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High pressure

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Articles 31 - 42 of 42

Full-Text Articles in Physical Sciences and Mathematics

Optical Cell For Combinatorial In Situ Raman Spectroscopic Measurements Of Hydrogen Storage Materials At High Pressures And Temperatures, Jason R. Hattrick-Simpers, Wilbur S. Hurst, Sesha S. Srinivasan, James E. Maslar Jan 2011

Optical Cell For Combinatorial In Situ Raman Spectroscopic Measurements Of Hydrogen Storage Materials At High Pressures And Temperatures, Jason R. Hattrick-Simpers, Wilbur S. Hurst, Sesha S. Srinivasan, James E. Maslar

Faculty Publications

An optical cell is described for high-throughput backscattering Raman spectroscopic measurements of hydrogen storagematerials at pressures up to 10 MPa and temperatures up to 823 K. High throughput is obtained by employing a 60 mm diameter × 9 mm thick sapphire window, with a corresponding 50 mm diameter unobstructed optical aperture. To reproducibly seal this relatively large window to the cell body at elevated temperatures and pressures, a gold o-ring is employed. The sample holder-to-window distance is adjustable, making this cell design compatible with optical measurement systems incorporating lenses of significantly different focal lengths, e.g., microscope objectives and single element …

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Variations In Winter Surface High Pressure In The Northern Hemisphere And Climatological Impacts Of Diminishing Arctic Sea Ice, Kristen D. Fox May 2010

Variations In Winter Surface High Pressure In The Northern Hemisphere And Climatological Impacts Of Diminishing Arctic Sea Ice, Kristen D. Fox

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

This study explores the role Arctic sea ice plays in determining mean sea level pressure and 1000 hPa temperatures during Northern Hemisphere winters while focusing on an extended period of October to March. This is accomplished by investigating two regions of the same size and comparable climatic zones and elevations in the Northern Hemisphere. A breakdown of 29 years of reanalysis data into average monthly values, anomalies, trends, and comparisons between regions serves as current data to compare with a computer model control run. Ensuring the control run accurately models current atmospheric patterns, altering the model inputs to have no …

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High Pressure Phase Transistions In The Lanthanide Sesquioxides, Jason Patrick Mcclure Jan 2009

High Pressure Phase Transistions In The Lanthanide Sesquioxides, Jason Patrick Mcclure

UNLV Theses, Dissertations, Professional Papers, and Capstones

Crystallizing into 5 known polymorphic forms, the rare-Earth sesquioxides RE 2 O 3 represent a family of 4-f electron compounds that have been the subject of study for many years. Aspects of the systematics in the structural phase transitions for RE 2 O 3 (RE=La, Sm, Eu, Gd, Y, Er, Yb, Lu) under pressure were studied using diamond anvil cells (DACs). As a part of this study, detailed equation of state (EOS) data for all these compounds were obtained through the use of angle-dispersive x-ray diffraction (XRD) where anomalies in compression data led to the detailed investigation into one particular …

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Static High Pressure Ft-Ir Spectroscopic Studies Of Tatb, Brian F. Yulga Jan 2009

Static High Pressure Ft-Ir Spectroscopic Studies Of Tatb, Brian F. Yulga

UNLV Theses, Dissertations, Professional Papers, and Capstones

Static high-pressure experiments utilizing diamond anvil cells (DACs) provide an alternative method to shockwave studies for extracting precise information on the physical and chemical properties of energetic materials. Due to mechanical restraints (e.g. small sample sizes and apertures), synchrotron radiation sources are ideal for probing the structure of materials at the molecular level. 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) is an insensitive (tertiary) high explosive (iHE) useful in military applications. Compared to other conventional iHEs, it is a safer and more stable energetic material. Its unique properties cause it to be of interest in the energetic materials research community. A series of Fourier-transform infrared …

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In Situ Element Quantification In The Hydrothermal Diamond Anvil Cell Using Synchrotron X-Ray Fluorescence With Applications Toward Subduction Zone Processes, Steven Joseph Maglio Jan 2009

In Situ Element Quantification In The Hydrothermal Diamond Anvil Cell Using Synchrotron X-Ray Fluorescence With Applications Toward Subduction Zone Processes, Steven Joseph Maglio

UNLV Theses, Dissertations, Professional Papers, and Capstones

Yttrium is used in geochemical investigations of arc volcanics and metamorphic geothermometers. The ability to use Y as a geochemical tool is predicated on an understanding of the mobility of Y during fluid-saturated conditions attending metamorphic and igneous processes. The goal of this work was to use the hydrothermal diamond anvil cell (HDAC) and synchrotron radiation X-ray fluorescence to quantify, in situ, the concentration of Y in aqueous fluids at 2-5 GPa and 650 - 800 °C; conditions likely at the oceanic lithosphere - mantle wedge interface in subduction zones. Previous studies have used modified diamond anvils which limits their …

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High Pressure Effects On Electron Transport And Structure Of Colossal Magnetoresistive Materials, Congwu Cui May 2003

High Pressure Effects On Electron Transport And Structure Of Colossal Magnetoresistive Materials, Congwu Cui

Dissertations

Pressure effects on the electronic, magnetic properties and structure of several typical colossal magnetoresistive manganites, La0.60Y0.07Ca0.33MnO3, Pr1-xCaxMn03 (X = 0.25, 0.30, 0.35), Nd1-xSrxMnO3 (x = 0.45, 0.50), were explored through high pressure resistivity and structure measurements. It was shown that pressure up to ~7 GPa induces more complicated charge, spin and lattice state changes than in the low pressure range explored previously. In La0.60Y0.07Ca0.33MnO3, pressure induces a local atomic structure transformation at a critical …

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H2o–D2o Condensation In A Supersonic Nozzle, Christopher H. Heath, Kiril A. Streletzky, Barbara E. Wyslouzil, Judith Woelk, Reinhard Strey Oct 2002

H2o–D2o Condensation In A Supersonic Nozzle, Christopher H. Heath, Kiril A. Streletzky, Barbara E. Wyslouzil, Judith Woelk, Reinhard Strey

Physics Faculty Publications

We examined the condensation of H2O, D2O, and four intermediate mixtures (20, 40, 60, and 80 mol % D2O) in a supersonic nozzle. Because the physical and chemical properties of protonated and deuterated water are so similar, this system is ideal for studying the change in condensation behavior as a function of condensible composition. In our experiments dilute mixtures of condensible vapor in N2 are expanded from three different stagnation temperatures resulting in a broad range of onset temperatures (190–238 K) and pressures (27–787 kPa). For a fixed stagnation temperature, the partial pressure required to maintain the onset of condensation …

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System For Electron Paramagnetic Resonance Measurements At High Pressure And Low Temperature, Ke Huang, Daniel L. Decker, H. Mark Nelson, J. Dean Barnett Oct 1997

System For Electron Paramagnetic Resonance Measurements At High Pressure And Low Temperature, Ke Huang, Daniel L. Decker, H. Mark Nelson, J. Dean Barnett

Faculty Publications

Major improvements have been made on the sensitive high pressure electron paramagnetic resonance (EPR) system developed previously in 1978 at this laboratory. These changes allow low temperature measurements and provide a more stable signal. The high pressure EPR cell is placed inside a vacuum chamber to provide thermal isolation, so that the system may be cooled by a closed cycle refrigerator to temperatures between 45 and 60 K, depending on the energy input to the modulation coil. The combination of high pressure and low temperature greatly expands the thermodynamic range over which EPR measurements can be made. An improved and …

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Surface Conductance Of A Copper Wire In A Fluid At High Pressure, Daniel L. Decker Jul 1987

Surface Conductance Of A Copper Wire In A Fluid At High Pressure, Daniel L. Decker

Faculty Publications

The three-dimensional flow of heat in a wire carrying a current and immersed in a liquid is solved in detail. Using this exact result the surface conductance of copper in petroleum ether has been measured as a function of pressure to 40 kbars. The measured surface conductance for copper in a fluid is very small, justifying approximations which yield results that are in agreement with a simplified one-dimensional heat-flow problem. Surprisingly, even at 40 kbars pressure a very large fraction of the joule heating within a wire with a length-to-diameter ratio of ~100 is dissipated through the ends of the …

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Proposed Thermodynamic Pressure Scale For An Absolute High-Pressure Calibration, Daniel L. Decker, J. Dean Barnett Feb 1970

Proposed Thermodynamic Pressure Scale For An Absolute High-Pressure Calibration, Daniel L. Decker, J. Dean Barnett

Faculty Publications

The field of high pressure has developed rapidly over the past few years to a point where relatively sophisticated experiments are being attempted. In many experiments it is no longer sufficient to qualitatively estimate the pressure or to base conclusions on experimental results tied to an empirical pressure parameter. One desires to accurately know the pressure dependence of physical quantities related to a true thermodynamic scale.

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Very High Pressure Effects Upon The Epr Spectrum Of Ruby, H. Mark Nelson, D. B. Larson, J. H. Gardner Sep 1967

Very High Pressure Effects Upon The Epr Spectrum Of Ruby, H. Mark Nelson, D. B. Larson, J. H. Gardner

Faculty Publications

The variation in the electron paramagnetic resonance (EPR) spectrum of ruby as a function of pressure has been observed to beyond 70 kbar for a magnetic field orientation parallel to the crystalline c axis. The data can be interpreted in terms of the usual spin Hamiltonian, where the spectroscopic splitting factor g|| has the same value as at ambient pressures, but where the zero-field splitting deltaincreases in a linear fashion from 0.38 to 0.43 cm. The experimental apparatus has been described previously, although important improvements in the pressure seal and in the pressure calibration have been made and are described …

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High Pressure Emergency Gates For Echo Dam, U.S. Department Of The Interior, Bureau Of Reclamation Jan 1923

High Pressure Emergency Gates For Echo Dam, U.S. Department Of The Interior, Bureau Of Reclamation

All U.S. Government Documents (Utah Regional Depository)

Invitations for bids, schedule, specifications and drawings of high pressure emergency gates for Echo Dam.

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