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Full-Text Articles in Physical Sciences and Mathematics

Anthropogenic Causes Of Copepod Mortality And Bacterial Decomposition Of Copepod Carcasses, Samantha L. Bickel Jan 2009

Anthropogenic Causes Of Copepod Mortality And Bacterial Decomposition Of Copepod Carcasses, Samantha L. Bickel

Dissertations, Theses, and Masters Projects

Although zooplankton carcasses can be quite prevalent within aquatic systems, they have largely been overlooked in most zooplankton population studies. Anthropogenic stressors can potentially increase the overall abundance of carcasses on a local scale. Once a carcass is present within a system, the fate of its biomass is of considerable interest as it may be remineralized within the water column or transported to depth. Through the collection of field samples I assessed the possibility of an anthropogenic stressor (boat-generated turbulence) as a potential source of nonconsumptive mortality. I also conducted a series of laboratory experiments to monitor the decomposition of …


A Numerical Modeling Study On Barotropic And Baroclinic Responses Of The Chesapeake Bay To Hurricane Events, Kyoung-Ho Cho Jan 2009

A Numerical Modeling Study On Barotropic And Baroclinic Responses Of The Chesapeake Bay To Hurricane Events, Kyoung-Ho Cho

Dissertations, Theses, and Masters Projects

The barotropic and baroclinic responses of the Chesapeake Bay to forcings from two hurricanes were investigated by using unstructured-grid three-dimensional hydrodynamic models. The model domain includes Chesapeake Bay proper, the tributaries, and its extended continental shelf in the mid-Atlantic Bight. Two hurricanes were studied: Hurricane Floyd of September, 1999 and Hurricane Isabel of September, 2003, both of which made landfall within 100 km of the Chesapeake Bay mouth. Hurricane Floyd in 1999 passed through the entrance of the Bay from southwest to northeast along the coastlines of Virginia as a Category 1 storm, whereas Hurricane Isabel in 2003 made landfall …


Calculation Of Equilibrants For Semipositive Matrices, Zheng Tong Jan 2009

Calculation Of Equilibrants For Semipositive Matrices, Zheng Tong

Dissertations, Theses, and Masters Projects

No abstract provided.


Identification And Quantification Of Polycyclic Musks And Methyl-Triclosan In Unknown Freshwater Fish Tissue Samples, Elizabeth Mara Jacobs Jan 2009

Identification And Quantification Of Polycyclic Musks And Methyl-Triclosan In Unknown Freshwater Fish Tissue Samples, Elizabeth Mara Jacobs

Dissertations, Theses, and Masters Projects

No abstract provided.


Cyclization Reactions Catalyzed By Bi(Iii) Compounds, Jia Liu Jan 2009

Cyclization Reactions Catalyzed By Bi(Iii) Compounds, Jia Liu

Dissertations, Theses, and Masters Projects

No abstract provided.


The Functionalization Of Carbon Nanosheets, Ronald A. Quinlan Jan 2009

The Functionalization Of Carbon Nanosheets, Ronald A. Quinlan

Dissertations, Theses, and Masters Projects

Carbon nanosheets are a novel two-dimensional nanostructure made up of 2-20 graphene atomic planes oriented with their in-plane axis perpendicular to the growth substrate. Previous efforts in developing nanosheet technology have focused on the characterization of the system and their development as an electron source due to the high atomic enhancement factor (beta) and low turn on field. Further investigation of nanosheets as high surface area electrodes revealed poor wetting by polymeric material and extreme hydrophobic behavior.;Because nanosheet technology has promise as a high surface area electrode material, this thesis research has focused on three areas of interest: the enhancement …


The Effect Of Realistic Focal Conditions On Strong -Field Double Ionization, Jay Paul Paquette Jan 2009

The Effect Of Realistic Focal Conditions On Strong -Field Double Ionization, Jay Paul Paquette

Dissertations, Theses, and Masters Projects

In recent years, a great deal of progress has been made in understanding the ionization processes that result from the interaction of an intense laser pulse with multielectron atoms. However, due to experimental limitations, the effect of the laser field's spatial dependence on strong-field processes has rarely been investigated. Presented in this work is a theoretical analysis of this spatial dependence including a proposal for an experimentally observable result of the phenomenon. We begin by outlining the elements of the laser field that will vary as a function of position and show their effects on simple free electron trajectories. We …


Dependence-Driven Techniques In System Design, Ningfang Mi Jan 2009

Dependence-Driven Techniques In System Design, Ningfang Mi

Dissertations, Theses, and Masters Projects

Burstiness in workloads is often found in multi-tier architectures, storage systems, and communication networks. This feature is extremely important in system design because it can significantly degrade system performance and availability. This dissertation focuses on how to use knowledge of burstiness to develop new techniques and tools for performance prediction, scheduling, and resource allocation under bursty workload conditions.;For multi-tier enterprise systems, burstiness in the service times is catastrophic for performance. Via detailed experimentation, we identify the cause of performance degradation on the persistent bottleneck switch among various servers. This results in an unstable behavior that cannot be captured by existing …


Enabling Technology For Non-Rigid Registration During Image-Guided Neurosurgery, Andriy Yuri Fedorov Jan 2009

Enabling Technology For Non-Rigid Registration During Image-Guided Neurosurgery, Andriy Yuri Fedorov

Dissertations, Theses, and Masters Projects

In the context of image processing, non-rigid registration is an operation that attempts to align two or more images using spatially varying transformations. Non-rigid registration finds application in medical image processing to account for the deformations in the soft tissues of the imaged organs. During image-guided neurosurgery, non-rigid registration has the potential to assist in locating critical brain structures and improve identification of the tumor boundary. Robust non-rigid registration methods combine estimation of tissue displacement based on image intensities with the spatial regularization using biomechanical models of brain deformation. In practice, the use of such registration methods during neurosurgery is …


Development Of A Storm Surge Model Using A High-Resolution Unstructured Grid Over A Large Domain, Tao Shen Jan 2009

Development Of A Storm Surge Model Using A High-Resolution Unstructured Grid Over A Large Domain, Tao Shen

Dissertations, Theses, and Masters Projects

A quasi-3D storm surge modeling system was developed for forecasting the storm surge and inundation in the Chesapeake Bay. The system was constructed with one large unstructured grid covering the Atlantic Coast from Nova Scotia to Florida and a smaller, limited domain unstructured grid covering the Chesapeake Bay, Virginia Beach, Hampton Roads and the adjacent continental shelf regions. It was demonstrated that, with the large domain grid, the model could simulate the hurricane induced storm surge reasonably well using astronomical tide at the open boundary condition and in turn, provide boundary condition for the limited domain model. Since the difficulty …


Interactions Between Macroalgae And The Sediment Microbial Community: Nutrient Cycling Within Shallow Coastal Bays, Amber Kay Hardison Jan 2009

Interactions Between Macroalgae And The Sediment Microbial Community: Nutrient Cycling Within Shallow Coastal Bays, Amber Kay Hardison

Dissertations, Theses, and Masters Projects

Ephemeral macroalgal blooms are considered a symptom of eutrophication in shallow coastal lagoons, but their influence on nutrient cycling dynamics in these systems is not fully understood. From 2006-2008, I conducted a series of experiments to determine the influence of living and senescent macroalgae on sediment carbon (C) and nitrogen (N) cycling in coastal lagoons along the Delmarva Peninsula, USA. In particular, I focused on how macroalgae affect the microbial community at the sediment-water interface of shallow subtidal sediments because this complex consortium of autotrophic (e.g. benthic microalgae, BMA) and heterotrophic (e.g. bacteria) organisms plays a critical role in nutrient …


Variability In Juvenile Growth, Mortality, Maturity, And Abundance Of American Shad And Blueback Herring In Virginia, Troy D. Tuckey Jan 2009

Variability In Juvenile Growth, Mortality, Maturity, And Abundance Of American Shad And Blueback Herring In Virginia, Troy D. Tuckey

Dissertations, Theses, and Masters Projects

Young-of-year (YOY) population dynamics of American shad and blueback herring in Virginia's rivers were examined with an emphasis on variability in growth and mortality rates. In addition, an analysis was conducted to relate juvenile abundance indices of American shad to adult indices to establish a stock-recruitment relationship. to accomplish the stock recruitment relationship, an additional study that examined maturation schedules and inter-annual variability in maturation schedules among stocks was performed. Results of population dynamics studies found that growth and mortality rates of American shad and blueback herring varied by river and year and that conspecific abundance was an important factor …


Mortality Of Diamondback Terrapins In Blue Crab Traps: Population Changes And Conservation In Southeastern Virginia, Megan Ann Rook Jan 2009

Mortality Of Diamondback Terrapins In Blue Crab Traps: Population Changes And Conservation In Southeastern Virginia, Megan Ann Rook

Dissertations, Theses, and Masters Projects

No abstract provided.


A Privacy Preserving Framework For Cyber-Physical Systems And Its Integration In Real World Applications, Haodong Wang Jan 2009

A Privacy Preserving Framework For Cyber-Physical Systems And Its Integration In Real World Applications, Haodong Wang

Dissertations, Theses, and Masters Projects

A cyber-physical system (CPS) comprises of a network of processing and communication capable sensors and actuators that are pervasively embedded in the physical world. These intelligent computing elements achieve the tight combination and coordination between the logic processing and physical resources. It is envisioned that CPS will have great economic and societal impact, and alter the qualify of life like what Internet has done. This dissertation focuses on the privacy issues in current and future CPS applications. as thousands of the intelligent devices are deeply embedded in human societies, the system operations may potentially disclose the sensitive information if no …


Numerical Modeling Of Eutrophication Dynamics In The Shallow Coastal Ecosystem: A Case Study In The Maryland And Virginia Coastal Bays, Taiping Wang Jan 2009

Numerical Modeling Of Eutrophication Dynamics In The Shallow Coastal Ecosystem: A Case Study In The Maryland And Virginia Coastal Bays, Taiping Wang

Dissertations, Theses, and Masters Projects

Shallow coastal bays and lagoons (mean depths <2-3 meters) are important buffer zones and links between terrestrial and deep marine ecosystems. They are inherently vulnerable to eutrophication, and are normally dominated by benthic primary producers such as seagrass, benthic micro- and macroalgae. There is an urgent need for quantitative models that are specifically designed for studying eutrophication dynamics in shallow coastal ecosystems. In this study, a hydrodynamic and water quality modeling system consisting of the hydrodynamic model UnTRIM and the water quality model CE-QUAL-ICM was applied to a representative shallow coastal bay ecosystem, the Maryland and Virginia Coastal Bays (MVCBs). A high-resolution unstructured model grid was generated to resolve the complex geometry. to address the important role played by benthic macroalgae, a benthic macroalgal module, which assimilated macroalgal kinetics from literature and recent laboratory studies, was incorporated into the water quality model framework. The module includes two representative macroalgal species, Ulva lactuca and Gracilaria vermiculophylla , common in the MVCBs, and employs the internal nutrient-limited growth kinetics proposed by Droop. The numerical modeling system has been calibrated against a comprehensive field monitoring data collected by the Maryland Department of Natural Resources in the MVCBs. The data include water level, current velocity, salinity, and major water quality variables, such as chlorophyll a, dissolved oxygen, and nutrients. The calibrated hydrodynamic model was used to calculate the physical transport time scales. The model estimated flushing time for the entire system is on the order of 2-3 months, which are much longer than typical time scales required by most biological processes. In addition, the local residence time is found to be extremely variable throughout the system. Depending on locations, the local residence time can vary from 0 to more than 200 days. The calculated transport time scales were further compared with spatial water quality distributions in the system. The comparisons demonstrate that physical circulations could substantially modulate biological processes in the system. By using the Droop equation, the benthic macroalgae's unique property, the so-called luxury uptake, was satisfactorily captured. Furthermore, the characteristic boom-and-bust life cycle of benthic macroalgae was qualitatively simulated using a box model. The expanded water quality model that includes the benthic macroalgal module reproduced both temporal and spatial distributions of observed benthic macroalgae and major water quality variables reasonably well in the MVCBs. The model results indicate that benthic macroalgae are highly important in regulating ecosystem metabolism in areas where they are abundant. Moreover, spring phytoplankton bloom was substantially suppressed when benthic macroalgae were present. The incorporation of a benthic macroalgal module also improved the model's predictive capability in simulating dissolved oxygen in shallow ecosystems affected by benthic macroalgae. In terms of nutrient budget, the model estimated that benthic macroalgae retain approximately 10% of annual nonpoint source nitrogen inputs from the watershed based on the simulation of year 2004. This is lower than that contributed by benthic microalgae reported in other shallow coastal bays such as the Lynnhaven Bay. It is suspected that the restricted distribution of benthic macroalgae in the MVCBs limited their role from the whole bay perspective. With the incorporation of a benthic macroalgae module, the overall water quality model prediction capability is improved.


Malware Detection And Analysis Via Layered Annotative Execution, Heng Yin Jan 2009

Malware Detection And Analysis Via Layered Annotative Execution, Heng Yin

Dissertations, Theses, and Masters Projects

Malicious software (i.e., malware) has become a severe threat to interconnected computer systems for decades and has caused billions of dollars damages each year. A large volume of new malware samples are discovered daily. Even worse, malware is rapidly evolving to be more sophisticated and evasive to strike against current malware analysis and defense systems. This dissertation takes a root-cause oriented approach to the problem of automatic malware detection and analysis. In this approach, we aim to capture the intrinsic natures of malicious behaviors, rather than the external symptoms of existing attacks. We propose a new architecture for binary code …


Polybrominated Diphenyl Ether Flame Retardants In Birds Of Prey From The U.S. And China, Da Chen Jan 2009

Polybrominated Diphenyl Ether Flame Retardants In Birds Of Prey From The U.S. And China, Da Chen

Dissertations, Theses, and Masters Projects

Polybrominated diphenyl ether (PBDE) flame retardants are widely used as non-reactive additives in textiles, polyurethane foams, plastics, furnishings, and electronic products. as a result of substantial, long-term usages, PBDEs have contaminated humans, wildlife, air, water, soil, and sediment, even in remote areas. Although the North American and Asian (particularly Chinese) markets have consumed the majority of global PBDE production, knowledge about PBDE contamination is limited in these two regions. Therefore, this research aimed to investigate PBDE contamination in some Chinese and North American areas by examining the birds of prey that have been considered as sensitive monitoring species for organochlorine …


Laser Desorption From A Room Temperature Ionic Liquid, Peter Ronald Harris Jan 2009

Laser Desorption From A Room Temperature Ionic Liquid, Peter Ronald Harris

Dissertations, Theses, and Masters Projects

We report laser desorption from a Room Temperature Ionic Liquid (RTIL) as a novel source for time of flight mass spectrometry. We use the 2nd harmonic of an Nd:YAG laser to deposit intensities of 1-50 MW/cm2 via backside illumination onto our RTIL desorption sample. A microstructured metal grid situated on top of a glass microscope slide coated with RTIL serves as our desorption sample. The RTIL we use, 1-Butyl, 3-Methylimidazolium Hexafluorophosphate, remains liquid at pressures below 10-8 torr. The use of liquid desorption sample allows for improved surface conditions, homogeneity and sample life as compared to Matrix Assisted Laser Desorption …


Measurement Of The Strange Quark Contribution To The Vector Structure Of The Proton, Sarah Katherine Phillips Jan 2009

Measurement Of The Strange Quark Contribution To The Vector Structure Of The Proton, Sarah Katherine Phillips

Dissertations, Theses, and Masters Projects

The goal of the G0 experiment is to determine the contribution of the strange quarks in the quark-antiquark sea to the structure of the nucleon. to this end, the experiment measured parity-violating asymmetries from elastic electron-proton scattering from 0.12 ≤ Q2 ≤ 1.0 (GeV/ c)2 at Thomas Jefferson National Accelerator Facility. These asymmetries come from the interference of the electromagnetic and neutral weak interactions, and are sensitive to the strange quark contributions in the proton. The results from the forward angle measurement, the linear combination of the strange electric and magnetic form factors GsE + etaGsM, suggest possible non-zero, Q …


Chaotic Scattering In An Open Vase-Shaped Cavity: Topological, Numerical, And Experimental Results, Jaison Allen Novick Jan 2009

Chaotic Scattering In An Open Vase-Shaped Cavity: Topological, Numerical, And Experimental Results, Jaison Allen Novick

Dissertations, Theses, and Masters Projects

We present a study of trajectories in a two-dimensional, open, vase-shaped cavity in the absence of forces The classical trajectories freely propagate between elastic collisions. Bound trajectories, regular scattering trajectories, and chaotic scattering trajectories are present in the vase. Most importantly, we find that classical trajectories passing through the vase's mouth escape without return. In our simulations, we propagate bursts of trajectories from point sources located along the vase walls. We record the time for escaping trajectories to pass through the vase's neck. Constructing a plot of escape time versus the initial launch angle for the chaotic trajectories reveals a …


Assessing Genetic Variation Within And Among Native Populations And Hatchery Stocks Of Crassostrea Ariakensis Using Microsatellite Markers, Jie Xiao Jan 2009

Assessing Genetic Variation Within And Among Native Populations And Hatchery Stocks Of Crassostrea Ariakensis Using Microsatellite Markers, Jie Xiao

Dissertations, Theses, and Masters Projects

Assessing genetic variation within and among native populations and hatchery stocks of Crassostrea ariakensis using microsatellite markers In response to the dramatic decline of eastern oyster (Crassostrea virginica) populations in the Chesapeake Bay, introduction of the non-native Asian oyster Crassostrea ariakensis has been proposed. Currently several hatchery stocks of C. ariakensis, derived from a few wild populations along the coast of Japan and China, are being maintained in U.S. hatcheries in the Pacific northwest and on the east coast. In recent years, as the risks of the proposed introduction are being assessed, these hatchery animals have been widely used for …


Songbirds, Pesticides, And Golf Courses: Exposure And Effects, Ryan Brennan Burdge Jan 2009

Songbirds, Pesticides, And Golf Courses: Exposure And Effects, Ryan Brennan Burdge

Dissertations, Theses, and Masters Projects

No abstract provided.


Water Quality In Headwater Streams: A Test Of Best Management Practices, Jonathan Worth Holley Jan 2009

Water Quality In Headwater Streams: A Test Of Best Management Practices, Jonathan Worth Holley

Dissertations, Theses, and Masters Projects

No abstract provided.


The Synthesis And Spectroscopic Study Of A Spirooxazine-Functionalized Poly(Phenylenevinylene), Jordan Thomas Walk Jan 2009

The Synthesis And Spectroscopic Study Of A Spirooxazine-Functionalized Poly(Phenylenevinylene), Jordan Thomas Walk

Dissertations, Theses, and Masters Projects

No abstract provided.


New Developments In Xanthate Ester Chemistry And The Potential For Protecting Group Applications, Matthew Hobson Jones Jan 2009

New Developments In Xanthate Ester Chemistry And The Potential For Protecting Group Applications, Matthew Hobson Jones

Dissertations, Theses, and Masters Projects

No abstract provided.


Using An Occupancy Modeling Framework To Test The Effects Of Habitat Variables On Pond Occupancy Of Mabee's Salamander (A Mabeei) And Marbled Salamander (A Opacum), Christy Michelle Fairman Jan 2009

Using An Occupancy Modeling Framework To Test The Effects Of Habitat Variables On Pond Occupancy Of Mabee's Salamander (A Mabeei) And Marbled Salamander (A Opacum), Christy Michelle Fairman

Dissertations, Theses, and Masters Projects

No abstract provided.


Environmental Analysis Of Selected Estrogens And Androgens: Applying Ultra-Performance Liquid Chromatography And Combating Matrix Interference, Stacie L. Rice Jan 2009

Environmental Analysis Of Selected Estrogens And Androgens: Applying Ultra-Performance Liquid Chromatography And Combating Matrix Interference, Stacie L. Rice

Dissertations, Theses, and Masters Projects

Investigations of environmental hormone contamination commonly utilize solidphase extraction (SPE) followed by high-performance liquid chromatography / (electrospray ionization) tandem mass spectrometry (HPLC/(ESI)MS2) in the detection of estrogens. Matrix interference is widely reported. In this study, androgens were targeted alongside estrogens as environmentally co-introduced endocrine disrupting chemicals. Analytical methods were developed in parallel for detection of several hormones from each class, with comparison of protocols and instrumental parameters. Ultraperformance LC (UPLC®), an emerging technology advertised for reduced retention times, was used in place of HPLC for hormone separation. Applicability to diverse aqueous samples was tested. Matrix interference was combated with two …


Toxicology Of Decabromodiphenyl Ether In Avian Embryos: Disposition Of The Flame Retardant Bde-209 In Yolk-Injected Chicken Embryos (Gallus Gallus), Samantha D. Sifleet Jan 2009

Toxicology Of Decabromodiphenyl Ether In Avian Embryos: Disposition Of The Flame Retardant Bde-209 In Yolk-Injected Chicken Embryos (Gallus Gallus), Samantha D. Sifleet

Dissertations, Theses, and Masters Projects

Polybrominated diphenyl ethers (PBDEs) are flame retardant chemicals of toxicological concern present in humans, wildlife, and the environment. Deca-BDE is the highest production product due to historical use patterns and recent regulatory limitations on the other two commercial formulations (Penta-BDE and Octa-BDE) in the U.S and Europe. The EU banned Deca-BDE starting July 1, 2008. However, it remains in usage in North America and elsewhere in the world. BDE-209 is the dominant congener in all Deca- BDE commercial products. BDE-209 has been reported to under go metabolic debromination to lesser brominated and more toxic and bioaccumulative congeners. However, insufficient data …


Quantifying The Overwash Component Of Barrier Island Morphodynamics: Onslow Beach, Nc, Amy C. Foxgrover Jan 2009

Quantifying The Overwash Component Of Barrier Island Morphodynamics: Onslow Beach, Nc, Amy C. Foxgrover

Dissertations, Theses, and Masters Projects

A quantification of the role that barrier island overwash plays in the evolution of Onslow Beach, a barrier island located on Marine Corps Base Camp Lejeune, North Carolina, is presented. Ground-penetrating radar (GPR) and sediment vibracores provide an estimate of the relevant-sand prism above a silty/peat contact underlying the island. The average thickness from the surface, as determined from lidar, to this geologically-defined base, is less than 1 m and equates a total volume of approximately 1.8 ± 1.1 × 106 m3 over the 4.8 km stretch of Onslow Beach from 1 km north of the New River Inlet to …


Nutrient Loading And System Response In The Coastal Lagoons Of The Delmarva, Juliette Christina Poleto Giordano Jan 2009

Nutrient Loading And System Response In The Coastal Lagoons Of The Delmarva, Juliette Christina Poleto Giordano

Dissertations, Theses, and Masters Projects

No abstract provided.