Physical Sciences and Mathematics Commons^™

Revealing The Core Dynamics Of Vesta: Insights From Experimental Investigations Of Electrical Resistivity And Thermal Conductivity, Oluwasanmi A. Orole Mr

Electronic Thesis and Dissertation Repository

Insights from high pressure and temperature experiments involving in-situ measurements of the electrical resistivity of Fe-5wt%Ni at temperatures of up to 2000 K, under pressures of 2-5 GPa in a 1000-ton cubic-anvil press have been used to reveal Vesta’s core dynamics. The Wiedemann–Franz law was used to calculate the thermal conductivity from the measured electrical resistivity data. Comparing the findings of this study with prior investigations on both pure Fe and Fe-10wt%Ni indicates that an increase in Ni ranging from 0-10wt% has negligible effect on the electrical resistivity of Fe alloys. By comparing the range of estimated heat flux through …

High-Pressure Studies Of Flexible Metal-Organic Frameworks And Their Performance For Co2 Adsorption Using Infrared Spectroscopy, Boqing Li

Electronic Thesis and Dissertation Repository

Metal-organic frameworks (MOFs) are crystalline porous materials comprising metal ions/clusters and organic linkers. MOFs feature very large surface area and broad tunability, which distinguish them from traditional CO₂ adsorbents. High external pressure can significantly modify the framework structures and CO₂ adsorption properties of MOFs. MIL-53(Al) and NH₂-MIL-53(Al) exhibit excellent CO₂ affinity by forming hydrogen bonds between bridging OH groups and adsorbed CO₂. We used in situ infrared spectroscopy to investigate the high-pressure performance of their framework structures and CO₂ adsorption capacities. Diamond anvil cell was employed to apply high pressures in gigapascal …

Investigations Of The High Pressure Effects On Structural Properties And Co2 Adsorption Performance Of Mofs Using Vibrational Spectroscopy, Shan Jiang

Electronic Thesis and Dissertation Repository

The pre- and post-combustion carbon dioxide capture has drawn much attention in the past few decades owing to the increasing concentration of CO₂ in the atmosphere. Among all the potential solid adsorbents for CO₂ capture, metal-organic frameworks (MOFs) are a promising class of materials due to their large surface areas, high tunability and their high selectivity for gas adsorption applications. It has been widely demonstrated that the application of high external pressure in gigapascal level can substantially tune the structure, pore size and opening of porous material. Consequently, the structural, as well as gas adsorption properties of these …

Electrical Resistivity Of Nickel, Iron And Iron-Silicon Alloy Melts At High Pressure With Implications For The Thermal Conductivity Of The Earth’S Core, Reynold E. Silber

Electronic Thesis and Dissertation Repository

The Earth’s liquid outer core (OC) is composed of Fe alloyed with up to 10% Ni and a small fraction of light elements. However, the effect of light elements such as Si on the transport properties of liquid Fe-alloy in Earth’s OC is not clear. Thermal conductivity (κ) and related electrical resistivity (ρ) are the least constrained parameters in OC. Therefore, the characterization of transport properties of Ni, Fe and Fe-Si at high pressure has important geophysical implications for the Earth’s core. The ρ of solid and liquid Ni, Fe and Fe 4%Si was measured at …

Pressure Tuning Of Energy Storage Materials Probed By In-Situ Vibrational Spectroscopy And Synchrotron Radiation, Pan Wang

Electronic Thesis and Dissertation Repository

Clean and renewable energy has drawn much attention recently due to the increasing demand for more energy and environmental issues. New materials have been developed and the improved performance of such materials have been achieved in the past decades. It has been proved that application of external high pressure can significantly tune the structure of materials. Consequently, the properties of the materials could also be modified. Therefore, in this thesis, we focused on the high-pressure studies of two classes of energy storage materials, hydrogen storage materials and solar cell materials. Ammonia borane (AB) has been extensively investigated as an excellent …

Investigating The Mechanism Of Deep-Focus Earthquakes Via In-Situ Acoustic Emission Experiments On Fe2sio4 At High Temperature And Pressure, Timothy Officer

Electronic Thesis and Dissertation Repository

In subduction zones, earthquakes are thought to be associated with faulting that arises from phase transformations. In order to test the viability of this mechanism experimentally, it was necessary to make microseismic measurements while the mineral under investigation was subjected to the pressure and temperature (P,T) conditions corresponding to their environment at depth. A system has been developed capable of making in situ acoustic emission (AE) measurements on samples under P,T conditions representative of the upper mantle and transition zone. Experiments were performed in a 3000-ton multi-anvil press using an 18/11 octahedral cell with 6 piezoelectric transducers mounted on the …

High Pressure Studies Of Nanostructured Tio2 And Li4ti5o12 Using Raman Spectroscopy And Synchrotron X-Ray Radiation, Fengping Xiao

Electronic Thesis and Dissertation Repository

Nanomaterials have been extensively studied due to their distinctive properties such as surface effect, small-size effect and quantum size effect. In recent year, investigations of the structural and phase transformations of nanomaterials under high pressure are receiving increasing attentions. In addition to composition and synthetic routes, pressure provides a clean way to adjust interatomic distance and hence affect the crystal structure and thus properties of the nanostructured materials.Two nanomaterials (i.e. TiO₂ and Li₄Ti₅O₁₂) with different morphologies are studied in this thesis.

In part I, the high-pressure behaviours of four hydrothermal synthesized 1D rutile …

In Situ High-Pressure Study Of Metal-Organic Frameworks And Their Performance For Co2 Storage Probed By Vibrational Spectroscopy, Yue Hu

Electronic Thesis and Dissertation Repository

Metal-organic frameworks (MOFs) are an important class of porous materials, owing to their potential applications in a variety of areas, including gas storage, molecular separations, catalysis, sensors and so on. Most importantly, their extraordinary surface areas, tunable pore properties and potential for industrial scale production have made MOFs a promising material for clean energy applications, such as CO₂ storage. The chemical and mechanical stabilities of MOFs play a crucial role in their CO₂ storage performance, which require extreme loading pressures that are far beyond ambient pressure at times. Application of high external pressure (e.g., in gigapascal range) on …

High Pressure And High Temperature Study Of Magnesiochromite And Its Geophysical Implications, N M Tauhid Belal Khan

Electronic Thesis and Dissertation Repository

Magnesiochromite (MgCr₂O₄) is commonly found in the Earth’s crust, upper mantle, meteorites, and possibly in lunar crust. Synchrotron X-ray diffraction measurements of MgCr₂O₄ using double-sided laser heating diamond anvil cell showed the dissociation of MgCr₂O₄ to Cr₂O₃+MgO at ~15 GPa and to Mg₂Cr₂O₅+Cr₂O₃ below and above ~1500 K, respectively. At above 20 GPa, only a single phase CaTi₂O₄-type structure of MgCr₂O₄ was observed at 1400-2000 K. Fitting the pressure-volume data …

Optical Properties, Electronic Structures And High Pressure Study Of Nanostructured One Dimensional Titanium Dioxide By Synchrotron Radiation And Spectroscopy, Ankang Zhao

Electronic Thesis and Dissertation Repository

One dimensional (1D) titanium dioxide (TiO₂) nanomaterials have been extensively studied in recent years due to their superior electrical, optical mechanical and chemical properties compared with their bulk counterparts. Two different kinds of 1D TiO₂ nanomaterials, TiO₂ nanowires (TiO₂ NW) and TiO₂ nanotubes (TiO₂ NT), are studied in this thesis by using various techniques.

In one study, TiO₂ NW synthesized by hydrothermal method and a series of calcinated TiO₂ NW were investigated by using absorption near edge structures (XANES), X-ray diffraction (XRD) and X-ray excited optical luminescence (XEOL). It is found …

In Situ High-Pressure Studies Of Energetic Materials By Vibrational Spectroscopy And X-Ray Diffraction, Liang Zhou

Electronic Thesis and Dissertation Repository

Nitrogen-rich materials have been considered as the most promising replacement of traditional energetic materials due to the large energy gap between the different nitrogen allotropes as well as the generation of environmental friendly nitrogen gas as the end-product. As a result, methods of synthesizing the nitrogen-rich materials have received increasing attention. Apart from the traditional chemical synthesis, high-pressure technique had been proved an effective tool to create such kinds of materials. However, several issues still existed concerning the high-pressure synthesis of energetic materials. Therefore, searching for precursors is of great interest. Here we report studies of four promising precursors, 5-aminotetrazole, …

In Situ High-Pressure Studies Of Ammonia Borane Derivatives By Vibrational Spectroscopy, Zhihao Yu

Electronic Thesis and Dissertation Repository

Hydrogen has been regarded as a promising candidate to replace the conventional fossil fuel, and thus attracted enormous research efforts. However, hydrogen storage remains to be a big challenge to its practical applications. Consequently, the investigation of suitable hydrogen storage materials has become a highly active research field. Here we reported the first high pressure studies of three promising hydrogen storage materials, N(CH₃)₃BH₃, NH(CH₃)₂BH₃ and NaNH₂BH₃ by Raman and IR spectroscopy.

First, N(CH₃)₃BH₃ was studied at room temperature and pressures up …

Strength, Elasticity And Phase Transition Study On Nacl And Mgo-Nacl Mixture To Mantle Pressures, Zhongying Mi

Electronic Thesis and Dissertation Repository

Rheological properties of the Earth control most of the important geological processes, such as mantle convection, plate tectonics, earthquakes and nature of thermal evolution. Most parts of the Earth consist of multi-phase polycrystalline aggregates with various composition and compressibility. Therefore, deformation studies on multi-phase materials are important to understand the rheological properties and convection of the Earth. NaCl and MgO with large contrast in elastic properties are excellent analogue materials for modelling the Earth that is generally made of both strong and weak materials. In addition, NaCl and MgO are widely used as pressure transmitting medium and pressure calibration standard …