Physical Sciences and Mathematics Commons^™

Inflammatory Properties Of Diet And Glucose-Insulin Homeostasis In A Cohort Of Iranian Adults, Nazanin Moslehi, Behnaz Ehsani, Parvin Mirmiran, Nitin Shivappa, Maryam Tohidi, James R. Hébert, Fereidoun Azizi

Faculty Publications

We aimed to investigate associations of the dietary inflammatory index (DII) with glucose-insulin homeostasis markers, and the risk of glucose intolerance. This cross-sectional study included 2975 adults from the Tehran Lipid and Glucose Study. Fasting plasma glucose (FPG), 2-h post-load glucose (2h-PG), and fasting serum insulin were measured. Homeostatic model assessment of insulin resistance index (HOMA-IR) and β-cell function (HOMA-B), and the quantitative insulin sensitivity check index (QUICKI) were calculated. Glucose tolerance abnormalities included impaired fasting glucose (IFG), impaired glucose tolerance (IGT), and type 2 diabetes (T2DM). DII scores were positively associated with 2h-PG (β = 0.04; p = 0.05). …

Sources, Distributions, And Dynamics Of Dissolved Organic Matter In The Canada And Makarov Basins, Yuan Shen, Ronald Benner, Lisa Robbins, Jonathan Wynn

Faculty Publications

A comprehensive survey of dissolved organic carbon (DOC) and chromophoric dissolved organic matter (CDOM) was conducted in the Canada and Makarov Basins and adjacent seas during 2010–2012 to investigate the dynamics of dissolved organic matter (DOM) in the Arctic Ocean. Sources and distributions of DOM in polar surface waters were very heterogeneous and closely linked to hydrological conditions. Canada Basin surface waters had relatively low DOC concentrations (69 ± 6 μmol L−1), CDOM absorption (a325: 0.32 ± 0.07 m−1) and CDOM-derived lignin phenols (3 ± 0.4 nmol L−1), and high spectral slope values (S275–295: 31.7 ± …

Sources, Distributions And Dynamics Of Dissolved Organic Matter In The Canada And Makarov Basins, Yuan Shen, Ronald Benner, Lisa L. Robbins, Jonathan G. Wynn

Faculty Publications

A comprehensive survey of dissolved organic carbon (DOC) and chromophoric dissolved organic matter (CDOM) was conducted in the Canada and Makarov Basins and adjacent seas during 2010–2012 to investigate the dynamics of dissolved organic matter (DOM) in the Arctic Ocean. Sources and distributions of DOM in polar surface waters were very heterogeneous and closely linked to hydrological conditions. Canada Basin surface waters had relatively low DOC concentrations (69 ± 6 μmol L−1), CDOM absorption (a325: 0.32 ± 0.07 m−1) and CDOM-derived lignin phenols (3 ± 0.4 nmol L−1), and high spectral slope values (S275–295: 31.7 ± …

Investigation Of Shadowing Effects In Typical Propagation Scenarios For High Speed Railway At 2350 Mhz, Liu Liu, Cheng Tao, David W. Matolak, Tao Zhou, Houjin Chen

Faculty Publications

Based on realistic measurements in China, shadowing characteristics at the frequency of 2350 MHz were investigated in typical High-Speed Railway environments. After confirming that the measured shadowing satisfies wide-sense stationarity (assessed via the reverse arrangement test method), we quantify the shadowing correlation. Three types of correlation models are compared for the shadowing characterization, and the Normalized Mean Square Error is used to determine the best matching model: a single decaying exponential function. Decorrelation distances were found to be 11.9 m, 17.7 m, and 8.3 m in our three HSR scenarios, respectively. The results should be useful for the evaluation and …

No Contact Terms For The Magnetic Field In Lorentz- And Cpt-Violating Electrodynamics, Karl Schober, Brett David Altschul

Faculty Publications

In a Lorentz- and CPT-violating modification of electrodynamics, the fields of a moving charge are known to have unusual singularities. This raises the question of whether the singular behavior may include δ-function contact terms, similar to those that appear in the fields of idealized dipoles. However, by calculating the magnetic field of an infinite straight wire in this theory, we demonstrate that there are no such contact terms in the magnetic field of a moving point charge.

No Contact Terms For The Magnetic Field In Lorentz- And Cpt-Violating Electrodynamics, Karl Schober, Brett Altschul

Faculty Publications

In a Lorentz- and CPT-violating modification of electrodynamics, the fields of a moving charge are known to have unusual singularities. This raises the question of whether the singular behavior may include δ-function contact terms, similar to those that appear in the fields of idealized dipoles. However, by calculating the magnetic field of an infinite straight wire in this theory, we demonstrate that there are no such contact terms in the magnetic field of a moving point charge.

Calcification Of The Planktonic Foraminiferaglobigerinabulloidesand Carbonate Ion Concentration Resultsfrom The Santa Barbara Basin, Emily B. Osborne, Robert C. Thunell, Brittney J. Marshall, Jessica A. Holm, Eric J. Tappa, Claudia R. Benitez-Nelson, Wei‐Jun Cai, Baoshan Chen

Faculty Publications

Planktonic foraminiferal calcification intensity, reflected by shell wall thickness, has been hypothesized to covary with the carbonate chemistry of seawater. Here we use both sediment trap and box core samples from the Santa Barbara Basin to evaluate the relationship between the calcification intensity of the planktonic foraminifera species Globigerina bulloides, measured by area density (µg/µm2), and the carbonate ion concentration of seawater ([CO32−]). We also evaluate the influence of both temperature and nutrient concentration ([PO43−]) on foraminiferal calcification and growth. The presence of two G. bulloides morphospecies with systematically different calcification properties and offset stable isotopic compositions was identified within …

Fulleretic Well-Defined Scaffolds: Donor–Fullerene Alignment Through Metal Coordination And Its Effect On Photophysics, Derek E. Williams, Ekaterina A. Dolgopolova, Danielle C. Godfrey, Evgeniya D. Ermolaeva, Perry J. Pellechia Dr., Andrew B. Greytak Prof. Dr., Mark Smith Dr., Stanislav M. Avdoshenko, Dr., Alexey A. Popov Dr., Natalia B. Shustova Prof. Dr.

Faculty Publications

Herein, we report the first example of a crystalline metal–donor–fullerene framework, in which control of the donor–fullerene mutual orientation was achieved through chemical bond formation, in particular, by metal coordination. The 13C cross-polarization magic-angle spinning NMR spectroscopy, X-ray diffraction, and time-resolved fluorescence spectroscopy were performed for comprehensive structural analysis and energy-transfer (ET) studies of the fulleretic donor–acceptor scaffold. Furthermore, in combination with photoluminescence measurements, the theoretical calculations of the spectral overlap function, Förster radius, excitation energies, and band structure were employed to elucidate the photophysical and ET processes in the prepared fulleretic material. We envision that the well-defined fulleretic donor–acceptor …

From Near And Far: Utilization Of In-Situ And Remotely Sensed Satellite Data From Nasa And Noaa, Jessica Rochelle Price Sutton

Theses and Dissertations

Satellite remote sensing observations have been used for numerous studies to better understand physical and biological properties over varying spatial and temporal scales. Depending on the satellite and sensor, the satellite-derived observations can provide high spatial and temporal resolution for many important physical and biological variables. While there are many limitations in utilizing satellite remote sensing products, there are also many advantages. This dissertation investigates three different applications for satellite remote sensing products to address climatological and ecological concerns. This dissertation is motivated by two overall research questions: (1) How can satellite remote sensing products be used to address important …

Ecohydrology And Groundwater Dynamics In A Salt Marsh Island, Andrea L. H. Hughes

Theses and Dissertations

Tidal salt marshes are extraordinarily productive and valuable ecosystems that provide via groundwater a not insignificant portion of coastal solute and nutrient budgets. Among the many goods and services they provide are habitat for diverse wildlife, protection for coastal communities during storms, and protection for coastal surface waters by filtering anthropogenic pollutants. One threat to the health of tidal salt marshes along the East Coast have been episodes of Acute Marsh Dieback (AMD) from 1999 to 2001. Dieback was observed at North Inlet salt marsh from 2000 to 2001. Since salt marsh hydrology is dominated by the local tidal regime, …

Small Mud And Sand Filled Paleochannels Offshore Charleston, Sc, Erin Smoak

Theses and Dissertations

The spatial variations of Quaternary sediments on the continental shelf record the progression of depositional environments during the latest sea-level rise, and are fundamental controls on submarine groundwater discharge (SGD) flow. SGD on continental shelves is an important but poorly constrained process. Spatial variations of lithologies on continental shelves, such as sand-filled paleochannels, are assumed to play a fundamental role in controlling where SGD occurs but coincident seismic mapping and sedimentological data are rare. Here we combine seismic mapping of paleochannel locations with sediment cores to examine the sedimentary characteristics of paleochannel fill and interfluvial deposits. To establish paleochannel locations …

Iron Uptake And Accumulation Is A Target Of Nickel Toxicity During The Lag Phase In Escherichia Coli, Geoffrey Tuttle Ford

Theses and Dissertations

Various transition metals are essential to all forms of life, and are only required in trace amounts. But this dependence comes as a double-edged sword. All organisms must maintain a careful intracellular quota that does not traverse outside an acceptable range. One transition metal in particular is nickel. The importance of this transition metal has been debated widely and its function varies greatly between organisms, including bacteria. However, the adverse effects caused by over exposure to this metal have been the center of much experimentation in recent years. Still, the mechanisms of nickel toxicity and the subsequent effects on cellular …

Determination Of The Polarization Observables Cx, Cz, And Py For Final-State Interactions In The Reaction −!D ! K+−!N, Tongtong Cao

Theses and Dissertations

The hyperon-nucleon (YN) interaction plays a key role in hypernuclei and strange nuclear matter and is an important part of the baryon-baryon interaction. While considerable progress has been made in the understanding of the nucleon-nucleon (NN) interaction, the YN interaction is less known. Some parameters of the YN potential can be obtained from the NN potential by using SU(3) symmetry. However, due to broken SU(3) there are parameters, which must be obtained from fits to experimental data. High-statistics data on exclusive photoproduction off the deuteron initiated with highly-polarized photons offer a unique opportunity to extract a large sample of polarization …

Ligand-Induced Magnetic Changes In Metal Thin Films, Fiona Senta Oberbeck-Oxsher

Theses and Dissertations

The investigation of magnetic properties of thin films whose surfaces were modified by organic molecules shows that the addition of any functional group to the surface measurably changes the magnetic properties. The effect often scales with ligand strength and is not limited to surfaces with ferromagnetic properties. Improving upon the technique developed by Knaus et al. [1], a stable and sensitive device was developed to measure this magnetic effect using the planar Hall effect (PHE) in order to shed light onto controversial questions of purported paramagnetism of thiolated gold. There is a measureable non-diamagnetic response of thin gold layers when …

Structural And Functional Studies Of Nicotinamide Adenine Dinucleotide And Streptolysin S Biosynthesis Proteins From Streptococcus Pyogenes, William T. Booth

Theses and Dissertations

Invasive infections caused by Streptococcus pyogenes, also known as Group A Strep (GAS), results in approximately 600,000 deaths annually. With evidence of antibiotic-resistant strains of this bacterium on the rise, there is a need for the identification of new drug targets to control these infections. In our approach we target the quinolinate-salvage pathway (QSP) and the streptolysin S (SLS) biosynthesis pathway. The QSP provides a secondary pathway for NAD+ biosynthesis within this organism; the SLS pathway leads to the formation of a quorum sensing molecule (SLS). We hypothesize that inhibition of the pathways will lead to GAS cell death or …

Sensitivity Of The Cuore Detector To Solar Axions, Dawei Li

Theses and Dissertations

The strong CP problem in Quantum Chromodynamics (QCD), predicts the neutron electric dipole moment to be a factor of 1010 larger than the observed upper bound [15]. Roberto Peccei and Helen Quinn [58, 63] proposed an elegant solution to this problem by introducing a global U(1)PQ symmetry that is spontaneously broken at an energy scale fa. A consequence of this symmetry-breaking is that a new spin-zero neutral pseudoscalar particle, the axion, is generated which is a Nambu-Goldstone boson [70, 78]. The “invisible axion” models with fa >> fEW, typically KSVZ and DFSZ models, have been proposed and recognized to be far-reaching …

The Development Of A High Resolution Deep-Uv Spatial Heterodyne Raman Spectrometer, Nirmal Lamsal

Theses and Dissertations

Raman spectroscopy is a light scattering technique that has a huge potential for standoff measurements in applications such as planetary exploration because a Raman spectrum provides a unique molecular fingerprint that can be used for unambiguous identification of target molecules. For this reason, NASA has selected a Raman spectrometer as one of the major instruments for its new Mars lander mission, Mars 2020, in the search for biomarkers that would be the indicators of past or present life. Raman scattering is strongest at UV wavelengths because of the inherent increase in the Raman cross section at shorter wavelengths and because …

North American Butterfly Association Counts At Congaree National Park: A Case Study For Connecting Citizen Science To Management, Austin Clarridge

Theses and Dissertations

Citizen science is becoming an ever more popular way for scientists and resource managers to deal with needs for large temporal and spatial scale datasets. It provides a free or low cost means for collection of extensive amounts of data across time and space while acting as a public education and outreach tool, empowering communities to be involved in the management decisions being made in their back yard. Though large, well-known citizen science programs such as the Christmas Bird Counts are being used extensively for peer reviewed literature and management decisions, there are numerous smaller, local counts that have the …

Bayesian Nonparametric Approaches To Multiple Testing, Density Estimation, And Supervised Learning, William Cipolli Iii

Theses and Dissertations

This dissertation presents methods for several applications of Polya tree models. These novel nonparametric approaches to the problems of multiple testing, density estimation and supervised learning provide an alternative to other parametric and nonparametric models. In Chapter 2, the proposed approximate finite Polya tree multiple testing procedure is very successful in correctly classifying the observations with non-zero mean in a computationally efficient manner; this holds even when the non-zero means are simulated from a mean-zero distribution. Further, the model is capable of this for “interestingly different” observations in the cases where that is of interest. Chapter 3 proposes discrete, and …

Quantum Dot Metrics For Preparative Chemistry And Fluorescence Applications, Yi Shen

Theses and Dissertations

Colloidal semiconductor quantum dots (QDs) are considered to be a promising candidate for bio-imaging and solar cells because of their extraordinary photo-physical properties. The ultimate goal of this dissertation is to design a reliable matrix and a reproducible method to prepare QDs-based biocompatible probe for fluorescence applications. Synthesis of quantum dots requires a large amount of ligands to improve the stability at high temperature. However, for further application and surface modification of QDs, excess ligands must be removed. In this dissertation, I will first describe using gel permeation chromatography (GPC) as a media to purify different types of QDs. A …

An Integrated Structural Analysis On Seismic Of A Paleo Mound Development (Woolsey Mound, Northern Gulf Of Mexico), Ricardo Tomas Troco Kabila

Theses and Dissertations

Woolsey Mound is ~1 km diameter thermogenic gas hydrate and cold seep (GHCS) complex system. It is located at ~900 m water depth in the Mississippi Canyon Lease Block 118 (MC–118) on the upper continental slope of the northern Gulf of Mexico (GOM). Due to its complex geology, widespread hydrate seepage activity and presence of benthic habitat, the mound serves as a permanent research site for a multidisciplinary seafloor observatory, thus providing insights into the dynamics of shallow fluid expulsion, their spatial and time variations and possible geological forcing mechanisms.

This study utilizes a set of high resolution 2D autonomous …

Temperature Dependent Transport Properties Of Chemical Vapor Deposition Graphene With Metal And Metal Hydride Surface Functionalization, Bochen Zhong

Theses and Dissertations

Graphene, a two-dimensional semi-conductor material containing carbon atoms tightly bonded together in a hexagonal structure, was first isolated by mechanical exfoliation in 2004. Over the past decade, it has drawn huge research interest due to its outstanding mechanical, thermal, and electrical properties. These unique properties of graphene lead to very high carrier mobility. In particular, after an annealing treatment to remove the residual impurities, the suspended graphene mobility exceeds 200,000 cm2/Vs. However, this value is highly reduced to only a few thousand cm2 /Vs in supported graphene on SiO2 or SiC substrates, due to different sources of scattering. For example, …

Satellite-Assisted Assessment Of The Effects Of Human Development On Coral Reefs, Roatan Honduras, Clayton A. Helm

Theses and Dissertations

Human intervention is degrading coastal marine environments on a global scale. Coral reefs are one of the most valuable ecosystems occupying coastal areas that provide a vast majority of consumable fish, recreational activities, and protection from extreme events, such as tropical cyclones. Unfortunately, as human development activities such as the construction of buildings, road infrastructure, and agriculture increase in coastal areas, so do the detrimental impacts on the health of coral reefs. Consequences of coastal development such as pollution, sedimentation, eutrophication, overfishing, and recreational activities have been linked to diminished coral health. A degraded coral ecosystem can often be identified …

Development And Application Of Bayesian Semiparametric Models For Dependent Data, Junshu Bao

Theses and Dissertations

Dependent data are very common in many research fields, such as medicine (repeated measures), finance (time series), traffic (clustered), etc. Effective control/modeling of the dependency among data can enhance the performance of the models and result in better prediction. In many cases, the correlation itself may be of great interest. In this dissertation, we develop novel Bayesian semi-/nonparametric regression models to analyze data with various dependence structures. In Chapter 2, a Bayesian non- parametric multivariate ordinal regression model is proposed to fit drinking behavior survey data from DWI offenders. The responses are two-dimensional ordinal data, drinking frequency and drinking quantity …

Novel Methods For Analyzing Longitudinal Data With Measurement Error In The Time Variable, Caroline Munindi Mulatya

Theses and Dissertations

In some longitudinal studies, the observed time points are often confounded with measurement error due to the sampling conditions, resulting into data with measurement error in the time variable. This type of data occurs mainly in observational studies when the onset of a longitudinal process is unknown or in clinical trials when individual visits do not take place as specified by the study protocol, but are often rounded to coincide with the study protocol. Methodological and inferential implications of error in time varying covariates for both linear and nonlinear models have been studied widely. In this dissertation, we shift attention …

A Comparison Of Framing In Two Environmental Conflicts, Alexander M. Iannone

Theses and Dissertations

Frames can be perspectives about people, objects, events, or settings that guide action based on past experiences and values. Conflicts are created by different stakeholders “holding conflicting frames.” Researchers in the past have used framing analysis to try and better understand environmental conflicts that tend to perpetuate for extended periods of time. A set of researchers have relied on specific framing categories and typologies as a framework for analysis. They have found that the strong presence or lack thereof certain frames can tell us a lot about conflict dynamics and shed light into the undercurrents driving the complexity of the …

Platinum Decoupling From Pge In Peridotitic Sulfides From The St. Elena Ophiolite In Costa Rica, Jessica A. Holm

Theses and Dissertations

The platinum group elements (Os, Ir, Ru, Rh, Pt, Pd) are important petrogenetic tracers of mantle processes and the Re-Os isotope system an important tool for tracing ancient depletion and refertilization processes in the mantle. A key characteristic of these elements is that they are siderophile and chalcophile, and their abundance in the Earth’s mantle is thought to be controlled by sulfides. Existing thermodynamic data suggests that at reducing conditions similar to those found at the early stages of serpentinization, PGE may exist as alloys in the mantle. While numerous studies report on the bulk peridotite PGE and sulfide PGE …

Behavior Of Rare Earth Elements And High-Field Strength Elements During Peridotite - Seawater Interaction, Carl Pasquale Frisby

Theses and Dissertations

Serpentinized abyssal peridotites are evidence for active communication between the Earth’s hydrosphere and the upper mantle, where exchange and retention of both major and trace elements occur. Rare earth elements (REE) and high-field strength elements (HFSE: Ti, Zr, Hf, Nb, Ta) are generally thought of as immobile during serpentinization. In partially serpentinized abyssal peridotites, clinopyroxenes typically retain radiogenic Nd and Hf isotopic signatures that have been used to infer the composition and high temperature processes in the upper mantle. However, bulk rock Nd isotopes in some serpentinized abyssal peridotites less radiogenic values that approach that of seawater, which has been …

Hydrodynamic Theories For Flows Of Active Liquid Crystals And The Generalized Onsager Principle, Xiaogang Yang, Jun Li, M. Gregory Forest, Qi Wang

Faculty Publications

We articulate and apply the generalized Onsager principle to derive transport equations for active liquid crystals in a fixed domain as well as in a free surface domain adjacent to a passive fluid matrix. The Onsager principle ensures fundamental variational structure of the models as well as dissipative properties of the passive component in the models, irrespective of the choice of scale (kinetic to continuum) and of the physical potentials. Many popular models for passive and active liquid crystals in a fixed domain subject to consistent boundary conditions at solid walls, as well as active liquid crystals in a free …

From The Sewing Room To The Ballroom, The Evolution Of Ballroom Dance Costumes, Jessica Marie Russell

Senior Theses

Although I have danced all my life, I only began to ballroom dance and dance socially after starting college at the University of South Carolina. While dancing with the Carolina Ballroom Club, I learned some of the history of ballroom dance from our instructors, but I never quite understood how we went from having very conservative court dances to the wide variety of ballroom dances where dancers wear extravagant costumes. I also have been sewing since I was a child; I helped do minor repairs in the costume room for ballet productions, and recently began making clothing for myself. I …