Physical Sciences and Mathematics Commons^™

The Effects Of Solution Ph, Temperature And Redox Environment On Corrosion And Oxide Formation On Inconel X-750, Mohsen Bahrami

Electronic Thesis and Dissertation Repository

Nickel-based superalloys have a wide range of applications in different industries due to their exceptional mechanical and corrosion-resistance properties. These alloys are widely employed in the nuclear industry. Inside a nuclear reactor, these alloys are exposed to a continuous flux of gamma-radiation. When exposed to gamma-radiation, water decomposes, resulting in the production of oxidizing and reducing species. These species have a considerable effect on the redox chemistry of the solution, which controls the overall corrosion behaviour of nickel-based superalloys.

Corrosion of metals and alloys involves several elementary steps. A comprehensive understanding of these steps and how they influence each other …

Brown Dwarf Atmospheres At High Cadence And Spectral Resolution: A Speed Limit On Brown Dwarf Rotation And A Spectroscopic Atlas Of A 1050 K Atmosphere, Megan E. Tannock

Electronic Thesis and Dissertation Repository

Brown dwarfs are sub-stellar objects that form like stars but are not sufficiently massive to sustain hydrogen fusion in their cores. Characterized by cool, molecule-rich atmospheres, brown dwarfs demonstrate great diversity in spectroscopic appearance and share many properties with giant exoplanets. In this thesis I present two investigations: the first is a detailed photometric and spectroscopic study of the three most rapidly rotating brown dwarfs. The second examines a spectrum of a cool brown dwarf at unprecedented spectral resolution and signal-to-noise ratio to study the accuracy of theoretical model photospheres.

Photometric monitoring of brown dwarfs has revealed that periodic variability …

Lunar Regolith Simulant Behaviours Affected By Shock Metamorphism And Mineralogy, Xiao Chen Zhang

Electronic Thesis and Dissertation Repository

There are still many gaps in improving the fidelity of lunar regolith simulants to simulate more properties. This study compares some fundamental physical and mineralogical properties of three types of lunar highland regolith simulants: LHS-1, a commercial product with high mineralogical fidelity; UWO-1G, an original simulant that is the main component of LHS-1; and UWO-1S, another original product that is attempted to produce shocked grains in lunar simulants from pulverizing and mixing impact rocks sourced from the Mistastin Crater.

Preliminary results indicated that even though all simulants are composed of mostly plagioclase minerals and have similar particle size distribution patterns, …

Equisingular Approximation Of Analytic Germs, Aftab Yusuf Patel

Electronic Thesis and Dissertation Repository

This thesis deals with the problem of approximating germs of real or complex analytic spaces by Nash or algebraic germs. In particular, we investigate the problem of approximating analytic germs in various ways while preserving the Hilbert-Samuel function, which is of importance in the resolution of singularities. We first show that analytic germs that are complete intersections can be arbitrarily closely approximated by algebraic germs which are complete intersections with the same Hilbert-Samuel function. We then show that analytic germs whose local rings are Cohen-Macaulay can be arbitrarily closely approximated by Nash germs whose local rings are Cohen- Macaulay and …

A Computational Study On A Globular Protein And An Intrinsically Disordered Protein, Cecilia Chavez Garcia

Electronic Thesis and Dissertation Repository

We present molecular dynamics (MD) simulations of two protein targets for drug design: Triosephosphate isomerase (TIM) and Methyl CpG binding protein 2 (MeCP2). First, we studied three TIM proteins: TcTIM, TbTIM and a chimeric protein (Mut1). The first two are homologous enzymes with high sequence similarity, albeit different biophysical parameters. The chimeric protein has TbTIM’s sequence and 13 single point mutations, which are sufficient to obtain TcTIM-like behaviour in reactivation experiments. We analyzed the residue interaction networks observed in the all-atom MD simulations, as well as their electrostatic interactions and the impact of simulation length on them. A conserved salt …

In Situ Study Of Geological Fluid Inclusions Using 23na Nuclear Magnetic Resonance Spectroscopy, Stephen Pilar

Electronic Thesis and Dissertation Repository

²³Na Magic Angle Spinning Solid State Nuclear Magnetic Resonance (MAS SS NMR) spectroscopy has been used to study natural geological samples of halite, fluorite, and quartz to evaluate the efficacy of NMR spectroscopy for in situ fluid inclusion analysis. NaCl calibration standards yielded a strong linear correlation (R²=0.9919) for salinity, albeit only over a ~1 ppm breadth of chemical shift. Fluid inclusions were successfully identified in all three types of minerals studied using MAS NMR. Chemical analysis with Inductively Coupled Plasma -- Mass Spectrometry (ICP-MS) was employed to quantify elemental contaminants in halite samples. Powder X-Ray Diffraction …

Metal Ligand Cooperative Complexes For Acceptorless Dehydrogenation Of Amines, Matthew D. Hoffman

Electronic Thesis and Dissertation Repository

Complexes of the type [M(Cp/Cp*)(MeCN)(P^R₂N^R′₂)]PF₆ (M = Fe, Ru) were synthesized and/or tested towards acceptorless dehydrogenation (AD) of amines. The primary amine benzylamine can undergo AD to form a mixture of products, and a selection of catalysts were employed in an attempt to control product selectivity. As a result, trends in product distribution were observed by modifying the primary and secondary coordination spheres on the catalyst. A new complex, [Fe(Cp)(MeCN)(P^Ph₂N^Ph₂)]PF₆ (3a) was synthesized and characterized and was found to be a completely selective dehydrogenation …

Effects Of Gamma-Radiation On The Evolution Of Copper Corrosion Dynamics In Deep Geological Repository Solution Environments, Lindsay J. Grandy

Electronic Thesis and Dissertation Repository

The Canadian plan for permanent disposal of used nuclear fuel involves a used fuel container (UFC), a carbon steel vessel with a copper coating to provide the corrosion protection. The corrosion conditions for the copper layer of the UFC are expected to involve small, stagnant water volumes, pH values between 6 and 9, and a continuous flux of γ-radiation emitted from the radionuclides trapped in the fuel matrix. While γ-radiation does not affect the copper metal directly, humid air and water will radiolytically decompose into redox-active and acidic species which will be produced at constant concentrations and can alter the …

The Synthesis And Application Of Polyglyoxylamides, Quinton Ea Sirianni

Electronic Thesis and Dissertation Repository

Self-immolative polymers (SIPs) are a subset of degradable polymers that can be triggered to fully depolymerize with a single stimulus event. This amplifying behaviour makes them ideal for real-world applications including sensors, recyclable plastics, and drug delivery vehicles. Polyglyoxylates (PGs) are a class of SIPs that can be synthesized in a one-pot reaction and designed to respond to different stimuli including light, heat, reduction, and oxidation. However, with the exception of poly(ethyl glyoxylate) (PEtG), the various glyoxylate monomers must be prepared and purified before polymerization, which can be difficult. Furthermore, PGs typically possess properties such as water-insolubility and low glass …

Cache-Friendly, Modular And Parallel Schemes For Computing Subresultant Chains, Mohammadali Asadi

Electronic Thesis and Dissertation Repository

The RegularChains library in Maple offers a collection of commands for solving polynomial systems symbolically with taking advantage of the theory of regular chains. The primary goal of this thesis is algorithmic contributions, in particular, to high-performance computational schemes for subresultant chains and underlying routines to extend that of RegularChains in a C/C++ open-source library.

Subresultants are one of the most fundamental tools in computer algebra. They are at the core of numerous algorithms including, but not limited to, polynomial GCD computations, polynomial system solving, and symbolic integration. When the subresultant chain of two polynomials is involved in a client …

Structural Tuning And Spectroscopic Characterizations Of Polysulfide As Battery Materials, Daiqiang Liu

Electronic Thesis and Dissertation Repository

Polysulfide materials have drawn extensive attention for next-generation battery development since the current lithium-ion battery has almost reached its limit regarding energy density and safety issues. Many phosphorus and sodium sulfide materials have been used in different battery types, such as solid-state and sodium-sulfur batteries. However, there are still issues that prevent these techniques from applications. In recent years, there has been increasing attention on investigations of the structural and phase transformations of electrode and electrolyte materials under high pressure. Many studies have shown that external pressure can affect structural properties and influence electrical properties. In this study, three battery-related …

Evolutionary Design Of Search And Triage Interfaces For Large Document Sets, Jonathan A. Demelo

Electronic Thesis and Dissertation Repository

This dissertation is concerned with the design of visual interfaces for searching and triaging large document sets. Data proliferation has generated new and challenging information-based tasks across various domains. Yet, as the document sets of these tasks grow, it has become increasingly difficult for users to remain active participants in the information-seeking process, such as when searching and triaging large document sets. During information search, users seek to understand their document set, align domain knowledge, formulate effective queries, and use those queries to develop document set mappings which help generate encounters with valued documents. During information triage, users encounter the …

Reconstructing Impact And Fluid Histories On Earth And Mars By Nanoscale Measurements, Gabriel A. Arcuri

Electronic Thesis and Dissertation Repository

The U-Pb geochronology minerals zircon (ZrSiO₄) and baddeleyite (ZrO₂) occur as microscopic grains in many planetary rocks, are among the oldest known solids, and preserve robust records of chemical, isotopic and orientation microstructures useful for reconstructing the evolution of early planetary lithospheres and hydrosphere. Less well known are the nanoscale characteristics of these long-lived minerals, and their connections, if any, to processes that operated at larger length scales in the crust important to habitability such as global planetary bombardment and fluid flow. The aim of this thesis was therefore to develop and apply nanoscale analytical techniques, …

Compound Sums, Their Distributions, And Actuarial Pricing, Ang Li

Electronic Thesis and Dissertation Repository

Compound risk models are widely used in insurance companies to mathematically describe their aggregate amount of losses during certain time period. However, evaluation of the distribution of compound random variables and the computation of the relevant risk measures are non-trivial. Therefore, the main purpose of this thesis is to study the bounds and simulation methods for both univariate and multivariate compound distributions. The premium setting principles related to dependent multivariate compound distributions are studied. .

In the first part of this thesis, we consider the upper and lower bounds of the tail of bivariate compound distributions. Our results extend those …

Allostratigraphy Of The Lower Colorado Group (Cretaceous) In South-West Alberta, Slavena Galic

Electronic Thesis and Dissertation Repository

Clastic, upper Albian-lower Cenomanian strata were deposited in a low-accommodation backbulge depozone of the Western Canada Foreland Basin in SW Alberta. These strata are lithologically very heterogeneous and encompass a spectrum of depositional environments along an alluvial to offshore transect. These rocks are assigned, in subsurface, to the Lower Colorado Group, and in outcrop to the upper Blairmore Group. Lithological heterogeneity, as a result of rapid lateral facies changes, resulted in diverse nomenclature that obscured genetic relationships between time-equivalent strata. The present study integrates wireline log, core, and outcrop data to establish a high-resolution allostratigraphic framework which allowed recognition of …

Combined Geochemical, Mineralogical, And Structural Investigation Of Auriferous Quartz Veins At The Vertigo Target, White Gold District, West-Central Yukon Territory, Canada, James C M Alexander

Electronic Thesis and Dissertation Repository

The Vertigo target on the southwestern JP Ross property is a gold-mineralized showing ~70 km south of Dawson City in the White Gold district, west-central Yukon Territory, Canada. Favourable gold-mineralized zones occur with pathfinder elements As-Ag-Te-Pb-Bi. This study uses digital borehole logging, petrography, electron probe microanalysis, and micro-x-ray fluorescence to evaluate the spatial, geochemical, and mineralogical distribution of Au mineralization at the Vertigo target. Petrographic and structural interpretations are contextualized with synchrotron radiation x-ray diffraction on 120 drill sample pulps. The clustering of diffraction patterns has revealed characteristic signatures of Au-mineralization with structural geometries coincident with the mineralogical clusters. The …

Non-Circular Hydraulic Jumps Due To Inclined Jets, Ahmed Mohamed Abdelaziz

Electronic Thesis and Dissertation Repository

When a laminar inclined circular jet impinges on a horizontal surface, it forms a non-circular hydraulic jump governed by a non-axisymmetric flow. In this thesis, we use the boundary-layer and thin-film approaches in the three dimensions to theoretically analyse such flow and the hydraulic jumps produced in such cases. We particularly explore the interplay among inertia, gravity, and the effective inclination angle on the non-axisymmetric flow.

The boundary-layer height is found to show an azimuthal dependence at strong gravity level only; however, the thin film thickness as well as the hydraulic jump profile showed a strong non-axisymmetric behaviour at all …

Distribution Of The P-Torsion Of Jacobian Groups Of Regular Matroids, Sergio R. Zapata Ceballos

Electronic Thesis and Dissertation Repository

Given a regular matroid $M$ and a map $\lambda\colon E(M)\to \N$, we construct a regular matroid $M_\lambda$. Then we study the distribution of the $p$-torsion of the Jacobian groups of the family $\{M_\lambda\}_{\lambda\in\N^{E(M)}}$. We approach the problem by parameterizing the Jacobian groups of this family with non-trivial $p$-torsion by the $\F_p$-rational points of the configuration hypersurface associated to $M$. In this way, we reduce the problem to counting points over finite fields. As a result, we obtain a closed formula for the proportion of these groups with non-trivial $p$-torsion as well as some estimates. In addition, we show that the …

Evaluating Cranial Nonmetric Traits In Mummies From Pachacamac, Peru: The Utility Of Semi-Automated Image Segmentation In Paleoradiology, Cameron J. Beason

Electronic Thesis and Dissertation Repository

Anthropologists employ biodistance analysis to understand past population interactions and relatedness. The objectives of this thesis are twofold: to determine whether a sample of five mummies from the pilgrimage centre, Pachacamac, on the Central Coast of Peru comprised local or non-local individuals through an analysis of cranial nonmetric traits using comparative samples from the North and Central Coasts of Peru and Chile; and to test the utility of machine-learning-based image segmentation in the image analysis software, Dragonfly, to automatically segment CT scans of the mummies such that the cranial nonmetric traits are visible. Results show that while fully automated segmentation …

Characterization Of Extracellular Vesicles By Surface-Enhanced Raman Spectroscopy, Nina M. Culum

Electronic Thesis and Dissertation Repository

Extracellular vesicles (EVs), which are nanoscale vesicles secreted by cells into biofluids, are of research interest due to their roles in intercellular communication. EVs released from mesenchymal stromal cells (MSCs) have tremendous potential in cell-free regenerative medicine, while EVs released from diseased cells are being studied as biomarkers for minimally invasive and early disease detection. Presented in this thesis are gold nanohole arrays for the capture and sensitive detection of EVs by surface-enhanced Raman spectroscopy (SERS), a plasmonic technique capable of single molecule detection. Herein, we have characterized EVs released from MSCs and ovarian cancer cells, with a focus on …

Functional Nanoparticles: Tin Monoxide And Molybdenum Disulfide Quantum Dots On Graphene Nanosheets, Denys Vidish

Electronic Thesis and Dissertation Repository

Light harvesting can be referred to the use of an ensemble of different nanoparticles, or quantum dots, or other absorbers to optimize the ability to capture a given spectrum of electromagnetic radiation (for example the solar spectrum under specific atmospheric conditions) in a light-absorbing system. To this end, different nanoparticles play complementary functions within the system and absorb or scatter light at different wavelength intervals. Light harvesting finds applications in fields as diverse as solar cells, photosynthesis and photocatalysis. Graphene supporting a set of different semiconducting nanoparticles has often been proposed as light harvesters. To further this concept, my thesis …

Revisiting Polycyclic Aromatic Hydrocarbon Emission In Photodissociation Regions, Ameek K. Sidhu

Electronic Thesis and Dissertation Repository

The mid-infrared (IR) spectrum of almost all objects in the Universe is dominated by a set of strong emission features characteristic of a class of large organic molecules made of carbon and hydrogen known as polycyclic aromatic hydrocarbons (PAHs). These molecules account for ~15% of the cosmic carbon and ~20% of the total IR power of the Milky Way and star-forming galaxies. They are strong absorbers of ultraviolet (UV) photons and release the absorbed energy through vibrational transitions that result in strong IR emission features. PAHs play a critical role in the evolution of the interstellar medium (ISM) as they …

Genus Bounds For Some Dynatomic Modular Curves, Andrew W. Herring

Electronic Thesis and Dissertation Repository

We prove that for every $n \ge 10$ there are at most finitely many values $c \in \mathbb{Q} $ such that the quadratic polynomial $x^2 + c$ has a point $\alpha \in \mathbb{Q} $ of period $n$. We achieve this by proving that for these values of $n$, every $n$-th dynatomic modular curve has genus at least two.

Synthesis And Characterization Of Re(I) Tricarbonyl Complexes Of 1,8-Naphthalimide, Priyanka Jagadeesa Prabhu

Electronic Thesis and Dissertation Repository

1,8-Naphthalimide fluorophores with amino-substituents absorb and emit in the visible region. The photophysical properties of this class of fluorophores can be modulated by altering the degree of Intramolecular Charge Transfer (ICT) in the excited state. Thus, several metal complexes with the 1,8-naphthalimide motif have been developed as cell imaging agents. In this project, four 1,8-naphthalimide ligands were synthesized by incorporating rigid linkers. Among these, three ligands also allowed the extension of π-conjugation to the naphthalimide moiety. In addition, a ligand was also synthesized without the use of a linker. Re(I) tricarbonyl complexes of these ligands were also synthesized and their …

A Generative-Discriminative Approach To Human Brain Mapping, Deepanshu Wadhwa

Electronic Thesis and Dissertation Repository

During everyday behaviours, the brain shows complex spatial patterns of activity. These activity maps are very replicable within an individual, but vary significantly across individuals, even though they are evoked by the same behaviour. It is unknown how differences in these spatial patterns relate to differences in behavior or function. More fundamentally, the structural, developmental, and genetic factors that determine the spatial organisation of these brain maps in each individual are unclear. Here we propose a new quantitative approach for uncovering the basic principles by which functional brain maps are organized. We propose to take an generative-discriminative approach to human …

Surface Morphology And Subsurface Ice Content Relationships In Arcadia Planitia, Mars And The Canadian High Arctic, Shannon M. Hibbard

Electronic Thesis and Dissertation Repository

As NASA and SpaceX prepare for future human missions to Mars as part of an In-situ Resource Utilization (ISRU) Space Act Agreement (SAA), we need more detailed characterization of ice at proposed landing sites to constrain ice accessibility, landing safety, and scientific value. Obtaining near-surface in situ water-ice can be used for rocket fuel and life support needs which would significantly reduce the mass needed for transport to and from Mars. Arcadia Planitia is the lowest-lying region in the northern hemisphere of Mars where abundant evidence exists for an ice-rich subsurface. Shallow Radar observations indicate a decameters-thick layer of water-ice …

Coevolution Of Hosts And Pathogens In The Presence Of Multiple Types Of Hosts, Evan J. Mitchell

Electronic Thesis and Dissertation Repository

How will hosts and pathogens coevolve in response to multiple types of hosts? I study this question from three different perspectives. First, I model a scenario in which hosts are categorized as female or male. Hosts invest resources in maintaining their immune system at a cost to their reproductive success, while pathogens face a trade-off between transmission and duration of infection. Importantly, female hosts are also able to vertically transmit an infection to their newborn offspring. The main result is that as the rate of vertical transmission increases, female hosts will have a greater incentive to pay the cost to …

Westernaccelerator：Rapid Development Of Microservices, Haoran Wei

Electronic Thesis and Dissertation Repository

Context & Motivation/problem: In the context that cloud platforms are widely adopted, Microservice Architecture (MSA) has quickly become the new paradigm for modern software development due to its great modularity, scalability, and resiliency, which fits well in the cloud environment. However, to embrace the benefits of MSA, organizations must overcome the challenges of adopting new methodologies and processes to deal with the extra development complexities that microservices created, e.g., establishing interface-based communication between distributed services and managing the configurations and locations of services. Consequently, creating a microservice-based application is relatively complex and effortful. Research Question: How to create a tool …

Stochastic Source Modelling And Tsunami Analysis Of The 2012 Mw 7.8 Haida Gwaii Earthquake, Karina Martinez Alcala

Electronic Thesis and Dissertation Repository

The Mw 7.8 2012 Haida Gwaii Earthquake triggered a tsunami that highlighted the importance of tsunami hazard assessment on Canada’s Pacific coast. Stochastic source modelling serves as a valuable method to assess future tsunami hazard and has not been performed for this region. The source models characterize the uncertainty of earthquake ruptures by considering variability in fault geometry and slip heterogeneity, which, in turn, allows the consideration of a wide range of tsunami scenarios in the Haida Gwaii region. The model predictions are constrained by observational data and past source inversion studies. One hundred twenty-eight stochastic tsunami scenarios are generated …

Symphas: A Modular Api For Phase-Field Modeling Using Compile-Time Symbolic Algebra, Steven A. Silber

Electronic Thesis and Dissertation Repository

The phase-field method is a common approach to qualitative analysis of phase transitions. It allows visualizing the time evolution of a phase transition, providing valuable insight into the underlying microstructure and the dynamical processes that take place. Although the approach is applied in a diverse range of fields, from metal-forming to cardiac modelling, there are a limited number of software tools available that allow simulating any phase-field problem and that are highly accessible. To address this, a new open source API and software package called SymPhas is developed for simulating phase-field and phase-field crystal in 1-, 2- and 3-dimensions. Phase-field …