Physical Sciences and Mathematics Commons^™

Triple Bottom Line As A Method To Increase Business Value And Foster Positive Social And Environmental Change, Jayleene West

Master's Theses

The Triple Bottom Line (TBL) business model has transformed the business world by changing the way businesses operate. By focusing on the people and the environment, businesses have grown to see substantial profit and avoid risks along the way. Companies are using the TBL to build their brand and customer loyalty by enhancing the environment and society. This paper analyzes four companies that are leaders in their industry and are founded on the TBL; Seventh Generation, New Belgium Brewing, Patagonia, and Ben & Jerry’s. Recommendations have been made by performing a literature review on the advantages and disadvantages of the …

Detection And Melting Of Surface-Bound Dna Using A Purely Electrochemical Approach, Denny Ho

Master's Theses

In this thesis, we demonstrate an electrochemical approach for monitoring the electric-field induced melting of surface-bound double-stranded DNA. The electrochemical routine involves repeated chronoamperometry pulses to melt the duplex and square wave voltammetry to monitor the extent of melting. We utilize a scanning potential and constant potential technique to generate melting curves and access the stability and kinetics of the DNA duplexes. Our method uses a mixed monolayer of thiol-modified DNA oligomers and mercaptohexanol on gold electrodes, are subsequently incubated with target DNA covalently modified with electroactive methylene blue. Under room temperature, 10 mM Tris, and optimized electrochemical parameters, DNA …

The Investigation Of The Chlorine Initiated Oxidation Of 2-Phenylethanol And Stability Of Superalkali Lithium Substituted Silyls., Adam Otten

Master's Theses

This thesis investigates the combustion potential of 2-phenylethanol and the superalkali properties of small lithium substituted silicon compounds. All combustion experiments were performed at the Advanced Light Source of Lawrence Berkeley National Laboratory at the Chemical Dynamics Beamline 9.0.2. The chlorine initiated oxidation of 2PE was investigated at 298 and 550 K using a multiplex photoionization mass spectrometer, coupled with the tunable vacuum ultraviolet radiation. Reaction products were identified using kinetic time traces and photoionization spectra.

Additionally, the stability of small superalkali silicon-lithium compounds has also been investigated. All structures and energetics were calculated using the CBS-QB3 composite method.

The …

Electropolymerization Of Polyaniline In The Presence Of Ferricyanide: Electrochemical, Spectroscopic And Gravimetric Studies, Lucas Marinelli

Master's Theses

In this work, ferricyanide-doped polyaniline (PANI) is electropolymerized by constant current and cyclic voltammetry (CV) measurements with simultaneous monitoring of mass changes using electrochemical quartz crystal microbalance (eQCM). Raman spectroscopy, Fourier transform infrared spectroscopy and CV measurements confirm the incorporation of the ferricyanide into the film and indicate modified electrical conductivity. UV-Vis absorbance spectroscopy and Raman spectroscopy confirm the conducting ‘emeraldine-salt’ state and confirm the presence of polarons, i.e. charge carriers.

The addition of ferricyanide during electropolymerization of the PANI film results in an increase of polymerization rate as confirmed using eQCM. A decrease in counter ion ingress/egress and an …

Potential Impacts Of The Purple Salt Marsh Crab, Sesarma Reticulatum, On Long Island Sound Salt Marshes, Jaymie Frederick

Master's Theses

Salt marshes are important, highly productive ecosystems that provide many ecological benefits, including shoreline protection. Salt marshes were long believed to be driven by bottom up forces, however, recent research has suggested that top down influences may impact the foundation species Spartina alterniflora, and consequently marsh structure. This study looked at patterns of Spartina alterniflora dieback along creek bank areas and assessed Sesarma reticulatum abundance spatially throughout the marsh to improve understanding as to whether Sesarma may be influencing the dieback phenomenon. Dieback was occurring in all three salt marshes studied, at two of those marsh sites the rate of …

Influence Of Natural And Anthropogenic Environmental Variability On Larval Fish Diet, Growth, And Condition In The Northcentral Gulf Of Mexico, Angie Hoover

Master's Theses

The northern Gulf of Mexico experiences high levels of freshwater runoff annually from various sources including the Mississippi River and Mobile Bay, among other sources. Early life history stages of fishes are especially vulnerable to environmental variability created by freshwater discharge. The objectives of this study were to describe the available prey field, diet, growth and condition of larval fishes with respect to various effects of freshwater discharge in the northern Gulf. The first chapter compared these parameters in larval Gulf Menhaden (Brevoortia patronus) collected from three different water masses characterized by physical and biological parameters after the …

Late Quaternary Evolution And Stratigraphic Framework Influence On Coastal Systems Along The North-Central Gulf Of Mexico, Usa, Robert Hollis

Master's Theses

Coastal systems in the Gulf of Mexico are threatened to reduced sediment supply, storm impacts and relative sea level rise (RSLR). The geologic record can provide insights of geomorphic threshold crossings (formation, progradation, transgression, destruction) to these forcing mechanisms to predict future barrier evolution to climate change. The stratigraphic framework and antecedent topography directly influence coastal evolution over geologic timescales. This study synthesizes ~2100km of geophysical data, 700+ sediment cores, and 63 radiocarbon dates to regionally map two sequence boundaries, multiple ravinement surfaces and fourteen depositional facies. One marine isotope stage (MIS) 6 valley’s fill provided up to 300 x10 …

Holocene Formation And Evolution Of Horn Island, Mississippi, Usa, Nina Gal

Master's Theses

Horn Island, one of the most stable barriers along the Mississippi-Alabama chain, provides critical habitat, helps regulate estuarine conditions in the Mississippi Sound, and reduces wave energy and storm surge for the mainland. This study integrates 2,200 km of high-resolution geophysics, 35 sediment cores, and 15 radiocarbon ages to better understand the formation and evolution of the island in response to sea-level rise, storms, and antecedent geology. The Biloxi and Pascagoula incised valleys converge at Horn Island and have played a profound role in the evolution of the system. Within the incised valleys, numerous shallow paleochannels between 4 and 9 …

Influence Of High Aspect Ratio Nanoparticle Filler Addition On Piezoelectric Nanocomposites, Jeremy A. Armas

Master's Theses

Piezoelectric nanogenerators (PNGs) are a new class of energy harvesting materials that show potential as a direct energy source for low powered electronics. Recently, piezoelectric polymers have been utilized for PNG technology due to low toxicity, high flexibility, and facile solution processing which provide manufacturing opportunities such as screen printing. Throughout the last decade, countless projects have focused on how to enhance the energy harvesting capabilities of these PNGs through the incorporation of nanoparticle fillers, which have been reported to enhance the piezoelectric properties of the film either directly through their intrinsic piezoelectric properties or through acting as surfaces for …

Cleaver: Classification Of Everyday Activities Via Ensemble Recognizers, Samantha Hsu

Master's Theses

Physical activity can have immediate and long-term benefits on health and reduce the risk for chronic diseases. Valid measures of physical activity are needed in order to improve our understanding of the exact relationship between physical activity and health. Activity monitors have become a standard for measuring physical activity; accelerometers in particular are widely used in research and consumer products because they are objective, inexpensive, and practical. Previous studies have experimented with different monitor placements and classification methods. However, the majority of these methods were developed using data collected in controlled, laboratory-based settings, which is not reliably representative of real …

Improving Ultra-Wideband Localization By Detecting Radio Misclassification, Cory A. Mayer

Master's Theses

The Global Positioning System (GPS) and other satellite-based positioning systems are often a key component in applications requiring localization. However, accurate positioning in areas with poor GPS coverage, such as inside buildings and in dense cities, is in increasing demand for many modern applications. Fortunately, recent developments in ultra-wideband (UWB) radio technology have enabled precise positioning in places where it was not previously possible by utilizing multipath-resistant wide band pulses.

Although ultra-wideband signals are less prone to multipath interference, it is still a bottleneck as increasingly ambitious projects continue to demand higher precision. Some UWB radios include on-board detection of …

Coastal Wetland Dynamics Under Sea-Level Rise And Wetland Restoration In The Northern Gulf Of Mexico Using Bayesian Multilevel Models And A Web Tool, Tyler Hardy

Master's Theses

There is currently a lack of modeling framework to predict how relative sea-level rise (SLR), combined with restoration activities, affects landscapes of coastal wetlands with uncertainties accounted for at the entire northern Gulf of Mexico (NGOM). I developed such a modeling framework – Bayesian multi-level models to study the spatial pattern of wetland loss in the NGOM, driven by relative RSLR, vegetation productivity, tidal range, coastal slope, and wave height – all interacting with river-borne sediment availability, indicated by hydrological regimes. These interactions have not been comprehensively investigated before. I further modified this model to assess the efficacy of restoration …

Sequence Stratigraphy Of Campanian-Maastrichtian Strata In Eastern Alabama, David Simmons

Master's Theses

Eastern Alabama is an area of interest due to the transition from the Gulf Coastal Plain to the Atlantic Coastal Plain. Coastal Plain investigations have been sparse compared to research conducted in the oil rich areas down dip in the Gulf of Mexico. A sequence stratigraphic framework using the T-R cycle methodology of Embry (2002) has been established by integrating surface and subsurface lithologic data with biostratigraphic zonations into Petra ®. High sedimentation from the ancestral Chattahoochee River and lower relative sea-level formed an additional depositional sequence within the Santonian-Campanian aged Blufftown Formation in eastern Alabama. The sequence is approximately …

A System For Conducting Laser-Induced Fluorescence Measurements On Gas Mixtures Exposed To Alpha Radiation, Patrick Ables

Master's Theses

This paper documents modifications to an existing vacuum system to allow laser-induced fluorescence spectroscopy measurements within simulated atmospheres under a variety of conditions. This added capability will expand the laboratory’s ability to experimentally validate a computational model that calculates the effects of radiation within the atmosphere. The computational model could reveal radiation-induced chemical products that can be used to develop an alternative detection method that can be implemented from a safe distance. The selection of molecules for experimental validation has been limited to those which can be detected utilizing cavity ringdown spectroscopy. The current model indicates nitric oxide and ozone …

Quantifying The Environmental Performance Of A Stream Habitat Improvement Project, Cody Morse

Master's Theses

River restoration projects are being installed worldwide to rehabilitate degraded river habitat. Many of these projects focus on stream habitat improvement (SHI), and an estimated 60%of the 37,000 projects listed in the National River Restoration Science Synthesis Program focus on SHI for salmon and trout species. These projects frequently lack a sufficient monitoring program or account for the environmental costs associated with SHI. The present study used life cycle assessment (LCA) techniques and topographic effectiveness monitoring to quantify environmental costs on the basis of geomorphic change. This methodology was a novel approach to assessing the cost-benefit relationship of SHI. To …

Hydrologic Response To Conifer Removal And Upslope Harvest In An Encroached Montane Meadow, Noël C. Fie

Master's Theses

Meadows are crucial components to larger river watersheds because of their unique hydrologic and ecological functions. Due to climate change, over grazing, and fire suppression, conifer encroachment into meadows has accelerated. In some western regions, nearly half of all meadow habitat has been loss due to conifer encroachment. Restoration of these hydrologic systems requires tree removal. Many studies exist that address the issue of conifer encroachment in montane meadows, however, few studies focus on the role that conifer removal plays on the encroaching meadow. Furthermore, few studies exist that document the hydrologic change from conifer removal and further restoration steps, …

Topographic Maps: Image Processing And Path-Finding, Calin Washington

Master's Theses

Topographic maps are an invaluable tool for planning routes through unfamiliar terrain. However, accurately planning routes on topographic maps is a time- consuming and error-prone task. One factor is the difficulty of interpreting the map itself, which requires prior knowledge and practice. Another factor is the difficulty of making choices between possible routes that have different trade-offs between length and the terrain they traverse.

To alleviate these difficulties, this thesis presents a system to automate the process of finding routes on scanned images of topographic maps. The system allows users to select any two points on a topographic map and …

Compiler Optimization Effects On Register Collisions, Jonathan S. Tan

Master's Theses

We often want a compiler to generate executable code that runs as fast as possible. One consideration toward this goal is to keep values in fast registers to limit the number of slower memory accesses that occur. When there are not enough physical registers available for use, values are ``spilled'' to the runtime stack. The need for spills is discovered during register allocation wherein values in use are mapped to physical registers. One factor in the efficacy of register allocation is the number of values in use at one time (register collisions). Register collision is affected by compiler optimizations that …

Funqual: User-Defined, Statically-Checked Call Graph Constraints In C++, Andrew P. Nelson

Master's Theses

Static analysis tools can aid programmers by reporting potential programming mistakes prior to the execution of a program. Funqual is a static analysis tool that reads C++17 code ``in the wild'' and checks that the function call graph follows a set of rules which can be defined by the user. This sort of analysis can help the programmer to avoid errors such as accidentally calling blocking functions in time-sensitive contexts or accidentally allocating memory in heap-sensitive environments. To accomplish this, we create a type system whereby functions can be given user-defined type qualifiers and where users can define their own …

An Empirical Study Of Alias Analysis Techniques, Andrew T. Tran

Master's Theses

As software projects become larger and more complex, software optimization at that scale is only feasible through automated means. One such component of software optimization is alias analysis, which attempts to determine which variables in a program refer to the same area in memory, and is used to relocate instructions to improve performance without interfering with program execution. Several alias analyses have been proposed over the past few decades, with varying degrees of precision and time and space complexity, but few studies have been conducted to compare these techniques with one another, nor to measure with program data to confirm …

Tessellated Voxelization For Global Illumination Using Voxel Cone Tracing, Sam Thomas Freed

Master's Theses

Modeling believable lighting is a crucial component of computer graphics applications, including games and modeling programs. Physically accurate lighting is complex and is not currently feasible to compute in real-time situations. Therefore, much research is focused on investigating efficient ways to approximate light behavior within these real-time constraints.

In this thesis, we implement a general purpose algorithm for real-time applications to approximate indirect lighting. Based on voxel cone tracing, we use a filtered representation of a scene to efficiently sample ambient light at each point in the scene. We present an approach to scene voxelization using hardware tessellation and compare …

Bird Abundance At Bird Feeders In Response To Temperature, Wind Speed And Precipitation During The Winter Season, Siddhant Kahal

Master's Theses

The goal of this project is to explore how 23 different bird species respond to 3 climatic attributes. These attributes are lower than average temperatures, wind speed and precipitation level. Information about the bird species and all of the data associated with them is provided by Project FeederWatch (PFW). This is a citizen based survey study that provides key information about bird species abundance through the use of backyard and community feeders. The study volunteers from across the United States and Canada monitor these bird feeders and note important information about the species such as the number of individuals seen. …

Acceleration Of Jaccard's Index Algorithm For Training To Tag Damage On Post-Earthquake Images, Kyle John Mulligan

Master's Theses

There are currently different efforts to use Supervised Neural Networks (NN) to automatically label damages on images of above ground infrastructure (buildings made of concrete) taken after an earthquake. The goal of the supervised NN is to classify raw input data according to the patterns learned from an input training set. This input training data set is usually supplied by experts in the field, and in the case of this project, structural engineers carefully and mostly manually label these images for different types of damage. The level of expertise of the professionals labeling the training set varies widely, and some …

Preparation Of Supramolecular Amphiphilic Cyclodextrin Bilayer Vesicles For Pharmaceutical Applications, Kate E. Frischkorn

Master's Theses

Recent pharmaceutical developments have investigated using supramolecular nanoparticles in order to increase the bioavailability and solubility of drugs delivered in various methods. Modification of the carbohydrate cyclodextrin increases the ability to encapsulate hydrophobic pharmaceutical molecules by forming a carrier with a hydrophobic core and hydrophilic exterior. Guest molecules are commonly added to these inclusion complexes in order to add stability and further increase targeting abilities of the carriers. One such guest molecule is adamantine combined with a poly(ethylene glycol) chain. Vesicles are formed by hydrating a thin film of amphiphilic cyclodextrin and guest molecules in buffer solution that mimics physiological …

Analyzing Global Cyber Attack Correlates Through An Open Database, Brady Benjamin Aiello

Master's Theses

As humanity becomes more reliant on digital storage and communication for every aspect of life, cyber attacks pose a growing threat. However, cyber attacks are generally understood as individual incidents reported in technological circles, sometimes tied to a particular vulnerability. They are not generally understood through the macroscopic lens of statistical analysis spanning years over several countries and sectors, leaving researchers largely ignorant of the larger trends and correlates between attacks. This is large part due to the lack of a coherent and open database of prominent attacks. Most data about cyber attacks has been captured using a repository of …

Real-Time Object Removal In Augmented Reality, Tyler Dahl

Master's Theses

Diminished reality, as a sub-topic of augmented reality where digital information is overlaid on an environment, is the perceived removal of an object from an environment. Previous approaches to diminished reality used digital replacement techniques, inpainting, and multi-view homographies. However, few used a virtual representation of the real environment, limiting their domains to planar environments.

This thesis provides a framework to achieve real-time diminished reality on an augmented reality headset. Using state-of-the-art hardware, we combine a virtual representation of the real environment with inpainting to remove existing objects from complex environments.

Our work is found to be competitive with previous …

Influencing Exploration In Actor-Critic Reinforcement Learning Algorithms, Andrew R. Gough

Master's Theses

Reinforcement Learning (RL) is a subset of machine learning primarily concerned with goal-directed learning and optimal decision making. RL agents learn based on a reward signal discovered from trial and error in complex, uncertain environments with the goal of maximizing positive reward signals. RL approaches need to scale up as they are applied to more complex environments with extremely large state spaces. Inefficient exploration methods cannot sufficiently explore complex environments in a reasonable amount of time, and optimal policies will be unrealized resulting in RL agents failing to solve an environment.

This thesis proposes a novel variant of the Actor-Advantage …

Jupyterlab_Voyager: A Data Visualization Enhancement In Jupyterlab, Ji Zhang

Master's Theses

With the emergence of big data, scientific data analysis and visualization (DAV) tools are critical components of the data science software ecosystem; the usability of these tools is becoming extremely important to facilitate next-generation scientific discoveries. JupyterLab has been considered as one of the best polyglot, web-based, open-source data science tools. As the next phase of extensible interface for the classic iPython Notebooks, this tool supports interactive data science and scientific computing across multiple programming languages with great performances. Despite these advantages, previous heuristics evaluation studies have shown that JupyterLab has some significant flaws in the data visualization side. The …

Field Investigation Of Stream-Aquifer Interactions: A Case Study In Coastal California, Devin Pritchard-Peterson

Master's Theses

This study is a detailed investigation of the dynamic interaction between a stream and an alluvial aquifer at Swanton Pacific Ranch in the Scotts Creek watershed in Santa Cruz County, California. The aquifer is an important source of groundwater for cropland irrigation and for aquatic ecosystem support. The potential for groundwater pumping to deplete Scotts Creek stream flows is a source of serious concern for land managers, fisheries biologists, and regulatory agencies due to the presence of federally protected steelhead trout (Oncorhynchus mykiss) and coho salmon (Oncorhynchus kisutch). An understanding of the interaction between the stream and pumped aquifer will …

Investigation On The Dissociative Photoionization Mechanism Of Furfural, Investigation Of The Absolute Photoionization Cross Sections Of Three Potential Propargylic Fuels, And Ab Initio Analysis On Potential Superbases Of Several Hyperlithiated Species: Li3f2o And Li3f2(Oh)N (N = 1, 2, 3), Matthew Winfough

Master's Theses

This thesis presents the study photoionization cross sections of three different propargylic biofuels; dipropargyl ether, propargyl alcohol, and propargylamine, in chlorine radical-initiated combustion experiments at the Chemical Dynamics Beamline (9.0.2) at the Advanced Light Source of the Ernest Orlando Berkeley National Laboratory in Berkeley, California. Additionally, the unimolecular dissociative photoionization mechanism of furfural was studied using photoelectron photoionization coincidence (PEPICO) spectroscopy at the vacuum ultraviolet beamline at the Swiss Light Source of the Paul Scherrer Institut in Villigen, Switzerland. Dissociation products and mechanisms for furfural were identified over a photon energy range of 10.9 to 14.5 eV. Lastly, a study …