Physical Sciences and Mathematics Commons^™

Refractive Index Chemical Sensing With Noble Metal Nanoparticles, Phillip Blake

Graduate Theses and Dissertations

Chemical sensing is a key component in modern society, especially in engineering applications. Because of their widespread impact, improvements to chemical sensors are a significant area of research. One class of sensors, plasmonic sensors, is being heavily researched because of their ability to detect low levels of analyte in near real time without destroying the analyte. This work studies a new class of plasmonic sensor that utilizes diffractive coupling to improve sensor performance. Specifically, this work outlines the first study of diffractive coupling sensors with typical nanoparticle shapes. Sensitivity of this new class of sensor is directly compared to typical …

Prehistoric Human Ecodynamics In The Rub Al-Khali Desert: Results Of Remote Sensing And Excavations In Dubai, United Arab Emirates, Jason T. Herrmann

Graduate Theses and Dissertations

Archaeological investigations in the Emirate of Dubai, UAE conducted by the Dubai Department of Archaeology and the University of Arkansas demonstrate that the desert inland of the Oman Peninsula was occupied not only during the Arabian Neolithic (8000-4400 BC), when the region experienced a moist period referred to as the Holocene Climatic Optimum (HCO), but also during the more arid millennia following the decline of the HCO into the Christian Era. During this period, desert settlement clustered near a band of oases, in contrast to the more widespread spatial distribution of remains of nomadic pastoralists from the Neolithic. Excavations at …

An Economic Alternative To The C Chart, Ryan William Black

Graduate Theses and Dissertations

Because the probability of Type I error is not evenly distributed beyond upper and lower three-sigma limits the c chart is theoretically inappropriate for a monitor of Poisson distributed phenomena. Furthermore, the normal approximation to the Poisson is of little use when c is small. These practical and theoretical concerns should motivate the computation of true error rates associated with individuals control assuming the Poisson distribution. An economic alternative to the c chart is described as a statistical model of upward shift from c0 to c1 and the two charts are compared in theory. For a range of c chart …

Design Of A Pretreatment And Enzymatic Saccharification Scheme Of Understory From Managed Pine Forest For A Biochemical-Refinery Platform: The Example Of The Sweetgum Tree, Angele Djioleu

Graduate Theses and Dissertations

The possibility of using sweetgum from southern pine dominated forests as a biobased refinery feedstock was investigated. First, a baseline hydrolysis scheme for sweetgum wood and bark was designed. Sweetgum wood and bark were pretreated with 0.98% (v/v) sulfuric acid at 140°C for 30, 40, 50, 60 or 70 min and at 160°C for 30, 40, 50 or 60 min. The water insoluble solid (WIS) fraction was hydrolyzed with a cellulase enzyme cocktail. Results showed that maximum xylose and glucose yields from the wood were 82 and 86%, respectively. Similarly, the respective maximum yields of xylose and glucose from the …

A Watershed Scale Evaluation Of Selected Second Generation Biofeedstocks On Water Quality, Gurdeep Singh

Graduate Theses and Dissertations

This study compares a novel simulation approach to the conventional Soil and Water Assessment Tool (SWAT) modeler's approach for targeting biofuel crop production on marginal lands. In conventional SWAT modeling approach, non-spatial definition of hydrological response units (HRUs) results in the simulation of biofuel crops on both marginal and non-marginal land. This study provides an alternative approach in which a marginal-land raster was integrated into the land use and land cover (LULC) raster in such a way that the land uses were divided into marginal and non-marginal components. This modified LULC was used for model setup which resulted in marginal …

Penetration Forces For Subsurface Regolith Probes, Ahmed Elshafie

Graduate Theses and Dissertations

Investigating planetary bodies using penetrometers can provide detailed information about its history and evolution. An estimation of subsurface density and porosity can be made from the shape of the penetration curve. Using penetrometers mounted on planetary platforms could be challenging due to the uncertainty of the subsurface composition and since the maximum allowed force for penetration is the weight of the lander or rover on the surface. Estimation of penetration forces can provide a reliable constraint on the maximum reachable depth without endangering the whole mission. Therefore, knowledge of the required penetration force to specific depths can be helpful in …

On The Representation Of Inverse Semigroups By Difunctional Relations, Nathan Bloomfield

Graduate Theses and Dissertations

A semigroup S is called inverse if for each s in S, there exists a unique t in S such that sts = s and tst = t. A relation σ contained in X x Y is called full if for all x in X and y in Y there exist x' in X and y' in Y such that (x, y') and (x', y) are in σ, and is called difunctional if σ satisfies the equation σ σ^-1 σ = σ. Inverse semigroups were introduced by Wagner and Preston in 1952 and 1954, respectively, and difunctional relations were …

Plasmonic And Photonic Designs For Light Trapping In Thin Film Solar Cells, Liming Ji

Graduate Theses and Dissertations

Thin film solar cells are promising to realize cheap solar energy. Compared to conventional wafer cells, they can reduce the use of semiconductor material by 90%. The efficiency of thin film solar cells, however, is limited due to insufficient light absorption. Sufficient light absorption at the bandgap of semiconductor requires a light path more than 10x the thickness of the semiconductor. Advanced designs for light trapping are necessary for solar cells to absorb sufficient light within a limited volume of semiconductor. The goal is to convert the incident light into a trapped mode in the semiconductor layer.

In this dissertation, …

Habitat Modeling Of Three Endemic Crayfish Species In The Black River Drainage Of Missouri And Arkansas: Factors Affecting Distribution And Abundance, Matthew Stephen Nolen

Graduate Theses and Dissertations

The Ozark faunal region of Missouri and Arkansas harbors a high level of aquatic biological diversity, especially in regards to endemic crayfish. Orconectes eupunctus, Orconectes marchandi, and Cambarus hubbsi are three such endemics that are threatened by a limited natural distribution and the invasions of Orconectes neglectus. I sought to determine how natural and anthropogenic factors influence these three species across multiple spatial scales. Local and landscape data were used in decision tree analyses (CART) to determine their influence effect on presence/absence and density of the three species. Predictive models were validated using k-fold cross validation. O. eupunctus presence was …

Pulse Sharpening Effects Of Thin Film Ferroelectric Transmission Lines, Robert J. Sleezer

Graduate Theses and Dissertations

Advances in material science have resulted in the development of electrically nonlinear high dielectric thin film ferroelectrics, which have led to new opportunities for the creation of novel devices. This dissertation investigated one such device: a low voltage nonlinear transmission line (NLTL). A finite element simulation of ferroelectric transmission lines showed that NLTLs are capable of creating shockwaves. Additionally, if the losses are kept sufficiently low, it was shown that voltage gain should be possible. Furthermore, a method of accounting for material dispersion was developed. Results from simulations including material dispersion showed that temporal solitons might be possible from a …

Exploring The Surface Liquid And Lake Regions Of Titan With Laboratory Experimentation And Cassini Spacecraft Data, Felix Casimir Wasiak

Graduate Theses and Dissertations

The surface liquids and lake regions of Titan are studied utilizing three unique techniques, the results of which are reported in this dissertation. The development of a facility to simulate the surface conditions of Titan, and to conduct experiments on samples within that facility, brings an understanding of Titan's surface not possible through observation and modeling alone. The properties of this facility are presented, including conceptual methodology, design, implementation, performance, and experimental results. The facility, the main component of which is a simulation chamber, allows for Titan temperatures of 90 - 94 K and a 1.5 bar N2 atmosphere. The …

Evaluation Of The Effects Of Absorption Field Product Architecture Type On Effluent Dispersal And Soil Chemical Properties In A Profile-Limited Soil, Nina J.M. Prater

Graduate Theses and Dissertations

On-site wastewater treatment systems (OWTSs) are commonly used by households in areas of low population density to treat household wastewater and recycle it back to the environment. The traditional absorption field product used in OWTSs is a pipe-and-gravel architecture type, which has been used for decades and is the basis for most design regulations. However, new products of differing architecture types including chambers, polystyrene-aggregate, pipe-and-tire-chip, and gravel-less-pipe systems have recently become available. A three-year field study was conducted in Bethel Heights, AR to assess the performance of several newer products and to compare different architecture types to the traditional pipe-and-gravel …

Diagenesis And Reservoir Characterization Of The Pennsylvanian Middle Atoka Formation, Sebastian And Logan Counties, West-Central Arkansas, Elvis Chekwube Bello

Graduate Theses and Dissertations

The Middle Atoka Formation evolved from a stable passive margin during the early Pennsylvanian time to a rapidly subsiding basin, with the sedimentary fill thickening greatly southward during the middle Pennsylvanian time. The basin dips in north-south direction. An east-west anticlines and synclines were observed.

The purpose of this study is to establish the stratigraphic units, reservoir geometry and distribution, and infer the depositional environments and reservoir quality. Well correlation and petrographic studies are used to achieve the goals.

Sandstone Point Count method was used. The Point Counts was divided into five categories. They include the framework grains (quartz, feldspar, …

Investigating The Sensitivity Of Goodness-Of-Fit Indices To Detect Measurement Invariance In The Bifactor Model, Jam Khojasteh

Graduate Theses and Dissertations

A Monte Carlo simulation study was conducted to evaluate the sensitivities of five commonly used goodness-of-fit indices to detect metric invariance properties of the bifactor model. The fit indices that performed the best in terms of power were Gamma and Mc. In addition, Gamma, Mc, CFI, and RMSEA all held Type I error to a minimum. However, only Gamma and CFI are recommended to use in the bifactor model because the other GOF indices have cutoff values that are too large. For Gamma and CFI values of -.026 to -.045 and -.004 to -.009, respectively indicate a lack of metric …

Stratigraphic Variations In The Carboniferous Section Across The Arkansas-Oklahoma State Line Arch, Tyler Dean Engelhardt

Graduate Theses and Dissertations

The State Line Arch is represented by a structural high that trends through the study area in a loose alignment with the Arkansas-Oklahoma state line. Evidence of the arch extending further to the north includes a structural high and stratigraphic variation at an outcrop on Highway 59 near Evansville Mountain in Crawford County, Arkansas. The exact timing of the formation of the arch remains undetermined, but upper Devonian thinning at the top of the arch indicates the structure is pre-Mississippian. The reason for the development of the arch is poorly understood, but evidence linking Mississippian-aged Waulsortian mounds to Precambrian Spavinaw …

Assessing The Impacts Of Surface Water Removal For Use In Natural Gas Extraction On A Watershed Level, Carrie Ann Davis

Graduate Theses and Dissertations

In this study, the Soil and Water Assessment Test (SWAT) was used as a tool to predict whether diffuse water removal from the Cadron Creek watershed for use with natural gas development would have an impact on downstream flow within the watershed. Cadron Creek watershed expands across four counties within Arkansas and is located in the Fayetteville Shale Gas region. This region is experiencing significant growth in natural gas development. Successful development of shale gas depends on the identification of what water supplies are available for production without interfering with community and environmental needs. The SWAT model used to evaluate …

New Applications Of Mass Spectrometry For Drug And Lipid Analysis, Elizabeth Lauren Emerson

Graduate Theses and Dissertations

Mass spectrometry is an important tool used in many different disciplines and settings that include forensics, drug discovery, environmental analysis, and proteomics. Gas chromatography - mass spectrometry (GC-MS) and matrix assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI - TOF MS) are two of the most important instruments used for analysis of compounds. Chapters 1 and 2 of this discussion use GC-MS for the investigation of synthetic cannabinoids in `K2' incense products and the detection of metabolites in urine samples from individuals suspected of consuming these mixtures. Analytical standards were synthesized and used for identification and confirmation of structures. Detection of …

Long-Term Effects Of Rice Rotation, Tillage, And Fertility On Near-Surface Soil Carbon And Nitrogen Cycling, Jill Marie Motschenbacher

Graduate Theses and Dissertations

Rice (Oryza sativa L.)-based cropping systems are different from other row crops due to the flood-irrigation scheme used from about one month after planting to a few weeks prior to harvest. The frequent cycling between anaerobic (i.e., flooding during the growing season) and aerobic (i.e., generally, the remainder of the year) conditions can influence the rate of soil organic matter (SOM) decomposition, which can greatly influence carbon (C) and nitrogen (N) storage and sequestration in the soil over time. Therefore, a study was conducted on a silt-loam soil (fine, smectitic, thermic, Typic Albaqualf) at the Rice Research and Extension Center …

Effects Of Testing Time On Anaerobic Toxicity Assessment, Omolola Atinuke Akintomide

Graduate Theses and Dissertations

Anaerobic digestion has been widely used for wastewater treatment for decades. Several Anaerobic Toxicity tests have been developed to screen wastewater for toxicity and assess the treatability of such toxicants. However, past research and reviews on Biochemical Methane Potential (BMP) test and Anaerobic Toxicity Assay (ATA) were considered in this study.

The experimental tests included ammonium-nitrogen and sodium chloride toxicity tests with varied concentration and solid retention time. These tests were designed to demonstrate the impact of ammonia- nitrogen and sodium chloride on the biological degradation process. The anaerobic test set-up includes bench-scale test reactors and respirometers used for measuring …

Magnitude And Frequency Of Floods For Rural, Unregulated Streams Of Tennessee By L-Moments Method, Hongxiang Yan

Graduate Theses and Dissertations

This study presents a regional frequency analysis of Tennessee using the well-known Bulletin-17B method standardly used in the United States and the relatively new and developing L-Moments methods. Flood frequency characteristics were defined for 416 gaging stations located primarily in rural and lightly developed areas of Tennessee. All the gaging stations have 10 or more years of record through 2006. Using the L-Moments method, the generalized extreme value distribution was identified as the most robust distribution for each of four hydrologic areas. Multiple regression equations were also calculated for estimating the flood frequency of ungaged, unregulated, rural streams in each …

The Development Of A High Performance Concrete To Store Thermal Energy For Concentrating Solar Power Plants, Emerson Esmond John

Graduate Theses and Dissertations

In recent years, due to rising energy costs as well as an increased awareness of the environmental effects of greenhouse gas emissions produced through traditional forms of energy production, there is great interest in developing alternative sources of energy. One of the most viable alternative energy sources is solar energy. In particular, concentrating solar power (CSP) technologies have been identified as an option for meeting utility needs in the U.S. Southwest. These systems are required to produce electricity not only during periods of high solar radiation but also during times of reduced radiation due to cloud cover, and even extend …

Locating And Protecting Facilities Subject To Random Disruptions And Attacks, Hugh Medal

Graduate Theses and Dissertations

Recent events such as the 2011 Tohoku earthquake and tsunami in Japan have revealed the vulnerability of networks such as supply chains to disruptive events. In particular, it has become apparent that the failure of a few elements of an infrastructure system can cause a system-wide disruption. Thus, it is important to learn more about which elements of infrastructure systems are most critical and how to protect an infrastructure system from the effects of a disruption. This dissertation seeks to enhance the understanding of how to design and protect networked infrastructure systems from disruptions by developing new mathematical models and …

Investing In An Agricultural Legacy, Leo Paul Goeringer

Graduate Theses and Dissertations

America's agricultural producers continue to age. According to the U.S. Census of Agriculture, the average age of farm operators increased from 55.3 in 2002 to 57.1 in 2007. During the same period, the Census shows a thirty percent decrease in the number of farmers under age 25. Young and beginning producers (YBPs) entering agriculture face high startup costs and a shortage of land to own or rent.

With these concerns in mind, this manuscript details the impact of an innovative proposed loan program for YBPs in Arkansas, which would offer concessionary interest rates and loan fees by participating banks for …

A Daily Temperature Record For Central Texas, 1896-2011, Matthew Kain Taylor

Graduate Theses and Dissertations

A continuous record of 882,693 daily maximum, minimum, and mean temperature measurements for seven weather stations in central Texas dating from August 1, 1896, to August 31, 2011, were screened and corrected for missing values and inhomogeneities. The resulting data were averaged to create a 115-year unbroken regional record of daily temperature for central Texas. This record indicates warming in daily, seasonal, and annual temperatures. Winter warm temperature extremes have increased over the period of record while warm temperature extremes during the summer months have remained largely unchanged. Summer heat wave days and the length of heat waves have increased …

An Extension To Particle Polarizability To Predict Coupling Behavior In Periodic Nanoplasmonic Arrays, Drew Dejarnette

Graduate Theses and Dissertations

Plasmonic nanoparticles organized in arrays interact to create spectral patterns which are amplified by individual particle polarizability. It was hypothesized that particle polarizability could be used as a predictor of spectral behavior from far-field interactions within the array. Inter-particle coupling produced an extraordinary peak in extinction efficiency at wavelengths equal to or larger than the single particle plasmon resonance peak. Interactions that produced constructive coupling were found to mimic changes in the particle polarizability model. Testing of the hypothesis was performed using the coupled dipole approximation with parametric characterization of array geometries, giving specific particle size and lattice constant combinations …

A Domain Specific Model For Generating Etl Workflows From Business Intents, Wesley Deneke

Graduate Theses and Dissertations

Extract-Transform-Load (ETL) tools have provided organizations with the ability to build and maintain workflows (consisting of graphs of data transformation tasks) that can process the flood of digital data. Currently, however, the specification of ETL workflows is largely manual, human time intensive, and error prone. As these workflows become increasingly complex, the users that build and maintain them must retain an increasing amount of knowledge specific to how to produce solutions to business objectives using their domain's ETL workflow system. A program that can reduce the human time and expertise required to define such workflows, producing accurate ETL solutions with …

Livestock Production And Wildlife-Based Tourism: Articulating Land-Use And Policy Conflicts In The Okavango Delta Ramsar Site In Botswana, Nelson Kgamanyane Sello

Graduate Theses and Dissertations

The management of common pool resources and policy conflicts between livestock and wildlife, two land-use types that take place in the same geo-spatial area has been a subject of debate among scholars for decades. This conflict in policies has engendered in communities which are beneficiaries attitudes that are either negative towards wildlife or favorable depending on the benefits they derive from them. This research therefore set out to understand the conflicts in the management of the Okavango Delta Ramsar Site (ODRS) where the OD is situated. The study used the grounded theory to collect and analyze the data in the …

What Factors Influence Consumers' Willingness To Purchase And Consume Carbon-Labeled Rice: A Comparative Study Between Arkansas And Belgium, John A. Kelley

Graduate Theses and Dissertations

Climate change is an issue of growing importance around the globe. As global population increases so does attention focused on human contributions to climate change. One major way humans contribute to climate change is through our diets. Agricultural production is a major source of global greenhouse emissions. It has been estimated that food production is responsible for a large majority of the methane and nitrous oxide which is emitted into our atmosphere each year. Carbon footprint labeling has been developed to give consumers a way to lower their footprint and help lower emissions of greenhouse gasses. At least one retailer, …

Sequence Stratigraphy And Depositional Systems Of The Mansfield Sand, Upper Atoka Formation, Arkoma Basin, Arkansas, Scott Cherry

Graduate Theses and Dissertations

The Mansfield sand is an informally named member of the Pennsylvanian Atoka Formation in Arkansas. Once a productive gas reservoir, the Mansfield is situated in a double plunging anticline in the southern portion of the Arkoma Basin. The formation is internally composed of sandstone units ranging in thickness from tens of feet to over a hundred feet interbedded with shale units ranging in thickness from several tens of feet to hundreds of feet. Previous studies have focused on the stratigraphy of the lower and middle Atoka. A detailed subsurface study of the stratigraphic framework of the Mansfield sand was conducted …

Phase Control In Atomic Coherence, Utsab Khadka

Graduate Theses and Dissertations

In this thesis, atomic coherence is used to enhance nonlinear optical processes in multi-level atoms. The multi-photon transitions are driven resonantly, and at the same time without absorptive losses, by using electromagnetically induced transparency (EIT), thereby allowing the study of χ⁽³⁾ and χ⁽⁵⁾ nonlinearities using weak driving fields. The coherently modified probe beam(s) and the atom-radiated signal fields arising from four- and six- wave- mixing (FWM and SWM) processes are measured in the spectral, temporal and spatial domains.

In a three-level ladder-type atomic system, multiple peaks having spectral asymmetries are observed in the EIT window as well as …