Physical Sciences and Mathematics Commons^™

Computation Of Real Radical Ideals By Semidefinite Programming And Iterative Methods, Fei Wang

Electronic Thesis and Dissertation Repository

Systems of polynomial equations with approximate real coefficients arise frequently as models in applications in science and engineering. In the case of a system with finitely many real solutions (the $0$ dimensional case), an equivalent system generates the so-called real radical ideal of the system. In this case the equivalent real radical system has only real (i.e., no non-real) roots and no multiple roots. Such systems have obvious advantages in applications, including not having to deal with a potentially large number of non-physical complex roots, or with the ill-conditioning associated with roots with multiplicity. There is a corresponding, but more …

Neurosurgical Ultrasound Pose Estimation Using Image-Based Registration And Sensor Fusion - A Feasibility Study, Utsav Pardasani

Electronic Thesis and Dissertation Repository

Modern neurosurgical procedures often rely on computer-assisted real-time guidance using multiple medical imaging modalities. State-of-the-art commercial products enable the fusion of pre-operative with intra-operative images (e.g., magnetic resonance [MR] with ultrasound [US] images), as well as the on-screen visualization of procedures in progress. In so doing, US images can be employed as a template to which pre-operative images can be registered, to correct for anatomical changes, to provide live-image feedback, and consequently to improve confidence when making resection margin decisions near eloquent regions during tumour surgery.

In spite of the potential for tracked ultrasound to improve many neurosurgical procedures, it …

Using A Real-Time Object Detection Application To Illustrate Effectiveness Of Offloading And Prefetching In Cloudlet Architecture, Xutong Zhu

Electronic Thesis and Dissertation Repository

In this thesis, we designed and implemented two versions of a real-time object de- tection application: A stand alone version and a cloud version. Through applying the application to a cloudlet environment, we are able to perform experiments and uses the results to illustrate the potential improvement that a cloudlet architecture can bring to mobile applications that require access to large amounts of cloud data or intensive com- putation. Potential improvements include data access speed, reduced CPU and memory usages as well as reduced battery consumption on mobile devices.

Evolution, Paleoecology, And Paleobiogeography Of The Late Ordovician Brachiopod Fauna Of Laurentia, Colin D. Sproat

Electronic Thesis and Dissertation Repository

During the early Katian (Late Ordovician), the North American craton was being inundated due to a major eustatic sea level rise and regional subsidence associated with the ongoing Taconic orogeny. The Trentonian brachiopod fauna, as a dominant group of the marine shelly benthos at that time, evolved and invaded the expanding epicontinental seas.

Three Trentonian brachiopod lineages were studied to trace their evolution. The Rostricellula-Rhynchotrema-Hiscobeccus lineage was characterized by an increase in shell size, globosity, and frilled lamellae, with Hiscobeccus becoming a prominent component of the Late Ordovician epicontinental brachiopod fauna.

Parastrophina is a widely reported but non-dominant taxon of …

The Circumstellar Environments Of B-Emission Stars By Optical Interferometry, Bethany Grzenia

Electronic Thesis and Dissertation Repository

A series of B-emission (Be) stars was observed interferometrically and numerically modelled to be consistent with the observations. Uniform geometrical disks were used to make first-order inferences about the configuration of the disk systems’ extended structures and their extent on the sky. Later, the Bedisk-Beray-2dDFTpipeline was used to make sophisticated non-local thermodynamic equilibrium (LTE) calculations of the conditions within the disks. In the first instance, sixteen stars were observed in the near-infrared (K-band, 2.2 micron) with the Palomar Testbed Interferometer (PTI). The Bedisk portion of the pipeline was used to model disk temperature and density structures for B0, B2, B5 …

Identifying Individual Driver Behaviour Using In-Vehicle Can-Bus Signals Of Pre-Turning Maneuvers, Mahboubeh Zardosht

Electronic Thesis and Dissertation Repository

All drivers have their own driving style while performing different driving maneuvers. They vary in using vehicle’s control devices such as the steering wheel, pedals, gears etc. In this thesis, we analyze driving behavior in different timeframes prior to turns. We employ data obtained from actual driving behavior in an urban environment collected from the CAN-Bus of an instrumented vehicle. Five CAN-Bus signals, vehicle speed, gas pedal pressure, brake pedal pressure, steering wheel angle, and acceleration, is collected for 5, 10, and 15 seconds of driving prior to each turn. We consider all turns for each driver as well as …

The Sudbury Impact Structure - New Insights Into The Origin And Emplacement Of The Basal Onaping Intrusion And The Parkin, Trill And Foy Offset Dykes Of The North Range, Denise Anders

Electronic Thesis and Dissertation Repository

The 1.85 Ga Sudbury impact structure is considered a remnant of a multi-ring basin with an estimated original diameter of 150-200 km. The so-called “Basal Onaping Intrusion” form discontinuous sheets between the Granophyre of the Sudbury Igneous Complex (SIC) and the Sandcherry Member of the Onaping Formation and had been considered part of the complex breccia series of the Onaping Formation. Based on the investigation of core and field samples from the North Range we conclude that the Basal Onaping Intrusion, in fact, are the roof rocks of the SIC and, thus, may represent the initial bulk composition of the …

The Character And Distribution Of Cu-Pge Mineralization At The Geordie Lake Deposit Within The Coldwell Complex, Ontario, Imran Meghji

Electronic Thesis and Dissertation Repository

Cu-PGE mineralization at the Geordie Lake Deposit (GLD) is spatially associated with weak to intense actinolite and albite alteration within gabbro and troctolite. Previous studies have determined a magmatic, and magmatic-hydrothermal origin of the deposit. The most significant Cu-PGE occurrence in the GLD is dominantly stratiform, and in contact with a basal syenite. Similar patterns of REE with progressive enrichment from troctolite, to gabbro, and basal syenite indicate that these lithologies are genetically linked. Major element geochemistry shows no discernable variation between the altered and unaltered samples. Whole rock δ¹⁸O analyses were conducted in equal intervals down the …

Uncertainty Analysis Of The Performance Of A System Of Best Management Practices For Achieving Phosphorus Load Reduction To Surface Waters, Jason D.M. Igras

Electronic Thesis and Dissertation Repository

The repeated occurrence of Lake Erie’s harmful algal blooms suggests an inadequate phosphorus management system that results in excessive loads to the lake. In response, Canadian and United States’ governments have issued a new management objective, a 40% reduction in total and dissolved reactive phosphorus loads relative to 2008. To provide scientific evidence to guide managers toward achieving their management objective, we used the International Organization of Standardization (ISO) 31010 Bowtie Risk Analysis Tool to analyze the performance of the phosphorus management system. The effectiveness of agricultural best management practices (BMPs) and their adoption were combined into a Bayesian belief …

Development Of Ultrasonic Techniques For Characterization Of Liquid Mixtures, William A. Cooke

Electronic Thesis and Dissertation Repository

To evaluate the suitability of ultrasonic techniques for on-line process monitoring applications, an ultrasonic probe was used to measure acoustic velocity, acoustic impedance, and isentropic compressibility of hydrocarbons (including n-, iso-, and cycloalkanes, toluene, mineral oil, and crude oil) and polar liquids (alcohols, water, salt water) over a temperature range of 25-60°C. Temperature, carbon chain length, molecular shape, and intermolecular forces had significant effects on ultrasonic parameters. Relationships between media characteristics and observed ultrasonic parameters were modeled using empirical-least squares equations. The same parameters were measured in binary mixtures of hydrocarbons in heptane, as well as polar liquids in ethanol. …

The Application Of Geophysical Inversion Techniques To The Nechalacho Rare Earth Element Deposit, Nt, Derek W. Kouhi

Electronic Thesis and Dissertation Repository

The Nechalacho deposit is a world-class rare earth element deposit located in the Thor Lake region approximately 100 kilometers southwest of Yellowknife, NT, Canada. Located within the Blatchford Lake Intrusion Complex, this deposit has the potential to be a large-scale economic asset due to its relatively shallow and sub-horizontal geometry. In this study, geophysical inversion techniques are used to model subsurface magnetic susceptibility and density in order to delineate the deposit. Isolated and joint inversion of both magnetic and gravity data provides similar models. Each inversion procedure delineates a shallow, sub-horizontal layer of high susceptibility and density in approximately the …

Model Of The Formation Of Iron Oxide Nanoparticles By Irradiation In Aqueous Media, Thomas I. Sutherland

Electronic Thesis and Dissertation Repository

This thesis aims to develop the mechanistic understanding of the formation of iron oxide nanoparticles by γ-irradiation. Under irradiation water breaks down into a wide array of redox active species (H•, •OH, H₂O₂, •e^-_(aq)) uniformly throughout the solution. These species are capable of rapidly interconverting any soluble Fe^II and insoluble Fe^III species resulting in the formation of nanoparticles with a narrow size distribution. The initial concentration of Fe²⁺ in the solution, the solution pH, the presence of any radical scavengers, the temperature of the reaction, and the dose rate of …

Nanostructured Air Electrodes And Electrochemical Reaction Mechanism Studies For Sodium-Oxygen Batteries, Hossein Yadegari

Electronic Thesis and Dissertation Repository

Alkali metal-O₂ batteries, i.e. Li- and Na-O₂, are considered as the next generation of energy saving technologies with potential application in electric transportation. The high theoretical energy density in these cells is related to the use of high energy alkali metals as negative and oxygen as the positive electrode materials. The performance of alkali metal-O₂ cells is highly dependent on the positive electrode material, where oxygen reduction and evolution reactions take place. Besides, the primary products of oxygen reduction reaction in these cells are typically metal oxides, which are insoluble in nonaqueous electrolytes, resulting in accumulation …

Algorithms For Glycan Structure Identification With Tandem Mass Spectrometry, Weiping Sun

Electronic Thesis and Dissertation Repository

Glycosylation is a frequently observed post-translational modification (PTM) of proteins. It has been estimated over half of eukaryotic proteins in nature are glycoproteins. Glycoprotein analysis plays a vital role in drug preparation. Thus, characterization of glycans that are linked to proteins has become necessary in glycoproteomics. Mass spectrometry has become an effective analytical technique for glycoproteomics analysis because of its high throughput and sensitivity. The large amount of spectral data collected in a mass spectrometry experiment makes manual interpretation impossible and requires effective computational approaches for automated analysis. Different algorithmic solutions have been proposed to address the challenges in glycoproteomics …

Utilization Of Lidar Intensity Data And Passive Visible Imagery For Geological Mapping Of Planetary Surfaces, Taylor M. Haid

Electronic Thesis and Dissertation Repository

While lidar has been historically used for generating digital terrain maps and as a navigation tool, recent research demonstrates that lidar has many potential scientific applications, including high resolution analysis of geological outcrops. Case studies were completed at the Tunnunik impact structure, Victoria Island, Arctic Canada, and the Nickel Rim South mine, Sudbury, Canada, to assess the fidelity of characterizing and differentiating mineralogical and lithological units remotely by integrating passive visible imagery with lidar intensity data. Unsupervised classification via k-means clustering was performed on the fused datasets, with results indicating that lithologies can indeed be successfully differentiated with minor a …

Essays In Market Structure And Liquidity, Adrian J. Walton

Electronic Thesis and Dissertation Repository

Market structure concerns the mechanisms for negotiating trades and the composition of trading participants, and can affect liquidity and price efficiency. More gains from trade can be realized from an asset that is more liquid, and a better allocation of risk and capital can be achieved when an asset’s price is more efficient so it is important to understand market structure. This thesis uses theory and empirical methods to examine the effects of a few specific aspects of market structure.

In Chapter 1, we study a novel market structure on the New York Stock Exchange (NYSE), the Retail Liqudity Program …

Microstructural Geochronology Of Zircon Across The Central Uplift Of The Vredefort Impact Structure, South Africa, Connor Lawrence Davis

Electronic Thesis and Dissertation Repository

The Vredefort central uplift, or ‘dome,’ represents the erosional remnant of one of the largest (~300 km diameter) and oldest (~2.020 Ga) terrestrial impact structures. This investigation was performed to help elucidate the complexity of the shock process on zircon, incorporating various electron beam methods, including BSE and SE imaging, EBSD, CL, and EDS (mapping and semi-quantitative compositional analysis). A new shock microstructural progression in terrestrial zircon is suggested, as well as a complete structure-wide analysis of impact melt inclusions in zircon. Regional trends in the effects of shock on zircon are included. Impact melt glass inclusion compositions vary widely, …

Formation And Past Evolution Of The Meteoroid Complex Of Comet 96p/Machholz, Abedin Yusein Abedin

Electronic Thesis and Dissertation Repository

The past dynamical evolution of the meteoroid streams associated with comet 96P/Machholz is investigated. The goal is to obtain a coherent picture of the past capture of this large comet into a short period orbit, and its subsequent breakup hierarchy. In particular, the aim is to constrain the earliest epoch that this large first precursor started to supply meteoroids into the interplanetary space. The fragments and meteoroid streams of that past cometary decay constitute a wide multiplex of interplanetary bodies, knows as the 96P/Machholz complex. The largest presently surviving fragment is comet 96P/Machholz, followed by a large amount of debris …

Investigating Mycotoxins And Secondary Metabolites In Canadian Agricultural Commodities Using High-Resolution Mass Spectrometry, Megan J. Kelman

Electronic Thesis and Dissertation Repository

Mycotoxins are secondary metabolites produced by fungi, which are harmful to humans and/or animals. Alternaria is a common fungal plant pathogen that can produce mycotoxins in agricultural commodities, such as processed wheat products, and fruit juices. Liquid chromatography mass spectrometry (LC-MS) is commonly used for the detection, characterization and quantitation of mycotoxins in agricultural products. Canadian Alternaria species were assessed to provide a risk assessment of their secondary metabolites in agricultural products by describing their global metabolome data obtained from the Orbitrap LC-MS instrument. Combination of this high mass accuracy data with post data-acquisition analysis techniques resulted in the discovery …

Emplacement Of The Foy, Hess And Pele Offset Dykes At The Sudbury Impact Structure, Canada, Eric A. Pilles

Electronic Thesis and Dissertation Repository

The 1.85 Ga Sudbury impact structure is the remnant of what is generally considered to have been an ~150–200 km diameter impact basin in central Ontario, Canada. The so-called Offset Dykes are impact melt dykes that are found concentrically around – and extending radially outward from – the Sudbury Igneous Complex (SIC), a ~3 km thick differentiated impact melt sheet. The dykes are typically composed of two main phases of granodiorite: an inclusion- and sulfide-rich granodiorite in the centre of the dyke, and an inclusion- and sulfide-poor granodiorite along the margins of the dyke. This study uses a combination of …

Novel Reactions Of Donor-Acceptor Cyclopropanes, And Diels-Alder Approach Towards Fargesine And Fumimycin, Polydoros Kyriacou

Electronic Thesis and Dissertation Repository

The first chapter of this thesis consists of two related projects that explore novel reactivity of donor-acceptor cyclopropanes, specifically 2-substituted cyclopropane 1,1-diesters. The first project involves the nucleophilic ring opening of donor-acceptor cyclopropanes with potassium organotrifluoroborates. It was found that during the ring opening of the cyclopropane, the diesters of the cyclopropane formed a malonyl-BF₂ complex. The complex could then be hydrolyzed to afford substituted malonates. The reaction was limited to aryl cyclopropanes and potassium alkynyltrifluoroborates. The second project in this chapter explores modifying the Kerr group’s previous synthesis of tetrahydro-1,2-oxazines, such that geminal allyl, methyl esters are now …

Hydraulic And Electrokinetic Delivery Of Remediants For In-Situ Remediation, Ahmed I. A. Chowdhury

Electronic Thesis and Dissertation Repository

Nano-scale zero valent iron (nZVI) has shown promising mobility and in-situ reactivity with chlorinated volatile organic compounds when injected into saturated porous media. The current study evaluated nZVI mobility and subsequent reactivity with in-situ contaminants in a variably saturated porous media. The nZVI particles, synthesized onsite at subzero temperatures, demonstrated complete trichloroethene (TCE) degradation within the target area. Furthermore, a three dimensional finite difference model (CompSim) was utilized to investigate nZVI mobility in variably saturated zones. Model predicted well head data were in very good agreement with field observations. Simulation results showed that the injected slurry migrated radially outward from …

Constraining The Formation And Alteration Of Sudbury Breccia, Ontario, Canada: Implications For Footwall Cu-Ni-Pge Exploration, Jonathan W. O'Callaghan

Electronic Thesis and Dissertation Repository

Sudbury breccia is an impactite situated in the footwall of the 1.85 Ga Sudbury impact structure, situated in Ontario. Developing exploration vectors towards Sudbury breccia-hosted Cu-Ni-PGE mineralization is inhibited by an insufficient understanding of the relative contributions of footwall lithologies versus impact melt. By combining whole-rock geochemistry, field observations, statistical modelling and petrography, this study has determined that Sudbury breccia is a parautochthonous shock melt, which does not require a melt sheet contribution. Furthermore, the trace metal content of the breccia is largely controlled by the assimilation of mafic footwall lithologies, the exception being breccia proximal to mineralization, where a …

Fabricating And Characterizing Chalcogenide Thin Films As Light Absorbing Layers In Solar Cells, Daniel Vaccarello

Electronic Thesis and Dissertation Repository

Solar cell development has been a focus in energy research, with light-absorbing layers as the key theme. Copper indium disulphide (CuInS₂) and copper zinc tin sulphide (Cu₂ZnSnS₄ or CZTS) have energy band gaps that are optimal for solar energy conversion. New preparation methods have been developed with practicality, safety, and low costs in mind. The one-pot method developed in this thesis group has been utilized to create nanocrystals that can be used to absorb light and generate current. The use of low temperatures and minimalistic reaction conditions has led to the production of CIS and …

Advances In Portmanteau Diagnostic Tests, Jinkun Xiao

Electronic Thesis and Dissertation Repository

Portmanteau test serves an important role in model diagnostics for Box-Jenkins Modelling procedures. A large number of Portmanteau test based on the autocorrelation function are proposed for a general purpose goodness-of-fit test. Since the asymptotic distributions for the statistics has a complicated form which makes it hard to obtain the p-value directly, the gamma approximation is introduced to obtain the p-value. But the approximation will inevitably introduce approximation errors and needs a large number of observations to yield a good approximation. To avoid some pitfalls in the approximation, the Lin-Mcleod Test is further proposed to obtain a numeric solution to …

Dicke’S Superradiance In Astrophysics, Fereshteh Rajabi

Electronic Thesis and Dissertation Repository

It is generally assumed that in the interstellar medium much of the emission emanating from atomic and molecular transitions within a radiating gas happen independently for each atom or molecule, but as was pointed out by R. H. Dicke in a seminal paper several decades ago this assumption does not apply in all conditions. As will be discussed in this thesis, and following Dicke’s original analysis, closely packed atoms/molecules can interact with their common electromagnetic field and radiate coherently through an effect he named superradiance. Superradiance is a cooperative quantum mechanical phenomenon characterized by high intensity, spatially compact, burst-like features …

Complex Event Processing As A Service In Multi-Cloud Environments, Wilson A. Higashino

Electronic Thesis and Dissertation Repository

The rise of mobile technologies and the Internet of Things, combined with advances in Web technologies, have created a new Big Data world in which the volume and velocity of data generation have achieved an unprecedented scale. As a technology created to process continuous streams of data, Complex Event Processing (CEP) has been often related to Big Data and used as a tool to obtain real-time insights. However, despite this recent surge of interest, the CEP market is still dominated by solutions that are costly and inflexible or too low-level and hard to operate.

To address these problems, this research …

Molecular Distance Maps: An Alignment-Free Computational Tool For Analyzing And Visualizing Dna Sequences' Interrelationships, Rallis Karamichalis

Electronic Thesis and Dissertation Repository

In an attempt to identify and classify species based on genetic evidence, we propose a novel combination of methods to quantify and visualize the interrelationships between thousand of species. This is possible by using Chaos Game Representation (CGR) of DNA sequences to compute genomic signatures which we then compare by computing pairwise distances. In the last step, the original DNA sequences are embedded in a high dimensional space using Multi-Dimensional Scaling (MDS) before everything is projected on a Euclidean 3D space.

To start with, we apply this method to a mitochondrial DNA dataset from NCBI containing over 3,000 species. The …

A Data Fusion Approach To Automated Decision Making In Intelligent Vehicles, Besat Zardosht

Electronic Thesis and Dissertation Repository

The goal of an intelligent transportation system is to increase safety, convenience and efficiency in driving. Besides these obvious advantages, the integration of intelligent features and autonomous functionalities on vehicles will lead to major economic benefits from reduced fuel consumption to efficient exploitation of the road network.

While giving this information to the driver can be useful, there is also the possibility of overloading the driver with too much information. Existing vehicles already have some mechanisms to take certain actions if the driver fails to act. Future vehicles will need more complex decision making modules which receive the raw data …

Collective Contextual Anomaly Detection For Building Energy Consumption, Daniel Berhane Araya

Electronic Thesis and Dissertation Repository

Commercial and residential buildings are responsible for a substantial portion of total global energy consumption and as a result make a significant contribution to global carbon emissions. Hence, energy-saving goals that target buildings can have a major impact in reducing environmental damage. During building operation, a significant amount of energy is wasted due to equipment and human-related faults. To reduce waste, today's smart buildings monitor energy usage with the aim of identifying abnormal consumption behaviour and notifying the building manager to implement appropriate energy-saving procedures. To this end, this research proposes the \textit{ensemble anomaly detection} (EAD) framework. The EAD is …