Physical Sciences and Mathematics Commons^™

Mechanistic Investigations Of The Iron(Iii)-Catalyzed Carbonyl-Olefin Metathesis Reaction, Susan Phan

Master's Theses

Iron(III)-catalyzed carbonyl-olefin ring-closing metathesis represents a new approach toward the assembly of molecules traditionally generated by olefinˆ’olefin metathesis or olefination. Herein, we report detailed synthetic, spectroscopic, kinetic, and computational studies to determine the mechanistic features imparted by iron(III), substrate, and temperature to the catalytic cycle. These data are consistent with an iron(III)-mediated asynchronous, concerted [2+2]-cycloaddition to form an intermediate oxetane as the turnover-limiting step. Fragmentation of the oxetane via Lewis acid-activation results in the formation of five- and six-membered unsaturated carbocycles.

A Study Into The Feasibility Of Using Natural Language Processing And Machine Learning For The Identification Of Alcohol Misuse In Trauma Patients, Andrew Phillips

Master's Theses

Alcohol misuse is a leading cause of premature death in the United States, with nearly a third of trauma patients found to have elevated blood alcohol levels upon admission. However, timely intervention has been shown to reduce this. It is thus important to be able to quickly screen patients to identify alcohol misuse. Many medical centers use standardized questionnaires to identify alcohol misuse, but since these instruments are not usually a part of routine care, there are many cases where it is not done.

In this study, large quantities of notes were processed with natural language processing and machine learning …

Toddler Activity Recognition Using Machine Learning, Pinky Sindhu

Master's Theses

Pinky Sindhu

Loyola University Chicago

TODDLER ACTIVITY RECOGNITION USING MACHINE LEARNING

Toddlers behave differently than adults, to say the least. It is valuable to accurately measure the specific types of physical activity (PA) in toddlers; such information can be analyzed to predict future health prospects in relation to conditions like obesity.

We attached ActiGraph accelerometers to the wrist and waist of toddlers and recorded PAs. Toddlers were videotaped, and their movements were annotated as 20 specific activities. These activities were classified into 3 summary activity intensities including sedentary, light intensity PA (LPA), and moderate to vigorous intensity PA (MVPA).

Automated …