Physical Sciences and Mathematics Commons^™

Investigating The Effect Of Electrolyte Concentration And Charging Protocol On Materials Utilization In Rechargeable Zinc Manganese Dioxide Batteries, Snehal H. Kolhekar

Dissertations and Theses

Achieving a highly cyclable, high energy density battery with MnO₂ cathodes encounters many obstacles. Chief among these is the inability of the widely-used γ-MnO₂ polymorph to retain its structural integrity when cycled to near full one-electron discharge capacity, which is about 280mAh/g for commercially available electrolytic manganese dioxide (EMD). In this one-electron range, discharge occurs by proton insertion producing Mn⁺³ which then reverts to γ-MnO₂ on charging. In the first part of the thesis, we investigate the root cause of failure of MnO₂ cathodes under deep cycling in the one-electron discharge range and establish a …

A New Mathematical Theory For The Dynamics Of Large Tumor Populations, A Potential Mechanism For Cancer Dormancy & Recurrence And Experimental Observation Of Melanoma Progression In Zebrafish, Adeyinka A. Lesi

Dissertations and Theses

Cancer, a family of over a hundred disease varieties, results in 600,000 deaths in the U.S. alone. Yet, improvements in imaging technology to detect disease earlier, pharmaceutical developments to shrink or eliminate tumors, and modeling of biological interactions to guide treatment have prevented millions of deaths. Cancer patients with initially similar disease can experience vastly different outcomes, including sustained recovery, refractory disease or, remarkably, recurrence years after apparently successful treatment. The current understanding of such recurrences is that they depend on the random occurrence of critical mutations. Clearly, these biological changes appear to be sufficient for recurrence, but are they …

Understanding The Effect Of Climate And Hydrometeorological Extremes On Natural And Human-Induced Hydrosystems, Jeongwoo Hwang

Dissertations and Theses

The contemporary hydrosystems of the United States involve a complex combination of natural and modified basins in the presence of changing climate and anthropogenic impacts. An enhanced understanding of the interdependence between climate forcings, human-induced interventions, and water balance in both natural and modified basins are essential for developing reliable and resilient hydrosystems and for better water resources management. In response, this dissertation focuses on investigating the hydroclimatology of natural and modified basins across the contiguous United States. It has three research objectives: (1) to explain flow alterations due to anthropogenic activities, especially dam operations, in modified basins and understand …

On The Improvements Of Boundary-Layer Representation For High Resolution Weather Forecasting In Costal-Urban Environments, David Melecio-Vazquez

Dissertations and Theses

As large urban centers around the world become more densely populated, the global conversion from natural to man-made land surfaces will only increase. These land-use changes affect the urban surface energy budget which in turn changes the structure of the planetary boundary layer (PBL) above. With current high-performance computing systems, meteorological and built environment information can be better utilized to quantify the anthropogenic effects of these modifications. Although these systems have improved forecasting near-surface weather conditions, a comprehensive approach to represent urban impacts on the PBL is still limited. Improved PBL representation can lead to better weather and climate forecasts, …

Adsorption Kinetics And Phase Behavior Of Particles Adsorbed At An Interface, Shaghayegh Darjani

Dissertations and Theses

The ability to predict the adsorption dynamic, phase behavior, and surface pressure of a monolayer of adsorbed particles in two-dimensional systems are key aspects of many current research areas. Examples include phase transitions in amphiphilic monolayers, emulsion stability due to particle adsorption at interfaces, and melting at an interface.

In this thesis, a new approach for deriving the equation of state for a two-dimensional lattice gas is proposed, based on arguments similar to those used in the derivation of the Langmuir-Szyszkowski equation of state for localized adsorption. This work aims to predict the adsorption kinetics and phase behavior of a …

Distributed Cross-Community Collaboration For The Cloud-Based Energy Management Service, Yu-Wen Chen, J. Morris Chang

Publications and Research

Customers’ participation is a critical factor for inte-grating the distributed energy resources via demand response and demand-side management programs, especially when customers become prosumers. Incentives need to be delivered by the energy management service to attract prosumers to operate their distributed energy resources and electricity loads grid-friendly actively. The cloud-based energy management service enables virtual trading for customers within the same community to minimize cost and smooth the fluctuation. With the potential fast-growing number of service providers and customers, the needs exist for efficiently collaborating across multiple service providers and customers. This paper proposes the distributed cross-community collaboration (XCC) for …

Fabrication Of Magnetocaloric La(Fe,Si)13 Thick Films, N H. Dung, N B. Doan, P De Rango, L Ranno, Karl G. Sandeman, N M. Dempsey

Publications and Research

La(Fe,Si)₁₃–based compounds are considered to be very promising magnetocaloric materials for magnetic refrigeration applications. Many studies have focused on this material family but only in bulk form. In this paper we report on the fabrication of thick films of La(Fe,Si)₁₃, both with and without post-hydriding. These films exhibit magnetic and structural properties comparable to bulk materials. We also observe that the ferromagnetic phase transition has a negative thermal hysteresis, a phenomenon not previously found in this material but which may have its origins in the availability of a strain energy reservoir, as in the cases of …

Optically Pumped Spin Polarization As A Probe Of Many-Body Thermalization, Daniela Pagliero, Pablo R. Zangara, Jacob Henshaw, Ashok Ajoy, Rodolfo H. Acosta, Jeffrey A. Reimer, Alexander Pines, Carlos A. Meriles

Publications and Research

Disorder and many body interactions are known to impact transport and thermalization in competing ways, with the dominance of one or the other giving rise to fundamentally different dynamical phases. Here we investigate the spin diffusion dynamics of ¹³C in diamond, which we dynamically polarize at room temperature via optical spin pumping of engineered color centers. We focus on low-abundance, strongly hyperfine-coupled nuclei, whose role in the polarization transport we expose through the integrated impact of variable radio-frequency excitation on the observable bulk ¹³C magnetic resonance signal. Unexpectedly, we find good thermal contact throughout the nuclear spin bath, …

Fibration Symmetries Uncover The Building Blocks Of Biological Networks, Flaviano Morone, Ian Leifer, Hernán A. Makse

Publications and Research

A major ambition of systems science is to uncover the building blocks of any biological network to decipher how cellular function emerges from their interactions. Here, we introduce a graph representation of the information flow in these networks as a set of input trees, one for each node, which contains all pathways along which information can be transmitted in the network. In this representation, we find remarkable symmetries in the input trees that deconstruct the network into functional building blocks called fibers. Nodes in a fiber have isomorphic input trees and thus process equivalent dynamics and synchronize their activity. Each …

Microfluidic Study Of The Electrocoalescence Of Aqueous Droplets In Crude Oil, Thomas Leary, Mohsen Yeganeh, Charles Maldarelli

Publications and Research

In electrocoalescence, an electric field is applied to a dispersion of conducting water droplets in a poorly conducting oil to force the droplets to merge in the direction of the field. Electrocoalescence is used in petroleum refining to separate water from crude oil and in droplet-based microfluidics to combine droplets of water in oil and to break emulsions. Using a microfluidic design to generate a two-dimensional (2D) emulsion, we demonstrate that electrocoalescence in an opaque crude oil can be visualized with optical microscopy and studied on an individual droplet basis in a chamber whose height is small enough to make …

Syllabus Ee330 Electromagnetics, Nicholas Madamopoulos

Open Educational Resources

Concepts covered in the undergraduate electrical engineering class of electromagnetics

Proceedings Of The Cuny Games Conference 6.0, Robert O. Duncan, Joseph Bisz, Christina Boyle, Kathleen Offenholley, Maura A. Smale, Carolyn Stallard, Deborah Sturm

Publications and Research

The CUNY Games Network is an organization dedicated to encouraging research, scholarship and teaching in the developing field of games-based learning. We connect educators from every campus and discipline at CUNY and beyond who are interested in digital and non-digital games, simulations, and other forms of interactive teaching and inquiry-based learning. These proceedings summarize the CUNY Games Conference 6.0, where scholars shared research findings at a three-day event to promote and discuss game-based pedagogy in higher education. Presenters could share findings in oral presentations, posters, demos, or play testing sessions. The conference also included workshops on how to modify existing …

Ii-Vi Type-Ii Quantum Dot Superlattices For Novel Applications, Vasilios Deligiannakis

Dissertations, Theses, and Capstone Projects

In this thesis, we discuss the growth procedure and the characterization results obtained for epitaxially grown submonolayer type-II quantum dot superlattices made of II-VI semiconductors. We have investigated the spin dynamics of ZnSe layers with embedded type-II ZnTe quantum dots and the use of (Zn)CdTe/ZnCdSe QDs for intermediate band solar cell (IBSC). Samples with a higher quantum dot density exhibit longer electron spin lifetimes, up to ~1 ns at low temperatures. Tellurium isoelectronic centers, which form in the ZnSe spacer regions as a result of the growth conditions, were also probed. A new growth sequence for type-II (Zn)CdTe/ZnCdSe (QDs) was …

Effect Of Direct-Current Magnetic Field On The Specific Absorption Rate Of Metamagnetic Comnsi: A Potential Approach To Switchable Hyperthermia Therapy, K C. Ugochukwu, M M. Sadiq, E S. Biegel, L Meagher, M R. Hill, Karl G. Sandeman, A Haydon, K Suzuki

Publications and Research

Materials with 1st order antiferromagnetic (AFM) to high-magnetization (MM) phase transition known for their inverse magnetocaloric effect, abrupt rise in magnetization and magnetoelastic coupling, are promising for application in combined simultaneous diagnosis and targeted cancer therapy. A therapy that combines alternating-current (ac) and direct-current (dc) magnetic fields for simultaneous magnetic hyperthermia therapy (MHT) and magnetic resonance imaging (MRI), using same magnetic particles for heating and as con- trast agents. We report a proof-of-concept study on the induction heating ability of 1st order metamagnetic material with moderate specific absorption rates (SAR) and no tendency for agglomeration, for potential MHT and MRI …

Adapting To Extreme Heat: Social, Atmospheric, And Infrastructure Impacts Of Air Conditioning In Megacities - The Case Of New York City, Harold Gamarro

Dissertations and Theses

Extreme heat events are becoming more frequent and intense in most large cities. Built-up surfaces also limit cooling mechanisms, leading to warmer conditions in cities, a phenomenon called the Urban Heat Island (UHI). This presents major challenges to reduce adverse health effects of hot weather, particularly in vulnerable populations like the elderly and low-income communities. Here we explore the overall impacts of increasing air conditioning (AC) system adoption in residences as an adaptive measure to reduce human health risks under heat waves, with New York City (NYC) as a case study. This study uses AC adoption data from the 2017 …

Macro - And Microstructure Evaluation And Field Applications Of Concrete With Recycled Glass Pozzolan, Marija Krstic

Dissertations and Theses

Concrete is the most used material in the world, second only to water. Conventional concrete is produced with Portland cement (PC). The production of cement is an energy intensive operation that has raised significant environmental concerns, since one ton of cement generates an equal ton of CO₂. In the USA about 90 million tons of cement are used annually, with 3 million tons used in New York. Most contemporary concrete applications for buildings and infrastructure use high-performance concrete (HPC) mixtures which are produced by replacing a percentage of cement with supplementary cementitious materials (SCMs), consisting mainly of fly-ash …

Lake Volume Data Analyses: A Deep Look Into The Shrinking And Expansion Patterns Of Lakes Azuei And Enriquillo, Hispaniola, Mahrokh Moknatian, Michael Piasecki

Publications and Research

This paper presents the development of an evenly spaced volume time series for Lakes Azuei and Enriquillo both located on the Caribbean island of Hispaniola. The time series is derived from an unevenly spaced Landsat imagery data set which is then exposed to several imputation methods to construct the gap filled uniformly‐spaced time series so it can be subjected to statistical analyses methods. The volume time series features both gradual and sudden changes the latter of which is attributed to North Atlantic cyclone activity. Relevant cyclone activity is defined as an event passing within 80 km and having regional monthly …

Toward Closing The Urban Surface Energy Balance Using Satellite Remote Sensing, Joshua Hrisko

Dissertations and Theses

The energy exchanges at the Earth’s surface are responsible for many of the processes that govern weather, climate, human health, and energy use. This exchange, commonly known as the surface energy balance (SEB), determines the near-surface thermodynamic state by partitioning the available energy into surface fluxes. The net all-wave radiation is often the primary energy source, while the heat storage and sensible and latent heat fluxes account for the majority of energy distributed elsewhere. While the SEB of various natural environments(trees, crops, soils) has been well-observed and modeled, the urban surface energy balance remains elusive. This is due to the …

V-Slam And Sensor Fusion For Ground Robots, Ejup Hoxha

Dissertations and Theses

In underground, underwater and indoor environments, a robot has to rely solely on its on-board sensors to sense and understand its surroundings. This is the main reason why SLAM gained the popularity it has today. In recent years, we have seen excellent improvement on accuracy of localization using cameras and combinations of different sensors, especially camera-IMU (VIO) fusion. Incorporating more sensors leads to improvement of accuracy,but also robustness of SLAM. However, while testing SLAM in our ground robots, we have seen a decrease in performance quality when using the same algorithms on flying vehicles.We have an additional sensor for ground …

Technological Challenges And Innovations In Cybersecurity And Networking Technology Program, Syed R. Zaidi, Ajaz Sana, Aparicio Carranza

Publications and Research

This era is posing a unique challenge to the Cybersecurity and related Engineering Technology areas, stimulated by the multifaceted technological boom expressed in accelerated globalization, digital transformation, the cloud, mobile access apps, and the Internet of Things (IoT)—where more and more devices are connected to the Internet every day. As the use of new Internet-based technologies increase; so does the risk of theft and misuse of sensitive information. This demands the awareness of cyber-criminality and the need for cyber hygiene in corporations, small businesses, and the government. As the need for experienced cybersecurity specialists has skyrocketed in recent years and …

Land Surface Temperature Variability Across India: A Remote Sensing Satellite Perspective, Satya Prakash, Hamidreza Norouzi

Publications and Research

Land surface temperature (LST) plays a key role in the surface energy budget computation and land surface process studies. The Moderate Resolution Imaging Spectroradiometer (MODIS) sensors onboard the Aqua and Terra satellites provide comprehensive global LST estimates at a fine spatial resolution. The MODIS products were recently upgraded to Collection 6, and shown to be more accurate than its predecessor Collection 5 products. In this study, LST and its variability have been examined across India from Collection 6 of the Aqua MODIS data at 0.05° spatial resolution for the period of 2003 to 2017. All-India mean LST characteristics show distinctive …

Minimalistic Peptide-Based Supramolecular Systems Relevant To The Chemical Origin Of Life, Daniela Kroiss

Dissertations, Theses, and Capstone Projects

All forms of life are based on biopolymers, which are made up of a selection of simple building blocks, such as amino acids, nucleotides, fatty acids and sugars. Their individual properties govern their interactions, giving rise to complex supramolecular structures with highly specialized functionality, including ligand recognition, catalysis and compartmentalization. In this thesis, we aim to answer the question whether short peptides could have acted as precursors of modern proteins during prebiotic evolution. Using a combination of experimental and computational techniques, we screened a large molecular search space for peptide sequences that are capable of forming supramolecular complexes with adenosine …

The Water/Energy Nexus: Climate, Consumption And Ecosystem Services, Hildegaard D. Link

Dissertations, Theses, and Capstone Projects

Water and energy are drivers of living systems. This work provides an assessment of the Water Energy Nexus in the United States, comparing the well-watered north-east and the arid west. Electric grid systems are most stressed on hot summer afternoons. Grid stress can lead to cascading failures of electricity, water and wastewater treatment systems. (Zimmerman, 2017) Water for power generation and/or water supply depend on ecosystem services. The ecosystem services and resource trade-offs embedded in provision of a watt of power and an ounce of potable water, however, have yet to be comprehensively enumerated nor have the cost relationships been …

An Optimized Encoding Algorithm For Systematic Polar Codes, Xiumin Wang, Zhihong Zhang, Jun Li, Yu Wang, Haiyan Cao, Zhengquan Li, Liang Shan

Publications and Research

Many different encoding algorithms for systematic polar codes (SPC) have been introduced since SPC was proposed in 2011. However, the number of the computing units of exclusive OR (XOR) has not been optimized yet. According to an iterative property of the generator matrix and particular lower triangular structure of the matrix, we propose an optimized encoding algorithm (OEA) of SPC that can reduce the number of XOR computing units compared with existing non-recursive algorithms. We also prove that this property of the generator matrix could extend to different code lengths and rates of the polar codes. Through the matrix segmentation …

Development Of Digital Bathymetry Maps For Lakes Azuei And Enriquillo Using Sonar And Remote Sensing Techniques, Michael Piasecki, Mahrokh Moknatian, Fred Moshary, Jorge Gonzalez

Publications and Research

This article presents an improved algorithm for optimization and development of a digital bathymetric model (DBM) for Lake Azuei (LA) (Haiti) and Lake Enriquillo (LE) (Dominican Republic) using the ANUDEM method. Both sonar data and contour lines of the lakes’ layout extracted using Landsat imagery were compiled for bathymetry development. We show that the performance of the ANUDEM method was strongly dependent on the density and irregularity of the spatial distribution of the data. Changing the resolution of the output grids and deriving auxiliary topographically corrected contours improved the ANUDEM performance and minimized the systematic errors of the method. Statistical …

Synthesis And Characterization Of Dielectric And Multiferroic Nanocrystalline Transition Metal Oxide Materials And Nanocomposites, Frederick A. Pearsall

Dissertations, Theses, and Capstone Projects

Nanocrystalline transition metal oxides with unique chemical, physical, magnetic and dielectric properties have very broad applications, ranging from photocatalysis, capacitor energy storage and 4-state memory. Frequency stable, high permittivity nanocomposite capacitors produced under mild processing conditions offer an attractive replacement to MLCCs derived from conventional ceramic firing. In one project reported herein, 0-3 nanocomposites were prepared using BaTiO₃ (barium titanate, BTO) nanocrystals, suspended in a poly(furfuryl alcohol) matrix, resulting in a stable, high effective permittivity, low and stable loss dielectric. Effective medium approximations were used to compare this with similar nanocomposite systems. The use of synthesized BTO nanocrystal photocatalysts …

Ligand Selectivity In The Recognition Of Protoberberine Alkaloids By Hybrid-2 Human Telomeric G-Quadruplex: Binding Free Energy Calculation, Fluorescence Binding, And Nmr Experiments, Nanjie Deng, Junchao Xia, Lauren Wickstrom, Clement Lin, Kaibo Wang, Peng He, Yunting Yin, Danzhou Yang

Publications and Research

The human telomeric G-quadruplex (G4) is an attractive target for developing anticancer drugs. Natural products protoberberine alkaloids are known to bind human telomeric G4 and inhibit telomerase. Among several structurally similar protoberberine alkaloids, epiberberine (EPI) shows the greatest specificity in recognizing the human telomeric G4 over duplex DNA and other G4s. Recently, NMR study revealed that EPI recognizes specifically the hybrid-2 form human telomeric G4 by inducing large rearrangements in the 50-flanking segment and loop regions to form a highly extensive four-layered binding pocket. Using the NMR structure of the EPI-human telomeric G4 complex, here we perform molecular dynamics free …

Proceedings Of The Cuny Games Conference 5.0, Robert O. Duncan, Joe Bisz, Julie Cassidy, Kathleen Offenholley, Carolyn Stallard, Deborah Sturm, Anders A. Wallace

Publications and Research

The CUNY Games Network is an organization dedicated to encouraging research, scholarship and teaching in the developing field of games-based learning. We connect educators from every campus and discipline at CUNY and beyond who are interested in digital and non-digital games, simulations, and other forms of interactive teaching and inquiry-based learning. The CUNY Games Conference distills its best cutting-edge interactive presentations into a two-day event to promote and discuss game-based pedagogies in higher education, focusing particularly on non-digital learning activities that faculty can use in the classroom every day. The conference will include workshops lead by CUNY Games Organizers on …

Rubik's Cube: A Visual And Tactile Learning Of Algorithms And Patterns, Lawrence Muller

Open Educational Resources

This is a classroom activity report on teaching algorithms as part of a second course in computer programming. Teaching an algorithm in an introductory level programming class is often a dry task for the instructor and the rewards for the student are abstract. To make the learning of algorithms and software more rewarding, this assignment employs a Rubik’s cube.

Observational Time Series For Lakes Azuei And Enriquillo: Surface Area, Volume, And Elevation, Mahrokh Moknatian, Michael Piasecki

Publications and Research

In this report, we present historical time series of surface area, volume, and elevation for lakes Azuei (Haiti) and Enriquillo (Dominican Republic). The intention is to present a history of the lakes’ levels for both bodies of water as derived from Landsat imagery that is augmented by reports and narratives that reach further back in time. We also summarize lake level time series data collected and developed through various other efforts and compare these data sets to our time series. The time series contains 45 years’ worth of data ranging from 1972 to 2017 which we developed from Landsat imagery …