Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
- Keyword
- Publication
- Publication Type
Articles 1 - 3 of 3
Full-Text Articles in Physical Sciences and Mathematics
Very High Pressure Effects Upon The Epr Spectrum Of Ruby, H. Mark Nelson, D. B. Larson, J. H. Gardner
Very High Pressure Effects Upon The Epr Spectrum Of Ruby, H. Mark Nelson, D. B. Larson, J. H. Gardner
Faculty Publications
The variation in the electron paramagnetic resonance (EPR) spectrum of ruby as a function of pressure has been observed to beyond 70 kbar for a magnetic field orientation parallel to the crystalline c axis. The data can be interpreted in terms of the usual spin Hamiltonian, where the spectroscopic splitting factor g|| has the same value as at ambient pressures, but where the zero-field splitting deltaincreases in a linear fashion from 0.38 to 0.43 cm. The experimental apparatus has been described previously, although important improvements in the pressure seal and in the pressure calibration have been made and are described …
Thermodynamics Of Metal-Ligand Interactions In Solution I. The Thermodynamics Of Metal-Cyanide Interaction ; Ii. Application Of The Entropy Titration Technique To Metal-Ligand Systems ; Iii. Log K, [Delta]H And [Delta]S Values For The Interaction Of Sulfate Ion With Metal Ions ; Iv. Interaction Of Mercuric Cyanide With Thiourea In Water-Ethanol Solvent Mixtures, Delbert J. Eatough
Theses and Dissertations
Log K values, valid at zero ionic strength are reported for the interaction in aqueous solution of CN- with Ni2+ and Hg2+ at 10°, 25° and 40°C, and with Pd2+ at 25°C. ∆H° and ∆S° values valid at zero ionic strength and 25°C are also reported for the interaction of CN- with Hg2+ and for the reaction Pd(CN)42- + CN- = Pd(CN)53-. In connection with the study of Pd2+ - CN- interaction, log K values for the hydrolysis of Pd2+ to give PqOH+ and Pd(OH)2 and an E° value for the reaction Pd(s) = Pd2+ + 2e- are reported. A …
Secondary Reactions And Partial Rate Factors In The Sulfonation Of Chlorobenzene And Toluene, Ernest Arthur Brown
Secondary Reactions And Partial Rate Factors In The Sulfonation Of Chlorobenzene And Toluene, Ernest Arthur Brown
Theses and Dissertations
The sulfonation of chlorobenzene, chlorobenzene-benzene, and toluene-benzene mixtures by sulfur trioxide in liquid sulfur dioxide at -12.5° C. was studied to obtain isomer distribution and relative rate data. The isomer distribution for the reaction on chlorobenzene was determined by an isotope dillution technique. Relative rate experiments were conducted by sulfonating C14 labeled benzene in competition with nonradioactive chlorobenzene and toluene and the count rate of the products was used to determine product composition. Ultraviolet spectrophotometry was also used to investigate variations in isomer distributions as a function of sulfur trioxide concentration. The apparent relative rates of sulfonation (kX/kB) as calculated …