Physical Sciences and Mathematics Commons^™

Using The Wrf Model To Simulate The Playa Breeze Over Dugway Proving Ground, Daniela Maria Spade

Open Access Theses & Dissertations

The aim of this model and observation based study is to investigate the Advanced Research Weather Research and Forecasting Model's (WRF-ARW, although WRF from hereout) ability to simulate the three-dimensional structure of playa breezes and drainage flows occurring in Dugway Proving Ground, Utah using sub-km nesting in addition to improved land use and terrain datasets (as compared to the default datasets provided with WRF), in addition to studying the diurnal cycle and interactions between the playa breeze and drainage flows. A playa breeze is a thermally forced air circulation system that develops near the edge of playas, which have properties …

Contributions To The Solution Of Large Nonlinear Systems Via Model-Order Reduction And Interval Constraint Solving Techniques, Leobardo Valera

Open Access Theses & Dissertations

Many engineering problems boil down to solving partial differential equations (PDEs) that describe real-life phenomena. Nevertheless, efficiently and reliably solving such problems constitutes a major challenge in computational sciences and in engineering in general.

PDE-based systems can reach sizes so large after they are discretized. The large size in these problems generate several issues, among them we can mention: large space of storing, computing time, and the most important, lost of accuracy. A popular approach to solving such problems is assume that the PDE's solution is in a subspace, and the solution is sought there. This assumption and later searching …

Single And Multiple Objective Biomass-To-Biofuel Supply Chain Optimization Considering Environmental Impacts, Claudia Evangelina Valles Sosa

Open Access Theses & Dissertations

Bioenergy has become an important alternative source of energy to alleviate the reliance on petroleum energy. Bioenergy offers diminishing climate change by reducing Green House Gas Emissions, as well as providing energy security and enhancing rural development. The Energy Independence and Security Act mandate the use of 21 billion gallons of advanced biofuels including 16 billion gallons of cellulosic biofuels by the year 2022. It is clear that Biomass can make a substantial contribution to supply future energy demand in a sustainable way. However, the supply of sustainable energy is one of the main challenges that mankind will face over …

Transition Metal Carbide (Tmc) Novel Materials For Novel Catalytic Applications, Svetlana Lagoykina

Open Access Theses & Dissertations

Transition metal carbides (TMC) constitute a diverse class of materials and traditionally have many technological applications. TMC became a subject of extensive research since 1973, when their platinum -like properties were discovered. They demonstrated high catalytical activity and selectivity in a variety of chemical reaction and have potential for some novel catalytic application.

This research is an effort to design new high effective, selective and stable bimetal or alkali promoted TMC catalyst. After extensive theoretical research a wide range of TMC, including bimetal and alkali promoted carbides, were synthesized by different methods. All solids were characterized by XRD and microscopy. …

Ac-Susceptibility Investigations Of Superspin Blocking And Freezing In Interacting Magnetic Nanoparticle Ensembles, Joshua Logan Morris

Open Access Theses & Dissertations

We have investigated the effect of dipolar interactions on the superspin blocking and freezing of 10 nm average size Fe3O4 magnetic nanoparticle ensembles. Our dynamic susceptibility data reveals a two-regime behavior of the blocking temperature, TB, upon diluting a Fe3O4/hexane magnetic nanoparticle fluid. As the nanoparticle volume ratio, Phi, is reduced from an as-prepared reference Phi = 1 to Phi = 1/96, the blocking temperature decreases from 46.1 K to 34.2 K, but higher values reenter upon further diluting the magnetic fluid to Phi = 1/384 (where TB = 42.5 K). We show that cooling below TB within the higher …

An Assessment Of The Role Of Roads In Population Demography And Genetic Structuring In Two Species Of Lizards In The Northern Chihuahuan Desert, Kevin Floyd

Open Access Theses & Dissertations

Roads can fragment habitat and increase mortality rates of wildlife, potentially reducing population sizes and gene flow, which in turn can reduce genetic diversity through genetic drift. Although negative road impacts have been found in a variety of taxa, not all species are impacted. For instance, species that move less and rarely encounter roads and those that avoid the roads are predicted to not be negatively affected. Yet tests of these predictions are uncommon, especially for reptiles and particularly lizards. Side-blotched lizards (Uta stansburiana) are small sit-and-wait predators, while the larger marbled whiptails (Aspidoscelis marmorata) are active foragers. Their responses …

Versatility Of N-Peptidyl And N-Glycopeptidyl Nitroindolines For The Formation Of Peptide/Glycopeptide Acids, Amides, And Thioesters, Luis Alfonso Barrera

Open Access Theses & Dissertations

N-acyl-7-nitroindolines are photoreactive compounds that are known to acylate a number of nucleophiles in inert aprotic solvents under neutral conditions when illuminated at 350 nm. We have assembled a MUC1-derived peptide and Tn or STn-containing MUC1 glycopeptides with a C-terminal photoreactive 7-nitroindoline linker attached to Sieber amide resin by solid phase peptide synThesis using the Fmoc strategy. This type of construction allows for the cleavage of fully protected photoreactive peptides/glycopeptides from the resin with dilute trifluoroacetic acid, or for the direct photorelease of protected peptide/glycopeptide derivatives. Here we demonstrate that N-peptidyl and N-glycopeptidyl 7-nitrindolines can be photochemically converted into their …

Synthesis Of Benzofused-P-Indolequinones From 1,4-Naphthoquinone And Selective N-Debenzylation By Dess-Martin Periodinane, Quang Huynh Luu

Open Access Theses & Dissertations

p-Indolequinones are important heterocycles since they display interesting bioactivities such as anticancer activities as well as the ability to trigger drug release in drug targeting research. Additionally, they are also useful in precursors for the synThesis of bioactive compounds. Over decades, many methodologies have been investigated for the synThesis of p-indolequinones. Among those, cyclization of quinones plays an important role in convenient synThesis of these compounds. However, the great majority of these methods only describe quinones as electrophiles in cyclization. In our research, we found an intramolecular nucleophilic attack of quinone to an in-situ generated carbonyl group and developed a …

Predicting Irrigation Efficiency In The Rio Grande Project, Gerardo Melendez

Open Access Theses & Dissertations

Surface water losses in the Bureau of Reclamation’s (USBR) Rio Grande Project have become more prevalent within the past few years of the drought of the 2000’s. Simple regressions were performed in order to find correlations and determine factors that may affect the flows within the Rio Grande Project. Correlations were found in the difference between Rio Grande below Caballo flows and Rio Grande at El Paso flows, and between the diversion ratio and groundwater levels. Caballo Reservoir release amounts were found to be fairly well correlated with the difference between the Rio Grande below Caballo and the Rio Grande …

Constructing Negotiated Meaning And Knowledge For The Sol Y Agua Project's Role-Playing Adventure Game Focused On Sustainability Problems In The El Paso-Rio Grande Area, Claudia Chihiro Santiago

Open Access Theses & Dissertations

Video games that address environmental sustainability issues could engage students. However, video games make simplifications and establish idealistic expectations that do not resemble real life sustainability challenges and settings. Game developers and scholars believe that depicting the complexity of the real world could help video games become effective educational tools. They call for additional procedures that incorporate information from actual settings and real life situations. Furthermore, scholars have argued that video games addressing sustainability issues can be improved or made more meaningful with the participation of youth from underrepresented populations, e.g., Latinos. The Sol y Agua project at The University …

Triphenylamine-, Porphyrin- And Fullerene-Based Derivatives For Photovoltaic And Other Applications, Danisha Marie Rivera Nazario

Open Access Theses & Dissertations

Proper collection of charges at the electrodes is an important process in organic solar cells. Interfacial layers between the electrodes and the photoactive layer have been design to improve charge collection and ohmic contacts. The most studied interfacial layer between the anode and the photoactive layer is the negatively charged polymer poly(3,4-ethylendioxythiophene):poly(styrenesulfonate) (PEDOT:PSS), that possesses good hole transporting ability. However, inhomogeneities at the surface of the electrode after deposition of the polymer lower the stability and performance of the OPV devices. Triphenylamine (TPA) derivatives have received increased attention in the organic solar cells (OSCs) field because of their favorable light …

Three Essays On Global Ict Phenomenon: Productivity Paradox, Organizational Ict Use, And Privacy In Social Networks, Faruk Arslan

Open Access Theses & Dissertations

This Dissertation aims to investigate the global diversity in information systems by studying three distinctive phenomena. The first essay investigates the existence of "IT Productivity Paradox" within firms operating in developing countries using an empirical approach. IT Productivity Paradox has been a widely investigated topic within the context of developed countries and primarily studied within the context of developing countries using a single country. Our research addresses a gap in the literature, which is the study of IT Productivity Paradox across several developing countries with diverse characteristics. The second essay studies the contextual factors (firm characteristics and perception of external …

Challenges In Assessing College Students' Conception Of Duality: The Case Of Infinity, Grace Olutayo Babarinsa-Ochiedike

Open Access Theses & Dissertations

Interpreting students' views of infinity posits a challenge for researchers due to the dynamic nature of the conception. There is diversity and variation among students' process-object perceptions. The fluctuations between studentsâ?? views however reveal an undeveloped duality conception. This study examined college students' conception of duality in understanding and representing infinity with the intent to design strategies that could guide researchers in categorizing students' views of infinity into different levels.

Data for the study were collected from N=238 college students enrolled in Calculus sequence courses (Pre-Calculus, Calculus I through Calculus III) at one of the southwestern universities in the U.S. …

Salt And Mineral Recovery From High Salinity Waters, Osvaldo Alejandro Broesicke

Open Access Theses & Dissertations

Natural salt springs in the Salt Fork Basin in Crosby County, Texas, result in the natural salt pollution of the Brazos River, rendering it unusable for most potable purposes. Previous research indicates that by intercepting the source of the pollution, water quality of the Brazos River can be greatly improved. This paper investigates and assesses two strategies for salt and mineral recovery using natural brine collected from the Salt Fork Basin, the first of which is presented in a separate work.

The research described in this paper evaluates the potential of a desulfation, soda-caustic softening, acidification/decarbonation, and evaporation process to …

Reinterpretation Of The Mesozoic Thrust Complex Of The Southern Spring Mountains, Nevada, Warren Harding Allen

Open Access Theses & Dissertations

The east verging Keystone thrust fault in the southern Spring Mountains west of Goodsprings, Nevada, is mapped with a sharp bend in its trace near Keystone Wash. This bend was previously explained in the context of out-of-sequence thrusting and a salient-recess relationship along the thrust system; a simple redirection of the Keystone thrust to a north verging thrust. Recent geochronological studies indicate that the east verging Keystone thrust to the north of Keystone Wash formed between 83-103Ma. Approximately 5 kilometers to the east a north verging branch of the fault system overlies rocks as young as 99Ma. At the location …

Depositional Facies And Interpretation Of Salt-Sediment Interaction In The Lower Triassic Moenkopi Formation Adjacent To The Castle Valley Salt Wall, Paradox Basin, Utah, Ann Marie Foster

Open Access Theses & Dissertations

Stratigraphic, sedimentologic and compositional data collected from the Triassic Moenkopi Formation adjacent to the Castle Valley salt anticline, Paradox Basin, Utah indicate passive diapirism of the salt wall with well-developed topography and exposed salt during the Early Triassic. Moenkopi strata thin to 150m on to the Castle Valley salt anticline and thicken to an estimated 275m away from it, indicating control of sedimentation by salt-generated topography. The distribution of nine terrestrial facies assemblages within Moenkopi Formation strata on the margins of Castle Valley Salt Wall, in combination with identification of three halokinetic sequences interpreted from stratal architecture adjacent to the …

Trace Element Behavior During Coal Combustion: Insights From Cadmium And Zinc Isotope Analysis, Fotios Fouskas

Open Access Theses & Dissertations

Due to its low cost and abundance, coal has been pervasively used in recent decades to meet large energy demands worldwide. Coal combustion provides the dominant electrical source in the U.S and produces over 100 million tons of coal combustion products (CCPs) per year domestically. The disposal/beneficial use of CCPs has the potential to release toxic trace elements, including cadmium (Cd) and zinc (Zn), into the environment. High temperature combustion of coal changes both physical states and chemical properties of Cd and Zn compounds in CCPs. Related processes such as evaporation and condensation, can lead to mass-dependent fractionation of Cd …

The Meteorological Conditions Affecting The Propagation Of Respiratory Diseases, Rosette Maria Gonzalez

Open Access Theses & Dissertations

Valley Fever, also known as Coccidioidomycosis, is endemic of the US Southwest. In 2012 this disease was the second most-reported disease in Arizona, according to the New Yorker January 2014 edition. The Paso Del Norte Region (PdN) is a semi-arid region with significant agricultural acreage and Valley Fever is known to be a threat in this region. It is our goal in this Thesis work to apply an existing PBL Height Program (e.g., Liu, et.al.) to the Paso Del Norte Region (PdN) to study the effect it has in the transmission of Valley Fever. Obtaining the PBLH as it evolves …

High Temperature Helical Tubular Receiver For Concentrating Solar Power System, Nazmul Hossain

Open Access Theses & Dissertations

In the field of conventional cleaner power generation technology, concentrating solar power systems have introduced remarkable opportunity. In a solar power tower, solar energy concentrated by the heliostats at a single point produces very high temperature. Falling solid particles or heat transfer fluid passing through that high temperature region absorbs heat to generate electricity. Increasing the residence time will result in more heat gain and increase efficiency. A novel design of solar receiver for both fluid and solid particle is approached in this paper which can increase residence time resulting in higher temperature gain in one cycle compared to conventional …

Japanese Computational Lexicon: A Computational Dictionary Of Japanese Verb Forms, Mayumi Kobayashi

Open Access Theses & Dissertations

This paper presents two main topics: a linguistic analysis of Japanese morphological lexicon focused on verb conjugation and a computational analysis of Japanese verb conjugation in Prolog programming. Prolog is one of the computer programming languages and is used to solve a problem logically with a number of statements called "clauses," which are defining various relationships of the entities. With respect to the linguistic aspect, this paper discusses Japanese verb formation, its conjugation patterns, twelve basic forms of Japanese verbs, and a Japanese morphophonemic process called “音便 (onbin)” by investigating 304 regular verbs and 2 irregular verbs. Among the several …

Iso-Power-Efficiency: An Approach To Scaling Application Codes With A Power Budget, Rogelio Long

Open Access Theses & Dissertations

For many applications, speedup saturates and parallel efficiency decreases if the problem size is held fixed while increasing the number of processors. For some problems, it is possible to maintain a fixed parallel efficiency by increasing both the problem size and the number of processing elements. The rate at which the problem size must increase to maintain constant efficiency for a given rate of increase of the number of processors is given by the iso-efficiency function. We have developed a new scalability function called iso-power-efficiency that determines the rate at which the problem size must increase to maintain constant efficiency …

Bounded Rationality In Decision Making Under Uncertainty: Towards Optimal Granularity, Joseph Anthony Lorkowski

Open Access Theses & Dissertations

Starting from well-known studies by Kahmenan and Tversky, researchers have found many examples when our decision making seems to be irrational. We show that this seemingly irrational decision making can be explained if we take into account that human abilities to process information are limited. As a result, instead of the exact values of different quantities, we operate with granules that contain these values. On several examples, we show that optimization under such granularity restriction indeed leads to observed human decision making. Thus, granularity helps explain seemingly irrational human decision making.

Similar arguments can be used to explain the success …

The Impacts Of Water Availability On Macroinvertebrate, Ector Matias Martell

Open Access Theses & Dissertations

In many regions around the world climate is changing and biotic communities are changing with it. In areas like the southwestern U.S., drought is one of the major sources of disturbance. Although droughts are an integral part of the natural hydrological cycles, they can have devastating effects on freshwater ecosystems when disrupted by extended periods of drought, resulting in changes to the structure and function of biotic communities. In this study, we surveyed four streams in the Sacramento Mountains of New Mexico from 2010 to 2014: Agua Chiquita, Rio Peñasco, Wills Creek, and the Sacramento River; These years encompassed an …

Crustal Structure Beneath The Eastern Nepal Himalayas And Southern Tibet From Receiver Function Analysis, Arjun Sharma Neupane

Open Access Theses & Dissertations

The Himalayas are the results of continental collision between the Indian plate and the Eurasian plate and serve as a natural site to study the physical causes and process of mountain building. The crustal structure beneath the Himalayas has been subject to numerous geophysical studies and the variation in the velocity structure across the Himalayan region suggests significant differences in the crustal structure between the southern and northern portion in that region. In this research, a P receiver function analysis has been conducted on data collected for 14 years (2000-2014) from 211 different stations in Eastern Nepal and Southern Tibet, …

Latina/O High School Students' Standpoint On Environmental Justice In A Border Community: A Phenomenological Study, Cynthia Christina Ontiveros

Open Access Theses & Dissertations

This qualitative research is a transcendental phenomenology seeking to understand Latin@ high school students’ perceptions and standpoints as they participated lessons that addressed border environmental justice issues in an underrepresented, marginalized community. Seven students from Borderland High School, enrolled in a senior level course, Environmental Science, participated in the study which focused on their experiences in an environmental justice air quality thematic unit built around the complex issues surrounding a local refinery, American Smelting and Refining Company (ASARCO). The study analyzed the meaning students made and their standpoints regarding the impact of the factory and its one-hundred year history polluting …

Novel Classification Of Slow Movement Objects In Urban Traffic Environments Using Wideband Pulse Doppler Radar, Berta Rodriguez Hervas

Open Access Theses & Dissertations

Every year thousands of people are involved in traffic accidents, some of which are fatal. An important percentage of these fatalities are caused by human error, which could be prevented by increasing the awareness of drivers and the autonomy of vehicles. Since driver assistance systems have the potential to positively impact tens of millions of people, the purpose of this research is to study the micro-Doppler characteristics of vulnerable urban traffic components, i.e. pedestrians and bicyclists, based on information obtained from radar backscatter, and to develop a classification technique that allows automatic target recognition with a vehicle integrated system. For …

Microscopic And Spectroscopic Analysis Of Cadmium Telluride, Jessica Goretty Salazar

Open Access Theses & Dissertations

Cadmium telluride (CdTe) remains one of the materials of interest in the fabrication of photovoltaic cells and infrared devices, mainly because of its suitable crystal structure as well as of its small, direct bandgap of 1.5 eV. Since development of such devices requires a high quality and low defect material, the goal of this study is to microscopically and spectroscopically examine not only crystallinity, but also the induced stress in the material due to the effect of substrate orientation. This information is valuable if optimization of sample growth conditions is envisioned. Prior to CdTe deposition by close-spaced sublimation (CSS), Si …

Heat Absorption Analysis By Falling Particles At High Temperatures For Concentrating Solar Power Systems, Arturo Sepulveda Fernandez

Open Access Theses & Dissertations

High temperature Heat Transfer Fluid (HTF) with Thermal Energy Storage (TES) for the Concentrated Solar Power (CSP) technology can provide a large and relatively cheaper storage option, as opposed to limited and expensive electrical battery storage with PV technology, and hence, it has potential to maintain a constant production when no sunlight is available. Research of material like aluminum, silicon, graphite could be potential candidates to work as thermal energy storage. Currently, nitrate and chloride molten salts are widely used as the TES medium for a CSP plant. However, molten salt, especially chlorides, must be handled carefully at high temperature …

Pre-Tuned Ridge Regression And Its Extension To Generalized Linear Models, Yaa Tawiah Wonkye

Open Access Theses & Dissertations

Ridge regression is regularization or shrinkage method and a common approach in dealing with multicollinearity in conventional regression analysis. Ridge regression is widely used by statistical analyst since it is one of the best compared to other regularization methods. Also, the introduction of high dimension and ultra-high dimensional data has become an issue of concern and ridge regression is one way of dealing with such data. One of the key issues associated with ridge regression is the determination of the tuning or ridge parameter. The common practice is to fit ridge regression for a different number of values of tuning …

Sequence Stratigraphy And Depositional Environment Of The Cambro-Ordovician Bliss Sandstone, Franklin Mountains Of El Paso, Texas, Drew Adam Chenoweth

Open Access Theses & Dissertations

The Bliss Formation formed along the Southwestern continental shelf of

Laurentia during the Late Cambrian and records the craton]wide Cambrian

transgression previously described by Sloss. This study divides the Bliss into five facies associations which were used to determine the depositional environments: 1) The Basal Transgressive Lag (BTL) was interpreted to be a high energy fluvial deposit the top of which has been reworked and winnowed during transgression. 2) The Lower Cyclic Sandstones and Silty Sandstones (LCSS) were interpreted to be be tidal delta or tidal estuary deposits composed of delta deposits, slackwater deposits, and tidal dunes within tidal channels. …