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Mössbauer Effect Study Of Filled Antimonide Skutterudites, Gary J. Long, Dimitri Hautot, Fernande Grandjean, Donald T. Morelli, Gregory P. Meisner

Chemistry Faculty Research & Creative Works

The iron-57 Mössbauer spectra of a series of Ce-filled antimonide skutterudites, Ce_xFe_4-yCo_ySb₁₂, where x varies from 0.22 to 0.98 and y varies from 0 to 3.5, have been measured at 295 K. In addition, the spectra of Ce_0.60Fe₂Co₂Sb₁₂ and Ce_0.82Fe₃CoSb₁₂ have been measured from 85 to 295 K and the spectra of Ce_0.35FeCo₃Sb₁₂ and Ce_0.98Fe₄Sb₁₂ have been measured from 4.2 to 295 K. The spectra, all of which consist of …