Physical Sciences and Mathematics Commons^™

Bioretention: Evaluating Their Effectiveness For Improving Water Quality In New England Urban Environments, Mary Dehais

Masters Theses 1911 - February 2014

Nonpoint source (NPS) pollution is one of the leading causes of water quality problems in the United States. Bioretention has become one of the more frequently used stormwater management practices for addressing NPS pollution in urbanized watersheds in New England. Yet despite increased acceptance, bioretention is not widely practiced. This study explores and evaluates the efficacy of bioretention for protecting urban water quality.

This research found that numerous monitoring methods are used by researchers and industry experts to assess the effectiveness of stormwater best management practices (BMPs) and low impact development (LID) practices that include bioretention. The two most common …

Electronic And Vibrational Spectroscopy Of Ni+(H2o), Jennifer S. Daluz

Masters Theses 1911 - February 2014

The electronic and vibrational spectra of Ni⁺(H₂O) were measured using photofragment spectroscopy. In the electronic spectrum, photodissociation is observed at photon energies above 16875 cm^-1. The only fragment observed is Ni⁺. The electronic spectrum consists of well-resolved peaks spaced by ~340 cm^-1, due to a vibrational progression in the excited electronic state. These peaks have complex sub-structure, consisting of a triplet, spaced by ~30 cm^-1. The sub-structure is due to rotational structure in a perpendicular transition of a prolate top molecule. In addition to this major progression, there …

A High-Resolution Temperature Record From Lakes Of The Lofoten Islands, Northwestern Norway Based On A New Uk37 Temperature Calibration From In Situ Measurements, Xiaohui Huang

Masters Theses 1911 - February 2014

Water filters and sediment trap samples were collected weekly from late May to early September 2009 from four lakes of the Lofoten archipelago, northwestern Norway, and were used to explore the applicability of the alkenone unsaturation index (UK37) for temperature reconstruction in limnic systems in the area. For the first time, we observed the occurrence of long-chain alkenones (LCAs) within the water columns of lakes in this region. Water filters from two of the four studied lakes contained measurable concentrations of alkenones that were restricted to spring turnover and disappeared with the onset of summer stratification. These results indicate that …

An Ecosystem Approach To The Sustainability Of Urbanizing Watersheds, Sarah L. Raposa

Masters Theses 1911 - February 2014

Political boundaries make watershed planning difficult despite the influence of many state and federal programs. Broad, top-down, watershed initiatives fail to reach many municipalities due to human resources, time and legalities. Thus, a watershed ecosystem based approach to city planning should be utilized in order to integrate a holistic and scientific foundation for land use decisions. However, there is a need for research for developing and applying a watershed approach to urbanizing watersheds.

The goal of this study is to provide a series of science based transferable recommendations upon which municipalities can make land use planning decisions. These recommendations are …

On The Retrieval Of The Beam Transverse Wind Velocity Using Angles Of Arrival From Spatially Separated Light Sources, Shiril Tichkule

Masters Theses 1911 - February 2014

For optical propagation through the turbulent atmosphere, the angle of arrival (AOA) cross-correlation function obtained from two spatially separated light sources carries information regarding the transverse wind velocity averaged along the propagation path. Two methods for the retrieval of the beam transverse horizontal wind velocity, v_t, based on the estimation of the time delay to the peak and the slope at zero lag of the AOA cross-correlation function, are presented. Data collected over a two week long experimental campaign conducted at the Boulder Atmospheric Observatory (BAO) site near Erie, CO was analyzed. The RMS difference between 10 s estimates of …

Determinants Of Health Care Use Among Rural, Low-Income Mothers And Children: A Simultaneous Systems Approach To Negative Binomial Regression Modeling, Swetha Valluri

Masters Theses 1911 - February 2014

The determinants of health care use among rural, low-income mothers and their children were assessed using a multi-state, longitudinal data set, Rural Families Speak. The results indicate that rural mothers’ decisions regarding health care utilization for themselves and for their child can be best modeled using a simultaneous systems approach to negative binomial regression. Mothers’ visits to a health care provider increased with higher self-assessed depression scores, increased number of child’s doctor visits, greater numbers of total children in the household, greater numbers of chronic conditions, need for prenatal or post-partum care, development of a new medical condition, and …

Pharmacological Chaperoning In Fabry Disease, Jerome Rogich

Masters Theses 1911 - February 2014

Fabry Disease is an X-­‐linked lysosomal storage disorder characterized by a variety of symptoms including hypohydrosis, seizures, cardiac abnormalities, skin lesions, and chronic pain. These symptoms stem from a lack of functional endogenous α-­‐ Galactosidase A (α-­GAL), which leads to an accrual of its natural substrate. The severity of the disease symptoms can be directly correlated with the amount of residual enzyme activity. It has been shown that an imino sugar, 1-deoxygalactonojirimycin (DGJ), can increase enzymatic activity and clear excess substrate. This pH-­‐dependent chaperoning phenomenon is believed to arise from the presence of aspartic acid 170 in the active site. …

Jarosite Formation At The Davis Mine, Rowe, Massachusetts, Karen S. Miller

Masters Theses 1911 - February 2014

This study investigates jarosite formation and stability patterns at the abandoned Davis Pyrite Mine in Rowe, Massachusetts. Jarosite, an iron-sulfate hydroxide, is found in acid mine drainage (AMD) environments, in acid sulfate soils, and on Mars. Jarosite and the iron oxides goethite and hematite are present at the site. Soil samples from the site were examined by XRD, SEM, and EDS. Five mineralogical areas were found, based on mineral abundance patterns. Jarosite exists in four of these areas. Two jarosite morphologies were identified. “Variable” jarosite, with partly-dissolved crystals of about 0.5 to 5 micrometers diameter, exists in spoil pile samples. …

Building Integrated Aquaculture, Erik A. Woodin

Masters Theses 1911 - February 2014

Exploratory research into a fresh concept, building integrated aquaculture, has found new information on the topic. Motives indicating building integrated aquaculture is important for sustainable development were identified. A review of the literature found relatively little in the way of experiments, aquaculture operations, and case studies which documented or demonstrated a deep understanding of the interactions between building and aquaculture systems. A simple experiment was conducted observing thermal energy and moisture interactions in simulated aquaculture facilities, some with tank covers and insulation. Two different retrofit programs were developed in a case study of building integrated aquaculture for an existing structure …

Growth Of Chromidia-Forming Vahlkampfiid Amoebae From Laguna Figueroa, Baja California Del Norte, Mexico And Eel Pond, Woods Hole, Massachusetts, U.S.A. Under Limited Oxygen Gas Conditions, Melishia I. Santiago

Masters Theses 1911 - February 2014

Paratetramitus jugosus, a vahlkampfiid amoebomastigote, was isolated into monoprotist/monobacterial (Bacillus sp.), cultures from laminated microbial mats (Laguna Figueroa, Baja California Norte, Mexico) and muds (Eel Pond, Woods Hole, Massachusetts). Chromidia, roughly spherical (2-4 µm in diameter) were released from both walled spherical cysts (10-12 µm) and phagocytotic amoebic forms. Desiccation-resistant walled chromidia, at first spherical, resorb their walls and develop into small pleiomorphic phagocytotic amoeba. Small amoebae feed and mature into typical monopodial vahlkampfiid adults confirming previous work (Dobell, 1913, and especially the analysis of a larger encysting vahlkampfiid amoeba associated with Long Island oyster disease studied at Woods Hole …

Attenuation Of Acid Mine Drainage Enhanced By Organic Carbon And Limestone Addition: A Process Characterization, Anna M. Gillmor

Masters Theses 1911 - February 2014

Surface and groundwaters in contact with mining-exposed pyritic materials have the capacity to generate acid mine drainage (AMD), an acidic, sulfate-rich, metals-laden effluent. The Davis Mine located in northwestern Massachusetts offers a model site to study the processes of natural attenuation of acid mine drainage. These include physico-chemical processes such as dilution and sorption, geochemical processes such as aluminosilicate weathering and biological processes such as transformation and cycling of sulfate, iron and acidity by bacterial metabolism. A focus of recent research undertaken at the site has been characterizing the presence and activity of these bacteria with an aim to stimulate …

Managing Vegetation To Restore Tern Nesting Habitat In The Gulf Of Maine, Juliet S. Lamb

Masters Theses 1911 - February 2014

Following catastrophic exploitation throughout the North Atlantic, breeding seabird populations have begun to recover thanks to regulatory protection and restoration and management efforts. As bird populations increase, new challenges emerge, including overgrowth of vegetation that limits the open nesting habitat favored by most tern species. Though managers have used a variety of measures to reduce vegetation cover, these techniques have rarely been quantified or compared experimentally.

During the summers of 2009 and 2010, I applied two different techniques, controlled burning and artificial weed barriers (muslin fabric and artificial turf) to experimental plots on Eastern Egg Rock and Outer Green Island, …

Landscapes Of Compassion: A Guatemalan Experience, Travis W. Shultz

Masters Theses 1911 - February 2014

ABSTRACT

LANDSCAPES OF COMPASSION: A GUATEMALAN EXPERIENCE

MAY 2011

TRAVIS WILLIAM SHULTZ

A.S., UNIVERSITY OF MASSACHUSETTS AMHERST

B.A., UNIVERSITY OF MASSACHUSETTS AMHERST

M.A., UNIVERSITY OF MASSACHUSETTS AMHERST

Directed by: Professor Peter Kumble, PhD

If landscape architecture can intertwine with the practice of social justice, how should academic training provide an atmosphere where this correlation is developed? In a professional degree program, such as landscape architecture, there are a plethora of skills among students that can be utilized no only in their future careers, but during their academic experience. By learning the tools while implementing them, there is a profound educational …

A New Species Of Moropus (Mammalia, Perissodactyla, Chalicotheriodea) In The Batesland Formation, Great Plains Area Of North America, Carolyn Rounds

Masters Theses 1911 - February 2014

The chalicothere Moropus was a rare perissodactyl present in the Great Plains region of North America through much of the Miocene. A temporal gap in named species of Moropus is present in the early Hemingfordian North American Land Mammal Age. This gap is filled by specimens currently referred to as Moropus sp. from the Batesland Formation in southwest South Dakota, and unnamed specimens of Moropus in the Runningwater Formation in northwestern Nebraska. A comparison of the fossils of Moropus nsp. from the Batesland Formation with those of previously described chalicothere species from the Greats Plains region, such as Moropus elatus, …