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2002

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Articles 151 - 180 of 3395

Full-Text Articles in Physical Sciences and Mathematics

New Statitstical Methods For The Estimation Of The Mean And Standard Deviation From Normally Distributed Censored Samples, Abou El-Makarim Abd El-Alim Aboueissa Dec 2002

New Statitstical Methods For The Estimation Of The Mean And Standard Deviation From Normally Distributed Censored Samples, Abou El-Makarim Abd El-Alim Aboueissa

Dissertations

The main objective of this dissertation is to estimate the mean /x and standard deviation cr of a normal population from left-censored samples. We have developed new methods for calculating estimates for the mean and standard deviation of a normal population from left-censored samples. Some of these methods based on traditional estimating procedures. A new method of obtaining the Cohen maximum likelihood estimates for fx and cr without the aid of an auxiliary table will be introduced. This new method will be used to extend Cohen table of estimating the Cohen A-parameter that is required for calculating the maximum likelihood …


Coordinated Target Assignment And Intercept For Unmanned Air Vehicles, Erik P. Anderson, Randal W. Beard, Michael A. Goodrich, Timothy W. Mclain Dec 2002

Coordinated Target Assignment And Intercept For Unmanned Air Vehicles, Erik P. Anderson, Randal W. Beard, Michael A. Goodrich, Timothy W. Mclain

Faculty Publications

This paper presents an end-to-end solution to the cooperative control problem represented by the scenario where unmanned air vehicles (UAVs) are assigned to transition through known target locations in the presence of dynamic threats. The problem is decomposed into the subproblems of: 1) cooperative target assignment; 2) coordinated UAV intercept; 3) path planning; 4) feasible trajectory generation; and 5) asymptotic trajectory following. The design technique is based on a hierarchical approach to coordinated control. Simulation results are presented to demonstrate the effectiveness of the approach.


Investigation Of The Corrosion Of Steel By Lead-Bismuth Eutectic (Lbe) Using Scanning Electron Microscopy And X-Ray Photoelectron Spectroscopy, Daniel Koury Dec 2002

Investigation Of The Corrosion Of Steel By Lead-Bismuth Eutectic (Lbe) Using Scanning Electron Microscopy And X-Ray Photoelectron Spectroscopy, Daniel Koury

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lead Bismuth Eutectic (LBE) has been proposed for use in programs for accelerator transmutation of waste. LBE is the leading candidate material as a spallation target and an option for the sub-critical blanket coolant. The corrosion of 316 and 316L stainless steels by LBE has been studied using UNLV's facilities for Scanning Electron Microscopy (SEM) and X-ray Photoelectron Spectroscopy (XPS). We have compared exposed and unexposed samples and studied the differences. Some amount of surface contamination is present on the samples and has been removed by ionbeam etching. The unexposed samples reveal typical stainless steel characteristics: a chromium oxide passivation …


2p Or Not 2p:The 14o(Α,2p) 16o Reaction Rate And Its Implications On Nova And X-Ray Burst Nucleosynthesis, Luc L. Dessieux, Jr. Dec 2002

2p Or Not 2p:The 14o(Α,2p) 16o Reaction Rate And Its Implications On Nova And X-Ray Burst Nucleosynthesis, Luc L. Dessieux, Jr.

Masters Theses

During explosive hydrogen burning, the catalytic CNO cycle suffers depletion by additional thermonuclear capture reactions on the members of the cycle. This "break out" from the β-limited CNO cycle has been suggested to occur in novae and X-ray bursts for temperatures greater than 0.4 GK [3,26,28]. At these temperatures α captures can occur on the CNO waiting point isotopes through the nuclear reactions

14O(α,p) 17F, 15O(α,γ) 19Ne, and 18Ne(α,γ) 21Na [3]. An additional reaction, 14O(α,2p)16O has been suggested as a possible break out path from the CNO cycle [49]. To investigate …


Crab Louse Infestation In Pre-Columbian America, F. M. Rick, G. C. Rocha, K. Dittmar, C. E. A. Coimbra Jr., Karl J. Reinhard, F. Bouchet, L. F. Ferreira, A. Araújo Dec 2002

Crab Louse Infestation In Pre-Columbian America, F. M. Rick, G. C. Rocha, K. Dittmar, C. E. A. Coimbra Jr., Karl J. Reinhard, F. Bouchet, L. F. Ferreira, A. Araújo

School of Natural Resources: Faculty Publications

Until now, Pthirus pubis infestation in ancient human populations had only been recorded in the Old World. We found crab lice on South American mummified bodies from the Atacama Desert region. Crab louse eggs were found attached to the pubic hairs of a 2,000-yr-old Chilean mummy. Well-preserved adults were found in sediment and clothing from a Peruvian mummy dated 1,000 yr ago. Paleoparasitological evidence expands the knowledge of the distribution of this ectoparasite in ancient populations. As with many other parasites, pubic lice recorded in Andean populations show the antiquity of this parasite in the New World. It is likely …


Multi-Scale Visualization Of Remote Sensing And Topographic Data Of The Amazon Rain Forest, Luciano E. Fonseca, F P. Miranda, C Beisl, J Souza-Fonseca Dec 2002

Multi-Scale Visualization Of Remote Sensing And Topographic Data Of The Amazon Rain Forest, Luciano E. Fonseca, F P. Miranda, C Beisl, J Souza-Fonseca

Center for Coastal and Ocean Mapping

PETROBRAS (the Brazilian national oil company) built a pipeline to transport crude oil from the Urucu River region to a terminal in the vicinities of Coari, a city located in the right margin of the Solimoes River. The oil is then shipped by tankers to another terminal in Manaus, capital city of the Amazonas state. At the city of Coari, changes in water level between dry and wet seasons reach up to 14 meters. This strong seasonal character of the Amazonian climate gives rise to four distinct scenarios in the annual hydrological cycle: low water, high water, receding water, and …


Arctic Ocean Physiography, Martin Jakobsson, Arthur Grantz, Yngue Kristoffersen, Ron Macnab Dec 2002

Arctic Ocean Physiography, Martin Jakobsson, Arthur Grantz, Yngue Kristoffersen, Ron Macnab

Center for Coastal and Ocean Mapping

The first order physiographic provinces of the Arctic Ocean has been defined using the recently updated International Bathymetric Chart of the Arctic Ocean (IBCAO) grid model as the main database and a semi-quantitative approach. The first step in our classification of physiographic provinces is an evaluation of seafloor gradients contained in a slope model that was derived from the IBCAO grid. The slope information reveals certain seafloor process-related features, which add to the bathymetric information. Using interactive 3D-visualization, the slope and bathymetric information were simultaneously analyzed and certain slope intervals of the Arctic Ocean seafloor were found to generally characterize …


Seafloor Characterization From Spatial Variation Of Multibeam Backscatter Vs."Best Estimated" Grazing Angle, Tianhang Hou, Larry A. Mayer, Christian De Moustier, Barbara J. Kraft Dec 2002

Seafloor Characterization From Spatial Variation Of Multibeam Backscatter Vs."Best Estimated" Grazing Angle, Tianhang Hou, Larry A. Mayer, Christian De Moustier, Barbara J. Kraft

Center for Coastal and Ocean Mapping

Backscatter vs. grazing angle, which can be extracted from multibeam backscatter data, depends on characteristics of the multibeam system and the angular responses of backscatter that are characteristic of different seafloor properties, such as sediment hardness and roughness. Changes in backscatter vs. grazing angle that are contributed by the multibeam system normally remain fixed over both space and time. Therefore, they can readily be determined and removed from backscatter data. The component of backscatter vs. grazing angle due to the properties of sediments varies from location to location, as the sediment changes. The sediment component of variability can be inferred …


An Integrated Bathymetric And Topographic Digital Terrain Model Of The Canadian Arctic Archipelago, Goran Alm, Ron Macnab, Martin Jakobsson, Johan Kleman, Mark Mccracken Dec 2002

An Integrated Bathymetric And Topographic Digital Terrain Model Of The Canadian Arctic Archipelago, Goran Alm, Ron Macnab, Martin Jakobsson, Johan Kleman, Mark Mccracken

Center for Coastal and Ocean Mapping

No abstract provided.


Lake Tahoe Bottom Characteristics Extracted From Shoals Lidar Waveform Data And Compared To Backscatter Data From A Multibeam Echo Sounder, G. Elston, James V. Gardner Dec 2002

Lake Tahoe Bottom Characteristics Extracted From Shoals Lidar Waveform Data And Compared To Backscatter Data From A Multibeam Echo Sounder, G. Elston, James V. Gardner

Center for Coastal and Ocean Mapping

The waveforms recorded by airborne lidar bathymetry (ALB) systems are currently processed only for depth information. In addition to bathymetry, multibeam echo sounder (MBES) systems provide backscatter data in which regions of different acoustic properties are distinguishable. These regions can often be correlated to different bottom types. Initial attempts to extract equivalent data from the ALB waveforms have confirmed the expectation that such information is encoded in those waveforms. Water clarity, bathymetry, and bottom type control the detailed shapes of ALB waveforms in different ways. Specific features of a bottom-reflected signal can be identified, for example its rise-time and amplitude, …


Resolving The Ripples (And A Mine): High-Resolution Multibeam Survey Of Martha's Vineyard Onr Mine Burial Program Field Area, Larry A. Mayer, Richard Raymond, Gerd Glang, Lloyd C. Huff Dec 2002

Resolving The Ripples (And A Mine): High-Resolution Multibeam Survey Of Martha's Vineyard Onr Mine Burial Program Field Area, Larry A. Mayer, Richard Raymond, Gerd Glang, Lloyd C. Huff

Center for Coastal and Ocean Mapping

In an effort to better understand the coastal processes responsible for the burial and exposure of small objects on the seafloor, the Office of Naval Research is sponsoring the Mine Burial Program. Among the field areas chosen for this program is the site of the Martha's Vineyard Coastal Observatory (MVCO), a permanent instrumented node in 12 m of water about 500 m off the southern shore of Martha?s Vineyard. In support of the ONR program, several site surveys of the MVCO area have been conducted (see Goff et al); here we report the result of the most recent of these …


Power Scaling Feasibility Of Chromium-Doped Ii-Vi Laser Sources And The Demonstration Of A Chromium-Doped Zinc Selenide Face-Cooled Disk Laser, Jason B. Mckay Dec 2002

Power Scaling Feasibility Of Chromium-Doped Ii-Vi Laser Sources And The Demonstration Of A Chromium-Doped Zinc Selenide Face-Cooled Disk Laser, Jason B. Mckay

Theses and Dissertations

Tunable lasers in the 2-4 µm wavelength range are needed for Air Force sensor applications. Chromium-doped II-VI materials are a promising class of laser material for tunable operation in this wavelength range, but until recently had not produced enough output power to meet application requirements. This dissertation investigates Cr2+:II-VI material properties and potential laser designs, then experimentally demonstrates and analyzes the performance of a Cr2+:ZnSe disk laser design that can produce sufficient output power. Cr2+:II-VI laser materials are found to be susceptible to overheating and thermal lensing, but are otherwise satisfactory laser materials. The …


Neural Supernets: Structuring Artificial Neural Networks According To Cluster Analysis, Simon Lucas Winberg Dec 2002

Neural Supernets: Structuring Artificial Neural Networks According To Cluster Analysis, Simon Lucas Winberg

Masters Theses

A typical feed forward neural network relies solely on its training algorithm, such as backprop or quickprop, to determine suitable weight values for an architecture chosen by the human operator. The architecture itself is typically a fully connected structuring of neurons and synapses where each hidden neuron is connected to every neuron in the next layer. Such architecture does not reflect the structure of the data used to train it. Similarly, in the case where random initial weight values are used, these initial weights are also unlikely to relate to the training set. Thus the job of the training algorithm …


Reaclibalive! (Reaclib Rate Library Interactive Viewer): A Software Package For Graphical Analysis Of Nuclear Reaction Rates For Astrophysics, Eric J. Lingerfelt Dec 2002

Reaclibalive! (Reaclib Rate Library Interactive Viewer): A Software Package For Graphical Analysis Of Nuclear Reaction Rates For Astrophysics, Eric J. Lingerfelt

Masters Theses

Nucleosynthesis occurs in such diverse astrophysical phenomena as ordinary stars, like our own Sun, supernovae, novae, X-ray bursts, and the Big Bang. Large sets of nuclear reaction rates for hundreds of seed isotopes are utilized in simulations of these nucleosynthesis processes. A cross-platform, Java software package called REACLIB aLIVe! has been developed with intuitive graphical interfaces and interactive controls to produce custom one-dimensional plots of reaction rates. The points used for these plots are calculated from exponential fits whose parameters, along with other quantities, make up the REACLIB Nuclear Reaction Rate Library. The software offers nuclear astrophysicists the capability to …


Individual-Based Modeling: Comparing Model Outputs To Telemetry Data With Application To The Florida Panther, Dinesh Raj Sharma Dec 2002

Individual-Based Modeling: Comparing Model Outputs To Telemetry Data With Application To The Florida Panther, Dinesh Raj Sharma

Masters Theses

Mean distance of the locations of an animal from the boundaries of its home range was presented as a measure of its space-use preference. Methods for evaluating the predictive ability of an individual-based model were also presented. These methods were applied to data on the Florida panther and some interesting results were obtained.

A strong negative correlation was observed between age and home range size of the panther, indicating constrained mobility of the panther during its old age. Space-use preference was also highly dependent on age of the panther. A general trend was found for panthers, which indicates they stay …


Applications Of Underground Structures For The Protection Of Critical Infrastructure, George H. Baker, Richard G. Little, Don A. Linger Nov 2002

Applications Of Underground Structures For The Protection Of Critical Infrastructure, George H. Baker, Richard G. Little, Don A. Linger

George H Baker

The U.S. President’s Commission on Critical Infrastructure Protection (PCCIP), convened in the wake of the bombing of the Murrah Federal Building in Oklahoma City, concluded that the nation’s physical security and economic security depend on our critical energy, communications, and computer infrastructures. While a primary motivating event for the establishment of the commission was the catastrophic physical attack of the Murrah Building, it is ironic that the commission focused its attention primarily on cyber threats. Their rationale was that cyber vulnerabilities posed a new, unaddressed challenge to infrastructure security. This approach was further questioned by the events of September 11, …


Supervisory Control And Data Acquisition (Scada) Systems, George H. Baker, Allan Berg Nov 2002

Supervisory Control And Data Acquisition (Scada) Systems, George H. Baker, Allan Berg

George H Baker

Our critical national infrastructure systems have become almost universally dependent upon computer-based control systems technically referred to as supervisory control and data acquisition (SCADA) systems. SCADA systems evolved from the telemetry and event-alarm systems developed in the early days of utilities. With the widespread use of SCADA systems, computers have become the "basis element" for much of our critical infrastructure. Thus, the disruption of controlling computer terminals and networks due to natural disasters, electric power failure, accidents or malicious activity can have catastrophic consequences.


Preparation And Electrochemical Lithium Intercalation Performance Of Different Shaped Carbon Nanotube, Mao-Hui Chen, Zhen-Cai Huang, Guo-Tao Wu, Jin-Kua You, Zu-Geng Lin Nov 2002

Preparation And Electrochemical Lithium Intercalation Performance Of Different Shaped Carbon Nanotube, Mao-Hui Chen, Zhen-Cai Huang, Guo-Tao Wu, Jin-Kua You, Zu-Geng Lin

Journal of Electrochemistry

In the present work, different shaped carbon nanotubes were produced by the general CVD and the template method at different temperature (600 ℃,700 ℃) with the reaction gas of acetylene. The morphology, structure and the electrochemical lithium intercalation performance were comparatively studied and characterized by TEM, HRTEM, SEM, XRD, Raman techniques and Charge/Discharge Test. It was found that the different preparation methods and temperatures all had an obvious effect on these properties of carbon nanotubes. In our samples, with the increase of preparation temperature, the degree of crystallinity decreased, and the reversible specific capacity increased respectively.


Electrocatalytic Oxidation Of Formic Acid On Molybdate-Modified Platinum Electrode, Jun-Hua Du, Xue-Hui Xu, Hong Li, Hong-Yu Cheng, Wei-Shan Li Nov 2002

Electrocatalytic Oxidation Of Formic Acid On Molybdate-Modified Platinum Electrode, Jun-Hua Du, Xue-Hui Xu, Hong Li, Hong-Yu Cheng, Wei-Shan Li

Journal of Electrochemistry

The electrochemical behavior of molybdates on a platinum electrode in H 2SO 4 solutions with different H 2SO 4 concentrations was studied by cyclic voltammetry and double chronoamperometry. Molybdates were reduced to adsorb hydrogen molybdenum bronzes on the platinum electrode in H 2SO 4 solutions during cathodically potential sweep. The hydrogen molybdenum bronzes were oxidized to different forms of hydrogen molybdenum bronzes with less hydrogen, depending on the H 2SO 4 concentration. Platinum electrode was modified by these hydrogen molybdenum bronzes. However, this modified electrode was not stable in H 2SO 4 solutions. The modified electrode was used to study …


Preparation And Performance Of Lifeo_2 Coated Nickel Oxide Cathode For Molten Carbonate Fuel Cells, Chun-Ming Wang, Fei Li, Ke-Ao Hu Nov 2002

Preparation And Performance Of Lifeo_2 Coated Nickel Oxide Cathode For Molten Carbonate Fuel Cells, Chun-Ming Wang, Fei Li, Ke-Ao Hu

Journal of Electrochemistry

A novel cathode for molten carbonate fuel cells was prepared by coating LiFeO 2 over the surface of porous NiO cathode by a simple combustion process. The analytical results of X-ray diffraction (XRD), energy dispersive analysis of X-ray (EDAX), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that the LiFeO 2 coating on the surface of NiO particles consisted of nonometer-sized LiFeO 2 grains and sintered tightly with the NiO particles. The LiFeO 2 coating dramatically reduced the contacting area of NiO with the carbonate melts, thus the solubility of NiO in the carbonate melts was decreased. Meanwhile, …


Theoretical Issues In The Economics Of International Trade And Environment., Meeta Keswani Mehra Dr. Nov 2002

Theoretical Issues In The Economics Of International Trade And Environment., Meeta Keswani Mehra Dr.

Doctoral Theses

In the wake of substantial trade liberalization in the world economy over the last two decades and growing environmental consciousness, the issues of the impacts of international goods trade and foreign direct investment (FDI) on local and global environment are becoming increasingly contentious. Whilst trade and FDI have been said to bring higher incomes and well-being for all, these are seen to act as "magnifiers" of environmental deterioration - especially in the developing countries. On the other hand, growing environmentalism is perceived to act as an impediment to freer trade and investment flows across countries. Hence, the central issues are …


An Investigation On Microstructure And Performance Of The Recasting Perfluorosulfonated Membrane, Feng-Ling Liu, Rong Zeng, Pei-Jin Li, Pin-Qing Wang, Chang-Hong Zhao Nov 2002

An Investigation On Microstructure And Performance Of The Recasting Perfluorosulfonated Membrane, Feng-Ling Liu, Rong Zeng, Pei-Jin Li, Pin-Qing Wang, Chang-Hong Zhao

Journal of Electrochemistry

The microsturcture and performance of the recasting perfluorosulfonated membrane were investigated by comparison with Nafion . The results indicated that although chemical components of the recasting membrane FYM1150 kept the same as Nafion , the dry FYM1150 differed from dry Nafion  membrane in structure, the former possessed some small pores which are not through-holes having a diameter of 50~300 nm while the latter had almost no pores; The mechanical properties of the FYM1150 were better than those of Nafion ; The discharge performance at high current density of MEA using FYM1150 membrane as an electrolyte was also better than …


Properties Of Domestic Natural Graphite Used For Li-Ion Batteries, Cui-Wei Du, Yu-Juan Zhao, Gang Zhang, Yin-Shun Wu, Qing-Guo Liu Nov 2002

Properties Of Domestic Natural Graphite Used For Li-Ion Batteries, Cui-Wei Du, Yu-Juan Zhao, Gang Zhang, Yin-Shun Wu, Qing-Guo Liu

Journal of Electrochemistry

The structure, physical characteristics and electrochemical properties of the natural graphite produced in Shandong province have been studied. The result of X-ray diffraction showed that the graphite consisted of hexagonal structure and rhombic structure (30% rhombic structure). It was fine crystal graphite. Used as a negative material of Lithium ion battery, the natural graphite showed excellent voltage and high energy capacity, but poor compatibility with electrolyte solution containing propylene carbonate (PC) for its own structure limitation.


Effect Of Dissolved Oxygen On The Corrosion Behavior Of Coalesced Copper And Stainless Steel-206 In Acetic Solutions, Rong-Zong Hu, Xiong-Cao Zhao, Yu-Hua Weng, Chang-Jian Lin Nov 2002

Effect Of Dissolved Oxygen On The Corrosion Behavior Of Coalesced Copper And Stainless Steel-206 In Acetic Solutions, Rong-Zong Hu, Xiong-Cao Zhao, Yu-Hua Weng, Chang-Jian Lin

Journal of Electrochemistry

Linear sweeping technique and dissolving oxygen sensor were used to study the effect of dissolved oxygen and relating factors on the corrosion behavior of coalesced copper and stainless steel-206 in acetic solutions. It was found: 1. The existing of dissolved oxygen is one of the important factors, which strongly influenced the corrosion behavior of coalesced copper and stainless steel-206 in acetic solution. 2. The existing of dissolved oxygen is benefitial to the preventing stainless steel-206 from corrosion in acetic solutions, but damage to the preventing coalesced copper from corrosion. 3. At the high temperature since the dissolved oxygen was escaping …


Searches For Excited Fermions In Ep Collisions At Hera, S. Chekanov, M. Derrick, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Yoshida, Margarita C. K. Mattingly, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Levi, A. Margotti, T. Massam, R. Nania, F. Palmonari, A. Pesci, G. Sartorelli Nov 2002

Searches For Excited Fermions In Ep Collisions At Hera, S. Chekanov, M. Derrick, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Yoshida, Margarita C. K. Mattingly, P. Antonioli, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Levi, A. Margotti, T. Massam, R. Nania, F. Palmonari, A. Pesci, G. Sartorelli

Faculty Publications

Searches in ep collisions for heavy excited fermions have been performed with the ZEUS detector at HERA. Excited states of electrons and quarks have been searched for in e+ p collisions at a centre-of-mass energy of 300 GeV using an integrated luminosity of 47.7 pb-1. Excited electrons have been sought via the decays e± → eγ, e± → eZ and e± → vW. Excited quarks have been sought via the decays q± → qγ and q± → qW. A search for excited neutrinos decaying via v± → vγ, v± → vZ and v± → eW is presented using e-p collisions …


Mechanistic Study Of Oxidation Of Hypophosphite On Pt Electrodes By Sniftirs, Tai-Xiang Jiang, Hui-Huang Wu Nov 2002

Mechanistic Study Of Oxidation Of Hypophosphite On Pt Electrodes By Sniftirs, Tai-Xiang Jiang, Hui-Huang Wu

Journal of Electrochemistry

The oxidation of hypophosphite on a polycrystalline platinum electrode was studied by SNIFTIRS and cyclic voltammetry, the in-situ IR spectra were analyzed as a function of Pt electrode potentials in the solution of 0.5 mol/L H 2SO 4+0.1 mol/L NaH 2PO 2. It was found that the dissociative adsorption of hypophosphite ions occurs on Pt surface, and the oxidation product is H 3PO 4, rather than H 2PO 3 - which was considered to produce on Ni electrodes, thereby a new insight into mechanism of hypophosphite oxidation on Pt in acidic media was provided.


Studies On The Inhibition Of Yki-05 Corrosion Inhibitor To 907a Steel In Different Immersed Environments, Hui Yu, Jian-Hua Wu, Hong-Ren Wang, Jian-Hua Qian, Guang-Zhang Chen Nov 2002

Studies On The Inhibition Of Yki-05 Corrosion Inhibitor To 907a Steel In Different Immersed Environments, Hui Yu, Jian-Hua Wu, Hong-Ren Wang, Jian-Hua Qian, Guang-Zhang Chen

Journal of Electrochemistry

The inhibition of YKI-05 Corrosion inhibitor in different conditions was studied using potentiodynamic polarization technique. The resuled shown that (i) the inhibitor film layer was formed stably on the surface of 907A steel electrode when it was persistently immersed in static seawater and the inhibition efficiency reached 90% or so. The inhibition mechanism is negative catalytic effect. (ii)the inhibitior film layer was not stable when the electrode was periodically immersed in seawater and was destroyed more significantly with the increase of electrode exposing time. The film was only a covered layer on the surface of electrode and it retarded both …


Steady State Simulation Of Ysz Intermediate-Temperature Fuel Cell, Zi-Jing Lin, Ye Gu, Xiao-Hua Zhang Nov 2002

Steady State Simulation Of Ysz Intermediate-Temperature Fuel Cell, Zi-Jing Lin, Ye Gu, Xiao-Hua Zhang

Journal of Electrochemistry

With a coupled 2D electrochemical and thermal modeling software, the characteristics of the steady state operation of the intermediate-temperature fuel cell with thin yttria-stabilized zirconia(YSZ) electrolyte was analyzed. The parameters of I-V equation were obtained from fitting the experiment results and the choice of grid points was determined by balancing the accuracy requirement and computational efficiency. The temperature fields at different operation circumstances such as flow designs, material choices for interconnect, were examined. The dependences of the output power and cell efficiency on the operating voltage at different temperatures were studied. Based upon the analysis of the temperature profile, it …


Review Of Mathematical Model For Proton Exchange Membrane Fuel Cell, Shan-Hai Ge, Bao-Lian Yi, Hua-Min Zhang Nov 2002

Review Of Mathematical Model For Proton Exchange Membrane Fuel Cell, Shan-Hai Ge, Bao-Lian Yi, Hua-Min Zhang

Journal of Electrochemistry

In the review with 49 references, the mathematical models for proton exchange membrane fuel cell (PEMFC) were summarized. The mechanistic model and empirical model were introduced. Transfer in the membrane, catalyst layer,diffusion layer and flow field of PEMFC were described. The importance of water and heat management was analyzed. The dimension, complexity and solving methods of the PEMFC model were discussed. The importance and validity to develop a model with time dimension are put forward.


Detection And Analysis Of Sec1 Immunological Reaction By Afm And Electrochemical Method, Sa-Ying Dong, Hong-Ren Wang Nov 2002

Detection And Analysis Of Sec1 Immunological Reaction By Afm And Electrochemical Method, Sa-Ying Dong, Hong-Ren Wang

Journal of Electrochemistry

The goals of this work were to demonstrate the ability of atomic force microscopy (AFM) to detect various immunological processes between antibodies and antigens.A sensor was designed by covalently linking the antibody of staphylococcal enterotoxin Cl (SEC1) on the self-assembled gold surface. This sensor permitted detection of antibody-antigen recognition events which were highly correlated with the topography under different conditions. The statistic data of AFM were analysed. As control experiments, nonspecific antigens and lower concentration SEC1 antigens were directly observed. In addition, an acidic solution was used to break the antigen-antibody pair and made the sensor reuse. Electrochemical evidence was …