Physical Sciences and Mathematics Commons^™

Geologic Face Mapping Methodology Utilizing Global Positioning Systems And Unmanned Aircraft Systems, Luke Whitenburg

Electronic Theses and Dissertations

Geologic field mapping has traditionally been a low-technology process, limited by time in the field and a delicate balance between data collection and coverage area. Advancements in Global Positioning Systems (GPS), Unmanned Aircraft Systems (UAS), and software packages offer new tools and techniques for collecting high volume, accurate geologic information. These tools can provide geologists with safe and efficient ways to collect and process greater volumes of field data.

Field data for this study was collected from three open pit mines using a Trimble Geo 7X GPS unit with Geo 7 Series Rangefinder module and a Phantom 4 Pro V2.0 …

Detection And Classification Of Diabetic Retinopathy Using Deep Learning Models, Aishat Olatunji

Electronic Theses and Dissertations

Healthcare analytics leverages extensive patient data for data-driven decision-making, enhancing patient care and results. Diabetic Retinopathy (DR), a complication of diabetes, stems from damage to the retina’s blood vessels. It can affect both type 1 and type 2 diabetes patients. Ophthalmologists employ retinal images for accurate DR diagnosis and severity assessment. Early detection is crucial for preserving vision and minimizing risks. In this context, we utilized a Kaggle dataset containing patient retinal images, employing Python’s versatile tools. Our research focuses on DR detection using deep learning techniques. We used a publicly available dataset to apply our proposed neural network and …

Comparative Analysis Of Surrogate Models For The Dissolution Of Spent Nuclear Fuel, Dayo Awe

Electronic Theses and Dissertations

This thesis presents a comparative analysis of surrogate models for the dissolution of spent nuclear fuel, with a focus on the use of deep learning techniques. The study explores the accuracy and efficiency of different machine learning methods in predicting the dissolution behavior of nuclear waste, and compares them to traditional modeling approaches. The results show that deep learning models can achieve high accuracy in predicting the dissolution rate, while also being computationally efficient. The study also discusses the potential applications of surrogate modeling in the field of nuclear waste management, including the optimization of waste disposal strategies and the …

Conversion Of Microcrystalline Cellulose To Hexane Using Hydrogenated Metal Oxides At Low Temperature And Pressure, Mubarak Osman

Electronic Theses and Dissertations

Increasing global energy demand and environmental concerns have fueled the exploration of sustainable and efficient methods for renewable fuel production. The conversion of cellulosic waste to hydrocarbon fuels using hydrogenated metal oxides presents a novel and eco-friendly approach to sustainably address energy demand. In this study, hydrogenated metal oxides were used as catalysts in a relatively low-temperature and atmospheric-pressure environment to facilitate the conversion of cellulosic waste into hydrocarbon fuels. Hydrogenated metal oxides have been introduced as potential hydrogen transfer catalysts. The expected result is the selective conversion of cellulose to hexane at relatively low temperatures, which significantly reduces energy …

Interpreting Shift Encoders As State Space Models For Stationary Time Series, Patrick Donkoh

Electronic Theses and Dissertations

Time series analysis is a statistical technique used to analyze sequential data points collected or recorded over time. While traditional models such as autoregressive models and moving average models have performed sufficiently for time series analysis, the advent of artificial neural networks has provided models that have suggested improved performance. In this research, we provide a custom neural network; a shift encoder that can capture the intricate temporal patterns of time series data. We then compare the sparse matrix of the shift encoder to the parameters of the autoregressive model and observe the similarities. We further explore how we can …

Magnetic Properties Of Zgnrs With Nitrogen And Fluorine Adsorbates, A Computational Study, Justin Petit

Electronic Theses and Dissertations

Imposing dimensional restrictions on graphene sheets and adding impurities can give rise to carbon nanostructures with magnetic properties. In this work, zigzag graphene nanoribbons, zGNRs, with nitrogen and fluorine adatoms are investigated for magnetic properties of interest for spin devices. Geometry optimizations were done determining which position along a zGNR electrode that N and F would favorably attach to. Edge positions were determined as the most stable attachment site. M-cell zGNR electrodes (M = 1-3) edge-functionalized by N and F adatoms were investigated with respect to their band structures and spin densities in antiferromagnetic and ferromagnetic, AFM and FM, configurations. …

Landslide Susceptibility And Tree Ring Eccentricity Analysis Along Unstable Slopes Of The New River Watershed, Anderson And Morgan Counties, Tn, Megan Palmer

Electronic Theses and Dissertations

Landslides are mass movements that affect infrastructure across East Tennessee, causing problems for the Tennessee Department of Transportation (TDOT). An assessment of conditions and locations of unstable slopes can aid TDOT in infrastructure management. Landslide susceptibility was evaluated for Anderson and Morgan counties, TN, off State Route 116 in the New River watershed. Susceptibility maps used a landslide inventory and six factors: elevation, slope, geology, distance from stream, rainfall, and curvature, input in forest-based classification and logistic regression models. Additionally, affected trees along these unstable slopes in Anderson and Morgan counties were cored to analyze mass movement impacts on tree …

Pathology And Osteological Observations Of Early Pliocene Rhinoceros, Teleoceras Aepysoma (Perissodactyla, Rhinocerotidae) From Gray Fossil Site, Tennessee, Thomas Scaife

Electronic Theses and Dissertations

Rhinoceroses were an important part of North America’s Paleogene and Neogene ecosystems, with Teleoceras aepysoma being one of the last representatives of this family. Specimens of T. aepysoma from the Gray Fossil Site (GFS) possess distinct/peculiar pathologies: including a pair of fused ribs and ankylosed phalanges. A qualitative description of the pathologies in the GFS T. aepysoma, including new material, was conducted to accurately identify pathologies and make interpretations about the life history of the GFS rhinos. Analysis suggests that rheumatoid arthritis is common in the lower limb bones of GFS rhinos. Additionally, the rib and toe pathologies are more …

Developing A Suitability Model And Feasibility Report For The Tennessee Mesonet, Tristan Holmes

Electronic Theses and Dissertations

Mesoscale networks, also known as Mesonets, are advanced environmental monitoring systems that consist of multiple high-quality weather stations that collect meteorological data at frequent intervals (5 minutes or less). Tennessee currently lacks a Mesonet system, and this study identifies suitable and feasible locations for stations in all 95 counties. Layers needed to develop the suitability model included land cover, road centerlines, elevation, flood zones, building footprints, and hydrologic soil types. Geospatial analysis techniques were used to process and combine these layers to identify suitable areas. Once suitable areas were determined, a feasibility assessment that examined land ownership, accessibility, and cell …

Multimodal Stylometry: A Novel Approach For Authorship Identification., Glory O. Adebayo

Electronic Theses and Dissertations

This dissertation introduces multimodal stylometry, a novel approach to authorship identification that integrates text and source code features for a comprehensive understanding of an author's unique style. Traditional stylometric methods have primarily focused on either text stylometry or source code stylometry, thereby neglecting the potential insights that multimodality may provide. This research aims to bridge this gap by proposing a framework that combines textual and source code data to enhance the accuracy and reliability of authorship identification. The study begins by reviewing existing literature on authorship identification and stylometry, highlighting the limitations of unimodal approaches. Leveraging recent advancements in multimodal …

Electrochemiluminescence Using Pencil Graphite Electrodes And Screen-Printed Carbon Electrodes Interfaced With A Simple Imaging System, Sandra Ehigiator

Electronic Theses and Dissertations

Electrochemiluminescence (ECL) is a phenomenon whereby electrochemical reactions generate a product that is capable of emitting light. ECL’s high sensitivity, selectivity, extremely low background, and relatively simple instrumentation make it particularly well-suited for chemical sensing and biosensing strategies. Here we report a simple ECL imaging system based on a camera interfaced with a zoom lens to compare pencil graphite electrode (PGE) and screen-printed carbon electrode (SPCE) arrays as ECL platforms. With this system, ECL signals generated from tris(2,2′- bipyridine)ruthenium(II) chloride hexahydrate ([Ru(bpy)3]2+) using co-reactant tri-n-propylamine (TPA) were linear with respect to [Ru(bpy)3]2+ concentrations from 9 to 450 μM. Detection limits …

Depositional Facies And Petrophysical Characterization Of The Leonardian Carbonate (Lower Clear Fork), Tex-Mex, S.E. Field, Central Basin Platform, West Texas, Seyram Nyamasekpor

Electronic Theses and Dissertations

The Lower Clear Fork from Tex-Mex, S.E. Field on the Central Basin Platform is a typical complex reservoir that displays high heterogeneity in lithological and petrophysical properties. The unit represents a producing reservoir succession of Leonardian platform carbonates deposited in shallow marine water during the Early Permian. The sediment of the Lower Clear Fork is composed of a mixed succession of dolomite interbedded with anhydrite, minor clay minerals, and siliciclastics. The high heterolithic nature of the reservoir makes efficient recovery of hydrocarbons difficult. This situation requires an understanding of the variability in depositional facies in terms of mineralogy, depositional textures …

Formalization Of A Security Framework Design For A Health Prescription Assistant In An Internet Of Things System, Thomas Rolando Mellema

Electronic Theses and Dissertations

Security system design flaws will create greater risks and repercussions as the systems being secured further integrate into our daily life. One such application example is incorporating the powerful potential of the concept of the Internet of Things (IoT) into software services engineered for improving the practices of monitoring and prescribing effective healthcare to patients. A study was performed in this application area in order to specify a security system design for a Health Prescription Assistant (HPA) that operated with medical IoT (mIoT) devices in a healthcare environment. Although the efficiency of this system was measured, little was presented to …

Predicting The Effects Of Precipitation On Groundwater Contamination Near Capped And Uncapped Coal Ash Storage Facilities In Louisville, Kentucky., Daryl Jialiang Chen

Electronic Theses and Dissertations

This study examines the impact of rainfall event characteristics and water table elevations on arsenic and boron contamination in groundwater near two coal ash ponds in Louisville, Kentucky. Utilizing data from 2011 to 2019, the research focuses on both capped and uncapped ponds at Mill Creek and Cane Run sites, employing Threshold Analysis, Regularized Discriminant Analysis (RDA) and Random Forest (RF) to assess contamination levels in groundwater. Analysis shows that capped ponds generally exhibit reduced arsenic levels, though variations exist depending on the contaminant and site. Key predictors such as maximum precipitation and river height were identified, highlighting their significant …

Synthesis, Electrical Conductivity, Electrocatalytic Activity For Water Splitting, And Pseudocapacitive Properties Of Perovskite Oxide Derivatives., Kinithi Meththa Kumari Wickramaratne

Electronic Theses and Dissertations

Developing green and sustainable energy solutions is crucial to addressing the energy and environmental challenges. Hydrogen is an attractive candidate given its high energy density and low carbon emission compared to gasoline and coal. Electrochemical water splitting through a water electrolyzer is recognized as a green method for generating hydrogen and oxygen gases. Developing cost-effective electrocatalysts to reduce overpotential in hydrogen and oxygen generation is essential for the overall process. The growing interest in perovskite oxides as versatile and sustainable catalysts is driven by their compositional flexibility, tunable electronic structure, earth abundance, and inherent catalytic performance. In our research, we …

Sustainable Methodologies For Synthesis Of Small Organic Molecules Using Micellar Catalysis., Deborah Sam Ogulu

Electronic Theses and Dissertations

Organic synthesis is a critical process in the creation of small molecule pharmaceuticals and agrochemicals. However, most methods for synthesizing these small molecules rely on toxic organic solvents as the reaction medium which account for approximately 80% of pharmaceutical waste. Moreover, many catalytic reactions require expensive endangered precious metals like palladium and costly metals. This dissertation presents research that aims to develop sustainable, eco-friendly reaction conditions to address these issues. We developed a ligand-free bimetallic nanocatalyst for the hydrogenation of unsaturated enones. This ligand-free nanocatalyst was prepared from nickel and ppm loading of palladium and was stabilized by harnessing the …

Strategy-Proof Social Choice Functions On Condorcet Domains., Flannery Marie Musk Wells

Electronic Theses and Dissertations

A social choice function is said to be strategy-proof if no voter has any motivation to lie about their true preference. Strategy-proofness is a desirable property of social choice functions so we consider here functions that always satisfy this property. We add to this property the additional desirable conditions of anonymity and neutrality and present domains on which we can get a characterization of majority rule as the only social choice function that satisfies these three properties. Furthermore, we consider what functions look like when we drop the condition of anonymity.

Assessing Sustainability Within The Brewing Industry: A Literature Review And Benchmarking Analysis., Elijah Thomas Miller

Electronic Theses and Dissertations

The goals of this study were twofold: to further examine sustainability within the brewing industry through a literature analysis across four academic journals, and a benchmarking analysis of a Louisville, Kentucky brewery’s resource consumption and emissions production. Publications related to the brewing industry were examined for the presence of sustainability keywords: “efficiency, sustainability, carbon footprint, climate change and greenhouse gas”. Benchmarking examined the local brewery’s primary production facility to determine their performance compared to other surveyed breweries pursuing sustainability across the country. Literature examination found noticeable discrepancies between the appearance of sustainability topics within article abstracts and their discussion within …

Ligand-Stabilized Sno2 As A High-Performance And Scalable Electron Transport Material For Inverted Perovskite Solar Cells., Sashil Chapagain

Electronic Theses and Dissertations

Over the past decade, perovskite solar cell (PSC) technology has attracted significant attention for its low material costs, simple fabrication processes, and impressive photovoltaic performance, with recent power conversion efficiencies (PCEs) surpassing 26%. This advancement marks PSCs as strong competitors to traditional silicon-based photovoltaics. Despite the high efficiency of PSCs, the path to commercialization is hindered by challenges in stability, scalability, and module efficiency. The stability and scalability of PSCs are primarily dependent on the successive charge transfer layers (CTLs) that are interfaced with the perovskite layer. Among CTLs, metal oxide (MO_x) CTLs are preferred for their cost-effectiveness, …

Using Dynamic Schemas For Query Optimization Over Json Data., Tomas Felipe Llano-Rios

Electronic Theses and Dissertations

Query optimization in document stores has traditionally relied on rule-based approaches, but recent research advocates for a shift towards cost-based optimization. However, this transition is hindered by the fragmented nature of existing approaches, stemming from the early development stage of cost-based query optimization for document databases. A key challenge lies in the absence of a standardized query language and semantics, exacerbated by the diverse and schema-less nature of JSON document collections. To tackle these challenges, the literature has proposed dynamic schemas, primarily utilized at parsing time. However, these schemas lack a formal foundation that describes meaningful semantics for query optimization. …

Development Of A High-Resolution Mid-Infrared Spectroscopy Apparatus For The Study Of Methane And Other Astrochemical Molecules., S M Shah Riyadh

Electronic Theses and Dissertations

This research documents steps towards building a novel spectroscopic technique, namely, cavity-enhanced double-resonance (CEDR) spectroscopy, for investigating methane (CH₄) and other molecules with significance in astrochemistry. These efforts focus on tackling the complexities of their ro-vibrational energy levels and the inefficiencies in analyzing vibrational spectra, particularly for molecules with high symmetry and strong intramolecular interactions. In the CEDR spectroscopy, the first photon, generated by a continuous-wave optical parametric oscillator (CW-OPO) locked to a Doppler-free saturation absorption line, excites the molecule from its ground level to a selected excited ro-vibrational (rotational-vibrational) level, e.g., that of the asymmetric CH-stretch mode. …

Multithreaded Applications On The Heterogeneous Research Computing Environment., Sungbo Jung

Electronic Theses and Dissertations

Bioinformatics is a domain that has experienced rapid research growth in recent years, as evidenced by the increasing number of articles in biomedical databases such as PubMed, which adds over a million publications every year. However, this also poses a challenge for researchers who need to find relevant citations for their work. Therefore, developing efficient indexing and searching methods for text data is crucial for Bioinformatics. One key technique for information retrieval is document inversion, which involves creating an inverted index to enable efficient searching through vast collections of text or documents. This Ph.D. research aims to design the research …

Utilizing Metal Ligand Cooperativity To Activate Small Molecules., Christine Burgan

Electronic Theses and Dissertations

The problems created from the excessive use of fossil fuels can be approached from two directions: capture the CO₂ from the atmosphere or develop alternative energy sources. The current industrial standards for these are environmental and/or health hazards and utilize precious metals, respectively. Metal ligand cooperativity (MLC) has emerged as a promising alternative to using precious metals to activate small molecules. In this dissertation, we focus on a series of metal complexes based on the ligand diacetyl-2-(4-methyl-thiosemicarbazone)-3-(2-hydrazinopyridine) (H₂L¹) for either hydrogen evolution or CO₂ capture. The novel complexes were characterized by ¹H NMR, …

Investigations Of Physical Properties Of Novel Magnetic And Non- Magnetic Two-Dimensional (2d) Alloys., Mohammed Ameen Irziqat

Electronic Theses and Dissertations

This research work reports investigations of structural and physical properties of novel magnetic and non-magnetic 2D alloys. Three techniques were utilized in this investigation: Angle-resolved polarized Raman spectroscopy (ARPRS), Electrical &Thermoelectric power measurements, Magneto-optic Kerr effect (MOKE) spectroscopy. ARPRS and MOKE experiments were constructed during the course of this work. ARPRS was used to study the anisotropy of 2-dimensional black-arsenic phosphors (b-AsxP1-x) as a function of arsenic concentration (x). It was observed experimentally that all Raman modes of the studied samples with x=0, 0.4, 0.8 exhibit polarization dependence. More interestingly, the polarization dependence of Raman modes due to the vibrations …

Electrochemical Modulation Of Surface Plasmon Wave To Investigate Dna-Based Sensing Platforms And Detection Of Sars-Cov2., Anil Sharma

Electronic Theses and Dissertations

This study offers a thorough comparative analysis of optical and electrical signaling strategies for assessing the electrochemical properties of different redox-labeled DNA-based biosensing platforms. In addition, it illustrates the development of an optical interrogation technique with electrochemical modulation of surface plasmon waves (ECM-SPW) as a route for analyzing and implementing DNA-based hybridization sensors. For those quantitative analyses, we chose a model sensing platform composed of a methylene blue (MB)-modified single-stranded DNA (ssDNA) signaling probe and an unlabeled capture ssDNA probe that complements the signaling probe. Two types of signaling probes were employed in this work: one with MB attached to …

Establishing “The Fossil Record”: A Database Of Vertebrate Paleontological Sites Across The State Of Tennessee, Sarah Mclaurine

Electronic Theses and Dissertations

Fossil localities across the state of Tennessee and the data related to those sites were compiled from Tennessee Division of Geology Bulletin 84, titled “Tennessee’s Prehistoric Vertebrates,” and stored in a Microsoft Access geodatabase housed by the Department of Collections at the East Tennessee State University Museum of Natural History located at the Gray Fossil Site. Included in the database are forms to enter new site localities, view information about those already entered, view and add data to a master faunal list for the state, view sites repository information and store and add documents that are key-word searchable from the …

The Interplay Of Spin, Charge, And Heat: From Metal/Insulator Heterostructures To Perovskite Bilayers, Sam M. Bleser

Electronic Theses and Dissertations

In this dissertation begin with an investigation of non-local spin transport in an amorphous germanium (a-Ge) sample via the inverse spin Hall effect (ISHE). In that study we show that commonly used techniques such as differential conductance and delta mode of a paired Keithley 6221/2182a for non-local resistance measurements can lead to false indicators of spin transport. Next, we turn out attention to a thickness dependent study in thermally-evaporated chromium (Cr) thin films on a bulk polycrystalline yttrium-iron-garnet (YIG) substrate. This project analyzed the spin transport in the Cr films versus thickness via the longitudinal spin Seebeck effect (LSSE). This …

Thermal, Electrical, And Spin Transport: Encompassing Low-Damping Ferromagnets And Antiferromagnetic/Ferromagnetic Heterostructures, Matthew Ryan Natale

Electronic Theses and Dissertations

Continuing technological advancements bring forth escalating challenges in global energy consumption and subsequent power dissipation, posing significant economic and environmental concerns. In response to these difficulties, the fields of thermoelectrics, spintronics, and spincaloritronics emerge as contemporary solutions, each presenting unique advantages. Thermoelectric devices, based on the Seebeck effect, other a passive, carbon-free energy generating solution from waste heat. Although current thermoelectric technology encounters hurdles in achieving optimal efficiencies without intricate designs or complex materials engineering, recently research into low-damping metallic ferromagnetic thin films have provided a new method to enhance spin wave lifetimes, thus contributing to thermoelectric voltage improvements. As …

Assessment Of Method Effects Of Keying And Wording In Instruments: A Mixed-Methods Explanatory Sequential Study, Lin Ma

Electronic Theses and Dissertations

This dissertation presents an innovative approach to examining the keying method, wording method, and construct validity on psychometric instruments. By employing a mixed methods explanatory sequential design, the effects of keying and wording in two psychometric assessments were examined and validated. Those two self-report psychometric assessments were the Effortful Control assessment (Ellis & Rothbart, 2001) and the Grit assessment (Duckworth & Quinn, 2009). Moreover, the quantitative phase utilized structural equation modeling to analyze 2,104 students’ responses and assess the construct of keying and wording. Various hypothetical models were investigated and evaluated. The reliability of each construct in each method was …

Phenomenological Inquiry Into Middle School Teachers’ Perception Of Creativity, Katalin Grajzel

Electronic Theses and Dissertations

Researchers do agree that creativity is an ability that can be developed and should be fostered (Guilford, 1958; Parnes, 1961). Teachers play an important role in creativity development and often serve as gatekeepers to identify gifted and talented students (Bianco et al., 2011; Novak & Jones, 2021; Schack & Starko, 1990). However, teachers’ judgment of their students’ creativity often only correlates weakly with the results of creativity measures (Kettler et al., 2018; Torrance, 1963). Therefore, in this study I explored teachers’ perception of creativity and creative students as well as factors that support or hinder creativity. The findings revealed that …