Physical Sciences and Mathematics Commons^™

Near-Field Optical Interactions And Applications, David Haefner

Electronic Theses and Dissertations

The propagation symmetry of electromagnetic fields is affected by encounters with material systems. The effects of such interactions, for example, modifications of intensity, phase, polarization, angular spectrum, frequency, etc. can be used to obtain information about the material system. However, the propagation of electromagnetic waves imposes a fundamental limit to the length scales over which the material properties can be observed. In the realm of near-field optics, this limitation is overcome only through a secondary interaction that couples the high-spatial-frequency (but non-propagating) field components to propagating waves that can be detected. The available information depends intrinsically on this secondary interaction, …

Numerical Computations For Pde Models Of Rocket Exhaust Flow In Soil, Brian Brennan

Electronic Theses and Dissertations

We study numerical methods for solving the nonlinear porous medium and Navier-Lame problems. When coupled together, these equations model the flow of exhaust through a porous medium, soil, and the effects that the pressure has on the soil in terms of spatial displacement. For the porous medium equation we use the Crank-Nicolson time stepping method with a spectral discretization in space. Since the Navier-Lame equation is a boundary value problem, it is solved using a finite element method where the spatial domain is represented by a triangulation of discrete points. The two problems are coupled by using approximations of solutions …

Structural, Electronic, Vibrational And Thermodynamical Properties Of Surfaces And Nanoparticles, Handan Yildirim

Electronic Theses and Dissertations

The main focus of the thesis is to have better understanding of the atomic and electronic structures, vibrational dynamics and thermodynamics of metallic surfaces and bi-metallic nanoparticles (NPs) via a multi-scale simulational approach. The research presented here involves the study of the physical and chemical properties of metallic surfaces and NPs that are useful to determine their functionality in building novel materials. The study follows the 'bottom-up' approach for which the knowledge gathered at the scale of atoms and NPs serves as a base to build, at the macroscopic scale, materials with desired physical and chemical properties. We use a …

Epitaxial Growth, Characterization And Application Of Novel Wide Bandgap Oxide Semiconductors, Jeremy Mares

Electronic Theses and Dissertations

In this work, a body of knowledge is presented which pertains to the growth, characterization and exploitation of high quality, novel II-IV oxide epitaxial films and structures grown by plasma-assisted molecular beam epitaxy. The two compounds of primary interest within this research are the ternary films NixMg1-xO and ZnxMg1-xO and the investigation focuses predominantly on the realization, assessment and implementation of these two oxides as optoelectronic materials. The functioning hypothesis for this largely experimental effort has been that these cubic ternary oxides can be exploited - and possibly even juxtaposed - to realize novel wide band gap optoelectronic technologies. The …

Micro-Electro-Mechanical Systems (Mems) And Agile Lensing-Based Modules For Communications, Sensing And Signal Processing., Syed Reza

Electronic Theses and Dissertations

This dissertation proposes the use of the emerging Micro-Electro-Mechanical Systems (MEMS) and agile lensing optical device technologies to design novel and powerful signal conditioning and sensing modules for advanced applications in optical communications, physical parameter sensing and RF/optical signal processing. For example, these new module designs have experimentally demonstrated exceptional features such as stable loss broadband operations and high > 60 dB optical dynamic range signal filtering capabilities. The first part of the dissertation describes the design and demonstration of digital MEMS-based signal processing modules for communication systems and sensor networks using the TI DLP (Digital Light Processing) technology. Examples of …

Fast Response Dual Frequency Liquid Crystal Materials, Qiong Song

Electronic Theses and Dissertations

Dual frequency liquid crystal (DFLC) exhibits a positive dielectric anisotropy at low frequencies and negative dielectric anisotropy at high frequencies. The frequency where dielectric anisotropy is zero is called crossover frequency. DFLC can achieve fast rise time and fast decay time with the assistance of applied voltage. However, one drawback of DFLC is that it has dielectric heating effect when driven at a high frequency. Thus, the first part of this dissertation is to develop low crossover frequency DFLC materials. The dielectric relaxation and physical properties of some single- and double-ester compounds were investigated. Experimental results indicate that the double-ester …

An Assessment Of Sea Turtle Nesting Behavior In Relation To Hurricane- And Restoration-Induced Beach Morphodynamics, Tonya Michele Long

Electronic Theses and Dissertations

Coastal habitats are highly dynamic and vulnerable to landscape-level disturbances such as storms and restoration projects. Along the east coast of Florida these areas are particularly valuable as they provide significant nesting habitat for two sea turtle species, the threatened loggerhead (Caretta caretta) and the endangered green turtle (Chelonia mydas). This coast was heavily impacted by three major hurricanes in 2004 and in some areas by large restoration projects in 2005. Recent remote sensing methods allow for broad evaluation of the shoreline and thus the ability to assess sea turtle nesting habitat at a landscape scale. I collected nesting data …

Experimental And Theoretical Approaches To Characterization Of Electronic Nonlinearities In Direct-Gap Semiconductors, Claudiu Cirloganu

Electronic Theses and Dissertations

The general goal of this dissertation is to provide a comprehensive description of the limitations of established theories on bound electronic nonlinearities in direct-gap semiconductors by performing various experiments on wide and narrow bandgap semiconductors along with developing theoretical models. Nondegenerate two-photon absorption (2PA) is studied in several semiconductors showing orders of magnitude enhancement over the degenerate counterpart. In addition, three-photon absorption (3PA) is studied in ZnSe and other semiconductors and a new theory using a Kane 4-band model is developed which fits new data well. Finally, the narrow gap semiconductor InSb is studied with regard to multiphoton absorption, free-carrier …

Search For Gas Giants Around Late-M Dwarfs, Rohit Deshpande

Electronic Theses and Dissertations

We carried out a near-infrared radial velocity search for Jupiter-mass planets around 36 late M dwarfs. This survey was the first of its kind undertaken to monitor radial velocity variability of these faint dwarfs. For this unique survey we employed the 10-m Keck II on Mauna Kea in Hawaii. With a resolution of 20,000 on the near-infrared spectrograph, NIRSPEC, we monitored these stars over four epochs in 2007. In addition to the measurement of relative radial velocity we established physical properties of these stars. The physical properties of M dwarfs we determined included the identification of neutral atomic lines, the …

Silicon-Sensitized Erbium Excitation In Silicon-Rich Silica For Integrated Photonics, Oleksandr Savchyn

Electronic Theses and Dissertations

It is widely accepted that the continued increase of processor performance requires at least partial replacement of electronic interconnects with their photonic counterparts. The implementation of optical interconnects requires the realization of a silicon-based light source, which is challenging task due to the low emission efficiency of silicon. One of the main approaches to address this challenge is the use of doping of silicon based matrices with optical centers, including erbium ions. Erbium ions incorporated in various hosts assume the trivalent state (Er3+) and demonstrate a transition at 1.54 μm, coinciding with optical transmission windows in both silicon and silica. …

Design, Synthesis And Characterization Of New Two-Photon Absorbing (2pa) Fluorescent Dyes And Bioconjugates, And Their Applications In Bioimaging, Carolina D. Andrade

Electronic Theses and Dissertations

The development of new multiphoton absorbing materials has attracted the attention of researchers for the last two decades. The advantages that multiphoton absorbing materials offer, versus their one-photon absorbing counterparts, rely on the nature of the nonlinearity of the absorption process, where two photons are absorbed simultaneously offering increased 3D resolution, deeper penetration, and less photobleaching and photodamage as a result of a more confined excitation. The applications of efficient two-photon absorbing materials have been extensively expanding into the fields of photodynamic therapy, microscopy, and optical data storage. One of the fields where an increased interest in multiphoton absorbing materials …

Survey Of Meteorite Physical Properties Density, Porosity And Magnetic Susceptibility, Robert J. Macke

Electronic Theses and Dissertations

The measurement of meteorite physical properties (i.e. density, porosity, magnetic susceptibility) supplements detailed chemical and isotopic analyses for small samples (thin sections or ~300 mg portions) by providing whole-rock data for samples massing in the tens of grams. With the advent of fast, non-destructive and non-contaminating measurement techniques including helium ideal-gas pycnometry for grain density, the Archimedean ―glass bead‖ method for bulk density and (with grain density) porosity, and the use of low-field magnetometry for magnetic susceptibility, all of which rely on compact and portable equipment, this has enabled a comprehensive survey of these physical properties for a wide variety …

A Wearable Head-Mounted Projection Display, Ricardo F. Martins

Electronic Theses and Dissertations

Conventional head-mounted projection displays (HMPDs) contain of a pair of miniature projection lenses, beamsplitters, and miniature displays mounted on the helmet, as well as a retro-reflective screen placed strategically in the environment. We have extened the HMPD technology integrating the screen into a fully mobile embodiment. Some initial efforts of demonstrating this technology has been captured followed by an investigation of the diffraction effects versus image degradation caused by integrating the retro-reflective screen within the HMPD. The key contribution of this research is the conception and development of a mobileHMPD (M-HMPD). We have included an extensive analysis of macro- and …

Initial-Value Technique For Singularly Perturbed Two Point Boundary Value Problems Via Cubic Spline, Luis G. Negron

Electronic Theses and Dissertations

A recent method for solving singular perturbation problems is examined. It is designed for the applied mathematician or engineer who needs a convenient, useful tool that requires little preparation and can be readily implemented using little more than an industry-standard software package for spreadsheets. In this paper, we shall examine singularly perturbed two point boundary value problems with the boundary layer at one end point. An initial-value technique is used for its solution by replacing the problem with an asymptotically equivalent first order problem, which is, in turn, solved as an initial value problem by using cubic splines. Numerical examples …

Detection And Approximation Of Function Of Two Variables In High Dimensions, Minzhe Pan

Electronic Theses and Dissertations

This thesis originates from the deterministic algorithm of DeVore, Petrova, and Wojtaszcsyk for the detection and approximation of functions of one variable in high dimensions. We propose a deterministic algorithm for the detection and approximation of function of two variables in high dimensions.

A Fpga-Based Architecture For Led Backlight Driving, Zhaoshi Zheng

Electronic Theses and Dissertations

In recent years, Light-emitting Diodes (LEDs) have become a promising candidate for backlighting Liquid Crystal Displays [1] (LCDs). Compared with traditional Cold Cathode Fluorescent Lamps (CCFLs) technology, LEDs offer not only better visual quality, but also improved power efficiency. However, to fully utilized LEDs' capability requires dynamic independent control of individual LEDs, which remains as a challenging topic. A FPGA-based hardware system for LED backlight control is proposed in this work. We successfully achieve dynamic adjustment of any individual LED's intensity in each of the three color channels (Red, Green and Blue), in response to a real time incoming video …

Determination Of The Activation Parameters Of Reaction Between [Fe(Cn6]-4 And K[Co(Hedta)No2]., Sammy Eni Eni

Electronic Theses and Dissertations

The kinetics of the oxidation of [Fe(CN)₆]^-4 by K[Co(HEDTA)NO₂] was studied in order to get the mechanism and the activation parameters of the reaction. Using a freshly-made Na₃PO₄ solution as the reaction medium with a pH of 6.00 the ionic strength was maintained at 0.10 M and the buffer molarity was 0.001 M.

The rate constant (k_obs) of the reaction between [Fe(CN)₆]^-4 and K[Co(HEDTA)NO₂] was determined at temperatures of 25.0°C, 27.5°C, 30.0°C, 35.0°, and 40.0°C. We explored this reaction by monitoring the evolution of ferricyanide, …

Vitis Seeds (Vitaceae) From The Late Neogene Gray Fossil Site, Northeastern Tennessee, Usa., Fade Gong

Electronic Theses and Dissertations

This study focuses on the morphometric and systematic studies of fossil vitaceous seeds recently recovered from the Gray Fossil Site (7-4.5 Ma, latest Miocene-earliest Pliocene) northeastern Tennessee. Morphologically, all fossil seeds correspond to the extant subgenus Vitis (genus Vitis) of the Vitaceae based on the smooth dorsal surface with a centrally positioned chalaza connected with a conspicuous chalaza-apex groove and short linear ventral infolds that are slightly diverged apically. A multivariate analysis based on 11 measured characters from 76 complete seeds identified three types of seeds, each representing a distinct morphotaxon. Based on comparison with modern and fossil vitaceous …

A Variation Of The Carleman Embedding Method For Second Order Systems., Charles Nunya Dzacka

Electronic Theses and Dissertations

The Carleman Embedding is a method that allows us to embed a finite dimensional system of nonlinear differential equations into a system of infinite dimensional linear differential equations. This technique works well when dealing with first-order nonlinear differential equations. However, for higher order nonlinear ordinary differential equations, it is difficult to use the Carleman Embedding method. This project will examine the Carleman Embedding and a variation of the method which is very convenient in applying to second order systems of nonlinear equations.

Predicting Flavonoid Ugt Regioselectivity With Graphical Residue Models And Machine Learning., Arthur Rhydon Jackson

Electronic Theses and Dissertations

Machine learning is applied to a challenging and biologically significant protein classification problem: the prediction of flavonoid UGT acceptor regioselectivity from primary protein sequence. Novel indices characterizing graphical models of protein residues are introduced. The indices are compared with existing amino acid indices and found to cluster residues appropriately. A variety of models employing the indices are then investigated by examining their performance when analyzed using nearest neighbor, support vector machine, and Bayesian neural network classifiers. Improvements over nearest neighbor classifications relying on standard alignment similarity scores are reported.

Banach Spaces On Infinitely Branching Trees, Annette B. Locke

Electronic Theses and Dissertations

An example of a Banach space, X_∞, with a nonseparable dual such that l₁ does not imbed in X_∞ is investigated. Not every weakly null sequence has a subsequence equivalent to the usual basis of c₀, but c₀ imbeds in many subspaces of X_∞. The space l₁ does imbed in X_∞^∗, the dual space of X_∞, yet weakly converging sequences in X_∞^∗ need not converge in norm.

A Phylogenetic Analysis Of Species Relationships In Hemlocks, The Genus Tsuga (Pinaceae)., Jordan David Baker

Electronic Theses and Dissertations

The genus Tsuga is comprised of eight extant species found in North America and East Asia and four species represented by fossils from Europe and Japan. This study presents the first phylogenetic analysis based on structural, biochemical, and molecular sequence data. Characters obtained from published and unpublished literature were combined with new morphological characters from seeds, seedlings, and leaf cuticle material. Results from parsimony analyses of these characters differed from the published molecular based phylogeny. The non-molecular based phylogeny resolves two separate clades, a North American and an Asian, but did not group the western North American species, as in …

Novel Strategy For The Synthesis Of Allenes., Mark-Henry Mbahmi Kamga

Electronic Theses and Dissertations

Allenes are very important chemical reagents in organic synthesis. Due to their high reactivity, they have been extensively used to carry out a variety of unique and effective chemical transformations including but not limited to ionic and free radical additions and transition metal catalyzed cyclizations. As the chemistry of this group of compounds is explored further and their applications expanded there is a need to develop alternative and cost effective methods for their synthesis. Our approach involves the synthesis of allenes from oxa-bicyclo-alkan-2-ones by methyllithium induced Eschenmoser fragmentation of the bicyclotosylhydrazone derivatives.

Studies Of Titanium Dioxide Nanoparticles And Surfactants Effects, Singly And In Combinations, On Luminescence Intensity Of Some Aromatic Compounds., Charles Anim Odame-Ankrah

Electronic Theses and Dissertations

Luminescence techniques are sensitive, selective, and widely used in analysis. Luminescence intensity is attenuated by quenchers. This research has focused on the use of surfactants such as CTAB, SDS, and TX-100 singly or together with TiO₂ nanoparticles to evaluate their individual and combined effects on some fluorescent aromatic compounds such as pyrene, fluoranthene, anthracene, phenanthrene, and carbazole. Rutile phase TiO₂ was synthesized using the low temperature sol-gel method. Carbazole and phenanthrene were severely quenched by all surfactants singly or in combination with TiO₂. Anthracene and fluoranthene showed some enhancement in their luminescence intensity. The most dramatic …

Studies Of Capsaicinoids Contents Of Locally Grown And Commercial Chilies Using Reversed-Phase High Performance Liquid Chromatography., John Kailemia Muchena

Electronic Theses and Dissertations

Capsaicinoids are a class of compounds responsible for the "heat" of hot peppers. Capsaicin and dihydrocapsaicin have the highest burning effect. The aim of this work is to separate and quantify the two major capsaicinoids in fruits harvested at different stages of development and at different seasons. Simple and rapid HPLC method involves 73:27% methanol water mobile phase with C₁₈ stationary phase and UV-Vis detector set at 210 nm. The method showed good reproducibility with 1.74% - 4.72% relative standard deviations, a linear response within 0.65–45.5 and 0.25-17.5 μg/mL for capsaicin and dihydrocapsaicin, respectively. The method achieved average recovery …

Computational Investigation Of Spin Traps Using Hybrid Solvation Models., Sai Sriharsha Manoj Konda

Electronic Theses and Dissertations

The cyclic nitrone 5,5-dimethyl-1-pyrroline-N-oxide (DMPO), and the lesser known linear phenyl-N-tert-butylnitrone (PBN) and its phosphorylated analogues have been used as spin traps for the investigation of free radicals in biological systems. Theoretical work on these molecules suggests that there are important differences in their properties between biological systems and isolated molecules in the gas phase, most likely resulting from intra and intermolecular hydrogen bonding. Most dielectric solvation models such as the polarized continuum model and COSMO are incapable of direct determination of solvent-spin trap chemical interactions. To examine this, hybrid models incorporating COSMO for long range effects and discrete solvent …

Studies Of The Preparations And Use Of Sol-Gel For Enzyme Immobilization And Analytical Applications., Suzana Hamdan

Electronic Theses and Dissertations

Much attention has been paid to immobilization of enzymes to improve enzyme stability and permit its reuse. Glucose oxidase entrapment in different kinds of silica sol-gel matrices was investigated. The enzyme showed stable activity for 11 uses in the sol-gel with tetramethyl orthosilicate (TMOS) as precursor, and at least 7 uses in the sol-gel induced electrochemically with tetraethyl orthosilicate (TEOS) as precursor. The sol-gel made with TEOS as precursor and HCl as catalyst showed stability in enzyme activity for 11 uses but the activity decreases on the same sol-gel when modified with silica nanoparticles. Factors such as optimal incubation time …

Independent Domination In Complementary Prisms., Joel Agustin Gongora

Electronic Theses and Dissertations

Let G be a graph and G̅ be the complement of G. The complementary prism GG̅ of G is the graph formed from the disjoint union of G and G̅ by adding the edges of a perfect matching between the corresponding vertices of G and G̅. For example, if G is a 5-cycle, then GG̅ is the Petersen graph. In this paper we investigate independent domination in complementary prisms.

Qualitative Models Of Neural Activity And The Carleman Embedding Technique., Azamed Yehuala Gezahagne

Electronic Theses and Dissertations

The two variable Fitzhugh Nagumo model behaves qualitatively like the four variable Hodgkin-Huxley space clamped system and is more mathematically tractable than the Hodgkin Huxley model, thus allowing the action potential and other properties of the Hodgkin Huxley system to be more readily be visualized. In this thesis, it is shown that the Carleman Embedding Technique can be applied to both the Fitzhugh Nagumo model and to Van der Pol's model of nonlinear oscillation, which are both finite nonlinear systems of differential equations. The Carleman technique can thus be used to obtain approximate solutions of the Fitzhugh Nagumo model and …

The Last Of The Mixed Triple Systems., Ernest Jum

Electronic Theses and Dissertations

In this thesis, we consider the decomposition of the complete mixed graph on v vertices denoted M_v, into every possible mixed graph on three vertices which has (like M_v) twice as many arcs as edges. Direct constructions are given in most cases. Decompositions of theλ-fold complete mixed graph λM_v, are also studied.