Physical Sciences and Mathematics Commons^™

Applications Of Femtosecond Coherent Anti-Stokes Raman Scattering In Combustion, Claresta Nicole Dennis

Open Access Dissertations

The dissertation deals with the further development of chirped-probe-pulse femtosecond coherent anti-Stokes Raman spectroscopy (CPP fs-CARS) for applications of gas phase thermometry and extension to methane concentration measurements. The main effort has been to assess the usefulness and robustness of the technique in turbulent combustors of practical interest. A primary aim has been to evaluate the use of CPP fs-CARS for vibrational N₂ thermometry in a highly turbulent environment. It has been suggested that due to the laser beam temporal overlap required for fs-CARS signal generation, the technique would be unsuccessful due to beam propagation retardation effects from density …

On The Occurrences Of Motifs In Recursive Trees, With Applications To Random Structures, Mohan Gopaladesikan

Open Access Dissertations

In this dissertation we study three problems related to motifs and recursive trees. In the first problem we consider a collection of uncorrelated motifs and their occurrences on the fringe of random recursive trees. We compute the exact mean and variance of the multivariate random vector of the counts of occurrences of the motifs. We further use the Cramér-Wold device and the contraction method to show an asymptotic convergence in distribution to a multivariate normal random variable with this mean and variance. ^ The second problem we study is that of the probability that a collection of motifs (of the …

Secure Platforms For Enforcing Contextual Access Control, Aditi Gupta

Open Access Dissertations

Advances in technology and wide scale deployment of networking enabled portable devices such as smartphones has made it possible to provide pervasive access to sensitive data to authorized individuals from any location. While this has certainly made data more accessible, it has also increased the risk of data theft as the data may be accessed from potentially unsafe locations in the presence of untrusted parties. The smartphones come with various embedded sensors that can provide rich contextual information such as sensing the presence of other users in a context. Frequent context profiling can also allow a mobile device to learn …

Divide And Recombine: Autoregressive Models And Stl+, Xiang Han

Open Access Dissertations

In this thesis multiple methods are proposed and applied to the Akamai CIDR time series data. The Akamai network is one of the world's largest distributed-computing platforms, with more than 250,000 servers in more than 80 countries. It is responsible for 15-20 percent of all web traffic. We obtained 110 GB raw CIDR data over a 18 month period, collected on the Akamai network from November 2011 to April 2013. ^ The Seasonal-Trend Decomposition procedure based on loess (STL+) is used to model the CIDR series. Motivated by the CIDR series analysis, we propose a general prediction based model selection …

Spatial Marked Point Processes: Models And Inferences, Yen-Ning E Huang

Open Access Dissertations

A spatial marked point process describes the locations of randomly distributed events in a region, with a mark attached to each observed point. Nowadays, the availability of spatiotemporal data is increasing and many spatiotemporal models are studied with applications in a wide range of disciplines. Spatial marked point processes are then extended to spatiotemporal marked point processes if time component is taken into account. In general, the marks can be quantitative or categorical variables. Independence between points and marks is a convenient assumption, but may not be true in practice. Tests for independence between points and marks are proposed previously, …

The Tessera D&R Computational Environment: Designed Experiments For R-Hadoop Performance And Bitcoin Analysis, Jianfu Li

Open Access Dissertations

D&R is a statistical framework for the analysis of large complex data that enables feasible and practical analysis of large complex data. The analyst selects a division method to divide the data into subsets, applies an analytic method of the analysis to each subset independently with no communication among subsets, selects a recombination method that is applied to the outputs across subsets to form a result of the analytic method for the entire data. The computational tasking of D&R is nearly embarrassingly parallel, so D&R can readily exploit distributed, parallel computational environments, such as our D&R computational environment, Tessera.^ In …

Usability Of Immersive Virtual Reality Input Devices, Christopher G. Mankey

Open Access Dissertations

This research conducts a usability analysis of human interface devices within an Immersive Virtual Reality Environment. The analysis is carried out for two different interface devices, a commercially available Intersense ^© Wand and a home built pinch glove and wireless receiver. Users were asked to carry out a series of minor tasks involving placement of shaped blocks into corresponding holes within an Immersive Virtual Reality Environment. Performance was evaluated in terms of speed, accuracy and precision via the collection of completion times, errors made and the precision of motion during the experiment.

Theory Of Density Functionals, Martin A. Mosquera-Tabares

Open Access Dissertations

Density functional theory is an alternative quantum mechanical theory that offers simple ways of performing calculations of the electronic properties of matter. Many different methods derive from density functional theory. The most appealing for its simplicity and rigor is the theory of Kohn and Sham. In this thesis I propose new methods in density-functional theory that are helpful to address some important problems in the application of the local-density approximation within Kohn-Sham DFT to the analysis of ground-states and dynamical properties of electronic systems.

Excited States Of Chromophores And Vibronic Interactions, Benjamin T. Nebgen

Open Access Dissertations

The main focus of my Ph.D. work has been on building a vibronic coupling model for multichromophores and extending that model to more general systems. This Dissertation serves as both a summary of this work as well as a manual for the two vibronic coupling programs I have written. It is my hope that the instructions written here are complete enough for any who would like to replicate my work on vibronic coupling on other systems. ^ Additionally, I have also worked on a few purely computational projects not directly related to the vibronic coupling work. The status of these …

Soil Quality And Nitrogen Cycling Dynamics Altered By Fertility Amendments In Intensively Managed Vegetable Production Systems, Matt A. Rudisill

Open Access Dissertations

Fresh market vegetable production in the Midwest U.S. is growing rapidly as a result of increased demand for locally-sourced food. High tunnels are becoming increasingly popular among Midwest vegetable growers as these structures offer many production benefits including season extension. However, vegetables require substantial fertility inputs, particularly nitrogen (N), in order to meet desired levels of productivity, and some fertility management strategies can negatively impact soil and environmental quality. This can be particularly problematic in high tunnels, where longer production periods and modification of the growing environment put these systems at greater risk for soil degradation. Identification of fertility practices …

Theory Of Topological Insulators And Its Applications, Parijat Sengupta

Open Access Dissertations

An important pursuit in semiconductor physics is to discover new materials to sustain the continuous progress and improvements in the current electronic devices. Traditionally, three material types are in use: 1) Metals 2) Semiconductors 3) Insulators. All the three material types are classified according to the energy gap between conduction and valence bands derived from band theory of solids. Recent theoretical predictions and confirmed by experimental observations have provided evidence that there exists materials which behave as insulators in the bulk but possess gapless conducting states on the surface. These new class of materials are called topological insulators (TI). In …

Relation Among Images: Modelling, Optimization And Applications, Bin Shen

Open Access Dissertations

In the last two decades, the increasing popularity of information technology has led to a dramatic increase in the amount of visual data. Many applications are developed by processing, analyzing and understanding such increasing data; and modelling the relation among images is fundamental to success of many of them. Examples include image classification, content-based image retrieval and face recognition. Given signatures of images, there are many ways to depict the relation among them, such as pairwise distance, kernel function and factor analysis. However, existing methods are still insufficient as they suffer from many real factors such as misalignment of images …

Scaling Finite Difference Methods In Large Eddy Simulation Of Jet Engine Noise To The Petascale: Numerical Methods And Their Efficient And Automated Implementation, Yingchong Situ

Open Access Dissertations

Reduction of jet engine noise has recently become a new arena of competition between aircraft manufacturers. As a relatively new field of research in computational fluid dynamics (CFD), computational aeroacoustics (CAA) prediction of jet engine noise based on large eddy simulation (LES) is a robust and accurate tool that complements the existing theoretical and experimental approaches. In order to satisfy the stringent requirements of CAA on numerical accuracy, finite difference methods in LES-based jet engine noise prediction rely on the implicitly formulated compact spatial partial differentiation and spatial filtering schemes, a crucial component of which is an embedded solver for …

Evaluation Of Yttrium-90 Positron Emission Tomography Dosimetry, Katherine N. Tapp

Open Access Dissertations

Purpose: Radioembolization is a novel treatment which utilizes the liver's unique dual system blood supply to trap yttrium-90 (⁹⁰Y) microspheres in microvasculature near liver tumors. Radioembolization dose planning and dosimetry are based on crude, inaccurate assumptions due to the lack of knowledge of patient specific ⁹⁰Y microsphere distribution. In recent years, the very small 3.1867e-5 internal pair production decay branch of ⁹⁰Y has been shown to allow for positron emission tomography (PET) imaging following radioembolization. This work explores the accuracy and limitation of ⁹⁰Y PET imaging due to the extremely low signal to noise (SNR) …

Optical Spectroscopy And Langmuir Probe Diagnostics Of Microwave Plasma In Synthesis Of Graphene-Based Nanomaterials, Alfredo D. Tuesta

Open Access Dissertations

Along with the revolutionary discovery and development of carbon nanostructures, such as carbon nanotubes and graphitic sheets, has arrived the potential for their application in the fields of medicine, bioscience and engineering due to their exceptional structural, thermal and electrical properties. As roll-to-roll plasma deposition systems begin to provide means for large scale production of these nanodevices, a detailed understanding of the environment responsible for their synthesis is imperative in order to more accurately design and control the growth of carbon nanodevices. To date, the understanding of the chemistry and kinetics that govern the synthesis of carbon nanodevices is only …

Algebraic Level Sets For Cad/Cae Integration And Moving Boundary Problems, Kritika Upreti

Open Access Dissertations

Boundary representation (B-rep) of CAD models obtained from solid modeling kernels are commonly used in design, and analysis applications outside the CAD systems. Boolean operations between interacting B-rep CAD models as well as analysis of such multi-body systems are fundamental operations on B-rep geometries in CAD/CAE applications. However, the boundary representation of B-rep solids is, in general, not a suitable representation for analysis operations which lead to CAD/CAE integration challenges due to the need for conversion from B-rep to volumetric approximations. The major challenges include intermediate mesh generation step, capturing CAD features and associated behavior exactly and recurring point containment …

Structured Deterministic Models Applied To Malaria And Other Endemic Diseases, Katia Patricia Vogt Geisse

Open Access Dissertations

This thesis includes modeling studies on three structured deterministic models. These models are used to study the disease dynamics of malaria or the joint disease dynamics of HIV and HSV-2. Each of the models includes multiple components containing individuals in various epidemiological classes for the purpose of addressing questions that are of interests to biologists and epidemiologists. Some of the compartments have a continuous age-structure, which is necessary for studying the specific biological questions under investigation.^ In Chapter 2 a chronological-age structured deterministic model for malaria is presented. The model includes the human and mosquito populations with the human population …

New Experimental And Theoretical Tools For Studying Protein Systems With Elements Of Structural Disorder, Tairan Yuwen

Open Access Dissertations

Disordered proteins are one class of proteins which do not possess well-folded three-dimensional structures as their native conformations. Many eukaryotic proteins have been found to be fully disordered or contain certain disordered regions. Disordered proteins usually display several characteristic properties, such as increased motional freedom and the conformational heterogeneity caused by that. The elements of structural disorder are commonly involved in many important biological functions and are implicated in many diseases. Therefore, the study of disordered proteins has become one of the most important research topics in recent years. This thesis presents results from three different research projects; the common …

Hydrogen Loading System Development And Evaluation Of Tritiated Substrates To Optimize Performance In Tritium Based Betavoltaics, Thomas E. Adams

Open Access Dissertations

State-of-the-art hydrogen loading system onto thin metallic films based on differential pressure in calibrated chambers has been developed for conditions pressures and temperatures up to 69 bar and 500°C, respectively. Experiments on hydrogen loading on to palladium films of thickness 50 and 250 nm were conducted at pressure ranging from 0.2 bar to 10 bar at temperature 310°C. For first time film hydrogen loading was carried out at 1 bar and at room temperature which temperature. Beta flux exiting surface of metal tritide films has been modeled with MC-SET (Monte Carlo Simulation of Electron Trajectories in solids). Surface beta flux …

The Barriers To Adopting Composting Toilets Into Use In Urban And Suburban Locations In The United States, Julia Branstrator

Open Access Theses

The amount of fresh water available in the world is a finite resource. Large quantities of the fresh water are located in remote locations, while more accessible sources of fresh water are disproportionately distributed around the world. Some populations lack reliable access to clean water for daily life, making the routine use of potable water in toilets of upper-income countries a questionable practice in terms of resource responsibility, energy use, and sustainable infrastructure. The innovative nature of composting toilets offers potential solutions to the downfalls of conventional, waterborne toilets. However, the path to adoption of composting toilets has encountered barriers …

Assessing Positional Accuracy And Correcting Point Data For Digital Soil Mapping At Varying Scales, Minerva J. Dorantes

Open Access Theses

Accuracy, timeliness, and the effect of scale of soil maps are rarely assessed. The recent increase in the use of GIS technologies and modelling software in natural resources and land management, has increased the demand for soil information at a finer resolution worldwide. Most of the world's developing countries rely on soils information at a scale that is too coarse for practical planning, and have obstacles impeding collection of new data, such as civil war and a lack of collection resources. The United States has an exhaustive collection of soils data at a fine scale. However, its location information is …

Vegetation And Soil Characteristics Of Pine Plantations And Naturally Regenerated Hardwood Forests On The Hoosier National Forest, Patrick James Duffy

Open Access Theses

During the 1930s there was widespread erosion on farmland and subsequent land abandonment. As a result, Pinus strobus L. (white pine), P. resinosa Aiton (red pine), and P. echinata Mill. (shortleaf pine) were planted in the Midwest to prevent erosion and rehabilitate sites. These species were selected due to their wide availability at the time. Currently, it is the goal of the U.S. Forest Service to provide a more natural and sustainable landscape, in part by removing these non-native Pinus stands and by replacing them with native hardwood species. The ultimate success of hardwood restoration depends, in part, on the …

High Voltage Rear Electric Drivetrain Design For A Parallelthrough-The-Road Plug-In Hybrid Electric Vehicle, Adam Garrett Fogarty

Open Access Theses

Purdue University was selected as one of 15 universities to participate in a three year Advanced Vehicle Technology Competition (AVTC) called EcoCar2: Plugging Into the Future. The vehicle built by the Purdue team was a Parallel-Through-The-Road Plug-in Hybrid Electric Vehicle (PTTR PHEV). The vehicle utilized a B20 diesel powertrain to power the front wheels, as well as a custom electric drivetrain to power the rear wheels. Using this vehicle during the final year of the competition, the team was successful in placing 4th overall as well as 2nd in the category of Well-To-Wheel (WTW) Greenhouse Gas Emissions. A stock 2013 …

Reverse-Phase Liquid Chromatography Of Small Molecules Using Silica Colloidal Crystals, Natalya Khanina

Open Access Theses

Capillaries packed with a silica colloidal crystal (SCC) of 470 nm nonporous particles have recently been shown to offer significant improvements in the peak width, resolution, and speed of protein analysis due to the reduction of the A and C term broadening contributions of the Van Deemter equation. While protein separations using this technology have shown vast improvements, small molecules remain largely unexplored. As the SCC allows for an approximately diffusion limited system, extremely high plate numbers are expected for small molecule separations. The research presented herein studies the feasibility of pressure-driven small molecule separation using SCCs and commercial instrumentation. …

Uncertainty, Irreversibility, And Investment In Secondgeneration Biofuels, Tanner Joseph Mccarty

Open Access Theses

The present study formalizes and quantifies the importance of uncertainty for investment in a corn-stover based cellulosic biofuel plant. Using a real options model we recover prices of gasoline that would trigger entry into the market and calculate the portion of that entry trigger price required to cover cost and the portion that corresponds to risk premium. We then discuss the effect of managerial flexibility on the entry risk premium and the prices of gasoline that would trigger mothballing, reactivation, and exit. Results show that the risk premium required by plants to enter the second-generation biofuel market is likely to …

Propogation Of Wind Turbine Noise Through Wakes And Turbulent Atmosphere, Yuan Peng

Open Access Theses

It is well known that the atmospheric inhomogeneities have great impact on sound propagation over long ranges. For the application of predicting wind turbine noise, either the flow wakes generated by rotating turbine blades or small-scale atmospheric turbulence can affect the propagation of sound over ground surfaces from individual turbines.

In this thesis, the effects of wake and atmospheric turbulence on the propagation of wind turbine noise are investigated. By introducing the Parabolic Equation (PE) method, the effects of atmospheric changes in sound speed can be incorporated at each marching step as the prediction of sound field advances in the …

Identifying Conditions To Optimize Lactic Acid Production From Food Waste, Raymond M. Redcorn

Open Access Theses

There is an increased demand for lactic acid for the production of biopolymers and to aid nutrient removal in wastewater treatment. Food waste offers a source of soluble sugars to produce lactic acid, which does not increase land demand, but digestion conditions have yet to be optimized when co-digested with primary sludge. Food waste was collected from cafeteria waste bins, homogenized and seeded with primary sludge. A Box Behnken Response surface design was used to optimize lactic acid production based on pH, temperature, loading rate, and retention time. Subsequent experiments verified and refined those conditions to optimize for both yield …

Indoor Acoustic Mapping And Geolocation, Thomas Shyy

Open Access Theses

The Global Positioning System (GPS) is widely used in navigations of flights, vehicles and travelers nowadays. However, the signals are not always available and there are some cases where the receptions of the GPS signal can be lost because of the presence of urban canyons, buildings, tunnels and forests. Another down side for the GPS is that indoor positioning can be really difficult because of the greater signal interference from the indoor.

On the other hand, the concept of echolocation has also been used for positioning purposes. Echolocation offers a promising approach to improve the quality of life of people …

Evaluation Of Collapse Indicators For Seismically Vulnerable Reinforced Concrete Buildings, Nicholas R. Skok

Open Access Theses

Older reinforced concrete buildings can be prone to column shear and compression failures during earthquakes because of inadequate transverse reinforcement. Cities in seismic areas still have large inventories of older and potentially deficient buildings. To analyze every building and estimate its vulnerability in detail is costly. A simple method to rank quickly older buildings according to their seismic vulnerability is needed to help engineers prioritize the use of resources for rehabilitating the most vulnerable buildings.

Four indicators of building damage or collapse were evaluated using numerical analysis and prior data from building surveys: column index (Hassan & Sozen, 1997), R …

Integration Of Z-Depth In Compositing, Kayla Steckel

Open Access Theses

It is important for video compositors to be able to complete their jobs quickly and efficiently. One of the tasks they might encounter is to insert assets such as characters into a 3D rendered environment that has depth information embedded into the image sequence. Currently, a plug-in that facilitates this task (Depth Matte®) functions by looking at the depth information of the layer it's applied to and showing or hiding pixels of that layer. In this plug-in, the Z-Depth used is locked to the layer the plug-in is applied. This research focuses on comparing Depth Matte® to a custom-made plug-in …