Physical Sciences and Mathematics Commons^™

Technology-Aided Participative Methods In Environmental Assessment: An International Perspective, Ainhoa Gonzalez, Alan Gilmer, Ronan Foley, John Sweeney, John Fry

Articles

Provisions for citizen involvement in the assessment of potential environmental effects of certain plans, programmes and projects are present in current legislation. An international survey revealed that public participation is common practice in European and some other countries worldwide. However, a number of issues are observed to affect public involvement in EIA/SEA processes and expert opinion differs when evaluating the effectiveness of existing participative methods. Results suggest that technology-aided methods can improve traditional participation processes. In particular, GIS has the potential to increase community knowledge and enhance involvement by communicating information more effectively. Variable accessibility to technology and data quality …

Multi-Algorithmic Cryptography Using Deterministic Chaos With Applications To Mobile Communications, Jonathan Blackledge

Articles

In this extended paper, we present an overview of the principal issues associated with cryptography, providing historically significant examples for illustrative purposes as part of a short tutorial for readers that are not familiar with the subject matter. This is used to introduce the role that nonlinear dynamics and chaos play in the design of encryption engines which utilize different types of Iteration Function Systems (IFS). The design of such encryption engines requires that they conform to the principles associated with diffusion and confusion for generating ciphers that are of a maximum entropy type. For this reason, the role of …

Object Detection And Classification With Applications To Skin Cancer Screening, Jonathan Blackledge, Dmitryi Dubovitskiy

Articles

This paper discusses a new approach to the processes of object detection, recognition and classification in a digital image. The classification method is based on the application of a set of features which include fractal parameters such as the Lacunarity and Fractal Dimension. Thus, the approach used, incorporates the characterisation of an object in terms of its texture.

The principal issues associated with object recognition are presented which includes two novel fast segmentation algorithms for which C++ code is provided. The self-learning procedure for designing a decision making engine using fuzzy logic and membership function theory is also presented and …

Equation Of State For A Van Der Waals Universe During Reissner–Nordstrom Expansion, Emil Prodanov, Rossen Ivanov, Vesselin Gueorguiev

Articles

In a previous work [E.M. Prodanov, R.I. Ivanov and V.G. Gueorguiev, Reissner-Nordström expansion, Astropart. Phys. 27 (2007) 150], we proposed a classical model for the expansion of the Universe during the radiation-dominated epoch based on the gravitational repulsion of the Reissner-Nordström geometry — naked singularity description of particles that "grow" with the drop of the temperature. In this work we model the Universe during the Reissner-Nordström expansion as a van der Waals gas and determine the equation of state.

Nearly-Hamiltonian Structure For Water Waves With Constant Vorticity, Adrian Constantin, Rossen Ivanov, Emil Prodanov

Articles

We show that the governing equations for two-dimensional gravity water waves with constant non-zero vorticity have a nearly-Hamiltonian structure, which becomes Hamiltonian for steady waves.

Evaluation Of A Naive Model For Square Wave Voltammetry At A Microelectrode, Patrick Enright, John Cassidy, Tony Betts

Articles

A square wave voltammetric waveform ( SWV) was applied to an inlaid microdisk electrode in a solution of K4[Fe(CN)6]. A simple model relying on the assumption of steady state current throughout the scan was used to model the current potential behaviour. However, experimental peak current magnitudes were between 30% and 50% greater than those predicted by the model. The model predicts an increase of peak current and peak width at half height with pulse height Esw and no effect of the parameters frequency, f and step height, ΔEs. Experimental peak current magnitudes and peak current magnitudes predicted by the model …

Existence Of A Solution To Hartree-Fock Equations With Decreasing Magnetic Field, Mattias Enstedt, Michael Melgaard

Articles

In the presence of an external magnetic field, we prove existence of a ground state within the Hartree–Fock theory of atoms and molecules. The ground state exists provided the magnetic field decreases at infinity and the total charge of nuclei exceeds , where is the number of electrons. In the opposite direction, no ground state exists if .

Luminescent Solar Concentrators: A Review Of Recent Results, Wilfrid G.J.H.M. Van Sark, Keith W.J. Barnham, Lenneke H. Slooff, Amanda J. Chatten, Andreas Buchtemann, Andreas Meyer, Sarah Mccormack, Rolf Koole, Daniel J. Farrell, Rahul Bose, Evert E. Bende, Antonius R. Burgers, Tristram Budel, Jana Quilitz, Manus Kennedy, Toby Meyer, C. De Mello Donega, Andries Meijerink

Articles

Luminescent solar concentrators (LSCs) generally consist of transparent polymer sheets doped with luminescent species. Incident sunlight is absorbed by the luminescent species and emitted with high quantum efficiency, such that emitted light is trapped in the sheet and travels to the edges where it can be collected by solar cells. LSCs offer potentially lower cost per Wp. This paper reviews results mainly obtained within the framework of the Fullspectrum project. Two modeling approaches are presented, i.e., a thermodynamic and a ray-trace one, as well as experimental results, with a focus on LSC stability.

Application Of The Fractal Market Hypothesis For Modelling Macroeconomic Time Series, Jonathan Blackledge

Articles

This paper explores the conceptual background to financial time series analysis and financial signal processing in terms of the Efficient Market Hypothesis. By revisiting the principal conventional approaches to market analysis and the reasoning associated with them, we develop a Fractal Market Hypothesis that is based on the application of non-stationary fractional dynamics using an operator of the type
∂² / ∂x² − σ^q(t) * ∂ ^q(t)/ ∂t^q(t)

where σ⁻¹ is the fractional diffusivity and q is the Fourier dimension which, for the topology considered, (i.e. the one-dimensional case) is related to the Fractal …

On An Integrable Two-Component Camassa-Holm Shallow Water System, Adrian Constantin, Rossen Ivanov

Articles

The interest in the Camassa-Holm equation inspired the search for various generalizations of this equation with interesting properties and applications. In this letter we deal with such a twocomponent integrable system of coupled equations. First we derive the system in the context of shallow water theory. Then we show that while small initial data develop into global solutions, for some initial data wave breaking occurs. We also discuss the solitary wave solutions. Finally, we present an explicit construction for the peakon solutions in the short wave limit of system.

Algebraic Discretization Of The Camassa-Holm And Hunter-Saxton Equations, Rossen Ivanov

Articles

The Camassa-Holm (CH) and Hunter-Saxton (HS) equations have an interpretation as geodesic flow equations on the group of diffeomorphisms, preserving the H1 and H.1 right-invariant metrics correspondingly. There is an analogy to the Euler equations in hydrodynamics, which describe geodesic flow for a right-invariant metric on the infinitedimensional group of diffeomorphisms preserving the volume element of the domain of fluid flow and to the Euler equations of rigid body whith a fixed point, describing geodesics for a left-invariant metric on SO(3). The CH and HS equations are integrable bi-hamiltonian equations and one of their Hamiltonian structures is associated to the …

Higher Derivatives Of Spectral Functions Associated With One-Dimensional Schrodinger Operators, Daphne Gilbert, B.J. Harris, S.M. Riehl

Articles

We investigate the existence and asymptotic behaviour of higher derivatives of the spectral function in the context of one-dimensional Schr¨odinger operators on the half-line with integrable potentials. In particular, we identify sufficient conditions on the potential for the existence and continuity of the n-th derivative, and outline a systematic procedure for estimating numerical upper bounds for the turning points of such derivatives. Explicit worked examples illustrate the development and application of the theory.

Contextualising Nanotechnology In Chemistry Education, Christine O'Connor, Hugh Hayden

Articles

This paper will give an example of a pedagogical approach taken in integrating nanotechnology into a chemistry degree course. In recent years nanotechnology has widely become part of the course content for undergraduate chemistry and physics degree curriculum. How contextualised the delivery of the subject matter may vary. The role of contextualisation of nanotechnology in the delivery of the content is the main focus of this paper, as to date in Ireland and many other countries nanotechnology has not been integrated into many chemistry degree courses but is slowly becoming the case. An evaluative methodology of the pedagogical approach for …

Method For Characterization Of Diffusion Properties Of Photopolymerisable Systems, Tzvetanka Babeva, Izabela Naydenova, Suzanne Martin, Vincent Toal

Articles

A novel approach for measuring the diffusion coefficients in photopolymerisable materials is proposed. The method is based on studying the evolution of the surface relief profile in a single illuminated spot using an interferometric surface profiler. It is shown that the observed post-exposure swelling in the illuminated spot is due to mass-transport of monomer from the unexposed to the exposed area driven by a monomer concentration gradient set up by the monomer polymerization in the exposed area. Appropriate choice of the thickness of the studied layers ensures both lateral movement of monomer and negligible contribution from the depth. The diffusion …

Implementation Of Phase-Only Modulation Utilizing A Twisted Nematic Liquid Crystal Spatial Light Modulator, Mohammad Mahmud, Izabela Naydenova, Vincent Toal

Articles

Twisted nematic liquid crystal spatial light modulators, (SLM) are widely used for amplitude modulation of light. The technique for measuring phase and amplitude modulation introduced by a twisted nematic cell is not new but the novelty here is that after characterisation of a Holoeye LC2002 TNLC device we were able to identify specific conditions that allow for its use as a pure 180 degree or more, phase modulator with little or no amplitude modulation at 514.5 nm laser wavelength. The phase shift introduced by the SLM was measured using a Mach-Zehnder interferometer. The experimentally measured and the theoretically predicted intensity …

Fabrication Of Switchable Liquid Crystal Devices Using Surface Relief Gratings In Photopolymer, Pavani Kotakonda, Izabela Naydenova, Robert Howard, Suzanne Martin, Vincent Toal

Articles

Holographically recorded surface relief gratings in dry, self-developing acrylamide based photopolymer were used to fabricate two types of switchable liquid crystal (LC) device. One is an electrically switchable LC diffraction grating and the other is an electrically switchable polarization rotator. The electrically switchable diffraction grating was characterized by measuring the dependence of the intensity in the first diffracted order on the applied electric field. The polarization rotator was characterized by studying the influence of the applied electric field on the twist angle and the variation of intensity in the zero and the first orders of diffraction.

Nanocomposites For Novel Holographic Applications, Izabela Naydenova, Svetlana Mintova, Suzanne Martin, Vincent Toal

Articles

Nanozeolites incorporated into photopolymerizable holographic recording materials can be used for holographic sensing, data storage, and optical systems design.

Covert Encryption And Document Authentication Using Texture Coding, Jonathan Blackledge, Mary Hallot

Articles

With the improvements in the quality of Commercial-Off-The-Shelf (COTS) printing and scanning devices, the ability to counterfeit documents has become a widespread problem. Consequently, there has been an increasing demand to develop digital watermarking techniques which can be applied to both electronic and printed images (and documents) that can be authenticated, prevent unauthorized copying and withstand abuse and degradation. In this paper , a new approach to digital watermarking is presented and a range of possible applications are considered. The process is defined by using concepts and techniques borrowed from Cryptography. It is based on computing a 'scramble image' by …

Improved High-Temperature Stability And Sun-Light-Driven Photocatalytic Activity Of Sulfur-Doped Anatase Tio2, Suresh Pillai, Declan Mccormack, Pradeepan Periyat, John Colreavy, Steve Hinder

Articles

No abstract provided.

A Visual Indication Of Environmental Humidity Using A Color Changing Hologram Recorded In A Self-Developing Photopolymer, Izabela Naydenova, Raghavendra Jallapuram, Vincent Toal, Suzanne Martin

Articles

A reflection hologram for visual indication of environmental humidity has been studied. The hologram is recorded in a self-developing photopolymer and changes color when exposed to a change in humidity and is fully reversible. The range of color change, reversibility, and the response time of the hologram have been studied in a controlled humidity environment. Fully reversible holograms with response times from few seconds to tens of minutes have been designed. Extremely sensitive bright visual humidity indicators, capable of dramatic color change within a few seconds of breathing on them are demonstrated

Prevention Of Staphylococcus Epidermidis Biofilm Formation Using A Low-Temperature Processed Silver-Doped Phenyltriethoxysilane Sol–Gel Coating, Niall Stobie, Brendan Duffy, Declan Mccormack, John Colreavy, Martha Hidalgo, Patrick Mchale, Steven Hinder

Articles

Sol–gel coatings which elute bioactive silver ions are presented as a potential solution to the problem of biofilm formation on indwelling surfaces. There is evidence that high-temperature processing of such materials can lead to diffusion of silver away from the coating surface, reducing the amount of available silver. In this study, we report the biofilm inhibition of a Staphylococcus epidermidis biofilm using a low-temperature processed silver-doped phenyltriethoxysilane sol–gel coating. The incorporation of a silver salt into a sol–gel matrix resulted in an initial high release of silver in de-ionised water and physiological buffered saline (PBS), followed by a lower sustained …

Practical Sensor For Measurement Of Nitrogen, Dusan Popovic, Vladimir Milosavljevic, Steven Daniels

Articles

This paper presents a method for precise measurement of atomic and molecular nitrogen in an oxygen-nitrogen dc plasma. This is achieved by monitoring the intensities of the atomic nitrogen spectral line at 821.6 nm and the molecular nitrogen bandhead at 337.1 nm, relative to the atomic oxygen spectral line at 844.7 nm. Oxygen is one of the most frequently used gases for surface chemical treatment, including deposition and etching, therefore the ability to measure and control the process and chemical composition of the process is essential. To validate this oxygen actimometry method for N2-xO2 (where x varies from 0 to …

A Cosmic Ray Current-Driven Instability In Partially Ionised Media, Brian Reville, John Kirk, Peter Duffy, Stephen O'Sullivan

Articles

We investigate the growth of hydromagnetic waves driven by streaming cosmic rays in the precursor environment of a supernova remnant shock. It is known that transverse waves propagating parallel to the mean magnetic field are unstable to anisotropies in the cosmic ray distribution, and may provide a mechanism to substantially amplify the ambient magnetic field. We quantify the extent to which temperature and ionisation fractions modify this picture. Using a kinetic description of the plasma we derive the dispersion relation for a collisionless thermal plasma with a streaming cosmic ray current. Fluid equations are then used to discuss the effects …

An Investigation Of Introductory Physics Students’ Approaches To Problem Solving, Laura Walsh, Robert Howard, Brian Bowe

Articles

This paper outlines ongoing research investigating students’ approaches to quantitative and qualitative problem solving in physics. This is an empirical study, which was conducted using a phenomenographic approach to analyse and interpret data from individual semi-structured interviews with students from introductory physics courses. The result of the study thus far is a preliminary set of hierarchical categories that describe the students’ problem-solving approaches when faced with various physics problems. The findings from the research presented here indicate that many introductory students in higher education do not approach problem solving in a strategic manner and many do not try to link …

A Three‐Dimensional Numerical Method For Modelling Weakly Ionized Plasmas, Stephen O'Sullivan, Turlough Downes

Articles

Astrophysical fluids under the influence of magnetic fields are often subjected to single- or two-fluid approximations. In the case of weakly ionized plasmas, however, this can be inappropriate due to distinct responses from the multiple constituent species to both collisional and non-collisional forces. As a result, in dense molecular clouds and protostellar accretion discs, for instance, the conductivity of the plasma may be highly anisotropic leading to phenomena such as Hall and ambipolar diffusion strongly influencing the dynamics.

Torsion-Free Groups And Modules With The Involution Property, Brendan Goldsmith, C. Meehan, S.L. Wallutis

Articles

An Abelian group or module is said to have the involution property if every endomorphism is the sum of two automorphisms, one of which is an involution. We investigate this property for completely decomposable torsion-free Abelian groups and modules over the ring of -adic integers.

A Note On Clean Abelian Groups, Brendan Goldsmith, P. Vamos

Articles

Nicholson defined a ring to be clean if every element is the sum of a unit and an idempotent. A module is clean if its endomorphism algebra is clean. We show that torsion-complete Abelian p-groups are clean and characterize the clean groups among the class of totally projective p-groups. An example is given of a clean p-group which is neither totally projective nor torsion- complete

Shellability Of Noncrossing Partition Lattices, Colum Watt, Thomas Brady, Christos Athanasiadis

Articles

We give a case-free proof that the lattice of noncrossing partitions associated to any finite real reflection group is EL-shellable. Shellability of these lattices was open for the groups of type $D_n$ and those of exceptional type and rank at least three.

Synthesis And Characterisation Of Tetra-Tetrazole Macrocycles, Andrew Bond, Adrienne Fleming, Fintan Kelleher, John Mcginley, Vipa Prajapati, Signe Skovsgaard

Articles

The syntheses of tetra-tetrazole macrocycles, containing two bis-tetrazole units linked by a variety of alkyl chain lengths from four to eight carbons, are described. The crystal structures of three of these derivatives are reported, and the molecular conformation in the solid state is compared to that of one previously reported tetra-tetrazole macrocycle and to other bis- and tris(tetrazole)benzene structures. The macrocycle conformation is influenced by the length of the alkyl chain linker, the relative orientation of the tetrazole rings on the benzene ring, and by intermolecular interactions. In the macrocycles based on 1,2-bis(tetrazole)benzene, the adjacent tetrazole rings on the benzene …

Growth Substrate Induced Functional Changes Elucidated By Ftir And Raman Spectroscopy In In-Vitro Cultured Human Keratinocytes., Aidan Meade, Fiona Lyng, Peter Knief, Hugh Byrne

Articles

Non-invasive measurements of cellular function in in-vitro cultured cell lines using vibrational spectroscopy require the use of spectroscopic substrates such as quartz, ZnSe and MirrIR etc. These substrates are generally dissimilar to the original in-vivo extracellular environment of a given cell line and are often tolerated poorly by cultured cell lines resulting in morphological and functional changes in the cell. The present study demonstrates various correlations between vibrational spectroscopic analyses and biochemical analyses in the evaluation of the interaction of a normal human epithelial keratinocyte cell line (HaCaT) with MirrIR and quartz substrates coated with fibronectin, laminin and gelatin. The …