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Articles 2791 - 2820 of 3529

Full-Text Articles in Physical Sciences and Mathematics

Analytical And Numerical Solutions Of Differentialequations Arising In Fluid Flow And Heat Transfer Problems, Erik Sweet Jan 2009

Analytical And Numerical Solutions Of Differentialequations Arising In Fluid Flow And Heat Transfer Problems, Erik Sweet

Electronic Theses and Dissertations

The solutions of nonlinear ordinary or partial differential equations are important in the study of fluid flow and heat transfer. In this thesis we apply the Homotopy Analysis Method (HAM) and obtain solutions for several fluid flow and heat transfer problems. In chapter 1, a brief introduction to the history of homotopies and embeddings, along with some examples, are given. The application of homotopies and an introduction to the solutions procedure of differential equations (used in the thesis) are provided. In the chapters that follow, we apply HAM to a variety of problems to highlight its use and versatility in …

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Development Of Theoretical And Computational Methods For Three-Body Processes, Juan Blandon Zapata Jan 2009

Development Of Theoretical And Computational Methods For Three-Body Processes, Juan Blandon Zapata

Electronic Theses and Dissertations

This thesis discusses the development and application of theoretical and computational methods to study three-body processes. The main focus is on the calculation of three-body resonances and bound states. This broadly includes the study of Efimov states and resonances, three-body shape resonances, three-body Feshbach resonances, three-body pre-dissociated states in systems with a conical intersection, and the calculation of three-body recombination rate coefficients. The method was applied to a number of systems. A chapter of the thesis is dedicated to the related study of deriving correlation diagrams for three-body states before and after a three-body collision. More specifically, the thesis discusses …

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Tunable Terahertz Detectors Based On Plasmon Exciation In Two Dimensional Electron Gasses In Ingaas/Inp And Algan/Gan Hemt, Himanshu Saxena Jan 2009

Tunable Terahertz Detectors Based On Plasmon Exciation In Two Dimensional Electron Gasses In Ingaas/Inp And Algan/Gan Hemt, Himanshu Saxena

Electronic Theses and Dissertations

The observation of voltage-tunable plasmon resonances in the terahertz range in two dimensional electron gas (2-deg) of a high electron mobility transistor (HEMT) fabricated from the InGaAs/InP and AlGaN/GaN materials systems is reported. The devices were fabricated from a commercial HEMT wafer by depositing source and drain contacts using standard photolithography process and a semi-transparent gate contact that consisted of a 0.5 [micro]m period transmission grating formed by electron-beam lithography. Narrow-band resonant absorption of THz radiation was observed in transmission in the frequency range 10-100 cm-1. The resonance frequency depends on the gate voltage-tuned sheet-charge density of the 2deg. The …

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Decoherence In Semiconductor Solid-State Quantum Computers, Diego Valente Jan 2009

Decoherence In Semiconductor Solid-State Quantum Computers, Diego Valente

Electronic Theses and Dissertations

In this dissertation we discuss decoherence in charge qubits formed by multiple lateral quantum dots in the framework of the spin-boson model and the Born-Markov approximation. We consider the intrinsic decoherence caused by the coupling to bulk phonon modes and electromagnetic environmental fluctuations. In the case of decoherence caused by phonon coupling, two distinct quantum dot configurations are studied and proposed as setups that mitigate its nocive effects : (i) Three quantum dots in a ring geometry with one excess electron in total and (ii) arrays of quantum dots where the computational basis states form multipole charge configurations. For the …

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Search, Characterization, And Properties Of Brown Dwarfs, Ramarao Tata Jan 2009

Search, Characterization, And Properties Of Brown Dwarfs, Ramarao Tata

Electronic Theses and Dissertations

A trend in polarization as predicted by theoretical models was validated, and atmospheric dust grain sizes and projected rotational velocities for these objects were estimated. Comprehensive studies of UDs are proving to be crucial not only in our understanding of UDs but also for star and planet formation as brown dwarfs represent their lower and upper mass boundaries, respectively. Brown dwarfs (BD) were mere theoretical astrophysical objects for more than three decades (Kumar (1962)) till their first observational detection in 1995 (Rebolo et al. (1995), Nakajima et al. (1995)). These objects are intermediate in mass between stars and planets. Since …

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In-Situ Gas Phase Catalytic Properties Of Metal Nanoparticles, Luis Ono Jan 2009

In-Situ Gas Phase Catalytic Properties Of Metal Nanoparticles, Luis Ono

Electronic Theses and Dissertations

Recent advances in surface science technology have opened new opportunities for atomic scale studies in the field of nanoparticle (NP) catalysis. The 2007 Nobel Prize of Chemistry awarded to Prof. G. Ertl, a pioneer in introducing surface science techniques to the field of heterogeneous catalysis, shows the importance of the field and revealed some of the fundamental processes of how chemical reactions take place at extended surfaces. However, after several decades of intense research, fundamental understanding on the factors that dominate the activity, selectivity, and stability (life-time) of nanoscale catalysts are still not well understood. This dissertation aims to explore …

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Wavefront Sensor For Eye Aberrations Measurements, Costin Curatu Jan 2009

Wavefront Sensor For Eye Aberrations Measurements, Costin Curatu

Electronic Theses and Dissertations

Ocular wavefront sensing is vital to improving our understanding of the human eye and to developing advanced vision correction methods, such as adaptive optics, customized contact lenses, and customized laser refractive surgery. It is also a necessary technique for high-resolution imaging of the retina. The most commonly used wavefront sensing method is based on the Shack-Hartmann wavefront sensor. Since Junzhong Liang's first application of Shack-Hartmann wavefront sensing for the human eye in 1994, the method has quickly gained acceptance and popularity in the ophthalmic industry. Several commercial Shack-Hartmann eye aberrometers are currently available. While the existing aberrometers offer reasonable measurement …

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Optical Nonlinear Interactions In Dielectric Nano-Suspensions, Ramy El-Ganainy Jan 2009

Optical Nonlinear Interactions In Dielectric Nano-Suspensions, Ramy El-Ganainy

Electronic Theses and Dissertations

This work is divided into two main parts. In the first part (chapters 2-7) we consider the nonlinear response of nano-particle colloidal systems. Starting from the Nernst-Planck and Smoluchowski equations, we demonstrate that in these arrangements the underlying nonlinearities as well as the nonlinear Rayleigh losses depend exponentially on optical intensity. Two different nonlinear regimes are identified depending on the refractive index contrast of the nanoparticles involved and the interesting prospect of self-induced transparency is demonstrated. Soliton stability is systematically analyzed for both 1D and 2D configurations and their propagation dynamics in the presence of Rayleigh losses is examined. We …

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Wavelength-Division-Multiplexed Transmission Using Semiconductor Optical Amplifiers And Electronic Impairment Compensation, Xiaoxu Li Jan 2009

Wavelength-Division-Multiplexed Transmission Using Semiconductor Optical Amplifiers And Electronic Impairment Compensation, Xiaoxu Li

Electronic Theses and Dissertations

Over the last decade, rapid growth of broadband services necessitated research aimed at increasing transmission capacity in fiber-optic communication systems. Wavelength division multiplexing (WDM) technology has been widely used in fiber-optic systems to fully utilize fiber transmission bandwidth. Among optical amplifiers for WDM transmission, semiconductor optical amplifier (SOA) is a promising candidate, thanks to its broad bandwidth, compact size, and low cost. In transmission systems using SOAs, due to their large noise figures, high signal launching powers are required to ensure reasonable optical signal-to-noise ratio of the received signals. Hence the SOAs are operated in the saturation region and the …

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Gabor Domain Optical Coherence Microscopy, Supraja Murali Jan 2009

Gabor Domain Optical Coherence Microscopy, Supraja Murali

Electronic Theses and Dissertations

Time domain Optical Coherence Tomography (TD-OCT), first reported in 1991, makes use of the low temporal coherence properties of a NIR broadband laser to create depth sectioning of up to 2mm under the surface using optical interferometry and point to point scanning. Prior and ongoing work in OCT in the research community has concentrated on improving axial resolution through the development of broadband sources and speed of image acquisition through new techniques such as Spectral domain OCT (SD-OCT). In SD-OCT, an entire depth scan is acquired at once with a low numerical aperture (NA) objective lens focused at a fixed …

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Nonlinear Femtosecond Near Infrared Laser Structuring In Oxide Glasses, Arnaud Royon Jan 2009

Nonlinear Femtosecond Near Infrared Laser Structuring In Oxide Glasses, Arnaud Royon

Electronic Theses and Dissertations

Three-dimensional femtosecond laser structuring has a growing interest because of its ease of implementation and the numerous possible applications in the domain of photonic components. Structures such as waveguides, diffraction gratings, optical memories or photonic crystals can be fabricated thanks to this technique. Its use with oxide glasses is promising because of several advantages; they are resistant to flux and ageing, their chemical composition can easily be changed to fit the well-defined requirements of an application. They can already be found in Raman amplifiers, optical fibers, fiber lasers, and other devices. This thesis is based on two axes. The first …

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Design And Fabrication Of Space Variant Micro Optical Elements, Pradeep Srinivasan Jan 2009

Design And Fabrication Of Space Variant Micro Optical Elements, Pradeep Srinivasan

Electronic Theses and Dissertations

A wide range of applications currently utilize conventional optical elements to individually transform the phase, polarization, and spectral transmission/reflection of the incident radiation to realize the desired system level function. The material properties and the feasibility of fabrication primarily impact the device and system functionality that can be realized. With the advancement in micro/nano patterning, growth, deposition and etching technology, devices with novel and multiplexed optical functionalities have become feasible. As a result, it has become possible to engineer the device response in the near and far field by controlling the phase, polarization or spectral response at the micro scale. …

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Femtosecond Laser Written Volumetric Diffractive Optical Elements And Their Applications, Jiyeon Choi Jan 2009

Femtosecond Laser Written Volumetric Diffractive Optical Elements And Their Applications, Jiyeon Choi

Electronic Theses and Dissertations

Since the first demonstration of femtosecond laser written waveguides in 1996, femtosecond laser direct writing (FLDW) has been providing a versatile means to fabricate embedded 3-D microstructures in transparent materials. The key mechanisms are nonlinear absorption processes that occur when a laser beam is tightly focused into a material and the intensity of the focused beam reaches the range creating enough free electrons to induce structural modification. One of the most useful features that can be exploited in fabricating photonic structures is the refractive index change which results from the localized energy deposition. The laser processing system for FLDW can …

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Study On Methods Of Simultaneous Multi-Component Analysis., Jennifer Bernice Ashie Dec 2008

Study On Methods Of Simultaneous Multi-Component Analysis., Jennifer Bernice Ashie

Electronic Theses and Dissertations

Many new instrumentation and different instrumental techniques have been developed to deal with increasing complexity of samples encountered. Many researchers also have coupled these instrumental techniques with chemometric algorithms to assist in the quantitative analysis of multi-component samples in the hope of alleviating the need of tedious separation and cleanup procedures. These newer chemometric procedures tend to be complex and difficult to understand and implement and are successful under different circumstances and conditions. In this study, we start from the very simple beginning and examine the factors that can present difficulties with obtaining the correct results and observe how the …

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Restrained And Other Domination Parameters In Complementary Prisms., Wyatt Jules Desormeaux Dec 2008

Restrained And Other Domination Parameters In Complementary Prisms., Wyatt Jules Desormeaux

Electronic Theses and Dissertations

In this thesis, we will study several domination parameters of a family of graphs known as complementary prisms. We will first present the basic terminology and definitions necessary to understand the topic. Then, we will examine the known results addressing the domination number and the total domination number of complementary prisms. After this, we will present our main results, namely, results on the restrained domination number of complementary prisms. Subsequently results on the distance - k domination number, 2-step domination number and stratification of complementary prisms will be presented. Then, we will characterize when a complementary prism is Eulerian or …

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Studies Of Surfactants Effect On Riboflavin Fluorescence And Its Determination In Commercial Food Products And Vitamin Tablets., William Emmanuel Ghann Dec 2008

Studies Of Surfactants Effect On Riboflavin Fluorescence And Its Determination In Commercial Food Products And Vitamin Tablets., William Emmanuel Ghann

Electronic Theses and Dissertations

A simple and economical fluorometer using blue LEDs excitation sources and simple PMT detection had been built, assembled, optimized, and employed for measurement of fluorescence from riboflavin (vitamin B2). Surfactants have been known to enhance the intensity of fluorescence of fluorescent compounds. Fluorescence analysis of riboflavin in the presence of various anionic, cationic, and nonionic surfactants was also conducted to determine if they could improve analysis. However, the surfactants employed did not seem to have any meaningful enhancement; in fact, some actually diminished the fluorescence intensity of riboflavin. The procedure was linear for riboflavin from 0.01 to 2.5 …

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Towards The Design And Syntheses Of Novel Triads Comprising Single Robson-Type Macrocyclic Dicopper(Ii) Cores Flanked By Two Terminal Polypyridyl Ruthenium(Ii) Complexes., Leslie Shane Moody Dec 2008

Towards The Design And Syntheses Of Novel Triads Comprising Single Robson-Type Macrocyclic Dicopper(Ii) Cores Flanked By Two Terminal Polypyridyl Ruthenium(Ii) Complexes., Leslie Shane Moody

Electronic Theses and Dissertations

Progress toward the syntheses of new tetranuclear bimetallic complexes of copper(II) and ruthenium(II) was realized. The designed triads comprise a central binuclear copper(II) complex with a tetraiminodiphenolate macrocyclic Robson-type compartmental ligand. In the envisioned complexes, the macrocyclic core is further functionalized by attachment of two polypyridyl ruthenium(II) complexes. A novel dibrominated dicopper(II) Robson complex was formed by the 2:2:2 condensation reaction of 4-bromo-2,6-diformylphenol and 1,3- diaminopropane with cupric chloride. Similarly, a new dibrominated dizinc(II) was synthesized from zinc tetrafluoroborate and the same diamine and dialdehyde. The new dicopper(II) complex did not heterocouple with borylated substrates under explored Suzuki reaction conditions. …

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Geochemical Impacts From Permanganate Oxidation Based On Field Scale Assessments., Kelly Ann Moore Dec 2008

Geochemical Impacts From Permanganate Oxidation Based On Field Scale Assessments., Kelly Ann Moore

Electronic Theses and Dissertations

In situ chemical oxidation (ISCO) using permanganate is a technology for treatment of organic hazardous wastes. This research is a review of 30 permanganate (MnO4-) ISCO sites to determine whether there are long term impacts on groundwater quality due to the introduction of the oxidant into the subsurface. A second objective is to determine if manganese concentration can be predicted by trends in specific pre and postoxidation monitored parameters (i.e., pH and oxidation reduction potential (ORP)). The final objective is to identify the effects of site and design conditions on groundwater conditions postoxidation. Results indicate that (1) …

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Erosion And Trail Building: A Case Study Of The East Tennessee State University Trail System., Joshua Callahan Aug 2008

Erosion And Trail Building: A Case Study Of The East Tennessee State University Trail System., Joshua Callahan

Electronic Theses and Dissertations

Natural and accelerated erosion from trail users affects the sustainability of trail systems. Designing and building sustainable trail systems will greatly decrease the effect that erosion has on a trail. Trails that allow multiple types of users, such as hiking and mountain biking, must be able to sustain both groups. At East Tennessee State University the trail system was originally designed for hiking. Mountain bikers have become the main user group on the trail system leading to erosion problems on certain areas of the trail due to trail design flaws. The study seeks to identify the problem areas of trail …

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Modeling The Progression Of Discrete Paired Longitudinal Data., Jonathan Wesley Hicks Aug 2008

Modeling The Progression Of Discrete Paired Longitudinal Data., Jonathan Wesley Hicks

Electronic Theses and Dissertations

It is our intention to derive a methodology for which to model discrete paired longitudinal data. Through the use of transition matrices and maximum likelihood estimation techniques by means of software, we develop a way to model the progression of such data. We provide an example by applying this method to the Wisconsin Epidemiological Study of Diabetic Retinopathy data set. The data set is comprised of individuals, all diabetics, who have had their eyes examined for diabetic retinopathy. The eyes are treated as paired data, and we have the results of the examination at the four unequally spaced time points …

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Interval Estimation For The Ratio Of Percentiles From Two Independent Populations., Pius Matheka Muindi Aug 2008

Interval Estimation For The Ratio Of Percentiles From Two Independent Populations., Pius Matheka Muindi

Electronic Theses and Dissertations

Percentiles are used everyday in descriptive statistics and data analysis. In real life, many quantities are normally distributed and normal percentiles are often used to describe those quantities. In life sciences, distributions like exponential, uniform, Weibull and many others are used to model rates, claims, pensions etc. The need to compare two or more independent populations can arise in data analysis. The ratio of percentiles is just one of the many ways of comparing populations. This thesis constructs a large sample confidence interval for the ratio of percentiles whose underlying distributions are known. A simulation study is conducted to evaluate …

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Contraction-Expansion Protocols., Nadine Katia Njoya Aug 2008

Contraction-Expansion Protocols., Nadine Katia Njoya

Electronic Theses and Dissertations

An approach to a new class of compounds known as bridgehead dienone is described. The route is based on a tandem contraction-expansion event in which the contraction triggers the expansion. The two steps involved are a palladium-catalyzed Favorskii contraction and a cis-divinyl cyclopropanone rearrangement. Progress towards these goals is reported.

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Monitoring Metal Containing Particulates Distribution On A College Campus Using Dandelion (Taraxacum Officinale) Leaves As Receptors., Suresh Chandra Regmi Aug 2008

Monitoring Metal Containing Particulates Distribution On A College Campus Using Dandelion (Taraxacum Officinale) Leaves As Receptors., Suresh Chandra Regmi

Electronic Theses and Dissertations

This study aims to determine the distribution of particulates carrying heavy metals at selected sites on a college campus using dandelion leaves as collectors. As a comparison, sites far away from the campus surrounding Bristol Motor Speedway Car Racing Stadium were also monitored. To reduce the probability of memory effects from the long-term atmospheric deposition or absorption of metals from soil a seasonal plant, dandelion, was used to monitor the metal contents. The metals monitored are cadmium, calcium, copper, chromium, iron, lead, and zinc. Fourteen sites were monitored and samples were collected once a week initially (growing time of the …

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Estimating The Difference Of Percentiles From Two Independent Populations., Romual Eloge Tchouta Aug 2008

Estimating The Difference Of Percentiles From Two Independent Populations., Romual Eloge Tchouta

Electronic Theses and Dissertations

We first consider confidence intervals for a normal percentile, an exponential percentile and a uniform percentile. Then we develop confidence intervals for a difference of percentiles from two independent normal populations, two independent exponential populations and two independent uniform populations. In our study, we mainly focus on the maximum likelihood to develop our confidence intervals. The efficiency of this method is examined via coverage rates obtained in a simulation study done with the statistical software R.

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Synthesis Towards Fulminic Acid And Its Derivatives In 1, 3-Dipolar Cycloaddition Reactions., Ophilia Ndi Toh Aug 2008

Synthesis Towards Fulminic Acid And Its Derivatives In 1, 3-Dipolar Cycloaddition Reactions., Ophilia Ndi Toh

Electronic Theses and Dissertations

A new approach to fulminic acid cycloadditions has been developed. At reduced temperatures, fulminic acid is generated in situ and undergoes 1, 3-diploar cycloaddition reactions with dipolarophiles to form isoxazolines and/or its dimers. This procedure represents a novel, safe general method for the one-step generation of fulminic acid, which complements existing potentially explosive protocols.

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Double Domination Of Complementary Prisms., Lamont D. Vaughan Aug 2008

Double Domination Of Complementary Prisms., Lamont D. Vaughan

Electronic Theses and Dissertations

The complementary prism of a graph G is obtained from a copy of G and its complement G̅ by adding a perfect matching between the corresponding vertices of G and G̅. For any graph G, a set D ⊆ V (G) is a double dominating set (DDS) if that set dominates every vertex of G twice. The double domination number, denoted γ×2(G), is the cardinality of a minimum double dominating set of G. We have proven results on graphs of small order, specific families and lower bounds on γ×2 …

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Finding Edge And Vertex Induced Cycles Within Circulants., Trina Marcella Wooten Aug 2008

Finding Edge And Vertex Induced Cycles Within Circulants., Trina Marcella Wooten

Electronic Theses and Dissertations

Let H be a graph. G is a subgraph of H if V (G) ⊆ V (H) and E(G) ⊆ E(H). The subgraphs of H can be used to determine whether H is planar, a line graph, and to give information about the chromatic number. In a recent work by Beeler and Jamison [3], it was shown that it is difficult to obtain an automorphic decomposition of a triangle-free graph. As many of their examples involve circulant graphs, it is of particular interest to find triangle-free subgraphs within circulants. As …

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Characterization Of Commercial Pectin Preparations By Spectroscopic And Chromatographic Techniques., Daniel Wayne Dixon May 2008

Characterization Of Commercial Pectin Preparations By Spectroscopic And Chromatographic Techniques., Daniel Wayne Dixon

Electronic Theses and Dissertations

Pectin has a long history as a food additive. However, elucidation of its fine structural and property relationships remains elusive. Recent research has focused on pectin's ability to complex with divalent heavy metals to aid in characterizing it. Commercial pectins of unknown composition were obtained from local grocers. Purified pectin samples from orange peel, lemon peel, and apple pomace, each of low and high levels of methyl esterification and of unknown distribution pattern were also purchased. Instead of metal complexation, several highly absorbing dyes such as Ruthenium Red, Nile Blue, and Acridine Orange were used to complex with the pectins …

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Bacterial Source Tracking In The Sinking Creek Watershed Using Antibiotic Resistance Analysis And Ribotyping., Lisa Kathleen Gallagher May 2008

Bacterial Source Tracking In The Sinking Creek Watershed Using Antibiotic Resistance Analysis And Ribotyping., Lisa Kathleen Gallagher

Electronic Theses and Dissertations

Fecal pollution of surface water is a significant environmental health issue. Indicator organisms are used to monitor microbial water quality, but often their presence does not coincide with the presence of pathogens. Bacterial source tracking is a term describing methods to determine the origin of fecal pollution based on bacterial traits. The objective of this research is to evaluate the use of 2 bacterial source tracking techniques, antibiotic resistance analysis (ARA) and ribotyping, to determine the sources of bacteria isolated from Sinking Creek. Based on the results of this study, ARA and ribotyping are not useful techniques for identifying sources …

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On The Attainability Of Upper Bounds For The Circular Chromatic Number Of K4-Minor-Free Graphs., Tracy Lance Holt May 2008

On The Attainability Of Upper Bounds For The Circular Chromatic Number Of K4-Minor-Free Graphs., Tracy Lance Holt

Electronic Theses and Dissertations

Let G be a graph. For k ≥ d ≥ 1, a k/d -coloring of G is a coloring c of vertices of G with colors 0, 1, 2, . . ., k - 1, such that d ≤ | c(x) - c(y) | ≤ k - d, whenever xy is an edge of G. We say that the circular chromatic number of G, denoted χc(G), is equal to the smallest k/d where a k/d -coloring exists. In [6], Pan and …

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