickly by using high-throughput (HT) methods for protein expression, purification, characterization and structure determination. This process is very challenging in every step. Therefore we selected nearly 200 cancer related proteins as targets to see the difficulties in trying to determine the web predicted …

Design And Assessment Of Compact Optical Systems Towards Special Effects Imaging, Vesselin Chaoulov

Electronic Theses and Dissertations

A main challenge in the field of special effects is to create special effects in real time in a way that the user can preview the effect before taking the actual picture or movie sequence. There are many techniques currently used to create computer-simulated special effects, however current techniques in computer graphics do not provide the option for the creation of real-time texture synthesis. Thus, while computer graphics is a powerful tool in the field of special effects, it is neither portable nor does it provide work in real-time capabilities. Real-time special effects may, however, be created optically. Such approach …

Tunable Liquid Crystal Photonic Devices, Yun-Hsing Fan

Electronic Theses and Dissertations

Liquid crystal (LC)-based adaptive optics are important for information processing, optical interconnections, photonics, integrated optics, and optical communications due to their tunable optical properties. In this dissertation, we describe novel liquid crystal photonic devices and their fabrication methods. The devices presented include inhomogeneous polymer-dispersed liquid crystal (PDLC), polymer network liquid crystals (PNLC) and phase-separated composite film (PSCOF). Liquid crystal/polymer composites could exist in different forms depending on the fabrication conditions. In Chap. 3, we demonstrate a novel nanoscale PDLC device that has inhomogeneous droplet size distribution. In such a PDLC, the inhomogeneous droplet size distribution is obtained by exposing the …

Formalization Of Input And Output In Modern Operating Systems: The Hadley Model, Matthew Gerber

Electronic Theses and Dissertations

We present the Hadley model, a formal descriptive model of input and output for modern computer operating systems. Our model is intentionally inspired by the Open Systems Interconnection model of networking; I/O as a process is defined as a set of translations between a set of computer-sensible forms, or layers, of information. To illustrate an initial application domain, we discuss the utility of the Hadley model and a potential associated I/O system as a tool for digital forensic investigators. To illustrate practical uses of the Hadley model we present the Hadley Specification Language, an essentially functional language designed to allow …

System Design And Optimization Of Optical Coherence Tomography, Avni Ceyhun Akcay

Electronic Theses and Dissertations

Optical coherence imaging, including tomography (OCT) and microscopy (OCM), has been a growing research field in biomedical optical imaging in the last decade. In this imaging modality, a broadband light source, thus of short temporal coherence length, is used to perform imaging via interferometry. A challenge in optical coherence imaging, as in any imaging system towards biomedical diagnosis, is the quantification of image quality and optimization of the system components, both a primary focus of this research. We concentrated our efforts on the optimization of the imaging system from two main standpoints: axial point spread function (PSF) and practical steps …

Interferometry-Based Free Space Communication And Information Processing, Muzamil Arshad Arain

Electronic Theses and Dissertations

This dissertation studies, analyzes, and experimentally demonstrates the innovative use of interference phenomenon in the field of opto-electronic information processing and optical communications. A number of optical systems using interferometric techniques both in the optical and the electronic domains has been demonstrated in the filed of signal transmission and processing, optical metrology, defense, and physical sensors. Specifically it has been shown that the interference of waves in the form of holography can be exploited to realize a novel optical scanner called Code Multiplexed Optical Scanner (C-MOS). The C-MOS features large aperture, wide scan angles, 3-D beam control, no moving parts, …

Network Intrusion Detection: Monitoring, Simulation And Visualization, Mian Zhou

Electronic Theses and Dissertations

This dissertation presents our work on network intrusion detection and intrusion sim- ulation. The work in intrusion detection consists of two different network anomaly-based approaches. The work in intrusion simulation introduces a model using explicit traffic gen- eration for the packet level traffic simulation. The process of anomaly detection is to first build profiles for the normal network activity and then mark any events or activities that deviate from the normal profiles as suspicious. Based on the different schemes of creating the normal activity profiles, we introduce two approaches for intrusion detection. The first one is a frequency-based approach which …

Optical Wave Propagation In Discrete Waveguide Arrays, Jared Hudock

Electronic Theses and Dissertations

The propagation dynamics of light in optical waveguide arrays is characteristic of that encountered in discrete systems. As a result, it is possible to engineer the diffraction properties of such structures, which leads to the ability to control the flow of light in ways that are impossible in continuous media. In this work, a detailed theoretical investigation of both linear and nonlinear optical wave propagation in one- and two-dimensional waveguide lattices is presented. The ability to completely overcome the effects of discrete diffraction through the mutual trapping of two orthogonally polarized coherent beams interacting in Kerr nonlinear arrays of birefringent …

High Gain / Broadband Oxide Glasses For Next Generation Raman Amplifiers, Clara Rivero

Electronic Theses and Dissertations

Interest in Raman amplification has undergone a revival due to the rapidly increasing bandwidth requirements for communications transmission, both for long haul and local area networks, and recent developments in the telecom fiber industry and diode laser technology. In contrast to rare earth doped fiber amplifiers, for which the range of wavelengths is fixed and limited, Raman gain bandwidths are larger and the operating wavelength is fixed only by the pump wavelength and the bandwidth of the Raman active medium. In this context, glasses are the material of choice for this application due to their relatively broad spectral response, and …

The Use And Development Of Laser Microdissection To Separate Spermatozoa From Epithelial Cells For Str Analysis, Christine Sanders

Electronic Theses and Dissertations

Short Tandem Repeat (STR) analysis has become a valuable tool in identifying the source of biological stains, particularly from the investigation of sexual assault crimes. Difficulties in analysis arise primarily in the interpretation of mixed genotypes when cell separation of the sexual assailant's sperm from the victim's cells is incomplete. The forensic community continues to seek improvements in cell separation methods from mixtures for DNA typing. This report describes the use of laser microdissection (LMD) for the separation of pure populations of spermatozoa from two-donor cell mixtures. In this study, cell separation was demonstrated by microscopic identification of histologically stained …

Coherence Properties Of Optical Near-Fields, Adela Apostol

Electronic Theses and Dissertations

Next generation photonics-based technologies will ultimately rely on novel materials and devices. For this purpose, phenomena at subwavelength scales are being studied to advance both fundamental knowledge and experimental capabilities. In this dissertation, concepts specific to near-field optics and experimental capabilities specific to near-field microscopy are used to investigate various aspects of the statistical properties of random electromagnetic fields in the vicinity of optically inhomogeneous media which emit or scatter radiation. The properties of such fields are being characterized within the frame of the coherence theory. While successful in describing the far-field properties of optical fields, the fundamental results of …

Liquid Crystal Materials And Tunable Devices For Optical Communications, Fang Du

Electronic Theses and Dissertations

In this dissertation, liquid crystal materials and devices are investigated in meeting the challenges for photonics and communications applications. The first part deals with polymer-stabilized liquid crystal (PSLC) materials and devices. Three polymer-stabilized liquid crystal systems are developed for optical communications. The second part reports the experimental investigation of a novel liquid-crystal-infiltrated photonic crystal fiber (PCF) and explores its applications in fiber-optic communications. The curing temperature is found to have significant effects on the PSLC performance. The electro-optic properties of nematic polymer network liquid crystal (PNLC) at different curing temperatures are investigated experimentally. At high curing temperature, a high contrast, …

Maldi-Tof Ms Data Processing Using Wavelets, Splines And Clustering Techniques., Shuo Chen

Electronic Theses and Dissertations

Mass Spectrometry, especially matrix assisted laser desorption/ionization (MALDI) time of flight (TOF), is emerging as a leading technique in the proteomics revolution. It can be used to find disease-related protein patterns in mixtures of proteins derived from easily obtained samples. In this paper, a novel algorithm for MALDI-TOF MS data processing is developed. The software design includes the application of splines for data smoothing and baseline correction, wavelets for adaptive denoising, multivariable statistics techniques such as clustering analysis, and signal processing techniques to evaluate the complicated biological signals. A MatLab implementation shows the processing steps consecutively including step-interval unification, adaptive …

Kinetics And Mechanism Of The Catalysis Of The Decomposition Of Hydrogen Peroxide By Schiff Base Complexes Of Copper(Ii)., Timothy Kum Beng

Electronic Theses and Dissertations

Spectroscopic studies have been used to describe the mechanism of the decomposition of hydrogen peroxide by solutions of a dimeric Cu(II) complex of a dissymetric Schiff base, [CuSALAD]₂.H₂O, and imidazole or methyl substituted imidazoles, B, which form monomeric CuSALAD.B₂ complexes, in aqueous ethanol solvent. Freezing point depression and vapor pressure lowering studies were carried out to confirm the dimeric nature of the [CuSALAD]₂.H₂O complex that had been previously reported. The stoichiometry of the [CuSALAD]₂.H₂O-imidazole equilibrium was extensively studied pointing to a 1:4 stoichiometry. The CuSALAD.B₂ adducts …

Requirement Elicitation Of Large Web Projects., David E. Frazier

Electronic Theses and Dissertations

One of the most important aspects of developing a large Web-based project is getting the correct requirements from the client. Time and money can be lost if the requirements are incomplete or inaccurate. Traditional Web design sources tend to gloss over this important activity.

Software engineering is a mature field that can help in the quest for more complete and accurate requirement gathering. This paper explores the ways that traditional software engineering techniques can be applied to Web projects. A methodology is presented based on both existing and new techniques. Several experiments are conducted to determine the usefulness of each …

Risk Perceptions Of Adults In The Town Of Unicoi, Tennessee, Regarding The Possible Building Of A Uranium Enrichment Plant., Shannon Kathleen Sellards

Electronic Theses and Dissertations

A prolonged siting controversy for a uranium enrichment facility has occurred in the Town of Unicoi, Tennessee. One hundred-seventy residents of Unicoi were interviewed using a questionnaire regarding the building of a proposed uranium enrichment facility for Unicoi. The questionnaire sought to determine relationships between residents’ risk perceptions and 18 variables. When the Fisher’s exact procedure was applied at α< 0.05, the results indicated several associations. Odds ratio measured the strength of association. Results are reported as crude measures of association. Risk perceptions were influenced by the choice of possible locations for the facility [p=0.0003; OR=32.6]. Residents' risk perceptions were associated with a history of working with nuclear materials [p=0.0476; OR=3.2]. Finally, risk perceptions were associated with residents' beliefs that the nuclear facility would affect their health [p=0.0001; OR=18.8]. These results are discussed in light of risk perception and communication theories.