Physical Sciences and Mathematics Commons^™

To Hydrate Or Chlorinate: A Regression Analysis Of The Levels Of Chlorine In The Public Water Supply, Drew A. Doyle

HIM 1990-2015

Public water supplies contain disease-causing microorganisms in the water or distribution ducts. In order to kill off these pathogens, a disinfectant, such as chlorine, is added to the water. Chlorine is the most widely used disinfectant in all U.S. water treatment facilities. Chlorine is known to be one of the most powerful disinfectants to restrict harmful pathogens from reaching the consumer. In the interest of obtaining a better understanding of what variables affect the levels of chlorine in the water, this thesis will analyze a particular set of water samples randomly collected from locations in Orange County, Florida. Thirty water …

Understanding The Influence Of Non-Covalent Interactions And Nanoparticle Geometries In Carbon Based Polymer Nanocomposites, Bradley Carroll Miller

Doctoral Dissertations

Low-loading polymer nanocomposites (PNC) are an area of great interest in polymer science. As nanoparticles (NP) are typically expensive in comparison to matrix materials; the low loading regime makes the most efficient use of materials, and represents the optimum for realizing cost effective, high-performance PNCs. However, formulating effective low-loading composites is not without challenges. In addition to the typical requirement of good dispersion for efficient translation of NP properties to the bulk, low-loading composites can sometimes exhibit anomalous (non-classical) dynamics, and unpredictable properties. It is within this context that this thesis aims to examine the effects of NP geometry and …

Rare Earth Production And Characterization Studies, Jake Anson Stewart

Doctoral Dissertations

The rare earths include elements Sc, Y, and La through Lu are important in many modern technologies. With the exception of Sc and Ce the rare earths are all have similar chemical behaviors with the preferred oxidation state in aqueous solution being +3. Currently, industrial purification of the rare earths is completed by counter current solvent extraction (CCSX). In most CCSX separations, Y extracts with Ho making their separation difficult. However, in a few systems Y exhibits an itinerant behavior. Carboxylic acids of varying sizes and substitutions were investigated in a study of Y itinerant behavior. It was found when …

Interface And Morphology Engineering In Solution-Processed Electronic And Optoelectronic Devices, Sanjib Das

Doctoral Dissertations

The first part of this dissertation focuses on interface and morphology engineering in polymer- and small molecule-based organic solar cells. High-performance devices were fabricated, and the device performance was correlated with nanoscale structures using various electrical, spectroscopic and microscopic characterization techniques, providing guidelines for high-efficiency cell design.

The second part focuses on perovskite solar cells (PSCs), an emerging photovoltaic technology with skyrocketing rise in power conversion efficiency (PCE) and currently showing comparable PCEs with those of existing thin film photovoltaic technologies such as CIGS and CdTe. Fabrication of large-area PSCs without compromising reproducibility and device PCE requires formation of dense, …

Solution And Surface Properties Of Architecturally- And Compositionally-Complex Block Copolymers And Their Binary Mixtures, Jesse Lawrence Davis

Doctoral Dissertations

The spontaneous generation of complex structures from polymeric building blocks provides a simple yet effective route to create useful soft matter structures having potential application in a variety of nanotechnologies. The topology, chemical structure, block composition, and sequence of the constituent building blocks of polymers are tunable through synthetic chemistry. This tunability offers attractive opportunities to generate complex, yet well-defined structures with control over the geometry, packing symmetry, and microdomain structure. This thesis work involves the study of the self-assembly behaviors of architecturally complex amphiphilic block copolymers (ABCs). ABCs are composed of two or more chemically distinct blocks that are …

Effective Field Theory Approach To Collective Motion In Atomic Nuclei, Eduardo Antonio Coello Perez

Doctoral Dissertations

Collective motion in heavy nuclei has been studied within collective and algebraic models, and within density functional theory. While they reproduce the energy spectra of these systems, their predictions for some electromagnetic transitions and moments do not lie within experimental uncertainty; in other words, these predictions are inconsistent with experimental data. An effective field theory approach to collective motion in heavy nuclei solves this long standing problem. Based on symmetry arguments only, the effective field theories, constructed as expansions in powers of a small parameter, consistently describe the energy spectra of nuclei exhibiting collective motion at low order in the …

Solar Modulation Of The Cosmic Ray Intensity And The Measurement Of The Cerenkov Reemission In Nova’S Liquid Scintillator, Philip James Mason

Doctoral Dissertations

The NOνA (NuMI Off-axis electron neutrino Appearance) experiment is a long baseline neutrino oscillation experiment at Fermi National Accelerator Laboratory. Its purpose is to observe the oscillation of ν_μ (muon neutrino) to ν_e (electron neutrino) and to investigate the neutrino mass hierarchy and CP violation in the neutrino sector. Two detectors have been built for this purpose, a Near Detector 300 feet underground at Fermilab, and a Far Detector, on the surface at Ash River, Minnesota.

The completion of NOνA’s Far Detector in October 2014 enabled not only the recent measurement of neutrino oscillations, but an array of …

Computational Simulation Of Mass Transport And Energy Transfer In The Microbial Fuel Cell System, Shiqi Ou

Doctoral Dissertations

This doctoral dissertation introduces the research in the computational modeling and simulation for the microbial fuel cell (MFC) system which is a bio-electrochemical system that drives a current by using bacteria and mimicking bacterial interactions found in nature. The numerical methods, research approaches and simulation comparison with the experiments in the microbial fuel cells are described; the analysis and evaluation for the model methods and results that I have achieved are presented in this dissertation.

The development of the renewable energy has been a hot topic, and scientists have been focusing on the microbial fuel cell, which is an environmentally-friendly …

Neuron Clustering For Mitigating Catastrophic Forgetting In Supervised And Reinforcement Learning, Benjamin Frederick Goodrich

Doctoral Dissertations

Neural networks have had many great successes in recent years, particularly with the advent of deep learning and many novel training techniques. One issue that has affected neural networks and prevented them from performing well in more realistic online environments is that of catastrophic forgetting. Catastrophic forgetting affects supervised learning systems when input samples are temporally correlated or are non-stationary. However, most real-world problems are non-stationary in nature, resulting in prolonged periods of time separating inputs drawn from different regions of the input space.

Reinforcement learning represents a worst-case scenario when it comes to precipitating catastrophic forgetting in neural networks. …

Algorithm-Based Fault Tolerance For Two-Sided Dense Matrix Factorizations, Yulu Jia

Doctoral Dissertations

The mean time between failure (MTBF) of large supercomputers is decreasing, and future exascale computers are expected to have a MTBF of around 30 minutes. Therefore, it is urgent to prepare important algorithms for future machines with such a short MTBF. Eigenvalue problems (EVP) and singular value problems (SVP) are common in engineering and scientific research. Solving EVP and SVP numerically involves two-sided matrix factorizations: the Hessenberg reduction, the tridiagonal reduction, and the bidiagonal reduction. These three factorizations are computation intensive, and have long running times. They are prone to suffer from computer failures.

We designed algorithm-based fault tolerant (ABFT) …

Novel Thermoplastic Elastomers Based On Benzofulvene: Synthesis And Mechanical Properties, Weiyu Wang

Doctoral Dissertations

Thermoplastic elastomers (TPEs) are of great importance both academically and technologically. Currently TPEs are the predominated form of styrene-diene copolymers. However, these styrenic TPEs have serious limitations in applications, especially at higher temperature, because of their low upper service temperature (UST). The work described in this dissertation aimed to developing thermoplastic elastomers with a higher UST and lower cost.

In order to develop TPEs with a higher UST, we employed benzofulvene, an anionically polymerizable monomer in hydrocarbon solvent at room temperature, as the glassy block and copolymerized it with isoprene to prepare polybenzofulvene-polyisoprene-polybenzofulvene (FIF) triblock copolymers. Among all triblock copolymers …

All-Acrylic Multigraft Copolymers: Synthesis And Structure-Property Relationship For Producing Next Generation Thermoplastic Elastomers, Andrew Brown Goodwin

Doctoral Dissertations

Polymer architecture and the advancement of molecular design using anionic and other controlled polymerization methods continues to be of significant research interest because of the tunable approach it provides, which can impact numerous applications ranging from thermoplastics to drug delivery systems. Among the numerous branched structures currently investigated, comb and graft copolymers continue to provide tailored materials which exhibit superior mechanical properties when compared to their di- and triblock linear counterparts. More specifically, the incorporation of two or more monomers into graft and multigraft constructions where the side chains are composed of a plastic (high T_g [glass transition temperature]) …

The Effect Of Composition And Architecture On Polymer Behavior In Homopolymer Blends And Inter-Filament Bonding In 3d Printed Models, Edward Roy Duranty

Doctoral Dissertations

This dissertation presents work that increases our understanding of the effects of composition and architecture on copolymer structure and dynamics and how they affect material diffusion between filaments in a 3D printed model. Copolymers are polymer chains made up of at least two different monomers. The ordering and arrangement of the two monomer species within a copolymer can have drastic effects on the behavior and properties of the copolymer.

The first chapter of this dissertation examines how the copolymer composition affects the structure and dynamics of the chain in a homopolymer blend. This study used a modified Monte Carlo BFM …

Batched Linear Algebra Problems On Gpu Accelerators, Tingxing Dong

Doctoral Dissertations

The emergence of multicore and heterogeneous architectures requires many linear algebra algorithms to be redesigned to take advantage of the accelerators, such as GPUs. A particularly challenging class of problems, arising in numerous applications, involves the use of linear algebra operations on many small-sized matrices. The size of these matrices is usually the same, up to a few hundred. The number of them can be thousands, even millions.

Compared to large matrix problems with more data parallel computation that are well suited on GPUs, the challenges of small matrix problems lie in the low computing intensity, the large sequential operation …

Bacterial Diversity And Function Within An Epigenic Cave System And Implications For Other Limestone Cave Systems, Kathleen Merritt Brannen-Donnelly

Doctoral Dissertations

There are approximately 48,000 known cave systems in the United States of America, with caves formed in carbonate karst terrains being the most common. Epigenic systems develop from the downward flow of meteoric water through carbonate bedrock and the solutional enlargement of interconnected subsurface conduits. Despite carbonate karst aquifers being globally extensive and important drinking water sources, microbial diversity and function are poorly understood compared to other Earth environments. After several decades of research, studies have shown that microorganisms in caves affect water quality, rates of carbonate dissolution and precipitation, and ecosystem nutrition through organic matter cycling. However, limited prior …

Battle Bot Ai – Patriot Bot, James Johnston

Computer Engineering

An entry in the the 'Battle Block AI' competition hosted by 'The AI Games'.

Mobilerp, Anthony Fata

Computer Engineering

MobilERP is a system that increases traceability of parts in a manufacturing process in a simple paperless way. The system contains three components, a desktop application, a mobile app, and a database. The mobile application allows employees to scan (using a bar code scanner) parts that they are working/finishing on during the manufacturing process. As the part goes down the assembly line, individuals will barcode scan using the app to track the progress. These changes would get updated to the database, where then the designated person can track the progress of the part as well as any problems or concerns …

Pthreads Profiler, Ryan Van Quinlan

Computer Science and Software Engineering

The goal of this senior project was to design and implement a program which would allow users to profile programs that utilize the Pthreads library. This profiler allows users to measure load balance and lock contention between threads as well as discover deadlocks. These tools can be essential to developers of multi-threaded applications, which are notoriously difficult to debug. Additionally, this tool can help find vital performance benefits by providing relative execution measurements. The profiler is written in C++ and utilizes the standard template library as well as glibc extensions.

Co-Rotational Finite Element Solid Simulation With Collisions, Patrick Riordan

Computer Science and Software Engineering

This paper is a tutorial on how to implement a deformable solid simulation with collisions based off of Matthias Mueller's Real Time Physics Course Notes. It covers the topics continuum mechanics, finite element analysis, implicit Euler integration, and handling collision.

Real Time Analytics On Digital Distraction, Kristian Welch

Computer Science and Software Engineering

Hypothesis: empirically measuring the users productivity has the potential to significantly increase their productivity. This paper is the documentation of the process of building software capable of verifying this hypothesis. Starting with the research which gives enough evidence to warrant the hypothesis, also included is commentary on the prototyping, design decisions, and iteration based on user feedback of the software.

Warranty Period And Product Price Optimization For Remanufactured Products, Yuxi Liu

Theses and Dissertations

This study considers a remanufactured electrical product under a tiered warranty policy. Warranty is key in ensuring a good manufacturer—consumer relationship. Manufacturers hope to minimize warranty costs while consumers believe that good warranty promises better product quality and reliability. This Thesis presents an optimal warranty period from the perspective of a manufacturer to maximize the total expected profits, while ensuring sustained consumer relation. We use real data from a local company with a global supply chain to provide a numerical example.

Arylboronates As H2o2 Or Photo-Inducible Dna Cross-Linking Agents: Design, Synthesis, Mechanism, And Anticancer Activity, Yibin Wang

Theses and Dissertations

Interest in the development of cancer therapies with improved selectivity and reduced host toxicity has been growing. In this thesis, we designed and synthesized a series of novel non-toxic arylboronic ester and biarylboronic ester derivatives that can be activated by hydrogen peroxide (H2O2) to induce DNA interstrand cross-link formation. The mechanism of DNA cross-linking induced by these arylboronates involves generation of phenol intermediates 1 followed by departure of leaving group (L) leading to quinone methides (QMs) 2, which directly cross-link DNA via alkylation. The QM formation is the rate-determining step for DNA cross-linking. The activity and selectivity of these compounds …

The Effects Of Prompted Tutoring On An Emporium Model Math Course, Juliette Michelle Young

Honors Theses

My research goal is to investigate how specific prompting of students would affect their involvement and progress in an emporium developmental math course. With the aim of increasing the students’ involvement and progress I tested a method that was in tended to increase students’ perceived connectedness with the classroom and promote the use of the available tutors and teachers. I monitored consenting students’ progress in the Spring 2015 courses and sent emails to students who met any one of three different criterion: (1) If the students time investment was below a threshold. (2) If the student’s mastery pace was less …

Spatial Analysis Of Distributions And Habitat Conditions Of Fallopia Japonica (Japanese Knotweed) Invasive Species Applying Unmanned Helicopter Remote Sensing, Jiazhen Zhang

Great Lakes Center Masters Theses

Abstract:

Fallopia japonica (Japanese knotweed) is a perennial herbaceous plant that is native to East Asia. It is considered as one of the worst invasive species worldwide because of its serious impact on biological diversity and human activities (Lowe et al., 2001). Once established, Japanese knotweed forms dense stands that shade and crowd out native plant species. The objectives of this research were to verify and confirm the distribution of Japanese knotweed as published online by the New York Department of Environmental Conservation (DEC) – iMap and to identify the geographic areas of spreading and the local habitat conditions. In …

Siguria E Rrjetave Kompjuterike, Blinera Ahmeti

Theses and Dissertations

Shpërndarja e internetit në përmasa më të mëdha filloi në fillim të viteve 1980. Qysh në këtë fillim lindi edhe nevoja për sigurinë e rrjetave kompjuterike, menjëherë pas shfaqjes së sulmeve të para që shkaktuan dëme në informacionet dhe sistemet kompjuterike. Ndryshimet shumë të shpejta në botën e kompjuterikës, aplikacioneve mobile dhe rrjetave pa kabllo kanë ndryshuar plotësisht tiparet e sigurisë së rrjetave. Qysh nga ajo kohë, sado që ka pasur zhvillime tepër të mëdha në botën e internetit, ende ka shumë ngecje në zhvillimin e metodave të sigurisë së rrjetave.

Problemet me sigurinë më së lehti dhe më së …

Implementimi Dhe Adaptimi I E-Commerce Në Kompanitë E Vogla Në Zvicër, Drilon Tahiri

Theses and Dissertations

Qëllimi i këtij hulumtimi është të shqyrtojë implementimin dhe adaptimin e e-commerce në kompanitë e vogla në Zvicër . Ky hulumtim përshkruan të gjitha përfitimet dhe pengesat me të cilat ballafaqohen kompanitë e vogla gjatë procesit të implementimit të e-commerce. Një hulumtim cilësor është kryer. Po ashtu është kryer edhe një intervistë me një menaxher të një kompanie të vogël në Zvicër.

Ky studim tregon se kompanitë e vogla në Zvicër kanë përparësi në implementimin dhe adaptimin e e-commerce në krahasim me vendet e tjera të Evropës, por ende ka pengesa të cilat mund të përmirësohen në të ardhmen.

Përfitimet …

Programimi Paralel Me Gpu, Kujtim Kërqeli

Theses and Dissertations

No abstract provided.

Zgjidhja E Problemeve Të Transportit Në Rrjetat Telekomunikuese Duke Kaluar Në Ran-In E Bazuar Në Ip, Meriton Ahmeti

Theses and Dissertations

Operimi i Radio paisjeve (Antenat) të operatorëve të ndryshëm të telefonisë mobile dhe ndërlidhja e tyre me Rrjetën Bërthamë (Core Network) mundësohet nga RAN (Radio Access Network) i cili jo domosdoshmërisht është i njejtë për operator të ndryshëm mobil.

Përgjatë viteve të zhvillimit të Telekomunikacionit në përgjithesi dhe të Komunikimeve mobile në veçanti, janë zhvilluar teknologji të reja për ta tejkalur problemin e diversitetit në mes të teknologjive të aplikuara në rrjetën e një operatori të telefonisë mobile por edhe për të tejkaluar kufizimet e ndryshme teknike.

Në aspektin e dizajnimit të rrjetës së operatorëve të telefonisë mobile gjithmonë kalimi …

Krahasimi I Teknologjive Për Implementimin Dhe Përkrahjen E Videove Në Ueb, Rinor Svarça

Theses and Dissertations

Në këtë punim diplome jemi munduar të analizojmë dy teknologjitë më të përdorura për lansimin e videove në internet Adobe Flash dhe HTML5, edhe pse nuk janë të ngjashme kanë të përbashkët mundësinë e shfaqjes së videove në ueb faqe, ku dhe jemi fokusuar më shumë në këtë të përbashkët të këtyre dy teknologjive. Gjithashtu kemi hulumtuar për historikun, zhvillimin, ngjashmëritë dhe dallimet që kanë, kemi analizuar edhe problemet e tye dhe si ka ardhur deri te zëvendësimi i Flash me HTML5 për një kohë mjaftë të shkurtër. Jemi munduar t’i krahasojmë të gjitha pjesët e përbashkëta dhe kemi paraqitur …

Krahasimi I Cms Platformave, Wordpress Dhe Umbraco Për Ndërtimin E Ueb Faqeve Të Korporatave, Shpëtim Rashiti

Theses and Dissertations

Në ditët e sotme përdorimi i ueb faqeve është shëndruar në një element shumë të rendësishëm për çdo kompani apo korporat, ku për çdo njërën është e rëndësishme që të kenë një ueb faqe përmes së cilës do të mund të prezantonin punën e tyre apo të shisnin produkte online. Këto ueb faqe apo sisteme kanë mjaft shumë përmbajtje dhe kërkojnë punë për tu realizuar për këtë arsye është shumë e rëndësishme që këto ueb faqe të ndërtohen duke përdorur ndonjë CMS (Content Management System) Platformë. Në praktikë egsistojnë mjaft CMS platforma mirëpo në këtë punim ne do të krahasojmë …