Physical Sciences and Mathematics Commons^™

Evaluating The Effect Of Hyporheic Exchange On Intake Temperatures Of Open-Loop Geothermal Wells In Glacigenic Outwash Aquifers, Nathan Grigsby

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Subsurface heat flow was simulated to study the effect of hyporheic exchange on groundwater intake temperatures of open-loop geothermal wells in glacigenic-outwash aquifers in the North American midcontinent. The model represents an aquifer kilometers wide, on the order of 100m thick, and directly connected to a perennial river. The aquifer has bimodal hydraulic conductivity with a geometric mean on the order of 100m/day, an effective thermal conductivity of 2.33W/mK, and specific heats on the order of 106J/(m^3 K) for water and 103J/kgK for solids. The aquifer is initially set to a temperature of 12.85 °C and the river is fixed …

Cometabolic Degradation Of Halogenated Aliphatic Hydrocarbons By Aerobic Microorganisms Naturally Associated With Wetland Plant Roots, Madelyn M. Smith

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Wetland systems provide both anaerobic (reducing) and aerobic (oxidizing) zones for the biodegradation of chlorinated aliphatic hydrocarbons (CAH). In particular, wetland plant roots provide micro-oxidizing environments for methanotrophic bacteria from the presence of methane, which is produced in anaerobic zones, and oxygen, which is brought to the subsurface by roots of wetland plants; this shows the potential for cometabolic degradation of common organic pollutants.

This study explored the natural attenuation of CAHs by methanotrophic bacteria naturally associated with roots of the common wetland plant, Carex comosa. Root microcosms were amended with varying concentrations of methane; trichloroethene; cis 1,2-dichloroethene; 1,2-dichloroethane; or …

Reservoir Characterization And Seismic Expression Of The Clinton Interval Over Dominion's Gabor Gas Storage Field In North-East Ohio, Scott Michael Bey

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In northeastern Ohio, an interval of interbedded sandstone and shale between the Queenston Shale and the Dayton Formation (both in the Silurian System) has long been referred to as the "Clinton interval". The Clinton interval has produced oil and gas for over a century, but has been converted locally to gas storage. Within the Clinton interval, reservoirs are commonly compartmentalized, in part because the sandstones are discontinuous but also because fractures enhance permeability in portions of otherwise continuous sandstones. The goal of this study is to characterize the Clinton interval within the Gabor gas storage field of Dominion East Ohio …

The Kozeny-Carman Equation Considered With A Percolation Threshold, Lee Brenson Porter Ii

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A procedure has been developed for calculating permeability (k) from the Kozeny-Carmen equation, a procedure that links ideas from percolation theory with the ideas of Koltermann and Gorelick (1995) and Esselburn et al. (2011). The approach focuses on the proportion of coarser pores that are occupied by finer sediments and defines a threshold proportion. For proportions below this threshold, the unoccupied coarser pores percolate. Following the ideas of Koltermann and Gorelick (1995), the effective grain-size term in the Kozeny-Carman equation is calculated using the geometric mean if below the threshold proportion, and with the harmonic mean if above. Following ideas …

Analysis Of An Eocene Bone-Bed, Contained Within The Lower Lisbon Formation, Covington County, Alabama, Angela Ann Clayton

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A fossiliferous lag layer is exposed, at low water levels, next to Point "A" Dam north of River Falls, Alabama. The location of the research site was a coastal region, during the Middle Eocene, and most likely an estuary with complex depositional systems due to the interaction of fluvial and tidal processes. Most of the vertebrate remains at this locality are well preserved and indicate a low-energy environment. The exposure consists of unconsolidated sands rich with Chondrichthyan and Reptilian remains. Little work has been conducted at this location and the exposure was thought to be conformable. With a thorough lithological …

Littoral Zone Structure, Energy Mobilization And Benthic Food Webs In Oligotrophic Northern Temperate Lakes, Shawn P. Devlin

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Lakes are usually described by pelagic-based characteristics such as trophic status or stratification and mixing regimes. These categorization schemes neglect among-lake differences in the physical and biological structure of the littoral zone. The extensive use of stable isotopes has led to a better integration of pelagic dynamics and littoral processes in limnology. In order to further our understanding of littoral trophic dynamics I conducted a detailed investigation of benthic primary production, littoral sediment bacterial production, and zoobenthic consumer resource use in oligotrophic temperate lakes. I have found that among-lake variation in benthic primary and bacterial production reflects littoral zone structure. …

Methylmercury In Mosquitoes: Impact Of A Large Coal-Fired Power Station In Central Ohio, Matthew J. Konkler

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Emissions from coal-fired utilities are the major anthropogenic source of mercury (Hg) to the atmosphere. Because emitted Hg may be deposited near the source, there are concerns on levels of toxic monomethylmercury (MeHg) in local biota. We investigated the potential impact of a large Hg-emitting (> 500 kg Hg y-1) coal-fired power station on MeHg levels in mosquitoes near the Conesville power station in central Ohio. Mosquitoes were sampled with CO2-baited traps at 23 locations within a 60 km radius of the utility and at three reference sites distant from Hg combustion sources. MeHg in mosquitoes within a 30-km radius …

Marine Vertebrate Remains From Middle-Late Devonian Bone Beds At Little Hardwick Creek In Vaughns Mill, Kentucky And At The East Liberty Quarry In Logan County, Ohio, John M. James

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Stratigraphic, lithologic, faunal and condont biozone analysis will provide insight to whether or not East Liberty Bone Bed, in Logan County, Ohio, and Little Hardwick Creek Bone Bed C, in Vaughns Mill, Kentucky, are chronostratigraphic correlations to one another; they are separated by 370 kilometers (230 miles). Material from each bed was collected and broken down in acid and analyzed. Remaining residue after acid treatment was analyzed under a dissecting microscope for lithological and fossil contents, identified from previous fossil vertebrate findings at other locations.

Final analysis of these beds showed that lithologically and faunally they are very similar. However, …

Estimating Permeability From The Grain-Size Distributions Of Natural Sediment, Lawrence Mastera

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Permeability, k, can be estimated using the Kozeny-Carman equation, given a grain-size distribution with any number of grain-size categories and the porosity of a sediment. A recursive method was developed to calculate the effective grain-size parameter, d, for sediment mixtures with more than three grain sizes. The method was tested on four sediment models of sand, gravelly sand, sandy gravel, and open-framework gravel created from grain-size distributions. The k estimated from the recursive method were consistent with physical measurements of k.

Dimethylmercury Production In Freshwater Sediments, David C. Kelly

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Dimethylmercury (DMHg) has been examined almost exclusively in marine environments to date, plays an uncertain role in the global cycling of Hg, and is produced by a currently unknown mechanism in natural systems. We examined DMHg production in microcosms containing 100 cm3 of freshwater sediment sampled from 3 wetlands and a lake near Dayton, Ohio. DMHg was produced from all sediments analyzed, and found that production is increased significantly by the addition of inorganic Hg from ~0.1pM to ~10pM, its production is unaffected by autoclaving the sediment, and organic carbon additions had no discernible effect on production. Its total concentrations …

Crustacean Endocrine Disruption Through A Pathway Involving Nuclear Receptors, Cyclic Nucleotides And Calcium Transporters, Laxminath Tumburu

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Endocrine disruption is a complex phenomenon in the sense that endocrine disrupting chemicals (EDCs) are known to act via multiple modes of action, but the mechanisms of actions are poorly understood. In crustaceans, calcium (Ca²⁺) apart from its role as a second messenger, is also a major constituent of the calcified exoskeleton which undergoes a periodic mineralization/demineralization process known as the molting cycle. Molt cycle is under the control of steroid hormones, ecdysteroids. EDCs disrupt this molting process via their interference with receptor-mediated ecdysteroid signaling. However, the hormonal regulation of Ca²⁺ flux in crustacean molting is poorly …

How The Growth Of The Frampton Fold Affected The Growth Of The Green Knoll Diapir, John A. Zinck

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The growth of structural features formed by the movement of the Louann Salt within the study area follows a fold-first model (Rowan et al., 2000), in which the formation of the Frampton Fold predates the formation of the Green Knoll Diapir. The Frampton Fold was formed during two growth episodes driven by movement of the Louann Salt within the study area. The folding and faulting resulting from these growth episodes created a conduit through which the autochthonous Louann Salt was extruded to the sea floor during the Pliocene. Following a depositional episode consisting of the early sequences of the Mississippi …

Estimating Evapotranspiration Using Remote Sensing: A Hybrid Approach Between Modis Derived Enhanced Vegetation Index, Bowen Ratio System, And Ground Based Micro-Meteorological Data, Sumantra Chatterjee

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We investigated water loss by evapotranspiration (ET) from the Palo Verde Irrigation District (PVID) and the Cibola National Wildlife Refuge (CNWR) in southern California bordering the Colorado River collaborating with the United States Bureau of Reclamation (U.S.B.R.). We developed an empirical model to estimate ET for the entire PVID using satellite derived MODIS enhanced vegetation index (EVI), and ground based measurements of solar radiation and vapor pressure. We compared our predictions with U.S.B.R. estimates through statistical cross validation and showed they agree with an error less than 8%. We tested the same model for an alfalfa field inside PVID to …

Reservoir Analysis Of The Clinton Interval In Stark And Summit Counties, Ohio, Dominick Andrew Wytovich

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The characteristics of a sandstone reservoir of Silurian age (the "Clinton interval") were analyzed using 382 geophysical well logs from the Dominion Gas storage field located in Stark and Summit Counties, Ohio. These sandstones have long been identified by the informal drillers' terms, White, Red, and Stray Clinton. Gamma ray logs were used to analyze the distribution of net stand thickness and its relation to initial production through the construction of isopach and net sand isolith maps. I constructed eight cross sections to identify and correlate the tops of three prominent sandstones and two marine flooding surfaces to evaluate reservoir …

Functional Identification Of Microorganisms That Transform Mercury In Marine Sediments, Lisa Romas

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Monomethylmercury (MMHg) is the toxic form of mercury (Hg) that biomagnifies in food webs, and human exposure to MMHg occurs predominantly via consumption of fish. The primary source of MMHg to the marine environment is thought to be in situ sedimentary production by benthic microorganisms, namely sulfate-reducing bacteria (SRB). I collected sediments from the continental shelf (stations 2 and 6) and slope (station 9) of the NW Atlantic Ocean, and amended them with various inhibitor and promoter solutions to target specific functional groups capable of Hg transformations. I also added stable enriched Hg isotopes to quantify gross Hg methylation and …

Mercury Speciation In Temperate Tree Foliage, Melissa Danielle Tabatchnick

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Cycling of mercury (Hg) and monomethylmercury (MMHg) in forest ecosystems can affect exposures of terrestrial and aquatic wildlife within the watershed. Litterfall has been posited to be a major source of MMHg and total Hg to the forest floor; however, the origin of MMHg associated with tree foliage is largely unknown. I tested the hypothesis that leaf MMHg would be controlled by root uptake and thereby proportional to levels in soil. Fresh leaves and associated soil samples were sampled from nine tree species (deciduous and coniferous) at 30 locations spanning a 1145 km2 area in southwest Ohio, a region presumed …

Trace Metal Fluxes In Southwest Ohio Watersheds, Avani Naik

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Land-use and watershed characteristics affect the cycling and transport of trace metals in rivers. I investigated the influence of different land uses and water physicochemistry on loadings, partitioning, and speciation of Hg, Zn, Cr, Ni, V, Cd, Cu, and Pb in three contrasting watersheds near the Dayton, Ohio metropolitan area over a 13-month period; Wolf Creek (urban/residential), Holes Creek (urban/residential), and Little Miami River (agricultural). Metal concentrations were related positively to discharge in each stream. Dissolved organic ligands appear to influence trace-metal partitioning between filtered and particle phases, however, particle-associated metals were dominant in each site. Total Hg concentrations and …

Biodegradation Of Groundwater Pollutants (Chlorinated Hydrocarbons) In Vegetated Wetlands: Role Of Aerobic Microbes Naturally Associated With Roots Of Common Plants, Christina Lynn Powell

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Chlorinated aliphatic hydrocarbons (CAHs) are often found as groundwater contaminants because of past industrial activities and disposal practices. CAHs pose a threat to human health and thus, create a need to find both natural and engineered processes that can remove these chlorinated compounds from the environment. Natural attenuation by oxidative biodegradation is especially important because it can allow for mineralization to carbon dioxide, a nontoxic end-product. The goal of this research was to evaluate the potential oxidative biodegradation of CAHs by microorganisms that are naturally associated with wetland plant roots. The research was divided into field work and laboratory batch …

Conversion Of Carbon Dioxide And Hydrogen Into Methane In Bench-Scale Microcosms And Packed Column Reactors, Brian Alexander Congiu

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Escalating energy demands, rising costs, and increasing awareness of the environmental impacts of current energy sources have created an immediate need for sustainable, alternative energy resources and innovative fuel technologies. It is believed that a potential carbon-neutral fuel source can be generated through the microbial production of methane gas by methanogenic archaea. Carbon dioxide captured from the atmosphere and renewable production of hydrogen can be used to support these microorganisms for the large-scale production of methane. Bench-scale investigations involving 160 mL serum bottle batch experiments and two 11L packed-column reactors were conducted to evaluate the feasibility and efficiency of microbial …

Transport Through Georeservoirs: Spatial Entropy In Hydraulic Properties, And Temporal Entropy In Residence Time Distributions, Lumeng Huang

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The general principle of maximum entropy can be used to guide the construction of flow and transport models parameters when are uncertain. The principle states that the model which maximizes the entropy should be chosen so that the full multiplicity or uncertainty is represented in the model outcomes.

In models for flow and transport through georeservoirs, the principle would commonly be applicable to the uncertainty in the model outcome for the time of travel through the system, in order to represent the full range of multiplicity in the distribution of residence times. Importantly, the model which maximizes the entropy in …

Eco-Epidemiological Analysis For Screening-Level Ecological Risk Assessment: A Geographic Information Systems Approach, Katherine E. Kapo

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The identification and prioritization of multiple watershed stressors and the corresponding development of optimal management strategies remains a challenge in ecological risk assessment. Eco-epidemiological analysis of archival environmental spatial databases integrates available biological, physical and chemical information to generate hypotheses based on stressor-response data relationships. A geographic information systems-based technique incorporating Bayesian weights-of-evidence analysis and weighted logistic regression (WOE/WLR) developed for and currently utilized in minerals exploration was extrapolated to the eco-epidemiological analysis of aquatic ecosystem data. Case studies within state of Ohio (USA) and England and Wales were conducted to demonstrate a method proof-of-concept in the context of various …

Conservation Genetics Of A Near Threatened Freshwater Mussel Species (Lampsilis Cardium) And Improved Prospects For Recovery: How Nuclear And Mitochondrial Dna Analyses Inform Natural History And Conservation, Chad D. Ferguson

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Freshwater mussels (Bivalvia: Unionidae) are among the most imperiled organisms in North America. While there is an urgent need for effective conservation planning and management of these organisms, important basic biological information is lacking. This research characterizes levels of genetic diversity and population structure in the Near Threatened (IUCN) freshwater mussel Lampsilis cardium in populations from Twin Creek (southwest Ohio), Little Darby and Big Darby Creeks (central Ohio), and Little Muskingum River (eastern Ohio) and assesses the extent to which regional geological events explain population structuring. Data from the congener Lampsilis ovata from Clinch River (Tennessee) are included for comparison. …

The Continuity Of High-Permeability Zones In Sedimentary Deposits, Arijit Guin

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Cubic lattice models were used to represent sedimentary deposits and their role as georeservoirs. The percolation of high-permeability zones was studied using both analytical and simulation approaches. The analytical approach was developed for single-scale sedimentary architecture. The approach showed that percolation is affected by cluster spatial correlation and by lattice size. It showed that correlation affects both high-permeability and low-permeability clusters equally, and thus correlation does not likely affect the percolation threshold for infinite lattices. On finite lattices, the analysis showed that the effect of correlation on lowering the percolation threshold can be understood through the truncation of low-permeability cluster-size …

Measuring The Permeability Of Open-Framework Gravel, James Thomas Ferreira Jr.

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Open-framework gravel has permeability, k, above the measurement range of most conventional constant-head permeameters used in laboratories. Here I addressed the challenge of measuring such high k by using a permeameter long enough that the differences in head across it were on the order of 10-3 m and therefore measurable. I collected data over the range from linear-laminar flow to non-linear, non-Darcian flow. In doing so, I verified that k was measured under Darcian flow. I measured k between 4,000 and 100,000 Darcies among experiments using different sediments.

Porosity And Permeability In Ternary Sediment Mixtures, Jason Dennis Esselburn

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Porosity and permeability were measured in mixtures of fine, medium, and coarse sand, where the volume fraction of each of the three components was systematically varied. The porosity varies non-linearly with the volume fractions, and can be modeled with a piecewise-linear approach. The permeability also varies non-linearly with the volume fractions. Permeability can be modeled with the Kozeny-Carman equation using a recursive approach for computing the representative grain size from those of the components in the mixture.

A Morphometric Analysis Of The Highly Variable Clypeasteroid, Periarchus Lyelli, Lauren Elizabeth Williamson

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The Late Eocene echinoid, Periarchus lyelli (Conrad, 1834), known for its wide geographic range, high abundance, and specific stratigraphic range, is an ideal example of a guide fossil. However, due to its highly variable test morphology, many have questioned if, in fact, this sand dollar is actually two or three distinct species that have been misclassified. A preliminary study on this subject has been performed on specimens from Mississippi, North Carolina and South Carolina (Williamson, 2006), showing significant separation in test shapes. Continuing previous research, this study analyzes the test shapes of P. lyelli over its entire North American geographic …

Bench-Scale Conversion Of Carbon Dioxide To A Hydrocarbon Fuel, Melissa L. Kennedy

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There is a growing concern about the effects of global warming that many believe is anthropogenically caused. As such, scientists are trying to uncover a viable alternative fuel source and establish a way to reduce atmospheric carbon dioxide levels. A potential solution that addresses both of these aspects would be to capture atmospheric carbon dioxide and convert it into a natural gas, in particular methane, which could be used as an energy source. A laboratory-scale experiment using 6 160 mL microcosms (3 with anaerobic wetland soil and 3 relatively soil free) and 2 7.2 L bioreactors was conducted to learn …

Linking Plume Spreading To Hierarchical Stratal Architecture, Ramya Ramanathan

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A new form of the Lagrangian-based model for macrodispersion of inert (non-reactive) solutes is presented. The model is based on a hierarchical expression of the spatial covariance of log-permeability representing a hierarchy of stratal unit types with a corresponding hierarchy of permeability subpopulations. The covariance expression representing the hierarchy of unit types is a linear sum of terms corresponding to the probability of transitioning across stratal unit types of different scales, and these terms are directly related to quantifiable geometric attributes of the hierarchical stratal architecture. The new macrodispersion model is also a linear sum of terms, with different integral …

Using Morphometrics, Phylogenetic Systematics And Parsimony Analysis To Gain Insight Into The Evolutionary Affinities Of The Calymenidae Trilobita, Alex J. Chestnut

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The most common trilobite in the Silurian carbonates of Ohio - especially the Springfield Dolomite - is a species that has been assigned to at least five genera over the past 100 years. This trilobite has been variously referred to as Calymene celebra, Apocalymene celebra, Flexicalymene celebra, Gravicalymene celebra, and Sthenarocalymene celebra. Reexamination of the species "Calymene" celebra through parsimony and morphometric analysis was conducted to properly place this calymenid species within the correct genus. What compounds the confusion is that the characters used to seperate the genera within the family Calymenidae, and therefore create the basis for the argument …

Hydrogeochemistry And Water Quality Of Echo Hills, Joel M. Kimball

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Ground water of the Echo Hills area in Clark County, Ohio was investigated for common water contaminants such as nitrate and coliform bacteria. Thirty-four water samples were collected from locations including private wells, streams and a spring. Nine of those samples were selected for nitrogen isotope analysis. Three locations were chosen for a tracer test. Additionally, well log data, historical water quality data, and GIS data were obtained from the Clark County Health Department in Springfield, Ohio. Results show that local agriculture likely has the greatest impact on ground water quality in Echo Hills especially the north-eastern portion, with local …