Physical Sciences and Mathematics Commons^™

Patterns In Trash: Factors That Drive Municipal Solid Waste Recycling, Jared Starr

Masters Theses 1911 - February 2014

Municipal recycling is driven by a variety of factors. Yet how these factors change over time is not well understood. I analyze a suite of contextual and program variable in multiple time periods, spanning 16 years, in the Commonwealth of Massachusetts. Based on the models run, I reach the surprising conclusion that most program variables have an insignificant effect on recycling rates. These findings can inform municipal officials and waste managers as they seek new ways to increase municipal recycling participation.

Push-Pull Molecules: Models And Polymer Building Blocks For Organic Photovoltaic Applications, Raymond Devaughn

Masters Theses 1911 - February 2014

Several fluorenone alkynyl based oligo conjugated molecules were synthesized and characterized. Most compounds exhibited UV-Vis absorption onset at ca. 500 nm and a PL emission onset of ~329-370 nm, with excimer emission suspected from most systems near ~530-560 nm. Experimentally determined E_HOMO and E_LUMO energies range from -6.02 to -5.73 eV and -3.47 and 3.55 eV, respectively, with the lowest experimental E_g lying at -2.26 eV for 2-(trimethoxyphenylacetylene)-fluorenone. Cyclic voltammetry indicates quasi-reversible reduction for all systems, with 2,7-bis(nitrophenylacetylene)fluorenone exhibiting a high reduction potential of -1.25 eV. Only 2,7-bis(trimethoxyphenylacetylene)fluorenone exhibited a quasi-reversible oxidation, due to electron rich methoxy …

Free Wake Potential Flow Vortex Wind Turbine Modeling: Advances In Parallel Processing And Integration Of Ground Effects, Nathaniel B. Develder

Masters Theses 1911 - February 2014

Potential flow simulations are a great engineering type, middle-ground approach to modeling complex aerodynamic systems, but quickly become computationally unwieldy for large domains. An N-body problem with N-squared interactions to calculate, this free wake vortex model of a wind turbine is well suited to parallel computation. This thesis discusses general trends in wind turbine modeling, a potential flow model of the rotor of the NREL 5MW reference turbine, various forms of parallel computing, current GPU hardware, and the application of ground effects to the model. In the vicinity of 200,000 points, current GPU hardware was found to be nearly 17 …

Energy Efficiency Programs At All Utilities: An Analysis Of The Factors That Lead Electric Utilities To Invest In Energy Efficiency, Christopher J. Pletcher

Masters Theses 1911 - February 2014

While the utilization of energy efficiency has grown in recent years, it has not been distributed evenly across the country. In some states, over 2% of a utility’s budget is spent on energy efficiency; in other states that number is 0. Much of the growth in energy efficiency has been due to state policies and the development utility-level energy efficiency programs. Yet, all utility programs are not created equal. Because they are often exempt from state regulation (and therefore state energy efficiency policy), publicly-owned utilities have traditionally lagged behind IOUs when it comes to EE programs.

This research quantifies energy …

Resin Volatiles Of Eastern Hemlock Induced By Its Non-Native Herbivores, Joshua D. Pezet

Masters Theses 1911 - February 2014

Eastern hemlock (Tsuga canadensis) is in decline because of infestation by the invasive hemlock woolly adelgid (Adelges tsugae; ‘HWA’) and, to a lesser extent, the elongate hemlock scale (Fiorinia externa; ‘EHS’). Many conifers respond to insect herbivory by inducing oleoresin-based defenses, however it is unknown whether eastern hemlock is capable of this inducible response. We conducted a plantation setting study of artificially infested saplings to determine if feeding by HWA or EHS induces changes in the tree’s volatile chemistry. The induced changes in volatiles we found were unlike the terpenoid-based defenses of related conifers. Only HWA feeding …

An Integrated Study Of The South-Central Part Of The Springerville Volcanic Field; The Final Piece, Marissa Mnich

Masters Theses 1911 - February 2014

The Springerville Volcanic Field (SVF) is a monogenetic volcanic field located in east-central Arizona and is the southernmost of several late Pliocene to Holocene volcanic fields along the margin of the Colorado Plateau. It encompasses an area of over 3000 km² and consists of over 450 vents, most of which are cinder cones, which produced mainly basaltic flows, between 2.1 and 0.3 Ma. About 85% of the SVF was previously mapped in detail by Condit, Crumpler and Aubele (1999). In the summers of 2010 and 2011, mapping was completed in the remaining portion of the field known as the …

Habitat Heterogeneity Concentrates Predators In The Seascape: Linking Intermediate-Scale Estuarine Habitat To Striped Bass Distribution, Cristina Kennedy

Masters Theses 1911 - February 2014

Predators are key components of aquatic ecosystems and innovative approaches to understanding their spatial distribution are imperative for research, effective management, and conservation. Discontinuities, created by abrupt changes between two unlike entities, are irregularly-distributed, intermediate-scale features that can have a disproportionate effect on organismal distribution within the seascape. Here I use the discontinuity concept to relate the distribution of a predator, striped bass (Morone saxatilis), to physical features within Plum Island Estuary (PIE), MA. I mapped the distribution of 50 acoustically-tagged striped bass during four monthly surveys at 40 sites to evaluate if heterogeneity in physical features concentrated …

Holocene Paleo-Environmental Variability Reconstructed From A Lake Sediment Record From Southeast Greenland, Gregory A. De Wet

Masters Theses 1911 - February 2014

Arctic climate variability over the Holocene has been both extensive and, at times, abrupt. Current understanding of these changes is still quite limited with few high-resolution paleoclimate records available for this period. In order to place observed and predicted 21^st century climate change in perspective, reliable and highly resolved paleo-reconstructions of Arctic climate are essential. Using an 8.5 m sediment core from Nanerersarpik Lake, this project will characterize climate changes during the Holocene, including the deglacial transition, the rapid changes that are known to have occurred around 8,200 years ago, the transition from Holocene thermal maximum (HTM) to the …

7700 Years Of Holocene Climatic Variability In Sermilik Valley, Southeast Greenland Inferred From Lake Sediments, Samuel H. Davin

Masters Theses 1911 - February 2014

During the latter half of the 20^th century until present day there has been an unprecedented rise in global annual mean temperatures accompanied by rising sea levels and a decrease in Northern Hemisphere snow cover, which if it continues will lead to widespread disruption of climate patterns, ecosystems, and present-day landscapes. It is therefore of critical importance to establish an expanded network of paleoclimate records across the globe in order to better assesses how the global climate system has changed in the past, that we may create a metric by which to address modern change. Herein is presented a7,700 …

A Gcm Comparison Of Plio-Pleistocene Interglacial-Glacial Periods In Relation To Lake El’Gygytgyn, Ne Arctic Russia, Anthony J. Coletti

Masters Theses 1911 - February 2014

Until now, the lack of time-continuous, terrestrial paleoenvironmental data from the Pleistocene Arctic has made model simulations of past interglacials difficult to assess. Here, we compare climate simulations of four warm interglacials at Marine Isotope Stage (MIS) 1 (9ka), 5e (127 ka), 11c (409 ka), and 31 (1072 ka) with new proxy climate data recovered from Lake El’gygytgyn, NE Russia. Climate reconstructions of the Mean Temperature of the Warmest Month (MTWM) indicate conditions 2.1, 0.5 and 3.1 ºC warmer than today during MIS 5e, 11c, and 31 respectively. While the climate model captures much of the observed warming during each …

A Non-Linear Eigensolver-Based Alternative To Traditional Self-Consistent Electronic Structure Calculation Methods, Brendan E. Gavin

Masters Theses 1911 - February 2014

This thesis presents a means of enhancing the iterative calculation techniques used in electronic structure calculations, particularly Kohn-Sham DFT. Based on the subspace iteration method of the FEAST eigenvalue solving algorithm, this nonlinear FEAST algorithm (NLFEAST) improves the convergence rate of traditional iterative methods and dramatically improves their robustness. A description of the algorithm is given, along with the results of numerical experiments that demonstrate its effectiveness and offer insight into the factors that determine how well it performs.

The Sedimentological And Geomorphological Response Of A Glacially Conditioned Watershed To Event Induced Flooding: Insights From The Connecticut River And Hurricane Irene, Laura Kratz

Masters Theses 1911 - February 2014

Tropical Storm Irene’s most extreme rainfall resulted in record-breaking sediment loads from upland tributaries to the Connecticut River. However, was the event exceptional with respect to resultant deposition downstream? Off-river waterbodies to the Lower Connecticut River, such as cut-off meanders and blocked valley lakes, are a particularly important floodplain environment, which have been shown to serve as a focal point for the trapping of sediment and associated contaminants. This study evaluates the relative role of extreme events like Tropical Storm Irene in infilling these off-river environments. To meet this objective we compare the magnitude and composition of resultant sedimentation from …

The Effect Of Leaves And Steel Support Cables On The Dynamic Properties Of Northern Red Oak (Quercus Rubra) With Co-Dominant Trunks, Mark Reiland

Masters Theses 1911 - February 2014

Natural frequency and damping ratio were measured for ten forest grown northern red oak trees with co-dominant trunks. Steels support cables were installed in the canopies of five of the sample trees prior to measurement. Free vibration testing was performed during periods when leaves were and were not present. An accelerometer mounted at the base of the co-dominant union measured the acceleration time history during the free vibration testing. Natural frequency was determined from the acceleration time history using power spectral density analysis. Damping ratios were calculated from the power spectral density plots using the half power bandwidth method.

Trees …

Deciphering The Age And Significance Of The Cora Lake Shear Zone: Athabasca Granulite Terrane, Northern Saskatchewan, Sean P. Regan

Masters Theses 1911 - February 2014

Interpreting the tectonic significance of high strain zones requires detailed knowledge of the P-T-t-D history of rocks on either side and of tectonized rocks within the shear zone. In-situ monazite geochronology is particularly useful because it generates a time-integrated framework of metamorphism and fabric development. This can be achieved by correlating monazite compositional domains with the growth and consumption of major phases. Furthermore, monazite can be a fabric forming mineral, and can be directly linked to structural fabrics and kinematics. The Cora Lake shear zone (CLsz) represents a major lithotectonic discontinuity within the deep crustal Athabasca Granulite terrain, and preserves …

From Indicators To Action: Evaluating The Usefulness Of Indicators To Move From Regional Climate Change Assessment To Local Adaptation Implementation, Sally Miller

Masters Theses 1911 - February 2014

As the effects of climate change become increasingly damaging and costly, a public and political consensus is building for planning that will protect private property and public infrastructure. Climate-related planning has primarily focused on mitigation, assessing vulnerability, and building adaptive capacity. Adaptation has not gained substantial ground in the area of implementation. The uncertainty associated with climate change projection and variability has emerged as a dominant barrier to adaptation. However, as knowledge accrues, the global and national science communities have been developing more detailed, fine-scale climate projections. Regional climate assessments are available for the sub-national climate regions in the U.S., …

Biomarker And Sedimentological Investigations Of Mis 8 Through Mis 12 From Lake El'gygytgyn, Ne Arctic Russia, Jeremy H. Wei

Masters Theses 1911 - February 2014

Abstract

Multiple proxy analysis of lake sediment records are crucial for understanding changes in environmental and climate conditions over historical and geological time. Most recently, the use of biomarker proxies coupled with sedimentological investigations provides a new approach for gaining insight into the lake processes that capture information about past climate change. This approach is applied here to better understand the paleoclimate record from Lake El’gygytgyn in Western Beringia. Multiple organic geochemical compound concentrations were measure as proxies for both aquatic and terrestrial biological productivity. Measurements of n-alkane (plant leaf waxes) as well as concentrations of the compounds arborinol …

The Role Of Structural Stormwater Best Management Practices, Impervious Surfaces And Natural Factors On Base Flow In Massachusetts, Kimberly B. Klosterman

Masters Theses 1911 - February 2014

This research conducted a GIS analysis of twenty-eight sub-watersheds in Massachusetts and considered five factors which the literature suggested influenced base flow. The literature suggested a positive relation between precipitation, forest cover and base flow and a negative relationship between impervious surfaces, soil drainage class, slope and base flow. A multiple regression analysis of the sub-watershed information confirmed the literature for two factors (soil drainage class and slope) and questioned it on three factors (impervious surfaces, precipitation, and forest cover). The resulting predictive equation indicated that imperviousness and precipitation were the most significant factors affecting base flow. The first derivative …

How Does Hydropeaking Alter The Hydrology Of A River Reach? A Combined Water Budget, Modeling, And Field Observation Study. Deerfield River, Massachusetts, Brian C. Yellen

Masters Theses 1911 - February 2014

Hydroelectric releases on the Deerfield River in northwestern Massachusetts affect surface water-groundwater interactions there by daily reversing the head gradient between river and groundwater. Artificially elevated stage drives river water into the riparian aquifer. Water budget analysis indicates that roughly 10% of this bank-stored water is permanently lost from the river system in a 19.5 km reach, likely as a result of transpiration by bank vegetation.

Field observations as well as two-dimensional modeling results show that water losses are not uniform throughout the study reach. Riparian aquifer transmissivity in river sub-reaches largely determines the magnitude of surface water-groundwater exchange as …

Synthesis Of Monomers For New Conjugated Polymers, Kedar Girish Jadhav

Masters Theses 1911 - February 2014

ABSTRACT

SYNTHESIS OF MONOMERS FOR NEW CONJUGATED POLYMERS

This dissertation addresses the problem of synthesis of different monomers for donor and acceptor polymers in photovoltaic applications. In general, functionalization of conjugated polymers and understanding of molecular packing of electron donors and electron acceptors are very important to produce efficient solar cells. As a result, it is important to design and synthesize novel monomers which will require making new π-conjugated donors and acceptors polymers and understand the influence of these new polymers in bulk heterojunction to design polymer solar cells. In this study, two different monomers were synthesized. The first monomer …

Evolution Of Volatile Content Of The Parent Magma Of The 1875 Eruption Of Askja Volcano, Iceland, Heather A. Clark

Masters Theses 1911 - February 2014

The bulk of the eruption of Askja in north central Iceland on March 28-29 1875 consisted of a plinian eruption that lasted 6-7 hours, produced 0.2 km³ of ash and rhyolitic pumice, and created a surge and partially welded ash/pumice fall deposit that crops out on the shore of the modern caldera lake (Sparks et al. 1981). We evaluate the volatile budget of the magma during the eruption and focus on water concentration in glass fragments and shards, glass adjacent to crystals, and melt inclusions (MIs). Sparks et al. (1981) estimated the gas exit velocity at the vent was …

Driver Dynamics And The Longitudinal Control Model, Gabriel G. Leiner

Masters Theses 1911 - February 2014

Driver psychology is one of the most difficult phenomena to model in the realm of traffic flow theory because mathematics often cannot capture the human factors involved with driving a car. Over the past several decades, many models have attempted to model driver aggressiveness with varied results. The recently proposed Longitudinal Control Model (LCM) makes such an attempt, and this paper offers evidence of the LCM's usefulness in modeling road dynamics by analyzing deceleration rates that are commonly associated with various levels of aggression displayed by drivers. The paper is roughly divided into three sections, one outlining the LCM's ability …

Diving Behavior And Identification Of Sex Of Breeding Atlantic Puffins (Fratercula Arctica), And Nest-Site Characteristics Of Alcids On Petit Manan Island, Maine, Sarah M. Spencer

Masters Theses 1911 - February 2014

During 2008 – 2009, we quantified foraging behavior of adult Atlantic puffins (Fratercula arctica) by deploying time-depth recorders (TDRs) on 18 adults and collected morphological measurements from 40 adults nesting on Petit Manan Island, Maine. Dive data were successfully retrieved from 5 birds foraging for 14 days in 2008, and 8 birds foraging for 18 days in 2009. Pooling across all birds, a total of 8,097 dives were recorded, with peaks in activity during 0400-0800 and 1600-2000, and no diving between 2100 and 0400. Mean (± SD) dives/bird/day was 276.4 (± 84.7), with dives grouped into bouts lasting …

A Paleoclimate Modeling Experiment To Calculate The Soil Carbon Respiration Flux For The Paleocene-Eocene Thermal Maximum, David M. Tracy

Masters Theses 1911 - February 2014

The Paleocene-Eocene Thermal Maximum (PETM) (55 million years ago) stands as the largest in a series of extreme warming (hyperthermal) climatic events, which are analogous to the modern day increase in greenhouse gas concentrations. Orbitally triggered (Lourens et al., 2005, Galeotti et al., 2010), the PETM is marked by a large (-3‰) carbon isotope excursion (CIE). Hypothesized to be methane driven, Zeebe et al., (2009) noted that a methane based release would only account for 3.5°C of warming. An isotopically heavier carbon, such as that of soil and C3 plants, has the potential to account for the …

A Combined Quadtree/Delaunay Method For 2d Mesh Generation, Simon Tang

Masters Theses 1911 - February 2014

Unstructured simplicial mesh is an integral and critical part of many computational electromagnetics methods (CEM) such as the finite element method (FEM) and the boundary element method (BEM). Mesh quality and robustness have direct impact on the success of these CEM methods.

A combined quadtree/Delunay 2D mesh generator, based on the early work of Schroeder (1991, PhD), is presented. The method produces a triangulation that approximates the original geometric model but is also topologically consistent. The key advantages of the method are: (a) its robustness, (b) ability to create a-priori graded meshes, and (c) its guaranteed mesh quality.

The method …

Holocene Climate And Environmental Changes: Disentangling Natural And Anthropogenic Signals In The Sedimentary Record Of Lake Lilandsvatnet (Nw Norway), Robert M. D'Anjou

Masters Theses 1911 - February 2014

This thesis presents a multi-proxy paleoenvironmental reconstruction from the sedimentary archives of Lilandsvatnet, a small arctic lake on Vestvågøy, in the Lofoten Islands, Norway. Lofoten has a rich history of human settlements existing throughout the Holocene. The catchment of Lilandsvatnet was the location of a prominent Viking chieftain farm that existed throughout the Iron Age, and the sedimentary archive contains a strong signal of prehistoric and historic human settlements and land-use practices. Paleoenvironmental reconstructions in this thesis show evidence for Holocene environmental variability in response to both natural and anthropogenic forcing. Cryptotephra deposits from Icelandic eruptions further contrain sediment chronology …

Reformulation Of The Muffin-Tin Problem In Electronic Structure Calculations Within The Feast Framework, Alan R. Levin

Masters Theses 1911 - February 2014

This thesis describes an accurate and scalable computational method designed to perform nanoelectronic structure calculations. Built around the FEAST framework, this method directly addresses the nonlinear eigenvalue problem. The new approach allows us to bypass traditional approximation techniques typically used for first-principle calculations. As a result, this method is able to take advantage of standard muffin-tin type domain decomposition techniques without being hindered by their perceived limitations. In addition to increased accuracy, this method also has the potential to take advantage of parallel processing for increased scalability.

The Introduction presents the motivation behind the proposed method and gives an overview …

Spatial And Temporal Correlations Of Freeway Link Speeds: An Empirical Study, Piotr J. Rachtan

Masters Theses 1911 - February 2014

Congestion on roadways and high level of uncertainty of traffic conditions are major considerations for trip planning. The purpose of this research is to investigate the characteristics and patterns of spatial and temporal correlations and also to detect other variables that affect correlation in a freeway setting. 5-minute speed aggregates from the Performance Measurement System (PeMS) database are obtained for two directions of an urban freeway – I-10 between Santa Monica and Los Angeles, California. Observations are for all non-holiday weekdays between January 1st and June 30th, 2010. Other variables include traffic flow, ramp locations, number of lanes and the …

Large Scale Image Retrieval From Books, Mao Zhao

Masters Theses 1911 - February 2014

Search engines play a very important role in daily life. As multimedia product becomes more and more popular, people have developed search engines for images and videos. In the first part of this thesis, I propose a prototype of a book image search engine. I discuss tag representation for the book images, as well as the way to apply the probabilistic model to generate image tags. Then I propose the random walk refinement method using tag similarity graph. The image search system is built on the Galago search engine developed in UMASS CIIR lab.

Consider the large amount of data …

Characterization Of Damage Zones Associated With Laboratory Produced Natural Hydraulic Fractures, Erin Bradley

Masters Theses 1911 - February 2014

Both joint sets and fault-related fractures serve as important conduits for fluid flow. In the former case, they can strongly influence both permeability and permeability anisotropy, with implications for production of water, hydrocarbons and contaminant transport. The latter can affect issues of fluid flow, such as whether a given fault seals or leaks, and fault mechanics. These fractures are commonly interpreted as Natural Hydraulic Fractures (NHFs), i.e., mode 1 fractures produced when pore fluid pressure exceeds the tensile strength of the rock. Various mathematical models have been a rich source of hypotheses to explain the formation and propagation of NHFs, …

Fractures Of The Dammam Dome Carbonate Outcrops: Their Characterization, Development, And Implications For Subsurface Reservoirs, Mohammed M. Al-Fahmi

Masters Theses 1911 - February 2014

The exposed Tertiary carbonates of the Dammam Dome present an opportunity to study fractures in outcrops within the oil-producing region of Eastern Saudi Arabia. The study focuses on: 1) the characterization of fractures, 2) interpretation of their fracturing mechanism, and 3) the implications for the deep carbonate reservoirs of the Dammam Dome. The characterization of the outcrop fractures is integrated with structural analysis of the near-surface horizons mapped from reflection seismic and well data. Fractures are observed within all exposed carbonate units, but predominantly within the widely exposed Middle Rus unit. The fractures are opening-mode, bed-bound joints that form orthogonal …