Physical Sciences and Mathematics Commons^™

Development Of A Dilatant Damage Zone Along A Thrust Relay In A Low-Porosity Quartz Arenite, Jennie E. Cook

Masters Theses

A damage zone developed along a backthrust fault system in well-cemented quartz arenite of theTuscarora Sandstone in the Alleghanian foreland thrust system consists of a network of NW-dipping thrusts that are linked by multiple higher-order faults and bound a zone of intense extensional fractures and breccias. The damage zone is unusual in that it preserves porous brittle fabrics despite formation at >5km depth. The damage zone developed at an extensional step-over between two independent, laterally propagating backthrusts. Continued displacement resulted in breaching of the relay and formation of faultbounded horses, and favored the formation of extensional fractures. The presence of …

Synthesis Of 123-Iodine Labeled Rofecoxib Analogues: Potential Nuclear Medicine Imaging Agents, Brandy U. Belue

Masters Theses

Single photon emission computed tomography (SPECT) is a medical imaging technique which provides three-dimensional images ofliving systems after introduction ofa radiolabeled pharmaceutical. Rofecoxib (4-[ 4-methylsulphonylphenyl]-3phenylfuran-2(SH)-one) is an inhibitor of the cycloxygenase-2 enzyme, an enzyme which has been found to promote cancer cell growth. The synthesis of a no-carrier-added iodine-123 labeled rofecoxib derivative is potentially of value for the detection of cancer utilizing SPECT.

Iodine-123 labeled -(3-Iodophenyl)-4-(methanesulfonylphenyl)-SH furan-2-one, 1, and 3-(4-Iodophenyl)-4-(methanesulfonylphenyl)-5H-furan-2-one, 2, were prepared from the respective potassium organotrifluoroborate salts. The trifluoroborates were prepared from a simple six step pathway.

Development Of A Dilatant Damage Zone Along A Thrust Relay In A Low-Porosity Quartz Arenite, Jennie E. Cook

Masters Theses

A damage zone developed along a backthrust fault system in well-cemented quartz arenite of the Tuscarora Sandstone in the Alleghanian foreland thrust system consists of a network of NW-dipping thrusts that are linked by multiple higher-order faults and bound a zone of intense extensional fractures and breccias. The damage zone is unusual in that it preserves porous brittle fabrics despite formation at >5km depth. The damage zone developed at an extensional step-over between two independent, laterally propagating backthrusts. Continued displacement resulted in breaching of the relay and formation of faultbounded horses, and favored the formation of extensional fractures. The presence …

Obtaining High Precision Results From Low Precision Hardware, Adam Donald Graham

Masters Theses

This document describes an attempt at acheiving high precision matrix multiplication results from the Lenslet EnLight256 Optical Signal Processor (OSP), which on its own can only produce results which are hardware limited to 8-bit signed integers. Due to it’s low precision, it’s has only limited applicability to real world problems, and if higher precision results were possible from the machine it could be used for more applications. A C library is developed for this thesis to allow high-precision results from the EnLight256. The library is described and results are given. Finally an implementation of the Jacobi Method on the EnLight256 …

Identification Of Terrestrial Alkalic Rocks Using Thermal Emission Spectroscopy: Applications To Martian Remote Sensing, Tasha Laurrelle Dunn

Masters Theses

We present a detailed study examining the use of laboratory thermal emission spectra (5-25 μm at 2 cm^-1 spectral sampling) for identification and classification of alkalic volcanic rocks. Modal mineralogies and derived bulk rock chemistries of a suite of terrestrial alkali basalts, trachyandesites, trachytes, and rhyolites were determined using linear spectral deconvolution. Model-derived mineral modes were compared to modes measured using an electron microprobe mapping technique to access the accuracy of linear deconvolution in determining mineral abundances. Standard deviations of 1σ of absolute differences between measured and modeled mineral abundances range from 0.68 to 15.02 vol %, with …

Virus Transport During Transient Unsaturated And Steady-State Saturated Flow Conditions In Memphis Aquifer Sand, Andrew Boruff Kenst

Masters Theses

The overall goal of this research was to determine the effect of transient unsaturated flow conditions on the transport of a virus in aquifer material. It was hypothesized that viruses would be transported at the same rate and over the same distance as the migration of the wetting front and that virus retention during transient unsaturated flow would be similar to that during steady-state saturated flow. Virus transport during transient unsaturated horizontal flow was experimentally compared with its behavior under steady-state saturated vertical flow. In the transient flow experiment, virus (ΦX174) suspension was introduced into an initially air-dry repacked Memphis …

Deciphering Eustatic And Tectonic Influences During Parasequence Development In The Mesoprotozoic Helena/Wallace Formation, Belt Supergroup, Montana And Idaho, Stephen Alan Welch

Masters Theses

The stratigraphic architecture of sedimentary basins results from a combination of changes in relative sea-level and tectonism, and resulting changes in sediment supply. The Helena/Wallace formations, Mesoproterozoic Belt Supergroup, Montana and Idaho, consists of >500 meters of stacked meter-scale cycles (parasequences) that record in situ carbonate deposition as well as siliciclastic deposition from both the Laurentian craton and an unknown (tectonically active?) western source. In this study, statistical methods and 2-D forward modeling are combined with geochemical provenance analysis to examine parasequence stacking patterns and decipher the relative eustatic and tectonic controls on sequence development.

Helena/Wallace parasequences are typically composed …

Pedologic Investigations In The Red River Region Of Eastern Kentucky: Relationship Of Soil Properties To Lithology, Slope Aspect, And Soil Quality To Prehistoric Indigenous Food Plot Locations, Jason D. Windingstad

Masters Theses

ABSTRACT

Part I

The Red River Valley of Eastern Kentucky contains cultural remains that point to the independent development of agriculture during the Late Archaic cultural period. The objective of this study is to gather quantitative data through the chemical and physical analysis of soils collected within a valley transect to gain insights into landscape processes and soil quality that may have played a role in the development of plant domestication. National Cooperative Soil Survey standards were used for field descriptions and the chemical and physical analysis of all samples. Soil quality values such as ECEC (ammonium acetate pH 7), …

Stratigraphic And Structural Relationships Of The Ocoee Supergroup, Southern Appalachians: Implications For Neoproterzoic Rift Basin Architecture And Paleozoic Collisional Orogenesis, James Ryan Thigpen

Masters Theses

The late Proterozoic-Early Cambrian Ocoee Supergroup (OSG)is the dominant lithostratigraphic sequence of the western Blue Ridge (WBR) province in southeast Tennessee, southwest North Carolina, and northern Georgia. The OSG is divided into the basal Snowbird Group (SG) that nonconformably overlies Grenvillian basement, the thick Great Smoky Group (GSG) that is usually in fault contact with the Snowbird Group, and the Walden Creek Group (WCG) that directly underlies the Cambrian Chilhowee Group and conformably overlies both the Snowbird and Great Smoky Groups. Traditional interpretations suggest that the OSG was deposited during late Neoproterozoic-Early Cambrian rifting along the southeast Laurentian margin, initially …

Structural And Stratigraphic Investigations Of The Bays Mountain Synclinorium, Parrottsville And A Portion Of Cedar Creek 7.5-Minute Quadrangles, East Tennessee, Neil E. Whitmer

Masters Theses

The southern Valley and Ridge foreland fold-thrust belt is comprised of a wedge of Lower Cambrian through Pennsylvanian sedimentary rocks that were folded and faulted during the late stages of the Alleghanian orogeny. Within one of the eastern thrust sheets lies the Bays Mountain synclinorium. Rocks as young as Middle Ordovician are preserved in the core of the synclinorium and record the evolution of a Taconian (Blountian) Sevier tectonic basin.

The Parrottsville and Cedar Creek 7.5-minute quadrangles are located on the southeastern flank of the Bays Mountain synclinorium of East Tennessee and contain rocks belonging to the Conasauga, Knox, and …

The Development Of Computational Tools For Halo Analysis And Study Of Halo Growth In The Spallation Neutron Source Linear Accelerator, Dirk A. Bartkoski

Masters Theses

The Spallation Neutron Source (SNS), being built at the Oak Ridge National Laboratory, utilizes a high intensity particle accelerator for neutron production. One of the challenges in SNS, as with all high intensity accelerators, is to minimize the amount of beam lost. High beam losses can cause costly damage and lead to residual activation of accelerator components, which complicates routine maintenance.

One of the key components in beam loss at SNS is the development and propagation of beam halo. Halo particles are those driven to large amplitudes by space charge forces between the beam particles or by mismatch between the …

Universal Geometric Camera Calibration With Statistical Model Selection, Chistopher Paul Broaddus

Masters Theses

We propose a new universal camera calibration approach that uses statistical information criteria for automatic camera model selection. It requires the camera to observe a planar pattern from different positions, and then closed-form estimates for the intrinsic and extrinsic parameters are computed followed by nonlinear optimization. In lieu of modeling radial distortion, the lens projection of the camera is modeled, and in addition we include decentering distortion. This approach is particularly advantageous for wide angle (fisheye) camera calibration because it often reduces the complexity of the model compared to modeling radial distortion. We then apply statistical information criteria to automatically …

Seasonal Forage Availability And Diet Of Reintroduced Elk In The Cumberland Mountains, Tennessee, Jason Lee Lupardus

Masters Theses

The Tennessee Wildlife Resources Agency (TWRA) reintroduced elk (Cervus elaphus manitobensis) into the Cumberland Mountains, Tennessee over a 3-year period beginning in December 2000. We radio-collared 160 elk and monitored them by aerial telemetry from February 2001 to June 2003. Locations (n = 1450) were used in a geographic information system (GIS) to develop a core herd home range (789-ha sampling area) to assess elk seasonal forage use and availability. We monitored diet and resource availability from November 2003 to October 2004 by vegetation sampling and microhistological analysis of feces. Tall fescue (Festuca arundinacea; 35.1%) dominated …

Applications Of Genetic Algorithms To A Variety Of Problems In Physics And Astronomy, Kevin Richard Williams

Masters Theses

Genetic algorithms are search techniques that borrow ideas from the biological process of evolution. By means of natural selection, genetic algorithms can be employed as robust numerical optimizers on problems that would normally be extremely problematic due to ill-behaved search spaces. The genetic algorithm has an advantage in that it is a global optimization strategy, as opposed to more conventional methods, which will often terminate at local maxima.

The success and resourcefulness of genetic algorithms as problem-solving strategies are quickly gaining recognition among researchers of diverse areas of study. In this thesis I elaborate on applications of a genetic algorithm …

A Reliability Case Study On Estimating Extremely Small Percentiles Of Strength Data For The Continuous Improvement Of Medium Density Fiberboard Product Quality, Weiwei Chen

Masters Theses

The objective of this thesis is to better estimate extremely small percentiles of strength distributions for measuring failure process in continuous improvement initiatives. These percentiles are of great interest for companies, oversight organizations, and consumers concerned with product safety and reliability. The thesis investigates the lower percentiles for the quality of medium density fiberboard (MDF). The international industrial standard for measuring quality for MDF is internal bond (IB, a tensile strength test). The results of the thesis indicated that the smaller percentiles are crucial, especially the first percentile and lower ones.

The thesis starts by introducing the background, study objectives, …

Effect Of Surface Morphology On Adsorption-Induced Bending Of Microcantilevers, Ramya Desikan

Masters Theses

Microcantilevers undergo bending due to molecular adsorption when adsorption is confined to a single surface. The origin of the adsorption-induced force is assumed to be surface stress variation due to molecular adsorption. Single crystal silicon cantilevers were etched for a series of different time periods using two different types of Potassium Hydroxide solutions in order to obtain a rough and a smooth finish on the cantilever surface. Cantilevers that approximately had the same resonance frequency in the rough and smooth etched categories were chosen for comparison in the experiment. Liquid phase adsorption of 1-Do-decan-thiol on the cantilevers having a thin …

Detection Of Enteric Viruses In East Tennessee Public Ground Water Systems, Trisha Baldwin Johnson

Masters Theses

A two-part study was conducted by University of Tennessee-Knoxville, the U.S. Geological Survey, and the U.S. Environmental Protection Agency-National Exposure Research Laboratory to (1) develop, validate, and test a real-time reverse transcription-polymerase chain reaction (real-time RT-PCR) assay for enteroviruses in ground water samples and to (2) perform the first survey of enteric viral occurrence in the karst aquifers of East Tennessee. Karst aquifers are expected to have a high susceptibility to viral contamination because of the rapid flow (100’s of m/day) and frequent occurrence of fecal indicator bacteria typically observed in these systems.

Real-time RT-PCR primers and probes specific for …

Automatic Service Discovery For Grid Computing: A Decentralized Approach To The Grid, Jeffrey Michael Larkin

Masters Theses

The purpose of this document is to explore the feasibility of a decentralized system for grid computing. A proof-of-concept grid computing system was created based on the GridSolve computing environment and multicast domain name server with service discovery. This experimental grid computing environment showed that reasonable results can be achieved in a decentralized environment. Using these results suggestions are made for future research in this area.

Enhanced Performance Monitoring - Extending Papi To Monitor Multiple Counter Domains, Kevin Scott London

Masters Theses

High performance computing is playing an increasingly important role in the scientific community. As simulations start replacing physical experiments there will be a need for larger computing resources and better optimized applications. The Performance Application Programming Interface (PAPI) already addresses the concerns for optimizing a serial application by providing a portable interface to the performance counters found on modern processors. Developers can use these counters to understand exactly how their application is running on the processor and use this information to determine the best way to optimize the application. This information is only a portion of the complete picture. As …

The Classification Of Links Of Up To And Including Thirteen Crossings, Dylan Joshua Faullin

Masters Theses

The prime links of up to 13 crossings are classified up to unoriented equivalence.

Experimental Investigation Of The Breakdown Of Dolomite And Isotope Transport In Rock Cores At 100 Mpa, 650–750 °C, Michael Thomas Deangelis

Masters Theses

The kinetics of the breakdown reaction dolomite = periclase + calcite + CO2 were investigated using cores of dolomitic marble. Two samples of Reed Dolomite from southwestern Nevada were cut into cylinders approximately 4×6 mm in size.

The cores were sealed in gold capsules with isotopically enriched water (H218O or HD 18O0.5 16 O0.5). The samples were heated in a cold-seal hydrothermal apparatus to 650–750 °C at 100 MPa for durations ranging from 2–59 days. The cores were then sectioned and examined by EMP, XRD, and SIMS techniques. All experiments show some amount of reaction regardless of duration or temperature. …

Monte Carlo Simulation Of Scatter In A Cone-Beam X-Ray Micro-Ct Scanner, Noel F. Black

Masters Theses

No abstract provided.

Thermodynamic Contributions Of Various Metal-Nucleotide Complexes Binding To Yeast Phosphoglycerate Kinase, Randall Allen Holzberger

Masters Theses

The purpose of this study was to determine the thermodynamic parameters of various enzyme-substrate complexes of Yeast Phosphoglycerate Kinase by using Isothermal Titration Calorimetry (ITC). The addition of metal-nucleotide substrate to a PGK solution elicited an exothermic response ranging from 0.5 kilocalories to 2.8 kilocalories. Titrations of MgATP and MgADP into PGK yielding binary complexes generated a greater amount of heat than titrations of MgADP into PGA-PGK and MgAMP-PCP into PGA-PGK yielding ternary complexes. The entropic contribution of the ternary complex formations was significantly greater than binary complex formations. Although entropic and enthalpic contributions varied, the Gibbs free energy remained …

Raman Under Ln2: A Simple Approach To Low Temperature Raman Spectroscopy, E. Darren Ellis

Masters Theses

Conventional low temperature Raman Spectroscopy techniques utilize expensive equipment to cool a sample to 77˚ K. In this work, a new technique for performing Raman Spectroscopy at liquid nitrogen temperatures is presented. This technique of taking data with the sample placed under liquid nitrogen provides a low cost alternative to conventional methods, and can be utilized by any lab with a Raman spectrometer without the purchase of additional equipment. Representative spectra for CCl₄, C₆₀, and Single Wall Carbon Nanotubes at room temperature and under liquid nitrogen are shown and compared as validation of the utility of …

Distribution And Transportation Of Coal Tar Contaminants In The Chattanooga Creek Floodplain, Dalphania Syreeta Dickerson

Masters Theses

In Chattanooga, Tennessee, tens of thousands of tons of coal tar were disposed of in Chattanooga Creek during operations of the Chattanooga Coke Plant (1918-1987). Coal tar is composed of thousands of organic compounds, which span a wide range of molecular weight. Many of these compounds are polycyclic aromatic hydrocarbons (PAHs) and are known carcinogens. Chattanooga Creek is an urban creek, which runs through the southern part of the city of Chattanooga and is surrounded by industrial development, residential neighborhoods, parks, and schools. Due to the hazardous nature of coal tar and coal tar constituents, portions of the creek and …

Studies Of Alkaline Phosphatase Inhibition By Metal Chelators Using Capillary Electrophoresis, Courtney A. Neel

Masters Theses

Alkaline phosphatase inhibition by metal chelators has been studied using capillary electrophoresis. The enzyme-inhibition assays were performed by electrophoretically mixing enzyme and inhibitor zones in a substrate filled capillary. Enzyme inhibition could be seen as a decrease in product formation as detected using laser-induced fluorescence. The enzyme-inhibition assays were adapted so they could be performed using a commercial CE system. Use of a commercial system is desirable for these assays due to ease of use and system features such as autosamplers and capillary and sample cooling. This technique could prove useful for pharmaceutical industries as a screening tool for new …

A Family Of Matrix Representations Of The Figure Eight Knot Group, Marvalisa M. Payne

Masters Theses

An exact computation is given of a new 1-parameter family of SL(4,R) representations of the figure eight knot group.

Investigating Keratoconus Using Optical Eye Modeling, Kevin Charles Baker

Masters Theses

Keratoconus (KC) is a corneal atrophy which causes a conical extrusion (cone). It is often misdiagnosed as optical defocus with astigmatism. In this thesis, computer KC eye models for various conditions are constructed. Using the KC eye model the influence on visual performance including the consequent refractive errors and the higher-order aberrations of KC eyes was investigated. The affects of cone shape, dimension (volume), and location on visual performance are also discussed. The modeled KC eyes are additionally used to evaluate the performance of a common eye vision-screening instrument. The simple photorefraction (PR) technique uses only one small light source …

Novel Algorithms And Datamining For Clustering Massive Datasets, Aruna K. Buddana

Masters Theses

Clustering proteomics data is a challenging problem for any traditional clustering algorithm. Usually, the number of samples is much smaller than the number of protein peaks. The use of a clustering algorithm which does not take into consideration the number of feature of variables (here the number of peaks) is needed. An innovative hierarchical clustering algorithm may be a good approach. This work proposes a new dissimilarity measure for the hierarchical clustering combined with a functional data analysis. This work presents a specific application of functional data analysis (FDA) to a highthrouput proteomics study. The high performance of the proposed …

Ametropic Eye Modeling, Bo Tan

Masters Theses

Using a commercial optical design software, a general ametropic eye model was constructed based on the measured data of 69 young adults. The experiment data was obtained from 2 published literatures. The correlation between refractive errors of the eyes and their axial lengths, cornea curvatures and intraocular powers was investigated and adopted into the modeling for the first time. The optical performance of the new model eye was evaluated and compared with published aberration data from human eyes. The comparison was performed on both on-axis and periphery vision. High-order wavefront aberrations that include the asymmetric properties of eyes and the …