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Full-Text Articles in Physical Sciences and Mathematics
Electron-Impact Vibrational Excitation Of Vibrationally Excited H2 Molecules Involving The Resonant 2(Sigma)G+ Rydberg-Excited Electronic State, R Celiberto, R. K. Janev, V Laporta, J Tennyson, J. M. Wadehra
Electron-Impact Vibrational Excitation Of Vibrationally Excited H2 Molecules Involving The Resonant 2(Sigma)G+ Rydberg-Excited Electronic State, R Celiberto, R. K. Janev, V Laporta, J Tennyson, J. M. Wadehra
Physics and Astronomy Faculty Research Publications
Electron-impact theoretical cross sections and rate coefficients for vibrational excitation of vibrationally excited H2 molecules, occurring through the H−2 resonant species in the 2Σ+g Rydberg-excited electronic state, are presented. The cross sections are calculated as functions of the incident electron energy by adopting the local-complex-potential model for resonant collisions and by using ab initio calculated molecular potentials and resonance widths. The calculations have been extended to all possible vibrational transitions linking all 15 vibrational levels of the electronic ground state of the H2 molecule. The corresponding rate coefficients are also obtained as a function of the electron temperature by assuming …
Cross Sections For 14-Ev E-H2 Resonant Collisions: Isotope Effect In Dissociative Electron Attachment, R Celiberto, R. K. Janev, J. M. Wadehra, A Laricchiuta
Cross Sections For 14-Ev E-H2 Resonant Collisions: Isotope Effect In Dissociative Electron Attachment, R Celiberto, R. K. Janev, J. M. Wadehra, A Laricchiuta
Physics and Astronomy Faculty Research Publications
The process of dissociative attachment of electrons to molecular hydrogen and its isotopes in the energy range at approximately 14 eV is investigated. The dissociative electron attachment cross sections for all six hydrogen isotopes are calculated over an extended range of electron energies using the local complex potential model with the excited Rydberg 2Σ+g electronic state of H2− acting as the intermediate resonant state. A significant isotope effect in theoretical electron attachment cross sections is observed, in agreement with previous predictions and experimental observations. A two-parameter analytic expression for the cross section is derived from the theory that fits accurately …