Physical Sciences and Mathematics Commons^™

The Development Of A High Performance Concrete To Store Thermal Energy For Concentrating Solar Power Plants, Emerson Esmond John

Graduate Theses and Dissertations

In recent years, due to rising energy costs as well as an increased awareness of the environmental effects of greenhouse gas emissions produced through traditional forms of energy production, there is great interest in developing alternative sources of energy. One of the most viable alternative energy sources is solar energy. In particular, concentrating solar power (CSP) technologies have been identified as an option for meeting utility needs in the U.S. Southwest. These systems are required to produce electricity not only during periods of high solar radiation but also during times of reduced radiation due to cloud cover, and even extend …

Stability Of Phyllosilicates On Mars, Patricia Gavin

Graduate Theses and Dissertations

This study investigates the stability of phyllosilicates on the surface of Mars through laboratory experiments and analysis of terrestrial analogs. Phyllosilicates are mostly found in the oldest Noachian terrains on Mars and hence hold clues to the planet's earliest aqueous and geologic history. Phyllosilicates relevant to Mars were heated up to ~1100°C for up to 24 hours and impacted with projectile velocities up to ~4.5 km/s. Heated samples were analyzed using x-ray diffraction (XRD) and Fourier Transform Infrared (FT-IR) spectroscopy in the near- (NIR, 1.0-2.5 µm) and mid-infrared (MIR, 5.0-15.0 µm) ranges. Impacted samples were also analyzed using Raman spectroscopy …

A Subsurface Stratigraphic Study Of The Middle Atoka, Sebastian County, Arkansas, Sara Beth Sutton

Graduate Theses and Dissertations

Raster log images were analyzed to study the subsurface stratigraphy of the Middle Atoka in the Arkoma Basin of the western portion (Sebastian County) of Arkansas. The most significant sandstone units of the Middle Atoka in this area were determined to be two generally coarsening-upward sequences in the lower portion of the formation. Based on lithologic correlations, these two units were determined to be the informally named Casey and Freiburg members of the Middle Atoka. Thickness information based on picked tops was used to create isopach maps of the units of interest. The log signatures and geometry of the sand …

The Relationship Between Middle Level School Science Programs And A Residential Environmental Learning Center, Ryan Mathew Walker

Graduate Theses and Dissertations

A multiple case study investigation examines the relationship between a residential environmental learning center and six schools that attend their program. Pre-experience interviews were conducted with teachers to gain understanding of how they integrate the residential experience with formal classroom instruction. On-site observations of teacher participation during the program provided insight into how they foster student learning during the experience. A student questionnaire was used to reveal students' perceptions of three areas of interest: 1) most meaningful aspects of the experience, 2) most confusing aspects of the experience and 3) topics they would like to know more about. These data …

A Reexamination Of The Eastern Collared Lizard (Crotaphytus Collaris Collaris) In Arkansas, Ashley A. Grimsley

Graduate Theses and Dissertations

Loss of suitable habitat is a threat to species worldwide. Habitat destruction, including loss, change, and fragmentation of habitat, is the leading cause of species extinction. Eastern collared lizards (Crotaphytus collaris collaris) are habitat specialists on glades. Both C. c. collaris and glade habitats are rare and of special concern in the state of Arkansas. Many glade populations have already been extirpated in the Ozarks of Arkansas and Missouri. Increasing knowledge of the distribution, habitat structure, and population dynamics of C. c. collaris is important to ensure the survival of this species in Arkansas.

A literature review of …

What Factors Influence Consumers' Willingness To Purchase And Consume Carbon-Labeled Rice: A Comparative Study Between Arkansas And Belgium, John A. Kelley

Graduate Theses and Dissertations

Climate change is an issue of growing importance around the globe. As global population increases so does attention focused on human contributions to climate change. One major way humans contribute to climate change is through our diets. Agricultural production is a major source of global greenhouse emissions. It has been estimated that food production is responsible for a large majority of the methane and nitrous oxide which is emitted into our atmosphere each year. Carbon footprint labeling has been developed to give consumers a way to lower their footprint and help lower emissions of greenhouse gasses. At least one retailer, …

Ultra-Low Voltage Digital Circuits And Extreme Temperature Electronics Design, Aaron J. Arthurs

Graduate Theses and Dissertations

Certain applications require digital electronics to operate under extreme conditions e.g., large swings in ambient temperature, very low supply voltage, high radiation. Such applications include sensor networks, wearable electronics, unmanned aerial vehicles, spacecraft, and energyharvesting systems. This dissertation splits into two projects that study digital electronics supplied by ultra-low voltages and build an electronic system for extreme temperatures. The first project introduces techniques that improve circuit reliability at deep subthreshold voltages as well as determine the minimum required supply voltage. These techniques address digital electronic design at several levels: the physical process, gate design, and system architecture. This dissertation analyzes …

Gain Of A Single Gas Electron Multiplier, Mythra Varun Nemallapudi

Graduate Theses and Dissertations

Gas Electron Multiplier (GEM) is a gaseous detector used in particle detection and is known for its high rate capability. Ever since its invention in 1997, GEM was applied in many areas and recently has been proposed to be installed in the CMS high η regions for upgrade at LHC, CERN. A complete understanding of the working and gain behaviour does not exist. GEM gain is influenced by charging up and this has been variedly interpreted in literature lacking consensus. I have attempted in this work through simulations and measurements to achieve a better understanding of single GEM gain and …

Water Quality Trends And Nutrient Loads For The Watershed Research And Education Center In Northwest Arkansas, 2009-2012, John Metrailer

Graduate Theses and Dissertations

Nitrogen, phosphorus, and sediment transport is a concern for Northwest Arkansas due to high exports through riverine discharge. Urban, agricultural, and pastured watersheds have been associated with increased N, P, and sediment concentrations when compared to forested catchments. The objective of this study was to evaluate discharge and nutrient loads associated with a small urban, agricultural (row crop), wetland influenced, and pasture/farmland sub-catchment within four ephemeral drainages and located at the Watershed Research and Education Center in Fayetteville, AR. Samples were collected during base flow conditions and periodic storm flow conditions from 2009-2012. Flow adjusted concentration trends were used to …

An Extension To Particle Polarizability To Predict Coupling Behavior In Periodic Nanoplasmonic Arrays, Drew Dejarnette

Graduate Theses and Dissertations

Plasmonic nanoparticles organized in arrays interact to create spectral patterns which are amplified by individual particle polarizability. It was hypothesized that particle polarizability could be used as a predictor of spectral behavior from far-field interactions within the array. Inter-particle coupling produced an extraordinary peak in extinction efficiency at wavelengths equal to or larger than the single particle plasmon resonance peak. Interactions that produced constructive coupling were found to mimic changes in the particle polarizability model. Testing of the hypothesis was performed using the coupled dipole approximation with parametric characterization of array geometries, giving specific particle size and lattice constant combinations …

Groundwater Quality Assessment From Domestic Water Wells In The Fayetteville Shale Gas Play Area In Central Arkansas, Anna Marie Nottmeier

Graduate Theses and Dissertations

This study establishes a spatially distributed domestic water well groundwater quality data set, throughout the Fayetteville Shale Gas Play (FSGP) in central Arkansas. The data set facilitates characterization of the geology and groundwater quality across the study area, benefits residents who may have concerns about the potential impacts on their well water quality, and provides a groundwater quality basis to which complaints can be compared and resolved. The assessment included: research of the study area, site reconnaissance, water sampling and collection, interviews with owners of the property, analytical analysis, Quality Assurance and Quality Control, and groundwater data interpretation.

The study …

Reservoir Characterization And Outcrop Analog: The Osagean Reeds Spring Formation (Lower Boone), Western Osage And Eastern Kay County, Oklahoma, Taylor Friesenhahn

Graduate Theses and Dissertations

The Reeds Spring Formation (Osagean) is a member of the Lower Mississippian carbonate series developed on the Cherokee Platform Province of northeastern Oklahoma. On the western flank of the Ozark Dome, these rocks dip in a west-southwest direction into the subsurface where they are oil and gas reservoirs. A series of road cuts and surface exposures are cropped out in the tri-state area of northwest Arkansas, northeastern Oklahoma, and southwestern Missouri. Outcrop characteristics, including an abundant amount of nodular, anastomosing chert, generally finer-grained carbonate texture, and stratigraphic relationships provide an analog for its subsurface counterpart. Based on core description and …

A Domain Specific Model For Generating Etl Workflows From Business Intents, Wesley Deneke

Graduate Theses and Dissertations

Extract-Transform-Load (ETL) tools have provided organizations with the ability to build and maintain workflows (consisting of graphs of data transformation tasks) that can process the flood of digital data. Currently, however, the specification of ETL workflows is largely manual, human time intensive, and error prone. As these workflows become increasingly complex, the users that build and maintain them must retain an increasing amount of knowledge specific to how to produce solutions to business objectives using their domain's ETL workflow system. A program that can reduce the human time and expertise required to define such workflows, producing accurate ETL solutions with …

Studies Toward The Total Synthesis Of Antascomicin B, David Ross Clay

Graduate Theses and Dissertations

The following dissertation describes synthetic efforts toward the synthesis of the C21-C34 fragment of antascomicin B. Our initial enzymatic approach is detailed as well as an asymmetric transfer hydrogenation (ATH) strategy that will be used in the eventual total synthesis of the molecule. Several investigations into anomalies observed during (ATH) reactions are also discussed.

Phase Control In Atomic Coherence, Utsab Khadka

Graduate Theses and Dissertations

In this thesis, atomic coherence is used to enhance nonlinear optical processes in multi-level atoms. The multi-photon transitions are driven resonantly, and at the same time without absorptive losses, by using electromagnetically induced transparency (EIT), thereby allowing the study of χ⁽³⁾ and χ⁽⁵⁾ nonlinearities using weak driving fields. The coherently modified probe beam(s) and the atom-radiated signal fields arising from four- and six- wave- mixing (FWM and SWM) processes are measured in the spectral, temporal and spatial domains.

In a three-level ladder-type atomic system, multiple peaks having spectral asymmetries are observed in the EIT window as well as …

Subsurface Planetary Investigation Techniques And Their Role For Assessing Subsurface Planetary Composition, Ahmed Elshafie

Graduate Theses and Dissertations

Subsurface planetary investigation techniques are of high interest and importance for the scientific community. Not only they can enhance our knowledge of the history of planetary formation but also can lead to information about its future. Whether the investigation is being conducted remotely using imagers, radars or physically using penetrometers or drills, a pre-existed knowledge of the mechanical and electrical properties of the subsurface regolith should be acquired for better data interpretation and analysis. Therefore, the main objective of this work is to investigate the mechanical and electrical properties of planetary analogs, understand their role for assessing the subsurface structure …

Orbital Periodicities Reflected In Ancient Surfaces Of Our Solar System And The Implications For A Record Of Early Life, Dixie Lee Androes

Graduate Theses and Dissertations

Uniformitarian processes, governed by invariant physical laws, remain the most reliable source for reconstructing the past. Driving many of the repetitive, predictable processes are the orbital dynamics of the Sun-Planet-Moon systems. Astronomical periodicities range from a few hours (tides) to thousands of years (Milankovitch). These periodicities, combined with geomorphic observations of planetary surfaces, constrain the time-dependent processes and allow for reconstruction of events and conditions favorable for sedimentary accumulations. This research suggests that seasonal sedimentary processes are dominant on Titan and Mars, and have played a significant role in the formation of ancient banded-iron formations (BIF's) on Earth.

Earth, Mars, …

Identifying Optimal Cellulosic Biomass Feedstock Supply Areas For Potential Biorefineries In Arkansas, Mark Cooper

Graduate Theses and Dissertations

In February 2010, the U.S. Environmental Protection Agency released the revised Renewable Fuel Standard (RFS2), mandating at least 36 billion gallons of renewable fuels to be produced annually in America, and blended into all on/off road, locomotive, and marine gasoline and diesel by the year 2022. America's existing biorefineries fall significantly short of being able to meet this mandate, resulting in the need for rapid expansion in the near future if this goal is to be met. The state of Arkansas has abundant resources to offer the renewable energy industry, if properly utilized. The goal of this thesis is to …

Investigation Of Negative Differential Resistance Phenomena In Quantum Well Heterostructures, Nazariy Andrushchak

Graduate Theses and Dissertations

Increasing interest in entirely new possibilities for quantum mechanical description of carriers transport is becoming more evident with the developing advancements in epitaxial growth technique. Consequently, molecular beam epitaxy (MBE) technique is considered to be the most precise technique that allows the growth of ultra-thin layers of different compositions.

Those structures can be designed to investigate the wave-nature of carriers, which broadens the possibilities in device design and fabrication for a specific area. In this thesis the fundamental study of the real space charge transfer (RST) mechanism that took place in quantum well heterostructures and led to the negative differential …

The Use Of Diatoms To Infer Environmental Change Of The Lower White River, Southeastern Arkansas, Ruchi Bhattacharya

Graduate Theses and Dissertations

This dissertation describes the limnology of the lower White River oxbow lakes in southeast Arkansas, inundated by the major 2008 spring flood. The flood water and sediment deposited in oxbow lakes were analyzed for water chemistry, sediment geochemistry and diatom assemblages and used as an analogue for past floods. The 2008 spring flood inundated and homogenized the entire floodplain; also represented by the predominantly planktonic diatom assemblage suggesting riverine input. Indicator species for eutrophication were also recorded consistent with the high nutrient content in the lakes. However, the variance in the surface diatom assemblage was best explained by the lake …

Data Integration And Reservoir Characterization Of The Pennsylvanian Bartlesville Sandstone, Caroline Vance O'Keefe

Graduate Theses and Dissertations

The Glenn Pool Oil Field of Northeastern Oklahoma was established as the first major oil discovery of the fledgling state of Oklahoma. Fully developed by 1912, the field is now nearing depletion even under secondary and tertiary recovery efforts after production for approximately 100 years. Large amounts of residual oil estimated to still be in place have motivated exploration into other recovery methods, including polymer flooding and horizontal drilling. Success of these programs is dependent upon accurate characterization of the reservoir. Because most of the drilling occurred many decades ago, much of the data associated with this field predates electric …

Experimental Simulations Of Dark Slope Streaks On Mars, Kelly Howe

Graduate Theses and Dissertations

Martian slope streaks were first observed in Viking images but their formation still remains ambiguous. Martian slope streaks are currently occurring geological phenomenon on Mars, which requires any formation theory to be in agreement with Mar's current temperature and pressure conditions. Planar morphology of martian slope streaks suggest a potential fluvial formation, but current conditions on Mars are not conducive to water remaining liquid long enough to erode the surface. Debris flows, fluid stains and dry dust avalanches have all been previously cited as a potential formation mechanism for martian slope streaks. Recent experimental simulations indicate that a fluvial source …

Mott Transition And Electronic Structure In Complex Oxide Heterostructures, Jian Liu

Graduate Theses and Dissertations

Strongly correlated electron systems, particularly transition metal oxides, have been a focus of condensed matter physics for more than two decades since the discovery of high-temperature superconducting cuprates. Diverse competing phases emerge, spanning from exotic magnetism to unconventional superconductivity, in proximity to the localized-itinerant transition of Mott insulators. While studies were concentrated on bulk crystals, the recent rapid advance in synthesis has enabled fabrication of high-quality oxide heterostructures, offering a new route to create novel artificial quantum materials.

This dissertation details the investigation on ultrathin films and heterostructures of 3d⁷(t_2g⁶e_g¹) systems with …

Territories,Territoriality, And Conservation Of The Louisiana Waterthrush And Its Habitat, The Watershed Of The Upper Buffalo National River, Leesia Cheryl Marshall

Graduate Theses and Dissertations

The Louisiana Waterthrush, Parkesia motacilla, is a migratory wood-warbler and breeding season resident of the eastern United States. Males defend breeding territories that extend linearly along clear, fast-flowing, gravel-bottomed, forest streams. Defense includes two song types, primary and extended song. As riverine specialists, birds rely upon aquatic invertebrates as prey and riparian habitat features for nesting. They use a unique foraging maneuver, leaf-pulling, that involves picking up or pulling a leaf from water, and turning it over to search for prey. Their relationship with riparian habitat introduces potential for Louisiana Waterthrushes to serve as indicators of stream health. The …

Integrating Human Variables In Cross-Boundary Monitoring Of Aberdare Preserves In Kenya, Peter K. Njuguna

Graduate Theses and Dissertations

This research critically examines extant data systems and their linkage of scientific research to policy and public education in east African highland forest conservation preserves. The research indicates that the current state of data and monitoring systems in the region imposes substantial limitations on the ability to manage these preserves. Major outcomes of those constraints manifest in unprecedented cross-boundary pressure such as encroachment and conversion of forest to agriculture, increased human-wildlife conflicts, and constrained relations among primary stakeholders. Current monitoring is biodiversity focused within preserves and fails to capture human dimensions in adjoining areas across preserve boundaries. This study proposes …

Exploring The Possibility Of Floating Orbits For Extreme Mass Ratio Binary Black Holes, Shasvath Jagat Kapadia

Graduate Theses and Dissertations

A binary black hole system, where each black hole orbits the system's center of mass, loses energy by emission of gravitational waves. This causes both black holes to spiral in towards each other. However, if the binary were to, by some mechanism, gain orbital energy at the same rate that it radiates away this energy, a non-decaying or “floating” orbit would result. The thesis uses superradiant scattering and tidal friction, which are two equivalent ways of looking at a process by which the system can gain orbital energy from the spin energy of either black hole, to determine the possibility …

Biological Strategies And Mathematical Approaches For Limiting Bacterial Contaminants And Chemical Pollutants In Bioethanol Fermentations, Alia Chahed Ep Limayem

Graduate Theses and Dissertations

During the most recent decades increased interest in fuel from biomass in the United States and worldwide has emerged each time petroleum derived-gasoline registered well publicized spikes in price. The willingness of the U.S. government to face the issues of more heavily high-priced foreign oil and climate change has led to more investment on plant-derived sustainable biofuel sources. Biomass derived from corn has become one of the primary feedstocks for bioethanol production for the past several years in the U.S. However, the argument of whether to use food as biofuel has led to a search for alternative non-food sources. Consequently, …

Synergy Of Alum And Chlorine Dioxide For Curbing Disinfection Byproduct Formation Potential At Central Arkansas Water, Corey W. Granderson

Graduate Theses and Dissertations

Central Arkansas Water (CAW), the water utility for Little Rock, AR, draws their source water from Lake Maumelle and Lake Winona. To curb disinfection byproduct (DBP) formation, CAW has begun retrofitting their two plants to use chlorine dioxide as an alternative primary disinfectant followed by free chlorine secondary disinfection in the distribution system. In this study, fluorescence parallel factor (PARAFAC) analysis was combined with free chlorine simulated distribution system (SDS) tests and DBP formation potential (DBPFP) tests to study the benefit of chlorine dioxide primary disinfection (CDPD) with alum coagulation. Of the DBPs screened, trichloromethane (TCM) was formed in highest …

Insider Threat Mitigation Models Based On Thresholds And Dependencies, Harini Ragavan

Graduate Theses and Dissertations

Insider threat causes great damage to data in any organization and is considered a serious issue. In spite of the presence of threat prevention mechanisms, sophisticated insiders still continue to attack a database with new techniques. One such technique which remains an advantage for insiders to attack databases is the dependency relationship among data items. This thesis investigates the ways by which an authorized insider detects dependencies in order to perform malicious write operations. The goal is to monitor malicious write operations performed by an insider by taking advantage of dependencies. A term called `threshold' is associated with every data …

Modeling Water Stability And Transport On Mars And Iapetus: Exploring Their Effects On Geomorphic And Atmospheric Processes, Edgard Giovanni Rivera-Valentin

Graduate Theses and Dissertations

The stability and transport of water on solid planetary surfaces strongly affects both atmospheric and surfaces processes. In this work, two bodies are specifically investigated where transport of water is relevant: Iapetus and Mars. Iapetus, an icy Kronian satellite, has a drastic albedo contrast on its surface and one of the darkest surfaces in the solar system. This extreme brightness contrast is suggested to occur via the transport of water ice from the leading hemisphere to the trailing hemisphere and the poles. Here a global heat and mass transfer model is developed for Iapetus in order to study the current …